Thermoelectric conversion element and thermoelectric conversion module

ABSTRACT

The present invention provides a thermoelectric element in which a thin film of p-type thermoelectric material and a thin film of n-type thermoelectric material, which are formed on an electrically insulating substrate, are electrically connected, in which the p-type thermoelectric material and the n-type thermoelectric material are selected from specific complex oxides with a positive Seebeck coefficient and specific complex oxides with a negative Seebeck coefficient, respectively. The present invention also provides a thermoelectric module using the thermoelectric element(s) and a thermoelectric conversion method. In the thermoelectric element of the present invention, since a p-type thermoelectric material and an n-type thermoelectric material are formed into a thin film on an electrically insulating substrate, the thermoelectric element of the invention can be formed on substrates having various shapes, thereby providing thermoelectric elements having various shapes.

TECHNICAL FIELD

The present invention relates to a thermoelectric element, athermoelectric module, and a thermoelectric conversion method.

BACKGROUND ART

In Japan, only about 30% of the primary energy supply is used aseffective energy, with about 70% being eventually lost to the atmosphereas heat. The heat generated by combustion in industrial plants,garbage-incineration facilities and the like is lost to the atmospherewithout being converted into other energy. In this way, we arewastefully discarding a vast amount of thermal energy, while acquiringonly a small amount of energy by combustion of fossil fuels or othermeans.

To increase the proportion of energy to be utilized, the thermal energycurrently lost to the atmosphere should be effectively used. For thispurpose, thermoelectric conversion, which directly converts thermalenergy to electrical energy, is an effective means. Thermoelectricconversion, which utilizes the Seebeck effect, is an energy conversionmethod for generating electricity by creating a difference intemperature between both ends of a thermoelectric material to produce adifference in electric potential.

In such a method for generating electricity utilizing thermoelectricconversion, i.e., thermoelectric generation, electricity is generatedsimply by setting one end of a thermoelectric material at a locationheated to a high temperature by waste heat, and the other end in theatmosphere, and connecting external resistances to both ends. Thismethod entirely eliminates the need for moving parts, such as the motorsor turbines generally required for power generation. As a consequence,the method is economical and can be carried out without releasing thegases by combustion. Moreover, the method can continuously generateelectricity until the thermoelectric material has deteriorated.Furthermore, thermoelectric generation enables power generation at ahigh power density. Therefore, it is possible to make electric powergenerators (modules) small and light enough to be used as mobile powersupplies for cellular phones, notebook computers, etc.

Therefore, thermoelectric generation is expected to play a role in theresolution of future energy problems. To realize thermoelectricgeneration, a thermoelectric module comprising a thermoelectric materialthat has both a high thermoelectric conversion efficiency and excellentproperties in terms of heat resistance, chemical durability, etc., willbe required.

CoO₂-based layered oxides such as Ca₃Co₄O₉ have been reported assubstances that achieve excellent thermoelectric performance in air athigh temperatures, and such thermoelectric materials are currently beingdeveloped (see Non-Patent Document 1, for example).

However, the development of a thermoelectric module (electric powergenerator) that is needed to realize efficient thermoelectric generationusing thermoelectric materials has been delayed so far.

Non-Patent Document 1: R. Funahashi et al., Jpn. J. Appl. Phys., 39,L1127 (2000)

DISCLOSURE OF THE INVENTION Problems to be Solved by Invention

The present invention has been made to solve the above problems. Aprincipal object of the invention is to provide a thermoelectric elementand a thermoelectric module that have both a high thermoelectricconversion efficiency and excellent properties in terms of thermalstability, chemical durability, etc., that are required to realizethermoelectric generation.

Means for Solving the Problems

The present inventors conducted extensive research to achieve the aboveobject. As a result, the inventors found that a thermoelectric elementhaving excellent properties can be obtained by forming a thin film ofp-type thermoelectric material and a thin film of n-type thermoelectricmaterial, each thermoelectric material comprising a specific complexoxide, on an electrically insulating substrate, and electricallyconnecting one end portion of the p-type thermoelectric material and oneend portion of the n-type thermoelectric material. The thermoelectricelement thus obtained has a high thermoelectric conversion efficiencyand excellent electrical conductivity as well as excellent thermalstability, chemical durability, etc., and exhibits excellent propertiesas a thermoelectric element.

More specifically, the present invention provides the followingthermoelectric elements, thermoelectric modules, and thermoelectricconversion methods.

1. A thermoelectric element comprising:

a thin film of p-type thermoelectric material,

a thin film of n-type thermoelectric material, and

an electrically insulating substrate,

the thin film of p-type thermoelectric material and the thin film ofn-type thermoelectric material being formed on the electricallyinsulating substrate and being electrically connected,

(i) the p-type thermoelectric material comprising at least one complexoxide selected from the group consisting of:

complex oxides represented by Formula (1): Ca_(a)A_(b) ¹Co_(c)A_(d)²O_(e), wherein A¹ is one or more elements selected from the groupconsisting of Na, K, Li, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Pb, Sr, Ba, Al,Bi, Y, and lanthanoids; A² is one or more elements selected from thegroup consisting of Ti, V, Cr, Mn, Fe, Ni, Cu, Ag, Mo, W, Nb, and Ta;2.2≦a≦3.6; 0≦b≦0.8; 2.0≦c≦4.5; 0≦d≦2.0; and 8≦e≦10, and

complex oxides represented by Formula (2): Bi_(f)Pb_(g)M_(h)¹Co_(i)M_(j) ²O_(k), wherein M¹ is one or more elements selected fromthe group consisting of Na, K, Li, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Pb,Ca, Sr, Ba, Al, Y, and lanthanoids; M² is one or more elements selectedfrom the group consisting of Ti, V, Cr, Mn, Fe, Ni, Cu, Ag, Mo, W, Nb,and Ta; 1.8≦f≦2.2; 0≦g≦0.4; 1.8≦h≦2.2; 1.6≦i≦2.2; 0≦j≦0.5; and 8≦k≦10;and

(ii) the n-type thermoelectric material comprising at least one complexoxide selected from the group consisting of:

complex oxides represented by Formula (3): Ln_(m)R_(n) ¹Ni_(p)R_(q)²O_(r), wherein Ln is one or more elements selected from the groupconsisting of lanthanoids; R¹ is one or more elements selected from thegroup consisting of Na, K, Sr, Ca, and Bi; R² is one or more elementsselected from the group consisting of Ti, V, Cr, Mn, Fe, Co, Cu, Mo, W,Nb, and Ta; 0.5≦m≦1.7; 0≦n≦0.5; 0.5≦p≦1.2; 0≦q≦0.5; and 2.7≦r≦3.3;

complex oxides represented by Formula (4): (Ln_(s)R_(t) ³)₂Ni_(u)R_(v)⁴O_(w), wherein Ln is one or more elements selected from the groupconsisting of lanthanoids; R³ is one or more elements selected from thegroup consisting of Na, k, Sr, Ca, and Bi; R⁴ is one or more elementsselected from the group consisting of Ti, V, Cr, Mn, Fe, Co, Cu, Mo, W,Nb, and Ta; 0.5≦s≦1.2; 0≦t≦0.5; 0.5≦u≦1.2; 0≦v≦0.5; and 3.6≦w≦4.4;

complex oxides represented by Formula (5): A_(x)Zn_(y)O_(z), wherein Ais Ga or Al; 0≦x≦0.1; 0.9≦y≦1; and 0.9≦z≦1.1; and

complex oxides represented by Formula (6): Sn_(xx)In_(yy)O_(zz), wherein0≦xx≦1; 0≦yy≦2; and 1.9≦zz≦3.

2. The thermoelectric element according to Item 1, wherein

the p-type thermoelectric material comprises at least one complex oxideselected from the group consisting of complex oxides represented by theformula: Ca_(a)A_(b) ¹Co₄O_(e), wherein A¹ is one or more elementsselected from the group consisting of Na, K, Li, Ti, V, Cr, Mn, Fe, Ni,Cu, Zn, Pb, Sr, Ba, Al, Bi, Y, and lanthanoids; 2.2≦a≦3.6; 0≦b≦0.8; and8≦e≦10, and complex oxides represented by the formula: Bi_(f)Pb_(g)M_(h)¹Co₂O_(k), wherein M¹ is one or more elements selected from the groupconsisting of Sr, Ca, and Ba; 1.8≦f≦2.2; 0≦g≦0.4; 1.8≦h≦2.2; and 8≦k≦10;

the n-type thermoelectric material comprises at least one complex oxideselected from the group consisting of complex oxides represented by theformula: Ln_(m)R_(n) ¹NiO_(r), wherein Ln is lanthanoid; R¹ is one ormore elements selected from the group consisting of Na, K, Sr, Ca, andBi; 0.5≦m≦1.2; 0≦n≦0.5; and 2.7≦r≦3.3, complex oxides represented by theformula: (Ln_(s)R_(t) ³)₂NiO_(w), wherein Ln is lanthanoid; R³ is one ormore elements selected from the group consisting of Na, K, Sr, Ca, andBi; 0.5≦s≦1.2; 0≦t≦0.5; and 3.6≦w≦4.4, and complex oxides represented bythe formula: Ln_(x)R_(y) ⁵Ni_(p)R_(q′) ⁶O_(r′), wherein Ln islanthanoid; R⁵ is one or more elements selected from the groupconsisting of Na, K, Sr, Ca, Bi, and Nd; and R⁶ is one or more elementsselected from the group consisting of Ti, V, Cr, Mn, Fe, Co, and Cu;0.5≦x≦1.2; 0≦y≦0.5; 0.5≦p≦1.2; 0.01≦q′≦0.5; and 2.8≦r′≦3.2.

3. The thermoelectric element according to Item 1, wherein the thin filmof p-type thermoelectric material and the thin film of n-typethermoelectric material are electrically connected by one of thefollowing methods:

bringing one end portion of the thin film of p-type thermoelectricmaterial into direct contact with one end portion of the thin film ofn-type thermoelectric material;

bringing one end portion of the thin film of p-type thermoelectricmaterial into contact with one end portion of the thin film of n-typethermoelectric material via an electrically conductive material;

bringing one end portion of the thin film of p-type thermoelectricmaterial into direct contact with one end portion of the thin film ofn-type thermoelectric material and covering the contact portion with anelectrically conductive material.

4. The thermoelectric element according to Item 1, wherein the thin filmof p-type thermoelectric material and the thin film of n-typethermoelectric material are formed on the same surface or on differentsurfaces of the electrically insulating substrate.

5. The thermoelectric element according to Item 1, wherein theelectrically insulating substrate is a substrate comprising a plasticmaterial.

6. The thermoelectric element according to Item 1, whereinthermoelectromotive force is at least 60 μV/K in a temperature range of293 K to 1073 K.

7. The thermoelectric element according to Item 1, wherein electricalresistance is 1 KΩ or lower in a temperature range of 293 K to 1073 K.

8. A thermoelectric module comprising a plurality of the thermoelectricelements of Item 1, wherein the thermoelectric elements are electricallyconnected in series such that an unconnected end portion of a p-typethermoelectric material of one thermoelectric element is electricallyconnected to an unconnected end portion of an n-type thermoelectricmaterial of another thermoelectric element.9. A thermoelectric conversion method comprising positioning one end ofthe thermoelectric module of Item 8 at a high-temperature portion andpositioning the other end of the module at a low-temperature portion.

In the thermoelectric element of the present invention, specific complexoxides are used as p-type and n-type thermoelectric materials; thinfilms of p-type and n-type thermoelectric materials are formed on anelectrically insulating substrate; and one end portion of the thin filmof p-type thermoelectric material and one end portion of the thin filmof n-type thermoelectric material are electrically connected.

Combined use of such complex oxides can provide a thermoelectric elementwith high thermoelectric conversion efficiency and good electricalconductivity. In addition, such complex oxides, when formed into a thinfilm, can be formed on substrates having various shapes, thereby easilyproviding thermoelectric elements having various shapes, which can beused in various applications, such as mounting on an electronic circuit,use in a fine portion, etc. Moreover, the thermoelectric module needs tobe formed into a fin shape when used in airflow, such as in a boiler ora car radiator so that the module does not cause pressure loss byinterrupting the airflow. In this application, thin film-typethermoelectric elements are useful.

Hereinafter, p-type thermoelectric materials and n-type thermoelectricmaterial used in the invention are described.

p-Type Thermoelectric Material

Usable as a p-type thermoelectric material is at least one oxideselected from the group consisting of complex oxides represented byFormulae (1) and (2):

complex oxides represented by Formula (1): Ca_(a)A_(b) ¹Co_(c)A_(d)²O_(e), wherein A¹ is one or more elements selected from the groupconsisting of Na, K, Li, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Pb, Sr, Ba, Al,Bi, Y, and lanthanoids; A² is one or more elements selected from thegroup consisting of Ti, V, Cr, Mn, Fe, Ni, Cu, Ag, Mo, W, Nb, and Ta;2.2≦a≦3.6; 0≦b≦0.8; 2.0≦c≦4.5; 0≦d≦2.0; and 8≦e≦10, and

complex oxides represented by Formula (2): Bi_(f)Pb_(g)M_(h)¹Co_(i)M_(j) ²O_(k), wherein M¹ is one or more elements selected fromthe group consisting of Na, K, Li, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Pb,Ca, Sr, Ba, Al, Y, and lanthanoids; M² is one or more elements selectedfrom the group consisting of Ti, V, Cr, Mn, Fe, Ni, Cu, Ag, Mo, W, Nb,and Ta; 1.8≦f≦2.2; 0≦g≦0.4; 1.8≦h≦2.2; 1.6≦i≦2.2; 0≦j≦0.5; and 8≦k≦10.

In the above Formulae (1) and (2), examples of lanthanoids include La,Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, etc.

The complex oxides represented by the above formulae have a laminatedstructure with alternating rock-salt structure layers and CoO₂ layers,wherein the rock-salt structure layers have the components Ca, Co, and Oin the ratio of Ca₂CoO₃, or the components Bi, M¹, and O in the ratio ofBi₂M₂ ¹O₄; and the CoO₂ layers have octahedrons with octahedralcoordination of six O to one Co, the octahedrons being arrangedtwo-dimensionally such that they share one another's sides. In theformer case, some of the Ca in Ca₂CoO₃ is substituted by A¹, and some ofthe Co of this layer and some of the Co of the CoO₂ layer are furthersubstituted by A². In the latter case, some of the Bi are substituted byPb or some of M¹, and some of the Co are substituted by M².

Such complex oxides have high Seebeck coefficients as p-typethermoelectric materials and excellent electrical conductivity. Forexample, they have a Seebeck coefficient of at least about 100 μV/K andan electrical resistivity of not more than about 50 mΩcm, preferably notmore than about 30 mΩcm, at temperatures of 100 K or higher; and theSeebeck coefficient tends to increase and the electrical resistivitytends to decrease as the temperature rises.

Among the complex oxides mentioned above, mentioned as a preferableexample is at least one complex oxide selected from the group consistingof complex oxides represented by the formula: Ca_(a)A_(b) ¹Co₄O_(e),wherein A¹ is one or more elements selected from the group consisting ofNa, K, Li, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Pb, Sr, Ba, Al, Bi, Y, andlanthanoids; 2.2≦a≦3.6; 0≦b≦0.8; and 8≦e≦10) and complex oxidesrepresented by the formula: Bi_(f)Pb_(g)M_(h) ¹Co₂O_(k), wherein M¹ isone or more elements selected from the group consisting of Sr, Ca, andBa; 1.8≦f≦2.2; 0≦g≦0.4; 1.8≦h≦2.2; and 8≦k≦10). Such complex oxides havea Seebeck coefficient of at least about 100 μV/K and an electricalresistivity of not more than about 100 mΩcm at temperatures of 100 K orhigher; and the Seebeck coefficient tends to increase and the electricalresistivity tends to decrease as the temperature rises.

n-Type Thermoelectric Material

Usable as an n-type thermoelectric material is at least one oxideselected from the group consisting of complex oxides represented byFormulae (3), (4), (5), and (6):

complex oxides represented by Formula (3): Ln_(m)R_(n) ¹Ni_(p)R_(q)²O_(r), wherein Ln is one or more elements selected from the groupconsisting of lanthanoids; R¹ is one or more elements selected from thegroup consisting of Na, K, Sr, Ca, and Bi; R² is one or more elementsselected from the group consisting of Ti, V, Cr, Mn, Fe, Co, Cu, Mo, W,Nb, and Ta; 0.5≦m≦1.7; 0≦n≦0.5; 0.5≦p≦1.2; 0≦q≦0.5; and 2.7≦r≦3.3;

complex oxides represented by Formula (4): (Ln_(s)R_(t) ³)₂Ni_(u)R_(v)⁴O_(w), wherein Ln is one or more elements selected from the groupconsisting of lanthanoids; R³ is one or more elements selected from thegroup consisting of Na, K, Sr, Ca, and Bi; R⁴ is one or more elementsselected from the group consisting of Ti, V, Cr, Mn, Fe, Co, Cu, Mo, W,Nb, and Ta; 0.5≦s≦1.2; 0≦t≦0.5; 0.5≦u≦1.2; 0≦v≦0.5; and 3.6≦w≦4.4;

complex oxides represented by Formula (5): A_(x)Zn_(y)O_(z), wherein Ais Ga or Al; 0≦x≦0.1; 0.9≦y≦1; and 0.9≦z≦1.1); and

complex oxides represented by Formula (6): SN_(xx)In_(yy)O_(zz), wherein0≦xx≦1; 0≦yy≦2; and 1.9≦zz≦3.

In the above formulae, examples of lanthanoids include La, Ce, Pr, Nd,Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Lu, etc. In Formula (3), the range of mis 0.5≦m≦1.7, and preferably 0.5≦m≦1.2.

The complex oxides represented by the above formulae have a negativeSeebeck coefficient and exhibit properties as n-type thermoelectricmaterials in that when a difference in temperature is created betweenboth ends of the oxide material, the electric potential generated by thethermoelectromotive force is higher at the high-temperature side than atthe low-temperature side.

More specifically, the above complex oxides represented by Formulae (3)and (4) have a negative Seebeck coefficient at temperatures of 373 K orhigher. For example, they may have a Seebeck coefficient of about −1 toabout −20 μV/K at temperatures of 373 K or higher. Furthermore, theabove complex oxides have excellent electrical conductivity and lowelectrical resistivity, and, for example, may have an electricalresistivity of about 20 mΩcm or less at temperatures of 373 K or higher.

The complex oxides represented by Formula (3) have a perovskite-typecrystal structure and the complex oxides represented by Formula (4) havea so-called layered perovskite-type crystal structure. The former isgenerally referred to as an ABO₃ structure and the latter as an A₂BO₄structure. In these complex oxides, some of Ln are substituted by R¹ orR³, and some of Ni are substituted by R² or R⁴.

The complex oxides represented by Formulae (5) and (6) are known as amaterial for a transparent electrically conductive film. For example,they have a Seebeck coefficient of about −100 μV/K or lower attemperatures of 100 K or higher and have excellent electricalconductivity, and exhibits low electrical resistivity as low as not morethan about 100 mΩcm at temperatures of 100 K or higher.

Among the above complex oxides, the complex oxides represented byFormula (5) have a hexagonal wurtz structure and the complex oxidesrepresented by Formula (6) have a cubic rutile structure or tetragonalbcc structure.

Among the complex oxides mentioned above, preferable examples include acomplex oxide selected from the group consisting of complex oxidesrepresented by the formula: Ln_(m)R_(n) ¹NiO_(r), wherein Ln is one ormore elements selected from the group consisting of lanthanoids; R¹ isone or more elements selected from the group consisting of Na, K, Sr,Ca, and Bi; 0.5≦m≦1.2; 0≦n≦0.5; and 2.7≦r≦3.3; complex oxidesrepresented by the formula: (Ln_(s)R_(t) ³)₂NiO_(w), wherein Ln is oneor more elements selected from the group consisting of lanthanoids; R³is one or more elements selected from the group consisting of Na, K, Sr,Ca, and Bi; 0.5≦s≦1.2; 0≦t≦0.5; and 3.6≦w≦4.4; and complex oxidesrepresented by the formula: Ln_(x)R_(y) ⁵Ni_(p)R_(q′) ⁶O_(r′), whereinLn is one or more elements selected from the group consisting oflanthanoids; R⁵ is one or more elements selected from the groupconsisting of Na, K, Sr, Ca, Bi, and Nd; and R⁶ is one or more elementsselected from the group consisting of Ti, V, Cr, Mn, Fe, Co, and Cu;0.5≦x≦1.2; 0≦y≦0.5; 0.5≦p≦1.2; 0.01≦q′≦0.5; and 2.8≦r′≦3.2.

Among the above, the complex oxides represented by the formulae:Ln_(m)R_(n) ¹NiO_(r) and (Ln_(s)R_(t) ³)₂NiO_(w), for example, have aSeebeck coefficient of −1 to −30 mV/K at temperatures of 100 K or higherand exhibits low electrical resistivity. For example, they may haveelectrical conductivity of not more than about 10 mΩcm at a temperatureof 100 K or higher.

The complex oxides represented by the formula: Ln_(x)R_(y) ⁵Ni_(p)R_(q′)⁶O_(r′) have a negative Seebeck coefficient at a temperature of 100° C.or higher, and have excellent electrical conductivity and exhibit lowelectrical resistivity as low as not more than about 10 mΩcm at atemperature of 100° C. or higher.

Thermoelectric Element

In the thermoelectric element of the present invention, the thin film ofp-type thermoelectric material and the thin film of n-typethermoelectric material are formed on an electrically insulatingsubstrate and one end portion of the thin film of p-type thermoelectricmaterial and one end portion of the thin film of n-type thermoelectricmaterial are electrically connected.

(1) Electrically Insulating Substrate

There is no limitation on an electrically insulating substrate insofaras the substrate does not deteriorate at the temperature at which thesubstrate is subjected to a heat treatment for forming a thin oxidefilm. Accordingly, various types of substrates can be used, including aninexpensive substrate. Moreover, a substrate having low thermalconductivity, such as a glass substrate, ceramic substrate and the like,can be used. The use of such substrate can sharply reduce the influenceof substrate temperature on the thermoelectric conversion efficiency ofthe thin film of complex oxide to be formed.

Various types of plastic materials, such as polyimide, etc., can also beused as a substrate insofar as the material does not deteriorate atheat-treatment temperature. When a thin film of a thermoelectricmaterial is formed by a vapor deposition method, aerosol depositionmethod or the like among the thin-film formation methods describedlater, a thin film having an excellent thermoelectric conversionefficiency can be formed without heat treatment. Therefore, on asubstrate of a plastic material having relatively low heat resistance,such as polyethylene, polypropylene, polystyrene, polyethyleneterephthalate (PET) and the like, a thin film of a thermoelectricmaterial having an excellent thermoelectric conversion efficiency can beformed. The present invention can employ various types of plasticmaterials as mentioned above as a substrate, and thus can be used inmany applications utilizing the properties such as flexibility,plasticity and the like of the plastic materials. Moreover, since a thinfilm of a thermoelectric material can be formed while applying nothermal damage to, for example, an organic thin-film transistor (organicTFT) or the like, the present invention can be applied to variousflexible devices.

In the invention, a substrate having low thermal conductivity of about10 W/m·K or lower at 25° C. is preferable, one having thermalconductivity of about 5 W/m·K or lower at 25° C. is more preferable, andone having thermal conductivity of about 2 W/m·K or lower at 25° C. iseven more preferable.

Various shapes of electrically insulating substrates can be used withoutlimitation, and the shape can be suitably determined in accordance withthe usage of the thermoelectric element to be obtained.

For example, in the case of a pipe-like substrate, a pipe-likethermoelectric element can be obtained by forming thin films of complexoxides on either or both sides of the pipe-like substrate. In thepipe-like thermoelectric element, thermoelectric generation can beconducted by passing a combustion gas through the pipe inside to createa temperature difference between the gas inlet side and the gas outletside. The use of such a thermoelectric element enables electricity to begenerated by using a motor vehicle exhaust gas.

When a flexible electrically insulating plastic film is used as asubstrate, the shape of a thermoelectric element can be varied bywinding or bending the plastic substrate even after obtaining thethermoelectric element by forming thin films of complex oxides on suchsubstrate.

(2) Thermoelectric Material Thin Film

The film thicknesses of a thin film of p-type thermoelectric materialand a thin film of n-type thermoelectric material are not limited. Thefilm thickness of the thin films may be suitably determined inaccordance with their usage to attain excellent thermoelectricconversion performance. For example, by setting the film thickness toabout 100 nm or more and preferably about 300 nm or more, excellentperformance can be demonstrated. For use as a thin film, the upper limitof the film thickness may generally be about 10 μm or less, preferablyabout 5 μm or less, and more preferably about 2 μm or less.

The shapes of a thin film of p-type thermoelectric material and a thinfilm of n-type thermoelectric material are not limited. The shape andsize of the thin film may be suitably determined in accordance with theshape of the substrate. For example, in the case of a plate-likesubstrate, a thin film of p-type thermoelectric material and a thin filmof n-type thermoelectric material can be formed on one surface of asubstrate, or a thin film of p-type thermoelectric material can beformed on one surface of the substrate and a thin film of n-typethermoelectric material can be formed on the other surface of thesubstrate. Such thin films may be formed on a part of or on the entiresurface of the substrate. By lengthening the long sides of a thin filmof a thermoelectric material as much as possible, a temperaturedifference between both the ends of the thin film of a thermoelectricmaterial can be increased to thereby raise the voltage. By shorteningthe long sides thereof, electrical resistance can be decreased.

Also, in the case of a pipe-like substrate, both thin films may beformed on the external surface of a pipe, or one thin film may be formedon the external surface of the pipe and the other thin film may beformed on the inside of the pipe in the same manner as described above.

(3) Thin-film Formation Method

There is no limitation to the methods for forming a thin film of p-typethermoelectric material and a thin film of n-type thermoelectricmaterial on an electrically insulating substrate insofar as a singlecrystal thin film or a polycrystal thin film with the above-identifiedcomposition can be formed.

Various known methods are usable, and, examples of such known methodsinclude thin film formation by vapor deposition; thin film formationusing a raw material solution, such as dip coating, spin coating, brushcoating, or spray-atomizing; aerosol deposition by spraying fineparticles of a complex oxide; etc. In addition, single-crystal thin filmformation methods such as a flux method using a flux and a method formelting and solidifying a raw material without using a flux may beemployed.

These film formation methods can be performed under known conditions.Hereinafter, typical methods among the above methods are specificallydescribed.

(i) Vapor Deposition:

A method for forming a thin film by vapor deposition is described inmore detail.

Any raw material can be used without limitation insofar as an oxide canbe formed by evaporating and depositing the raw material onto asubstrate by vapor deposition. For example, usable are metals; oxides;various compounds (carbonate, etc.); and the like, all of which comprisea constituent metal element. In addition, a material comprising two ormore of the constituent elements of an intended complex oxide may beused.

Such raw materials are mixed in such a manner as to yield the same metalratio as that of an intended complex oxide and the mixture can be usedas it is. In particular, such a mixture of raw materials is preferablyheated. The heated material is easy to handle in the vapor depositiondescribed later.

There is no limitation on the heating conditions for such raw materials.For example, such raw materials may be sintered at high temperatures atwhich a crystal of a complex oxide represented by the above-describedformula is formed, or such raw materials may be calcined at relativelylow temperatures to form a calcinate without forming an oxide crystal.Various heating methods, such as an electric heating furnace, a gasheating furnace, etc., can be employed without limitation. The heatingatmosphere may generally be an oxidizing atmosphere such as in an oxygenstream, in air, etc. Such raw materials can also be heated in an inertgas atmosphere.

There is no limitation to the vapor deposition method insofar as anoxide thin film can be formed on a substrate using the above-mentionedraw material(s). For example, physical-vapor-deposition is preferableand specific examples thereof include pulsed laser deposition,sputtering, vacuum deposition, ion-plating, plasma-assisted-deposition,ion-assisted-deposition, reactive deposition, laser ablation, etc. Amongthese methods, pulsed laser deposition is preferable because compositionvariation is not likely to occur during the vapor deposition of acomplex oxide comprising multi-elements.

A complex oxide may be deposited while heating a substrate at about 400°C. to about 600° C., or may be deposited at room temperature. When acomplex oxide is deposited while heating a substrate, the complex oxideis formed on a substrate, thereby usually eliminating a heat treatment.Some complex oxides deposited on a substrate at room temperature have avery low degree of crystallization, and thus cannot exhibit goodthermoelectric conversion performance. In this case, such a complexoxide can be given good thermoelectric conversion performance by heatingto promote crystallization of the oxide.

The heat treatment temperature may be, for example, about 600° C. toabout 740° C. Heat treatment in this temperature range can promote thecrystallization of a thin film of complex oxide and thus achieve goodthermoelectric performance. An excessively low heat treatmenttemperature fails to promote crystallization to a sufficient level,which lowers the thermoelectric conversion performance, and thus is notdesirable. On the other hand, an excessively high heat treatmenttemperature causes another phase to appear, which also lowers thethermoelectric conversion performance, and thus is not desirable either.

The heat treatment may generally be performed in an oxidizingatmosphere, such as in air or in an atmosphere containing about 5% orhigher of oxygen. The heat treatment can be performed under variouspressures, such as reduced pressure, atmospheric pressure, and increasedpressure. For example, the pressure may be in the range of about 10⁻³ Pato about 2 MPa.

The heat treatment time varies depending on the size of the substrate,the thickness of the thin film of complex oxide, etc. The heat treatmentmay be performed in such a manner that the thin film of complex oxide issufficiently crystallized, and may generally be performed for about 3minutes to about 10 hours, and preferably about 1 hour to about 3 hours.

An intended thin film of complex oxide can be formed according to theabove-described method.

(ii) Spin Coating:

Next, spin coating is described in detail as a method for forming a thinfilm of complex oxide using a raw material solution.

A solution containing a dissolved raw material having a constituentmetal element of an intended complex oxide is usable as a raw materialsolution. The raw material is not limited insofar as the material canform an oxide when heated. Metals, oxides, various compounds (chlorides,carbonates, nitrates, hydroxides, alkoxide compounds, etc.) and the likeare usable as raw materials.

Usable as a solvent are water; organic solvents, such as toluene,xylene, and the like; etc. The concentration of the raw material in thesolution is not limited insofar as the solution contains a metalcomponent in the same proportion as that of an intended complex oxide,and may be, for example, about 0.01 to about 1 mol/l.

Such a raw material solution is dropped in small portions onto asubstrate rotating at high rotation rates. The solution uniformlyspreads onto the substrate due to the centrifugal force caused by therotation. The solvent is then evaporated, forming a precursor of a thinfilm of the intended complex oxide. The rotation rate of the substrateis not limited, and may be determined suitably depending on the solutionviscosity or the thickness of the film to be formed.

Subsequently, this precursor is heat-treated in air to form a thin filmof complex oxide. The heat treatment conditions are not limited insofaras an intended complex oxide is formed. In general, a solvent is removedby heating the precursor at about 300° C. to about 500° C. for about 1to about 10 hours, and then further heating the result at about 500° C.to about 1000° C. for about 1 to about 20 hours, thereby forming apolycrystalline thin film of an intended complex oxide.

(iii) Aerosol Deposition:

In the case of aerosol deposition, a coating film of a complex oxide canbe formed by spraying fine-particles of an intended complex oxide with acarrier gas onto a substrate.

Fine particles of a complex oxide can be obtained by mixing the rawmaterial of a complex oxide in such a manner as to yield the same metalratio as that of the intended complex oxide, sintering the mixture in anoxygen-containing atmosphere, and, as required, pulverizing the result.The average particle diameter of a complex oxide may be about 0.5 μm toabout 5 μm.

Examples of carrier gas include nitrogen gas, helium (He) gas, etc. Acoating film of complex oxide can be formed by spraying a complex oxidepowder onto a substrate using such a carrier gas at a gas flow of about5 to about 10 L/minute and at a distance between a nozzle and asubstrate of about 10 to about 30 mm within a reduced pressure chamberhaving a pressure of about 10 Pa to about 8 kPa. During this process,the substrate is not necessarily heated, but, when heated at about 200to about 600° C., the adhesion between the coating film to be formed andthe substrate can be increased.

After being formed, a coating film is not necessarily heated, but, asrequired, when heated at about 200 to about 700° C. for about 10 minuetsto about 4 hours in an oxygen-containing atmosphere, the crystallinityof the coating film to be formed can be further increased.

(iv) Single Crystal Thin-film Formation Method

Next, a method for forming a single crystal thin film of complex oxideis described.

According to this method, raw materials are mixed in such a manner as tohave the same element ratio as that of the intended complex oxide, themixture is melted on a substrate by heating, and the melt is cooledgradually, providing a single-crystal thin film. Any raw material can beused without limitation insofar as a mixture of the raw materials canform a homogeneous melt when heated. For example, metals, oxides,various compounds (carbonates, etc.), and the like can be used. Acompound containing two or more constituent elements of an intendedcomplex oxide is also usable.

More specifically, a single-crystal thin film can be formed by heating araw material mixture to form a melt in a uniform solution state, andcooling the melt. The heating time is not limited, and the heatingtreatment may be performed until a uniform solution state is attained.There is no limitation on the heating method and an electric heatingfurnace, gas heating furnace and the like can be used. The raw materialmay be melted in an oxidizing atmosphere, such as in an oxygen stream,in air or the like. A raw material, when containing a sufficient amountof oxygen, can be melted in, for example, an inert gas atmosphere.

The cooling method is not limited. For example, a raw material in asolution state may be cooled as a whole, or a cooled substrate may beimmersed in a container containing a molten raw material, to therebygrow a single crystal thereon.

The cooling rate is not limited, but slow cooling is preferable in orderto form a single-crystal thin film. This is because as the cooling rateis increased, a large number of crystals are grown on the substrate toform a so-called polycrystalline thin film. For example, a cooling rateof about 50° C./h or lower may be employed.

Instead of directly melting a raw material mixture, another ingredientmay be added to a raw material mixture so as to adjust the melting pointfor forming a melt, and then the mixture is melted by heating. Themethod of adding an additive (a flux component) other than materialscontaining metal elements of a complex oxide and melting the mixture isreferred to as a so-called “flux method”. In flux methods, a fluxcomponent contained in a raw material mixture is partially melted byheating, and the whole raw material mixture is dissolved to form asolution due to chemical change, dissolution effect and the like of themolten component. Thus, the raw material mixture can be melted at lowertemperatures compared with a method for directly cooling the rawmaterial mixture. By cooling the raw material in a solution state at asuitably controlled cooling rate, an intended single crystal can begrown due to supersaturation accompanied by cooling. During this coolingprocess, grown is a single crystal complex oxide with a solid phasecomposition in phase equilibrium with a solution phase that is formedwhen the raw material is melted. Therefore, based on the relationshipbetween the solution phase composition and the solid phase (singlecrystal) composition, which are in an equilibrium state, a proportion ofeach raw material in a raw material mixture can be determined accordingto the composition of the complex oxide to be formed.

In this method, the flux component contained in the raw material remainsas a solvent component, and is not contained in the single crystal to begrown.

Such a flux component may be selected from substances which have a lowermelting point compared with the raw material of the thin film, and whichhave the capability of sufficiently dissolving a raw material in themelt to be formed and which do not adversely affect the properties of anintended complex oxide. For example, alkali metal compounds,boron-containing compounds and the like can be used.

Specific examples of alkali metal compounds include alkali metalchlorides, such as lithium chloride (LiCl), sodium chloride (NaCl), andpotassium chloride (KCl), and hydrates thereof; alkali metal carbonates,such as lithium carbonate (Li₂CO₃), sodium carbonate (Na₂CO₃), andpotassium carbonate (K₂CO₃), etc.; and the like. A specific example ofboron-containing compounds is boric acid (B₂O₃), etc. These additivescan be used singly or as a mixture of two or more thereof.

The content of such a flux component is not limited, and can bedetermined depending on the heating temperature considering thesolubility of the raw material in the melt to be formed in such a mannerthat the melt will contain the raw material in as high a concentrationas possible.

There is no limitation on the method for melting a raw material mixture,and the raw material mixture may be heated to form a melt in a uniformsolution state on a substrate. The heating temperature varies dependingon the flux component used. For example, the raw material mixture may bemelted by heating at temperatures of about 800 to about 1000° C. forabout 20 to about 40 hours.

There is no limitation on the heating method and an electric heatingfurnace, gas heating furnace and the like can be used. The raw materialmay be melted in an oxidizing atmosphere, such as in an oxygen stream,in air or the like. A raw material, when containing a sufficient amountof oxygen, can be melted in, for example, an inert gas atmosphere.

Although the cooling rate is not limited, a polycrystalline thin filmmay be formed at a high cooling rate and a single-crystal thin film maybe easy to form at a low cooling rate. For example, a single crystalthin film can be formed at a cooling rate of about 50° C./h or lower.

The size, yield and the like of the single-crystal thin film of complexoxide to be formed varies depending on the type and composition of theraw material, the composition of the molten components, the coolingrate, etc. For example, when the molten mixture is cooled at a coolingrate of about 50° C./h or lower until it is solidified, needlelike orplate-like single crystals with a width of about 0.5 mm or more, athickness of about 0.5 mm or more, and a length of about 5 mm or morecan be obtained.

Subsequently, components other than the intended single crystal complexoxide are removed from solidified product formed by cooling, therebyforming a single crystal thin film of the target complex oxide as itadheres to a substrate.

Components other the complex oxide can be removed as follows. Forexample, a water-soluble component, e.g., chloride, adhering to asingle-crystal complex oxide, can be removed by repeated washing withdistilled water and filtration, and, as required, washing with ethanol.

(4) Thermoelectric Element:

A thermoelectric element of the present invention is obtained byelectrically connecting one end of a thin film of p-type thermoelectricmaterial and one end of a thin film of n-type thermoelectric material,which are formed on a substrate.

It is preferable to use the thermoelectric materials in combination suchthat the sum of the absolute values of the thermoelectromotive forces ofthe p-type thermoelectric material and the n-type thermoelectricmaterial is, for example, at least about 60 μV/K, and preferably atleast about 100 μV/K, at all temperatures in the range of 293 to 1073 K(absolute temperature). It is also preferable that each of thesethermoelectric materials has an electrical resistivity of not more thanabout 100 mΩcm, preferably not more than about 50 mΩcm, and morepreferably not more than about 10 mΩcm, at all temperatures in the rangeof 293 to 1073 K (absolute temperature).

There is no limitation to methods for electrically connecting the thinfilms. For example, one end of a thin film of p-type thermoelectricmaterial and one end of a thin film of n-type thermoelectric materialmay be brought into direct contact with each other, or one end of a thinfilm of p-type thermoelectric material and one end of a thin film ofn-type thermoelectric material may be brought into contact via anelectrically conductive material.

Specific methods for electrically connecting one end of a thin film ofp-type thermoelectric material and one end of a thin film of n-typethermoelectric material are not limited. Preferable is a method forconnecting the materials in such a manner that a thermoelectromotiveforce of at least 60 μV/K and an electrical resistance of 1 KΩ or lowercan be maintained for the thermoelectric element at all temperatures inthe range of 293 to 1073K (absolute temperature).

The electrical resistance caused by connecting thermoelectric materialsdepends on the connection method, area of the connected portion, typeand size of electrically conductive material used, etc. In general, itis preferable to determine connecting conditions so that the resistanceof the connected portion relative to that of the entire thermoelectricelement is about 50% or less, preferably about 10% or less, and morepreferably about 5% or less.

Hereinafter, a specific example of a method for electrically connectingthermoelectric materials is described with reference to the drawings.Each drawing shows a front view and a plan view of a thermoelectricelement in which one end of a thin film of p-type thermoelectricmaterial and one end of a thin film of n-type thermoelectric materialare electrically connected on a substrate.

FIGS. 1( a) to (c) show a thermoelectric element in which one end of athin film of p-type thermoelectric material 2 and one end of a thin filmof n-type thermoelectric material 3, which are formed on the samesurface of a substrate 1, are brought into direct contact with eachother.

FIGS. 1( d) and (e) show a thermoelectric element in which onethermoelectric material is brought into direct contact with the othermaterial while partially covering the other material at the contactportion of the thin films. A thermoelectric element having thisstructure can obtain more excellent electrical connection.

FIGS. 2( a) to (c) show a thermoelectric element in which one end of athin film of p-type thermoelectric material 2 and one end of a thin filmof n-type thermoelectric material 3, which are formed on a substrate 1,are connected via an electrically conductive material 4.

Any electrically conductive material can be used insofar as anelectrical resistance of the connected portion of a p-typethermoelectric material and an n-type thermoelectric material can beheld low. For example, metal paste, solder, electrically conductiveceramics, and the like can be used. In particular, electricallyconductive ceramics, a paste containing a noble metal, such as gold,silver, platinum, and the like are preferable because such material doesnot melt, and maintains its chemical stability and low resistance attemperatures as high as about 1073 K. A thin film of such anelectrically conductive material may be formed by vapor deposition, suchas sputtering, etc.

FIG. 3 shows the structure of a thermoelectric element in which one endof a thin film of p-type thermoelectric material 2 and one end of a thinfilm of n-type thermoelectric material 3, which are formed on asubstrate 1, are brought into direct contact with each other and thecontact portion is covered with an electrically conductive material 4.In an element thus structured, the thin films can ensure more excellentelectrical connection at the contact portion thereof.

FIGS. 4( a) to (c) show a thermoelectric element in which a thin film ofp-type thermoelectric material 2 and a thin film of n-typethermoelectric material 3 are formed on the same surface of a substratewithout being in contact, and both the thin films are electricallyconnected with each other on a side surface of the substrate. In FIGS.4( a) to (c), FIG. 4( a) shows a thermoelectric element in which boththe thin films are directly connected with each other on a side surfaceof the substrate. FIG. 4( b) shows a thermoelectric element in whichboth the thin films are connected via an electrically conductivematerial 4 on a side surface of the substrate. FIG. 4( c) shows athermoelectric element in which a thin film of p-type thermoelectricmaterial 2 and a thin film of n-type thermoelectric material 3 arebrought into contact with, at a corner of the substrate, a thin film ofan electrically conductive material 4 formed on a side surface of thesubstrate to thereby establish an electrical connection between the thinfilms. In this case, a metal paste, solder, electrically conductiveceramics, etc., can be used as the electrically conductive material 4 asin the thermoelectric element shown in FIG. 2, and an electricallyconductive film formed by vapor deposition may also be used. In thiscase, as an electrically conductive material formed on a side surface ofthe substrate, a thin film of p-type thermoelectric material or a thinfilm of n-type thermoelectric material may be used, and, in addition, athin film in which a thin film of p-type thermoelectric material and athin film of n-type thermoelectric material are completely or partiallylaminated are also usable.

In the thermoelectric element shown in FIG. 4( a) in whichthermoelectric materials are electrically connected on a side surface ofthe substrate, a better electrical connection can be ensured by bringingboth the thin films into direct contact and covering the contact portionwith an electrically conductive material, or by partially or completelylaminating both the thermoelectric materials on a side surface of thesubstrate.

The thermal conductivity of each of the thermoelectric elements shown inFIGS. 1 to 4 can be reduced over the element by using a substrate with acut formed as shown in FIG. 5 and separately forming a thin film ofp-type thermoelectric material and a thin film of n-type thermoelectricmaterial on either side of the cut portion formed in the substrate.

Thermoelectric Module

The thermoelectric module of the invention comprises a plurality of theabove-described thermoelectric elements, wherein the thermoelectricelements are connected in series such that an unconnected end portion ofa p-type thermoelectric material of one thermoelectric element isconnected to an unconnected end portion of an n-type thermoelectricmaterial of another thermoelectric element.

There is no limitation to the methods for connecting thermoelectricelements, and, for example, the above-described methods for connectingthermoelectric materials to form a thermoelectric element can besimilarly applied.

FIG. 6 schematically shows one embodiment of a thermoelectric module.The thermoelectric module uses thermoelectric elements in each of whichone end of a thin film of p-type thermoelectric material 2 and one endof a thin film of n-type thermoelectric material 3 are brought intodirect contact on the same surface as shown in FIG. 1( a), and thethermoelectric module is formed by connecting a plurality of suchthermoelectric elements in series by connecting an unconnected endportion of the p-type thermoelectric material 2 and an unconnected endportion of the n-type thermoelectric material 3 via an electricallyconductive material 5. The number of thermoelectric elements used in onemodule is not limited, and can be suitably determined depending on therequired electric power.

Similarly in the case of producing a thermoelectric element as shown inFIG. 2, a noble metal paste, solder, or electrically conductive ceramicscan be used as the electrically conductive material 5 for connectingthermoelectric elements. As the electrically conductive ceramics, thesame complex oxides as in the p-type thermoelectric material or n-typethermoelectric material can also be used.

In addition to a method for connecting unconnected end portions of aplurality of thermoelectric elements formed on different substrates, amethod for electrically connecting unconnected end portions of aplurality of thermoelectric elements formed on the same substrate can beemployed. According to the latter method, a thermoelectric module can beeasily obtained by forming a required number of thin films of p-typethermoelectric material and thin films of n-type thermoelectric materialon the same substrate to form thermoelectric elements through theapplication of the above-described method for forming a thin film of athermoelectric material, and then connecting an end portion of eachelement.

The thermoelectric module of the invention can produce an electricalpotential difference by positioning one end thereof at ahigh-temperature side and the other end thereof at a low-temperatureside. For example, in the module of FIG. 6, a portion where a thin filmof p-type thermoelectric material and a thin film of n-typethermoelectric material are brought into direct contact may be disposedat a high-temperature side and the other end portion may be disposed ata low-temperature side.

Moreover, as shown in the perspective view of FIG. 7, usable is apipe-like thermoelectric module which is obtained by forming a thin filmof p-type thermoelectric material 2 and a thin film of n-typethermoelectric material 3 on either or both surfaces of a pipe-likesubstrate 1 in parallel with the longitudinal direction of thesubstrate. The p-type thermoelectric material and the n-typethermoelectric material are electrically connected at one opening sideto form a thermoelectric element on the pipe-like substrate. A pluralityof such thermoelectric elements are then formed on the pipe-likesubstrate, and an unconnected end portion of each thermoelectric elementis connected with each other, providing a pipe-like thermoelectricmodule. According to such a pipe-like thermoelectric module,thermoelectric generation can be carried out by positioning one openingside of the thermoelectric module at a high-temperature side andpositioning the other opening side at a low-temperature side. Moreover,thermoelectric generation can also be carried out by passing ahigh-temperature gas through the pipe to create a temperature differencebetween a gas inlet portion and a gas outlet portion of the pipe.

Examples of heat sources for the high-temperature side includehigh-temperature heat of about 473K or higher generated in automobileengines, industrial plants, thermal power stations, atomic powerstations, garbage-incineration facilities, microturbines, boilers, andthe like; and low-temperature heat of about 293K to about 473K, such assolar heat, boiling water, body temperature, etc.

EFFECT OF THE INVENTION

In the thermoelectric element of the invention, a thin film of p-typethermoelectric material and a thin film of n-type thermoelectricmaterial are formed on an electrically insulating substrate. Thus, thethermoelectric element of the invention can be formed on various formsof substrates, providing various forms of thermoelectric elements.Therefore, the thermoelectric element of the invention can be used invarious applications, and, for example, can be installed in anelectronic circuit, used in a minute portion, etc. Since a plasticsubstrate can also be used, the thermoelectric element of the inventioncan also be applied to various flexible devices.

The thermoelectric element of the invention comprises a combination of ap-type thermoelectric material and an n-type thermoelectric material,each of which comprise a specific complex oxide, and have a highthermoelectric conversion efficiency and good electrical conductivity.Such a thermoelectric element is formed by the thermoelectric materialswith high thermoelectric conversion efficiency as well as excellentthermal stability, chemical durability, etc., and exhibits excellentperformance.

The thermoelectric module of the invention employing such athermoelectric element is given excellent thermal resistance, andtherefore it is not damaged and its electricity generating propertiesare not easily deteriorated even when the high-temperature side israpidly cooled to room temperature from a high temperature of about1000K.

Since the thermoelectric module of the invention can be small in sizeand has a high output density and also has excellent thermal shockresistance as described above, the thermoelectric module of theinvention can be applied to not only industrial plants,garbage-incineration facilities, thermal power stations, and atomicpower stations but also automobile engines with rapidly changingtemperatures.

Moreover, since the thermoelectric module can generate electricity fromheat energy having a temperature of about 473 K or lower and can alsoachieve a high integration of thermoelectric elements, thethermoelectric module, when provided with a heat source, can be used asa power supply which does not require recharging, for use in portableequipment such as mobile phones, laptop computers, etc.

BRIEF DESCRIPTION OF THE DRAWINGS

FIGS. 1( a) to (e) are plan views and front views showing fiveembodiments of a thermoelectric element.

FIGS. 2( a) to (c) are plan views and front views showing otherembodiments of a thermoelectric element.

FIG. 3 is a plan view and a front view of another embodiment of athermoelectric element.

FIGS. 4( a) to (c) are plan views and front views showing otherembodiments of a thermoelectric element.

FIG. 5 is a plan view of a substrate for a thermoelectric element havinga cut portion.

FIG. 6 is a perspective view showing a thermoelectric module formed on apipe-like substrate.

FIG. 7 is a plan view showing one embodiment of a thermoelectric module.

FIG. 8 is a view schematically showing the thermoelectric element ofExample 1.

FIG. 9 is a view schematically showing the thermoelectric element ofeach of Examples 9 to 16.

FIG. 10 is a view schematically showing the thermoelectric element ofeach of Examples 17 to 24.

FIG. 11 is a view schematically showing the thermoelectric element ofeach of Examples 25 to 40.

FIG. 12 is a view schematically showing the thermoelectric element ofeach of Examples 41 to 48.

FIG. 13 is a view schematically showing the thermoelectric element ofeach of Examples 49 to 51.

FIG. 14 is a graph showing the temperature dependency of electricalresistance with regard to the thermoelectric element of Example 1.

DESCRIPTION OF REFERENCE NUMERALS

-   1. substrate-   2. p-type thermoelectric material-   3. n-type thermoelectric material-   4,5. electrically conductive substrate

BEST MODE FOR CARRYING OUT THE INVENTION

Hereinafter, the present invention will be described in more detail withreference to Examples.

Example 1

After a target material (sintered body) for use in pulsed laserdeposition was produced according to the following method, athermoelectric element was produced by pulsed laser deposition.

(1) Preparation of a Target Material

(i) Target Material for Producing a p-type Thermoelectric Material

Using bismuth oxide (Bi₂O₃), strontium carbonate (SrCO₃) and cobaltoxide (Co₃O₄) as a raw material, these materials were mixed in such amanner as to yield the atomic ratio of Bi:Sr:Co of 2:2:2. The mixturewas calcined at 800° C. in air for 10 hours using an electric furnace,molded under pressure and heated at 850° C. for 20 hours, giving atarget material for producing a p-type thermoelectric material in theform of a disk-like sintered body with a diameter of 2 cm and athickness of 3 mm.

(ii) Target Material for Producing an n-type Thermoelectric Material

Using lanthanum nitrate (La₂(NO₃)₃.6H₂O) as a source of La, bismuthnitrate (Bi(NO₃)₃.6H₂O) as a source of Bi, and nickel nitrate(Ni(NO₃)₂.6H₂O) as a source of Ni, these materials were completelydissolved in distilled water in such a manner as to yield the atomicratio of La:Bi:Ni of 0.9:0.1:1.0. The solution was thoroughly mixedwhile stirring in a crucible of alumina, and solidified by evaporatingthe water. The solidified product was calcined at 600° C. in air for 10hours to decompose the nitrate. The obtained calcinate was crushed, andthen molded under pressure. The molded body was heated at 1000° C. in a300 ml/min oxygen stream for 20 hours, thereby producing a targetmaterial for an n-type thermoelectric material in the form of adisk-like sintered body with a diameter of 2 cm and a thickness of 3 mm.

(2) Production of Thermoelectric Elements

Using each target material, a thin film of p-type thermoelectricmaterial and a thin film of n-type thermoelectric material weresuccessively deposited on an 8 mm×8 mm×1 mm quartz glass plate as asubstrate by pulsed laser deposition using an argon fluoride (ArF)excimer laser. The p-type thermoelectric material and n-typethermoelectric material were deposited using a mask with an L-shapedopening in such a manner as to overlap each other at the short leg ofthe L shape. The L-shaped opening of the mask had a length of 8 mm and awidth of 3 mm on condition that the opening had a width of 5 mm at theportion having 2 mm width at one end in the longitudinal direction. Eachthin film was formed at room temperature without heating the substrate.Specific film formation conditions were as follows.

Laser: ArF excimer laser

Laser output: 150 mJ

Repetition frequency: 5 Hz

Pressure: 5×10⁻⁵ Torr

Distance between a target and a substrate: 3 cm

Substrate: quartz glass

Substrate temperature: room temperature

The thin film of p-type thermoelectric material and the thin film ofn-type thermoelectric material were formed by the above-describedmethod. The thin films were then heated at 650° C. for 2 hours in air,producing a thermoelectric element.

The thermoelectric element obtained had the same shape as thethermoelectric element shown in FIG. 1( d). The thin film of p-typethermoelectric material and the thin film of n-type thermoelectricmaterial were formed at an interval of 2 mm, each film having a lengthof 8 mm, a width of 3 mm and a film thickness of 1 to 2 μm. A 2 mm widthend portion of each thin film was overlapped with each other, therebyestablishing an electrical connection. The thermoelectric element thusobtained is schematically shown in FIG. 8.

Examples 2 to 8

The same procedure as in Example 1 was performed except that a thin filmof p-type thermoelectric material and a thin film of n-typethermoelectric material with the compositions shown in Table 1 wereformed, producing thermoelectric elements of Examples 2 to 8. In Tables1 to 3, the value of e is in the range of 8 to 10, k is in the range of8 to 10, r is in the range of 2.7 to 3.3, w is in the range of 3.6 to4.4 and r′ is in the range of 2.8 to 3.2.

Examples 9 to 16

Thermoelectric materials with the compositions as shown in Table 1 areused. A thin film of platinum with a length of 8 mm and a thickness of0.5 μm was formed by sputtering on a portion having 1 mm width from oneside of the 8 mm×8 mm surface of an 8 mm×8 mm×1 mm quartz glass plate asa substrate. The platinum thin film was formed at room temperature invacuo using argon as a sputtering gas.

Next, a thin film of p-type thermoelectric material with a length of 8mm was deposited on a portion having 3 mm width from one sideperpendicular to the band-like platinum thin film formed, and a thinfilm of n-type thermoelectric material was further deposited on aportion having 3 mm width from the side opposite to the portion wherethe thin film of p-type thermoelectric material was deposited. Each thinfilm was deposited by pulsed laser deposition under the same conditionsas in Example 1. Subsequently, a heat treatment was performed under thesame conditions as in Example 1, producing a thermoelectric element.

The thermoelectric element thus obtained had the same shape as theelement shown in FIG. 2( c). The thin film of p-type thermoelectricmaterial and the thin film of n-type thermoelectric material were formedat an interval of 2 mm, each film having a width of 3 mm, a length of 8mm and a thickness of 1 to 2 μm. Each thin film partially overlappedwith the platinum thin film, thereby establishing an electricalconnection. The thermoelectric element is schematically shown in FIG. 9.

Examples 17 to 24

Using a mask with an L-shaped opening, a thin film of p-typethermoelectric material and a thin film of n-type thermoelectricmaterial were deposited on an 8 mm×8 mm×1 mm quartz glass substrate. TheL-shaped opening of the mask had a width of 3 mm and a length of 8 mm oncondition that the opening had a width of 4 mm at the portion having 2mm width at one end in the longitudinal direction. The p-typethermoelectric material and the n-type thermoelectric material weredeposited in such a manner that the end portion of the short leg of eachL-shaped deposit was brought into contact with each other at the halfwayportion of the glass substrate. The p-type thermoelectric material andthe n-type thermoelectric material used in Examples 17 to 24 had thecompositions shown in Table 1 and were deposited by pulsed laserdeposition in the same manner as in Example 1. Subsequently, a heattreatment was performed under the same conditions as in Example 1,producing a thermoelectric element.

The thermoelectric element thus obtained had the same shape as theelement shown in FIG. 1( a). The thin film of p-type thermoelectricmaterial and the thin film of n-type thermoelectric material were formedat an interval of 2 mm, each film having a width of 3 mm, a length of 8mm and a thickness of 1 to 2 μm. The thin films had a linear contactwith each other at the end portion of the short leg of the L shape,thereby establishing an electrical connection. The thermoelectricelement thus obtained is schematically shown in FIG. 10.

Examples 25 to 32

A p-type thermoelectric material was deposited on one side surface (8mm×1 mm surface) of an 8 mm×8 mm×1 mm quartz glass substrate, and thenan n-type thermoelectric material was deposited thereon.

Next, an 8 mm long thin film of p-type thermoelectric material wasdeposited on a portion having a 3 mm width from one side of the 8 mm×8mm surface of the quartz glass substrate. Subsequently, an 8 mm longthin film of n-type thermoelectric material was further deposited on aportion having a 3 mm width from the side opposite to the portion wherethe thin film of p-type thermoelectric material was deposited. The thinfilm of p-type thermoelectric material and the thin film of n-typethermoelectric material were deposited in such a manner that the 3 mmlong side of each thin film was in contact with a thermoelectricmaterial formed on a side surface of the substrate. The p-typethermoelectric material and the n-type thermoelectric material used inExamples 25 to 32 had the compositions shown in Table 2 and weredeposited by pulsed laser deposition in the same manner as in Example 1.Subsequently, a heat treatment was performed under the same conditionsas in Example 1, producing a thermoelectric element.

The thermoelectric element thus obtained had the same shape as theelement shown in FIG. 4( c). The thin film of p-type thermoelectricmaterial and the thin film of n-type thermoelectric material were formedat an interval of 2 mm, each film having a width of 3 mm, a length of 8mm and a thickness of 1 to 2 μm. The thin films were in contact with, ata corner of the substrate, the electrically conductive film which wasformed on the side surface of the substrate and which was composed ofthermoelectric materials (a laminate film of a p-type thermoelectricmaterial and an n-type thermoelectric material), thereby establishing anelectrical connection. The thermoelectric element thus obtained isschematically shown in FIG. 11.

Examples 33 to 40

A platinum was deposited on one side surface (8 mm×1 mm surface) of an 8mm×8 mm×1 mm quartz glass substrate in the same manner as in Examples 9to 16.

Next, an 8 mm long thin film of p-type thermoelectric material wasdeposited on a portion having a 3 mm width from one side of the 8 mm×8mm surface of the quartz glass substrate. Subsequently, an 8 mm longthin film of n-type thermoelectric material was further deposited on aportion having a 3 mm width from the side opposite to the portion wherethe thin film of p-type thermoelectric material was deposited. The thinfilm of p-type thermoelectric material and the thin film of n-typethermoelectric material were deposited in such a manner that the 3 mmlong side of each thin film was in contact with a platinum thin filmformed on a side surface of the substrate. The p-type thermoelectricmaterial and the n-type thermoelectric material used in Examples 33 to40 had the compositions shown in Table 2 and were deposited by pulsedlaser deposition in the same manner as in Example 1. Subsequently, aheat treatment was performed under the same conditions as in Example 1,producing a thermoelectric element.

The thermoelectric element thus obtained had the same shape as theelement shown in FIG. 4( c). The thin film of p-type thermoelectricmaterial and the thin film of n-type thermoelectric material were formedat an interval of 2 mm, each film having a width of 3 mm, a length of 8mm and a thickness of 1 to 2 μm. The thin films were in contact with, ata corner of the substrate, the electrically conductive film which wasthe platinum thin film and was formed on the side surface of thesubstrate, thereby establishing an electrical connection. Thethermoelectric element thus obtained is schematically shown in FIG. 11.

Examples 41 to 48

A p-type thermoelectric material was deposited in such a manner as tohave a length of 4 mm from one side of one side surface (8 mm×1 mmsurface) of an 8 mm×8 mm×1 mm quartz glass substrate. Subsequently, ann-type thermoelectric material was further deposited in such a manner asto have a length of 4 mm from the opposite side of the same sidesurface. The thin film of p-type thermoelectric material and the thinfilm of n-type thermoelectric material had a linear contact with eachother at the 1 mm long side.

Next, an 8 mm long thin film of p-type thermoelectric material wasdeposited on a portion having a 3 mm width from one side of the 8 mm×8mm surface of the quartz glass substrate. Subsequently, an 8 mm longthin film of n-type thermoelectric material was further deposited on aportion having a 3 mm width from the side opposite to the portion wherethe thin film of p-type thermoelectric material was deposited. The thinfilm of p-type thermoelectric material was deposited in such a mannerthat the 3 mm long side was in contact with the p-type thermoelectricmaterial formed on one side surface of the substrate at a corner of thesubstrate. The thin film of n-type thermoelectric material was depositedin such a manner that the 3 mm long side was in contact with the n-typethermoelectric material formed on one side surface of the substrate at acorner of the substrate. The p-type thermoelectric material and then-type thermoelectric material used in Examples 41 to 48 had thecompositions shown in Table 2 and were deposited by pulsed laserdeposition in the same manner as in Example 1. Subsequently, a heattreatment was performed under the same conditions as in Example 1,producing a thermoelectric element.

The thermoelectric element thus obtained had the same shape as theelement shown in FIG. 4( a). The thin film of p-type thermoelectricmaterial and the thin film of n-type thermoelectric material were formedat an interval of 2 mm, each film having a width of 3 mm, a length of 8mm and a thickness of 1 to 2 μm. The thin film of the thermoelectricmaterial was in contact with, at a corner of the substrate, the thinfilm of the thermoelectric material formed on the side surface of thesubstrate, thereby establishing an electrical connection. Thethermoelectric element thus obtained is schematically shown in FIG. 12.

Examples 49 to 51

On one side surface of a shorter side (3 mm×1 mm surface) of a quartzglass substrate with a length of 8 mm, width of 3 mm and a thickness of1 mm, an electrically conductive film comprising a thin film ofplatinum, Ca_(2.7)Bi_(0.3)Co₄O_(e) or La_(0.9)Bi_(0.1)NiO_(r) wasdeposited. Platinum was deposited in the same manner as in Examples 9 to15, and Ca_(2.7)Bi_(0.3)Co₄O_(e) or La_(0.9)Bi_(0.1)NiO_(r) wasdeposited in the same manner as in Example 1.

Subsequently, a p-type thermoelectric material with a compositionrepresented by Ca_(2.7)Bi_(0.3)Co₄O_(e) was deposited on one 8 mm×3 mmsurface of the glass substrate and an n-type thermoelectric materialwith a composition represented by La_(0.9)Bi_(0.1)NiO_(r) was depositedon the other 8 mm×3 mm surface thereof. Each thin film was deposited inthe same manner as in Example 1. Subsequently, a heat treatment wasperformed under the same conditions as in Example 1, producing athermoelectric element.

In the thermoelectric element thus obtained, the thin film of p-typethermoelectric material and the thin film of n-type thermoelectricmaterial were in contact with the electrically conductive filmcomprising platinum, Ca_(2.7)Bi_(0.3)Co₄O_(e) or La_(0.9)Bi_(0.1)NiO_(r)at a corner of the substrate, thereby establishing an electricalconnection. The thermoelectric element thus obtained is schematicallyshown in FIG. 13.

Property Test Example 1

Seebeck coefficients of the p-type thermoelectric material and then-type thermoelectric material of the thermoelectric element obtained inExample 1 were measured at room temperature by the method describedbelow.

First, a heater was wound around one of two K-type thermocouples andheated. One thermocouple was brought into contact with one end of thethermoelectric material and the other thermocouple was brought intocontact with the other end of the thermoelectric material. Thetemperature and generated voltage were measured. This generated voltagewas divided by the temperature difference between the two thermocouplesto determine the Seebeck coefficient of each thermoelectric material. Asa result, the Seebeck coefficient of the p-type thermoelectric materialpart was 85 μV/K and the Seebeck coefficient of the n-typethermoelectric material part was −13 μV/K.

The Seebeck coefficients of the thermoelectric elements obtained inExamples were measured in the same manner as described above, whichshowed that the Seebeck coefficient of the p-type thermoelectricmaterial part of each Example was in the range of 60 to 120 μV/K and theSeebeck coefficient of the n-type thermoelectric material part of eachExample was in the range of −5 to −25 μV/K.

In each thermoelectric element, a platinum wire was adhered by applyingsilver paste to each end opposite to the end where the p-typethermoelectric material and the n-type thermoelectric material wereelectrically connected. The platinum wires were connected to avoltmeter, and the element was placed in an electric furnace and heatedto 500° C. The one end portion of the thermoelectric element, to whichthe platinum wires were adhered, was air-cooled using an air pump,thereby creating a temperature difference of 30 to 40° C. between thelow-temperature portion and the high-temperature portion. The generatedvoltage (open circuit voltage) at this time was measured.

The thermoelectric element obtained in Example 1 had a generated voltage(open circuit voltage) of 3.4 mV. The generated voltages (open circuitvoltages) of the thermoelectric elements obtained in the Examples areshown in Tables 1 to 3.

FIG. 14 is a graph showing the temperature dependency of the electricalresistance of the thermoelectric element obtained in Example 1. Theelectrical resistance was in the range of 350 to 1000Ω at temperaturesfrom room temperature to 650° C.

As the high-temperature portion, the end where the p-type thermoelectricmaterial and the n-type thermoelectric material were electricallyconnected was heated to 500° C. The other end was then air-cooled, tocreate a temperature difference of 38° C. At this time, thethermoelectric element obtained in Example 1 had output of powergeneration of 8.3 nW. Tables 1 to 3 also show the output of powergeneration measured in the same manner as described above with referenceto the thermoelectric elements obtained in the Examples.

TABLE 1 Open circuit voltage (mV) Output (nW) High High temperaturetemperature portion 500° C. Electrical portion 500° C. Temperatureresistance Temperature p-type thermoelectric material/ difference (Ω)difference Examples n-type thermoelectric material 30 to 40° C. 500° C.30 to 40° C. 1 Bi₂Sr₂Co₂O_(k)/La_(0.9)Bi_(0.1)NiO_(r) 3.4 350 8.3 2Bi_(2.2)Sr_(2.2)Co₂O_(k)/LaNiO_(r) 3.2 360 7.1 3Bi_(1.8)Pb_(0.4)Sr_(1.8)Ca_(0.4)Co₂O_(k)/LaNi_(0.9) 3.1 365 6.6Cu_(0.1)O_(r′) 4 Bi₂Ba₂Co₂O_(k)/La_(1.8)Bi_(0.2)NiO_(w) 3.3 355 7.7 5Ca_(2.7)Bi_(0.3)Co₄O_(e)/La_(0.9)Bi_(0.1)NiO_(r) 2.9 490 4.3 6Ca₃Co₄O_(e)/LaNiO_(r) 2.6 510 3.3 7Ca_(3.3)Na_(0.3)Co₄O_(e)/LaNi_(0.9)Cu_(0.1)O_(r′) 2.7 520 3.5 8Ca_(2.7)Bi_(0.3)Co₄O_(e)/La_(1.8)Bi_(0.2)NiO_(w) 2.9 530 4.0 9Bi_(1.2)Sr₂Co₂O_(k)/La_(0.9)Bi_(0.1)NiO_(r) 3.1 370 6.5 10Bi_(2.2)Sr_(2.2)Co₂O_(k)/LaNiO_(r) 3.2 375 6.8 11Bi_(1.8)Pb_(0.4)Sr_(1.8)Ca_(0.4)Co₂O_(k)/ 3.0 380 5.9LaNi_(0.9)Cu_(0.1)O_(r′) 12 Bi₂Ba₂Co₂O_(k)/La_(1.8)Bi_(0.2)NiO_(w) 3.2375 6.8 13 Ca_(2.7)Bi_(0.3)Co₄O_(e)/La_(0.9)Bi_(0.1)NiOr 2.8 530 3.7 14Ca₃Co₄O_(e)/LaNiO_(r) 2.8 550 3.6 15Ca_(3.3)Na_(0.3)Co₄O_(e)/LaNi_(0.9)Cu_(0.1)O_(r′) 2.7 530 3.4 16Ca_(2.7)Bi_(0.3)Co₄O_(e)/La_(1.8)Bi_(0.2)NiO_(w) 2.9 540 3.9 17Bi₂Sr₂Co₂O_(k)/La_(0.9)Bi_(0.1)NiO_(r) 3.1 370 6.5 18Bi_(2.2)Sr_(2.2)Co₂O_(k)/LaNiO_(r) 3.3 370 7.4 19Bi_(1.8)Pb_(0.4)Sr_(1.8)Ca_(0.4)Co₂O_(k)/ 3.0 360 6.3LaNi_(0.9)Cu_(0.1)O_(r′) 20 Bi₂Ba₂Co₂O_(k)/La_(1.8)Bi_(0.2)NiO_(w) 3.1380 6.3 21 Ca_(2.7)Bi_(0.3)Co₄O_(e)/La_(0.9)Bi_(0.1)NiO_(r) 3.0 510 4.422 Ca₃Co₄O_(e)/LaNiO_(r) 2.9 520 4.0 23Ca_(3.3)Na_(0.3)Co₄O_(e)/LaNi_(0.9)Cu_(0.1)O_(r′) 2.9 500 4.2 24Ca_(2.7)Bi_(0.3)Co₄O_(e)/La_(1.8)Bi_(0.2)NiO_(w) 2.7 530 3.4

TABLE 2 Open circuit voltage (mV) Output (nW) High High temperaturetemperature portion 500° C. Electrical portion 500° C. Temperatureresistance Temperature p-type thermoelectric material/ difference (Ω)difference Examples n-type thermoelectric material 30 to 40° C. 500° C.30 to 40° C. 25 Bi₂Sr₂Co₂O_(k)/La_(0.9)Bi_(0.1)NiO_(r) 2.9 390 5.4 26Bi_(2.2)Sr_(2.2)Co₂O_(k)/LaNiO_(r) 3.0 370 6.1 27Bi_(1.8)Pb_(0.4)Sr_(1.8)Ca_(0.4)Co₂O_(k)/ 3.2 385 6.6LaNi_(0.9)Cu_(0.1)O_(r′) 28 Bi₂Ba₂Co₂O_(k)/ 3.1 390 6.2La_(1.8)Bi_(0.2)NiO_(w) 29Ca_(2.7)Bi_(0.3)Co₄O_(e)/La_(0.9)Bi_(0.1)NiO_(r) 2.9 560 3.8 30Ca₃Co₄O_(e)/LaNiO_(r) 2.7 550 3.3 31 Ca_(3.3)Na_(0.3)Co₄O_(e)/ 2.8 5503.6 LaNi_(0.9)Cu_(0.1)O_(r′) 32Ca_(2.7)Bi_(0.3)Co₄O_(e)/La_(1.8)Bi_(0.2)NiOw 2.8 540 3.6 33Bi₂Sr₂Co₂O_(k)/La_(0.9)Bi_(0.1)NiO_(r) 3.1 375 6.4 34Bi_(2.2)Sr_(2.2)Co₂O_(k)/LaNiO_(r) 3.3 390 7.0 35Bi_(1.8)Pb_(0.4)Sr_(1.8)Ca_(0.4)Co₂O_(k)/LaNi_(0.9) 3.0 380 5.9Cu_(0.1)O_(r′) 36 Bi₂Ba₂Co₂O_(k)/La_(1.8)Bi_(0.2)NiO_(w) 3.1 375 6.4 37Ca_(2.7)Bi_(0.3)Co₄O_(e)/La_(0.9)Bi_(0.1)NiO_(r) 2.9 520 4.0 38Ca₃Co₄O_(e)/LaNiO_(r) 2.8 550 3.6 39 Ca_(3.3)Na_(0.3)Co₄O_(e)/ 2.9 5703.7 LaNi_(0.9)Cu_(0.1)O_(r′) 40Ca_(2.7)Bi_(0.3)Co₄O_(e)/La_(1.8)Bi_(0.2)NiO_(w) 2.7 555 3.3 41Bi₂Sr₂Co₂O_(k)/La_(0.9)Bi_(0.1)NiO_(r) 2.9 400 5.3 42Bi_(2.2)Sr_(2.2)Co₂O_(k)/LaNiO_(r) 3.1 405 5.9 43Bi_(1.8)Pb_(0.4)Sr_(1.8)Ca_(0.4)Co₂O_(k)/ 3.2 390 6.6LaNi_(0.9)Cu_(0.1)O_(r′) 44 Bi₂Ba₂Co₂O_(k)/La_(1.8)Bi_(0.2)NiO_(w) 3.0385 5.8 45 Ca_(2.7)Bi_(0.3)Co₄O_(e)/La_(0.9)Bi_(0.1)NiO_(r) 3.1 530 4.546 Ca₃Co₄O_(e)/LaNiO_(r) 2.9 520 4.0 47 Ca_(3.3)Na_(0.3)Co₄O_(e)/ 2.7525 3.5 LaNi_(0.9)Cu_(0.1)O_(r′) 48 Ca_(2.7)Bi_(0.3)Co₄O_(e)/ 2.8 5603.5 La_(1.8)Bi_(0.2)NiO_(w)

TABLE 3 Open circuit voltage (mV) Output (nW) High High temperaturetemperature portion portion 500° C. Electrical 500° C. Temperatureresistance Temperature Electrically p-type thermoelectric material/difference (Ω) difference Examples conductive film n-type thermoelectricmatetial 30 to 40° C. 500° C. 30 to 40° C. 49 PtCa_(2.7)Bi_(0.3)Co₄O_(e)/La_(0.9)Bi_(0.1)NiO_(r) 2.8 490 4.0 50Ca_(2.7)Bi_(0.3)Co₄O_(e)Ca_(2.7)Bi_(0.3)Co₄O_(e)/La_(0.9)Bi_(0.1)NiO_(r) 3.2 540 4.7 51La_(0.9)Bi_(0.1)NiO_(r) Ca_(2.7)Bi_(0.3)Co₄O_(e)/La_(0.9)Bi_(0.1)NiO_(r)3.5 500 4.5

Example 52

After a sputtering target was produced by the following method, athermoelectric element was produced by sputtering.

(1) Preparation of a Target

(i) Target Material for Producing a p-type Thermoelectric Material

Using bismuth oxide (Bi₂O₃), strontium carbonate (SrCO₃) and cobaltoxide (Co₃O₄) as a raw material, these materials were mixed in such amanner as to yield the atomic ratio of Bi:Sr:Co of 2:2:2. The mixturewas calcined at 800° C. in air for 10 hours using an electric furnace,molded under pressure and heated at 850° C. for 20 hours. A copper platewas covered with the obtained powder in such a manner that a diameter is10 cm and a thickness is 2 mm, giving a target material for producing ap-type thermoelectric material.

(ii) Target Material for Producing an n-type Thermoelectric Material

Using lanthanum nitrate (La₂(NO₃)₃.6H₂O) as a source of La, bismuthnitrate (Bi(NO₃)₃.6H₂O) as a source of Bi, and nickel nitrate(Ni(NO₃)₂-6H₂0) as a source of Ni, these materials were completelydissolved in distilled water in such a manner as to yield the atomicratio of La:Bi:Ni of 0.9:0.1:1.0. The solution was thoroughly mixedwhile stirring in a crucible of alumina, and solidified by evaporatingthe water. The solidified product was calcined at 600° C. in air for 10hours to decompose the nitrates. The obtained calcinate was crushed, andthen molded under pressure. The molded body was heated at 1000° C. in a300 ml/min oxygen stream for 20 hours. A copper plate was covered withthe obtained powder in such a manner that a diameter is 10 cm and athickness is 2 mm, giving a target material for producing an n-typethermoelectric material.

(2) Production of Thermoelectric Elements

Using each target material, a thin film of p-type thermoelectricmaterial and a thin film of n-type thermoelectric material weresuccessively deposited on an 8 mm×8 mm×1 mm polyimide film as asubstrate by RF sputtering. The p-type thermoelectric material andn-type thermoelectric material were deposited using a mask with anL-shaped opening in such a manner as to overlap each other at the shortleg of the L shape. The L-shaped opening of the mask had a length of 8mm and a width of 3 mm on condition that the opening had a width of 5 mmat the portion having 2 mm width at one end in the longitudinaldirection. The substrate was not heated and the temperature increase dueto plasma was adjusted to 260° C. or lower. Specific film formationconditions were as follows.

Sputtering gas: Ar

RF power: 50 to 200 W

Substrate: polyimide film

A thin film of p-type thermoelectric material and a thin film of n-typethermoelectric material were formed by the above-described method.

The thermoelectric element thus obtained had the same shape as theelement shown in FIG. 1( d). The thin film of p-type thermoelectricmaterial and the thin film of n-type thermoelectric material were formedat an interval of 2 mm, each film having a length of 8 mm, a width of 3mm, and a thickness of 1 to 2 μm. A 2 mm width end portion of each thinfilm was overlapped with each other, thereby establishing an electricalconnection. The thermoelectric element thus obtained is schematicallyshown in FIG. 8.

Examples 53 to 59

The same procedure as in Example 52 was performed except that a thinfilm of p-type thermoelectric material and a thin film of n-typethermoelectric material with the compositions shown in Table 4 wereformed, thereby producing thermoelectric elements of Examples 53 to 59.The heating temperature during the production of a raw material powdervaried in the range of 700 to 1100° C. depending on the specificcomposition.

In Table 4, the value of e is in the range of 8 to 10, k is in the rangeof 8 to 10, r is in the range of 2.7 to 3.3, w is in the range of 3.6 to4.4 and r′ is in the range of 2.8 to 3.2.

The thermoelectric elements obtained in Examples 52 to 59 were measuredfor the generated voltage (open circuit voltage), electrical resistanceand power generation output in the same manner as in Example 1. Table 4shows the measurement results.

TABLE 4 Open circuit voltage (mV) High Output (nW) temperature Hightemperature portion 100° C. Electrical portion 100° C. Temperatureresistance Temperature p-type thermoelectric material/ difference (Ω)difference Examples n-type thermoelectric material 30 to 40° C. 100° C.30 to 40° C. 52 Bi₂Sr₂Co₂O_(k)/La_(0.9)Bi_(0.1)NiO_(r) 1.5 670 0.84 53Bi_(2.2)Sr_(2.2)Co₂O_(k)/LaNiO_(r) 1.3 680 0.62 54Bi_(1.8)Pb_(0.4)Sr_(1.8)Ca_(0.4)Co₂O_(k)/ 1.2 685 0.52LaNi_(0.9)Cu_(0.1)O_(r′) 55 Bi₂Ba₂Co₂O_(k)/La_(1.8)Bi_(0.2)NiO_(w) 1.4675 0.72 56 Ca_(3.7)Bi_(0.3)Co₄O_(e)/La_(0.9)Bi_(0.1)NiO_(r) 1.1 7100.42 57 Ca₃Co₄O_(e)/LaNiO_(r) 0.9 720 0.28 58Ca_(3.3)Na_(0.3)Co₄O_(e)/LaNi_(0.9)Cu_(0.1)O_(r′) 1.0 730 0.34 59Ca_(2.7)Bi_(0.3)Co₄O_(e)/La_(1.8)Bi_(0.2)NiO_(w) 1.1 740 0.41

Example 60

After a raw material powder for aerosol deposition was prepared by thefollowing method, a thermoelectric element was produced by aerosoldeposition using a sheet of polyimide resin (tradename: Capton) as asubstrate.

(1) Production of a Raw Material Powder

(i) p-type Thermoelectric Material Powder

Using calcium carbonate (CaCo₃), bismuth oxide (Bi₂O₃) and cobalt oxide(Co₃O₄) as a raw material, these materials were mixed in such a manneras to yield the atomic ratio of Ca:Bi:Co of 2.7:0.3:4. The mixture wascalcined at 800° C. in air for 10 hours using an electric furnace,molded under pressure and sintered at 850° C. for 20 hours. The sinteredbody was crushed using a ball mill, yielding a raw material powder withan average particle diameter of 4 μm for a p-type thermoelectricmaterial represented by the formula: Ca_(2.7)Bi_(0.3)CO₄O_(e).

(ii) n-type Thermoelectric Material Powder

Using lanthanum nitrate (La₂(NO₃)₃.6H₂0) as a source of La, bismuthnitrate (Bi(NO₃)₃.6H₂O) as a source of Bi, and nickel nitrate(Ni(NO₃)₂.6H₂O) as a source of Ni, these materials were completelydissolved in distilled water in such a manner as to yield the atomicratio of La:Bi:Ni of 0.9:0.1:1.0. The solution was thoroughly mixedwhile stirring in a crucible of alumina, and solidified by evaporatingthe water. The solidified product was calcined at 600° C. in air for 10hours to decompose the nitrates. The obtained calcinate was crushed, andthen molded under pressure. The molded body was heated at 1000° C. in a300 ml/min oxygen stream for 20 hours. The sintered body was thencrushed using a ball mill, yielding a raw material powder with anaverage particle diameter of 4 μm for an n-type thermoelectric materialrepresented by the formula: La_(0.9)Bi_(0.1)NiO_(r).

(2) Production of Thermoelectric Elements

A thin film of p-type thermoelectric material and a thin film of n-typethermoelectric material were successively deposited onto an 8 mm×8mm×0.05 mm polyimide (tradename: Capton) sheet as a substrate in areduced chamber having a pressure of 1 KPa, producing a thermoelectricelement. The p-type thermoelectric material and n-type thermoelectricmaterial were deposited using a mask with an L-shaped opening in such amanner as to overlap each other at the short leg of the L shape. TheL-shaped opening of the mask had a length of 8 mm and a width of 3 mm oncondition that the opening had a width of 5 mm at the portion having 2mm width at one end in the longitudinal direction. Each film was formedat room temperature without heating the substrate.

Specific film formation conditions were as follows. Helium (He) was usedas a carrier gas, the raw material powder for p-type thermoelectricmaterial and the raw material powder for n-type thermoelectric materialwere successively sprayed at a gas flow rate of 7 L/minute and at adistance between a nozzle and a substrate of 15 mm, providing athermoelectric element on which a thin film of p-type thermoelectricmaterial and a thin film of n-type thermoelectric material were formed,each film having a thickness of about 50 μm. After the formation of thethin films, no heating was performed.

The thermoelectric element thus obtained had the same shape as theelement shown in FIG. 1( d). The thin film of p-type thermoelectricmaterial and the thin film of n-type thermoelectric material were formedat an interval of 2 mm, each film having a length of 8 mm and a width of3 mm. A 2 mm width end portion of each thin film was overlapped witheach other, thereby establishing an electrical connection. When thehigh-temperature portion of the element was heated by an electric heaterto 150° C. and the low-temperature portion was adjusted to 120° C., apower of 4.7 nW was generated.

Examples 61 to 67

The same procedure as in Example 60 was performed except that a thinfilm of p-type thermoelectric material and a thin film of n-typethermoelectric material with the compositions shown in Table 5 wereformed, thereby producing the thermoelectric elements of Examples 61 to67. The heating temperature during the production of a raw materialpowder varied in the range of 700 to 1100° C. depending on the specificcomposition.

In Table 5, the value of e is in the range of 8 to 10, k is in the rangeof 8 to 10, r is in the range of 2.7 to 3.3 and w is in the range of 3.6to 4.4.

The thermoelectric elements obtained in Examples 60 to 67 were measuredfor generated voltage (open circuit voltage), electrical resistance andpower generation output in the same manner as in Example 1. Table 5shows the measurement results.

TABLE 5 Open circuit voltage (mV) High temperature Output (nW) portion100° C. Electrical High temperature Temperature resistance portion 100°C. p-type thermoelectric material/ difference (Ω) Temperature differenceExamples n-type thermoelectric material 30 to 40° C. 100° C. 30 to 40°C. 60 Ca_(2.7)Bi_(0.3)Co₄O_(e)/La_(0.9)Bi_(0.1)NiO_(r) 1.5 330 1.7 61Ca₃Co₄O_(e)/LaNiO_(r) 1.2 360 1.0 62Ca_(2.7)Bi_(0.3)Co₄O_(e)/La_(1.8)Bi_(0.2)NiO_(w) 1.4 365 1.3 63Ca₃Co₄O_(e)/La₂Ni_(0.9)Cu_(0.1)O_(w) 1.3 355 1.2 64Bi₂Sr₂Co₂O_(k)/La_(0.9)Bi_(0.1)NiO_(r) 0.9 490 0.4 65Bi_(2.2)Sr_(2.2)Co₂O_(k)/LaNiO_(r) 1.1 510 0.6 66Bi_(1.8)Pb_(0.2)Ca₂Co₂O_(k)/ 1.1 480 0.6 La_(1.8)Bi_(0.2)NiO_(w) 67Bi_(2.1)Ca_(0.4)Sr_(1.7)Co₂O_(k)/ 1.0 490 0.5 La₂Ni0.9Co_(0.1)O_(w)

Example 68

After a sputtering target was produced by the following method, athermoelectric element was produced by sputtering.

(1) Preparation of a Target

(i) Target Material for Producing a p-type Thermoelectric Material

Using bismuth oxide (Bi₂O₃), strontium carbonate (SrCO₃) and cobaltoxide (Co₃O₄) as a raw material, these materials were mixed in such amanner as to yield the atomic ratio of Bi:Sr:Co of 2:2:2. The mixturewas calcined at 800° C. in air for 10 hours using an electric furnace,molded under pressure and heated at 850° C. for 20 hours. A copper platewas covered with the obtained powder in such a manner that a diameter is10 cm and a thickness is 2 mm, giving a target material for producing ap-type thermoelectric material.

(ii) Target Material for Producing an n-type Thermoelectric Material

5 wt % of gallium oxide (Ga₂O₃) was added to zinc oxide (ZnO), and themixture was sintered, producing a disk-like sintered target 10 cm indiameter and 3 mm in thickness.

(2) Production of a Thermoelectric Element

Using each target material, a thin film of p-type thermoelectricmaterial and a thin film of n-type thermoelectric material weresuccessively deposited on an 8 mm×8 mm×0.5 mm polyimide film as asubstrate by RF sputtering. The p-type thermoelectric material andn-type thermoelectric material were deposited using a mask with anL-shaped opening in such a manner as to overlap each other at the shortleg of the L shape. The L-shaped opening of the mask had a length of 8mm and a width of 3 mm on condition that the opening had a width of 5 mmat the portion having 2 mm width at one end in the longitudinaldirection. The substrate was not heated and the temperature increase dueto plasma was adjusted to 260° C. or lower. Specific film formationconditions were as follows.

Sputtering gas: Ar, O₂

RF power: 50 to 200 W

Substrate: polyimide film

A thin film of p-type thermoelectric material and a thin film of n-typethermoelectric material were formed by the above-described method.

The thermoelectric element thus obtained had the same shape as theelement shown in FIG. 1( d). The thin film of p-type thermoelectricmaterial and the thin film of n-type thermoelectric material were formedat an interval of 2 mm, each film having a length of 8 mm, a width of 3mm and a thickness of 1 to 2 μm. A 2 mm width end portion of each thinfilm was overlapped with each other, thereby establishing an electricalconnection. The thermoelectric element thus obtained is schematicallyshown in FIG. 8.

Examples 69 to 75

The same procedure as in Example 68 was performed except that a thinfilm of p-type thermoelectric material and a thin film of n-typethermoelectric material with the compositions shown in Table 6 wereformed, thereby producing the thermoelectric elements of Examples 69 to75. The heating temperature for producing the raw material powder variedin the range of 700 to 1100° C. depending on the specific composition.

In Table 6, the value of e is in the range of 8 to 10, k is in the rangeof 8 to 10, z is in the range of 0.9 to 1.1 and zz is in the range of1.9 to 3.

The thermoelectric elements obtained in Examples 68 to 75 were measuredfor generated voltage (open circuit voltage), electrical resistance andpower generation output in the same manner as in Example 1. Table 6shows the measurement results.

TABLE 6 Open circuit voltage (mV) High temperature Output (nW) portion100° C. Electrical High temperature Temperature resistance portion 100°C. p-type thermoelectric material/ difference (Ω) Temperature differenceExamples n-type thermoelectric material 30 to 40° C. 100° C. 30 to 40°C. 68 Bi₂Sr₂Co₂O_(k)/Ga_(0.1)Zn_(0.9)O_(z) 2.9 570 3.69 69Bi_(2.2)Sr_(2.2)Co₂O_(k)/Al_(0.1)Zn_(0.9)O_(z) 2.6 590 2.86 70Bi_(1.8)Pb_(0.4)Sr_(1.8)Ca_(0.4)Co₂O_(k)/ 2.7 610 2.99In_(0.1)Zn_(0.9)O_(z) 71 Bi₂Ba₂Co₂O_(k)/Sn_(0.1)In_(1.9)O_(zz) 2.5 5852.67 72 Ca_(3.7)Bi_(0.3)Co₄O_(e)/Ga_(0.1)Zn_(0.9)O_(z) 2.6 610 2.77 73Ca₃Co₄O_(e)/Al_(0.1)Zn_(0.9)O_(z) 2.8 600 3.27 74Ca_(3.3)Na_(0.3)Co₄O_(e)/In_(0.1)Zn_(0.9)O_(z) 2.4 605 2.38 75Ca_(2.7)Bi_(0.3)Co₄O_(e)/Sn_(0.1)In_(1.9)O_(zz) 2.2 595 2.03

Hereinafter, as Reference Examples, the various property values aregiven for various thermoelectric materials each comprising a complexoxide with a specific composition.

Reference Example 1

A complex oxide having properties of the p-type thermoelectric materialrepresented by the formula Ca_(a)A_(b) ¹Co_(c)A_(d) ²O_(e) orBi_(f)Pb_(g)M_(h) ¹Co_(i)M_(j) ²O_(k) was prepared by the followingmethod.

Using carbonate or oxide comprising an element of an intended complexoxide as starting materials, these starting materials were mixed in sucha manner as to yield the same element ratio as that of the complexoxides represented by the formula shown in Tables 7 to 74. The mixturewas calcined at 1073 K for 10 hours in air to yield a calcinate. Thecalcinate was crushed and molded under pressure, and the molded body washeated in a 300 mL/min oxygen stream for 20 hours. The result wascrushed and molded under pressure, and the molded body was hot-presssintered in air under uniaxial pressure of 10 MPa for 20 hours, therebyproducing complex oxides for a p-type thermoelectric material. Theheating temperature for producing each complex oxide varied in the rangeof 1073 to 1273 K depending on the specific composition. The hot-presstemperature during the production of each complex oxide varied in therange of 1123 to 1173 K depending on the specific composition

The complex oxides obtained were measured for the Seebeck coefficient at700° C., electrical resistivity at 700° C. and thermal conductivity at700° C. Tables 7 to 74 show the measurement results.

TABLE 7 p-type Electrical Seebeck Resistivity Thermal CompositionCoefficient mΩcm Conductivity Ca_(a)A¹ _(b)Co_(c)A² _(d)O_(e) μV/K (700°C.) (700° C.) W/mk (700° C.) Ca₃Co₄O₉ 205 5.5 2.5 Ca_(2.7)Na_(0.3)Co₄O₉198 4.2 2.2 Ca_(2.7)K_(0.3)Co₄O₉ 195 6 2.2 Ca_(2.7)Li_(0.3)Co₄O₉ 200 7.22.4 Ca_(2.7)Ti_(0.3)Co₄O₉ 205 6.8 2.6 Ca_(2.7)V_(0.3)Co₄O₉ 198 5.7 2.5Ca_(2.7)Cr_(0.3)Co₄O₉ 199 6.2 3 Ca_(2.7)Mn_(0.3)Co₄O₉ 210 6.8 2.6Ca_(2.7)Fe_(0.3)Co₄O₉ 202 8 2.9 Ca_(2.7)Ni_(0.3)Co₄O₉ 204 7.9 1.9Ca_(2.7)Cu_(0.3)Co₄O₉ 197 6.9 2.2 Ca_(2.7)Zn_(0.3)Co₄O₉ 205 5.9 2.6Ca_(2.7)Pb_(0.3)Co₄O₉ 201 7.8 2.5 Ca_(2.7)Sr_(0.3)Co₄O₉ 196 6.3 3Ca_(2.7)Ba_(0.3)Co₄O₉ 202 6.5 1.9 Ca_(2.7)Al_(0.3)Co₄O₉ 203 6.4 2Ca_(2.7)Bi_(0.3)Co₄O₉ 208 8.2 2.2 Ca_(2.7)Y_(0.3)Co₄O₉ 198 7.5 2.3Ca_(2.7)La_(0.3)Co₄O₉ 199 6.9 1.9 Ca_(2.7)Ce_(0.3)Co₄O₉ 201 8.1 3.1Ca_(2.7)Pr_(0.3)Co₄O₉ 207 7.6 2.6 Ca_(2.7)Nd_(0.3)Co₄O₉ 190 5.9 2.7Ca_(2.7)Sm_(0.3)Co₄O₉ 198 5.8 2.4 Ca_(2.7)Eu_(0.3)Co₄O₉ 199 7.2 1.9Ca_(2.7)Gd_(0.3)Co₄O₉ 201 8.2 3 Ca_(2.7)Dy_(0.3)Co₄O₉ 200 7.1 2.1Ca_(2.7)Ho_(0.3)Co₄O₉ 206 6.5 2.2 Ca_(2.7)Er_(0.3)Co₄O₉ 205 6.9 2.6Ca_(2.7)Yb_(0.3)Co₄O₉ 198 7 2.7 Ca₃Co_(3.8)Ti_(0.2)O₉ 200 6.8 1.9Ca₃Co_(3.8)V_(0.2)O₉ 203 7.2 2.9 Ca₃Co_(3.8)Cr_(0.2)O₉ 201 5.9 2.4

TABLE 8 Ca₃Co_(3.8)Mn_(0.2)O₉ 208 8.1 2.6 Ca₃Co_(3.8)Fe_(0.2)O₉ 198 7.22.7 Ca₃Co_(3.8)Ni_(0.2)O₉ 199 6.4 1.9 Ca₃Co_(3.8)Cu_(0.2)O₉ 207 5.9 3Ca₃Co_(3.9)Ag_(0.1)O₉ 198 6 2.7 Ca₃Co_(3.9)Mo_(0.1)O₉ 196 5.9 2.7Ca₃Co_(3.9)W_(0.1)O₉ 200 7.2 2.8 Ca₃Co_(3.9)Nb_(0.1)O₉ 198 8.1 2.2Ca₃Co_(3.9)Ta_(0.1)O₉ 205 6.9 2.5 Ca_(2.7)Na_(0.3)Co_(3.8)Ti_(0.2)O₉ 2056.2 2.6 Ca_(2.7)Na_(0.3)Co_(3.8)V_(0.2)O₉ 198 6.8 2Ca_(2.7)Na_(0.3)Co_(3.8)Cr_(0.2)O₉ 195 8 1.9Ca_(2.7)Na_(0.3)Co_(3.8)Mn_(0.2)O₉ 200 7.9 2.3Ca_(2.7)Na_(0.3)Co_(3.8)Fe_(0.2)O₉ 205 6.9 2.5Ca_(2.7)Na_(0.3)Co_(3.8)Ni_(0.2)O₉ 198 5.9 2.7Ca_(2.7)Na_(0.3)Co_(3.8)Cu_(0.2)O₉ 199 7.8 2.5Ca_(2.7)Na_(0.3)Co_(3.9)Ag_(0.1)O₉ 210 6.3 2.6Ca_(2.7)Na_(0.3)Co_(3.9)Mo_(0.1)O₉ 202 6.5 2.4Ca_(2.7)Na_(0.3)Co_(3.9)W_(0.1)O₉ 207 6.4 2.3Ca_(2.7)Na_(0.3)Co_(3.9)Nb_(0.1)O₉ 198 8.2 2.2Ca_(2.7)Na_(0.3)Co_(3.9)Ta_(0.1)O₉ 196 7.5 2.1Ca_(2.7)K_(0.3)Co_(3.8)Ti_(0.2)O₉ 198 8.1 1.8Ca_(2.7)K_(0.3)Co_(3.8)V_(0.2)O₉ 205 7.6 2.7Ca_(2.7)K_(0.3)Co_(3.8)Cr_(0.2)O₉ 196 5.9 2.6Ca_(2.7)K_(0.3)Co_(3.8)Mn_(0.2)O₉ 205 5.8 2.5Ca_(2.7)K_(0.3)Co_(3.8)Fe_(0.2)O₉ 198 7.2 2.1Ca_(2.7)K_(0.3)Co_(3.8)Ni_(0.2)O₉ 198 8.2 2.3Ca_(2.7)K_(0.3)Co_(3.8)Cu_(0.2)O₉ 195 7.1 2.7Ca_(2.7)K_(0.3)Co_(3.9)Ag_(0.1)O₉ 200 6.5 2.8 Ca_(2.7)K_(0.3)Co₃₉Mo_(0.1)O₉ 203 6.9 2.5 Ca_(2.7)K_(0.3)Co_(3.9)W_(0.1)O₉ 201 7 2.4Ca_(2.7)K_(0.3)Co_(3.9)Nb_(0.1)O₉ 208 7.2 2.8Ca_(2.7)K_(0.3)Co_(3.9)Ta_(0.1)O₉ 198 6.8 3Ca_(2.7)Li_(0.3)Co_(3.8)Ti_(0.2)O₉ 207 5.9 1.9

TABLE 9 Ca_(2.7)Li_(0.3)Co_(3.8)V_(0.2)O₉ 198 8.1 2.6Ca_(2.7)Li_(0.3)Co_(3.8)Cr_(0.2)O₉ 199 7.2 2.5Ca_(2.7)Li_(0.3)Co_(3.8)Mn_(0.2)O₉ 210 6.4 3Ca_(2.7)Li_(0.3)Co_(3.8)Fe_(0.2)O₉ 202 5.9 1.9Ca_(2.7)Li_(0.3)Co_(3.8)Ni_(0.2)O₉ 204 6 2Ca_(2.7)Li_(0.3)Co_(3.8)Cu_(0.2)O₉ 197 5.9 2.2 Ca₂₇Li_(0.3)Co_(3.9)Ag_(0.1)O₉ 205 7.2 2.3Ca_(2.7)Li_(0.3)Co_(3.9)Mo_(0.1)O₉ 201 8.1 1.9Ca_(2.7)Li_(0.3)Co_(3.9)W_(0.1)O₉ 196 6.9 3.1Ca_(2.7)Li_(0.3)Co_(3.9)Nb_(0.1)O₉ 202 5.7 2.6Ca_(2.7)Li_(0.3)Co_(3.9)Ta_(0.1)O₉ 203 6.2 2.7Ca_(2.7)Ti_(0.3)Co_(3.8)Ti_(0.2)O₉ 198 8 1.9Ca_(2.7)Ti_(0.3)Co_(3.8)V_(0.2)O₉ 199 7.9 3Ca_(2.7)Ti_(0.3)Co_(3.8)Cr_(0.2)O₉ 201 6.9 2.1Ca_(2.7)Ti_(0.3)Co_(3.8)Mn_(0.2)O₉ 207 5.9 2.2Ca_(2.7)Ti_(0.3)Co_(3.8)Fe_(0.2)O₉ 190 7.8 2.6Ca_(2.7)Ti_(0.3)Co_(3.8)Ni_(0.2)O₉ 198 6.3 2.7Ca_(2.7)Ti_(0.3)Co_(3.8)Cu_(0.2)O₉ 199 6.5 2.5Ca_(2.7)Ti_(0.3)Co_(3.9)Ag_(0.1)O₉ 201 6.4 1.9Ca_(2.7)Ti_(0.3)Co_(3.9)Mo_(0.1)O₉ 200 5.8 2.9Ca_(2.7)Ti_(0.3)Co_(3.9)W_(0.1)O₉ 206 7.2 2.4Ca_(2.7)Ti_(0.3)Co_(3.9)Nb_(0.1)O₉ 205 8.2 2.6Ca_(2.7)Ti_(0.3)Co_(3.9)Ta_(0.1)O₉ 198 7.1 2.7Ca_(2.7)V_(0.3)Co_(3.8)Ti_(0.2)O₉ 196 6.9 3Ca_(2.7)V_(0.3)Co_(3.8)V_(0.2)O₉ 202 7 2.7Ca_(2.7)V_(0.3)Co_(3.8)Cr_(0.2)O₉ 203 7.2 2.7Ca_(2.7)V_(0.3)Co_(3.8)Mn_(0.2)O₉ 208 6.8 2.8Ca_(2.7)V_(0.3)Co_(3.8)Fe_(0.2)O₉ 198 7.2 2.2Ca_(2.7)V_(0.3)Co_(3.8)Ni_(0.2)O₉ 199 5.9 2.5Ca_(2.7)V_(0.3)Co_(3.8)Cu_(0.2)O₉ 201 8.1 2.7Ca_(2.7)V_(0.3)Co_(3.9)Ag_(0.1)O₉ 207 7.2 2.6Ca_(2.7)V_(0.3)Co_(3.9)Mo_(0.1)O₉ 190 6.4 2Ca_(2.7)V_(0.3)Co_(3.9)W_(0.1)O₉ 198 5.9 1.9Ca_(2.7)V_(0.3)Co_(3.9)Nb_(0.1)O₉ 199 6 2.3Ca_(2.7)V_(0.3)Co_(3.9)Ta_(0.1)O₉ 201 5.9 2.5

TABLE 10 Ca_(2.7)Cr_(0.3)Co_(3.8)Ti_(0.2)O₉ 206 8.1 2.5Ca_(2.7)Cr_(0.3)Co_(3.8)V_(0.2)O₉ 207 6.9 2.6Ca_(2.7)Cr_(0.3)Co_(3.8)Cr_(0.2)O₉ 198 5.7 2.4Ca_(2.7)Cr_(0.3)Co_(3.8)Mn_(0.2)O₉ 199 6.2 2.3Ca_(2.7)Cr_(0.3)Co_(3.8)Fe_(0.2)O₉ 210 6.8 2.2Ca_(2.7)Cr_(0.3)Co_(3.8)Ni_(0.2)O₉ 202 8 2.2Ca_(2.7)Cr_(0.3)Co_(3.8)Cu_(0.2)O₉ 204 7.9 2.4Ca_(2.7)Cr_(0.3)Co_(3.9)Ag_(0.1)O₉ 197 6.9 2.6Ca_(2.7)Cr_(0.3)Co_(3.9)Mo_(0.1)O₉ 205 5.9 2.5Ca_(2.7)Cr_(0.3)Co_(3.9)W_(0.1)O₉ 201 7.8 3Ca_(2.7)Cr_(0.3)Co_(3.9)Nb_(0.1)O₉ 196 6.3 2.6Ca_(2.7)Cr_(0.3)Co_(3.9)Ta_(0.1)O₉ 202 6.5 2.9Ca_(2.7)Mn_(0.3)Co_(3.8)Ti_(0.2)O₉ 208 8.2 2.2Ca_(2.7)Mn_(0.3)Co_(3.8)V_(0.2)O₉ 198 7.5 2.6Ca_(2.7)Mn_(0.3)Co_(3.8)Cr_(0.2)O₉ 199 6.9 2.5Ca_(2.7)Mn_(0.3)Co_(3.8)Mn_(0.2)O₉ 201 8.1 3Ca_(2.7)Mn_(0.3)Co_(3.8)Fe_(0.2)O₉ 207 7.6 1.9Ca_(2.7)Mn_(0.3)Co_(3.8)Ni_(0.2)O₉ 190 5.9 2Ca_(2.7)Mn_(0.3)Co_(3.8)Cu_(0.2)O₉ 198 5.8 2.2Ca_(2.7)Mn_(0.3)Co_(3.9)Ag_(0.1)O₉ 199 7.2 2.3Ca_(2.7)Mn_(0.3)Co_(3.9)Mo_(0.1)O₉ 201 8.2 1.9Ca_(2.7)Mn_(0.3)Co_(3.9)W_(0.1)O₉ 200 7.1 3.1Ca_(2.7)Mn_(0.3)Co_(3.9)Nb_(0.1)O₉ 206 6.5 2.6Ca_(2.7)Mn_(0.3)Co_(3.9)Ta_(0.1)O₉ 205 6.9 2.7Ca_(2.7)Fe_(0.3)Co_(3.8)Ti_(0.2)O₉ 201 7.2 1.9Ca_(2.7)Fe_(0.3)Co_(3.8)V_(0.2)O₉ 196 6.8 3Ca_(2.7)Fe_(0.3)Co_(3.8)Cr_(0.2)O₉ 202 6.4 2.1Ca_(2.7)Fe_(0.3)Co_(3.8)Mn_(0.2)O₉ 203 8.2 2.2Ca_(2.7)Fe_(0.3)Co_(3.8)Fe_(0.2)O₉ 205 7.5 2.6Ca_(2.7)Fe_(0.3)Co_(3.8)Ni_(0.2)O₉ 198 6.9 2.7Ca_(2.7)Fe_(0.3)Co_(3.8)Cu_(0.2)O₉ 195 8.1 2.5Ca_(2.7)Fe_(0.3)Co_(3.9)Ag_(0.1)O₉ 200 7.6 1.9Ca_(2.7)Fe_(0.3)Co_(3.9)Mo_(0.1)O₉ 205 5.9 2.9Ca_(2.7)Fe_(0.3)Co_(3.9)W_(0.1)O₉ 198 5.8 2.4

TABLE 11 Ca_(2.7)Fe_(0.3)Co_(3.9)Nb_(0.1)O₉ 199 7.2 2.6Ca_(2.7)Fe_(0.3)Co_(3.9)Ta_(0.1)O₉ 210 8.2 2.7Ca_(2.7)Ni_(0.3)Co_(3.8)Ti_(0.2)O₉ 204 6.5 3Ca_(2.7)Ni_(0.3)Co_(3.8)V_(0.2)O₉ 197 6.9 2.7Ca_(2.7)Ni_(0.3)Co_(3.8)Cr_(0.2)O₉ 205 7 2.7Ca_(2.7)Ni_(0.3)Co_(3.8)Mn_(0.2)O₉ 201 7.2 2.8Ca_(2.7)Ni_(0.3)Co_(3.8)Fe_(0.2)O₉ 196 6.8 2.2Ca_(2.7)Ni_(0.3)Co_(3.8)Ni_(0.2)O₉ 202 4.2 2.5Ca_(2.7)Ni_(0.3)Co_(3.8)Cu_(0.2)O₉ 203 6 2.7Ca_(2.7)Ni_(0.3)Co_(3.9)Ag_(0.1)O₉ 208 7.2 2.6Ca_(2.7)Ni_(0.3)Co_(3.9)Mo_(0.1)O₉ 198 6.8 2Ca_(2.7)Ni_(0.3)Co_(3.9)W_(0.1)O₉ 199 5.7 1.9Ca_(2.7)Ni_(0.3)Co_(3.9)Nb_(0.1)O₉ 199 6.2 2.3Ca_(2.7)Ni_(0.3)Co_(3.9)Ta_(0.1)O₉ 210 6.8 2.5Ca_(2.7)Cu_(0.3)Co_(3.8)Ti_(0.2)O₉ 204 7.9 2.5Ca_(2.7)Cu_(0.3)Co_(3.8)V_(0.2)O₉ 197 6.9 2.6Ca_(2.7)Cu_(0.3)Co_(3.8)Cr_(0.2)O₉ 205 5.9 2.4Ca_(2.7)Cu_(0.3)Co_(3.8)Mn_(0.2)O₉ 201 7.8 2.3Ca_(2.7)Cu_(0.3)Co_(3.8)Fe_(0.2)O₉ 196 6.3 2.2Ca_(2.7)Cu_(0.3)Co_(3.8)Ni_(0.2)O₉ 202 6.5 2.7Ca_(2.7)Cu_(0.3)Co_(3.8)Cu_(0.2)O₉ 203 6.4 2.6Ca_(2.7)Cu_(0.3)Co_(3.9)Ag_(0.1)O₉ 208 8.2 2Ca_(2.7)Cu_(0.3)Co_(3.9)Mo_(0.1)O₉ 198 7.5 1.9Ca_(2.7)Cu_(0.3)Co_(3.9)W_(0.1)O₉ 199 6.9 2.3Ca_(2.7)Cu_(0.3)Co_(3.9)Nb_(0.1)O₉ 201 8.1 2.5Ca_(2.7)Cu_(0.3)Co_(3.9)Ta_(0.1)O₉ 207 7.6 2.7Ca_(2.7)Zn_(0.3)Co_(3.8)Ti_(0.2)O₉ 198 5.8 1.9Ca_(2.7)Zn_(0.3)Co_(3.8)V_(0.2)O₉ 199 7.2 2.3Ca_(2.7)Zn_(0.3)Co_(3.8)Cr_(0.2)O₉ 201 8.2 2.5Ca_(2.7)Zn_(0.3)Co_(3.8)Mn_(0.2)O₉ 200 7.1 2.7Ca_(2.7)Zn_(0.3)Co_(3.8)Fe_(0.2)O₉ 206 6.5 2.5Ca_(2.7)Zn_(0.3)Co_(3.8)Ni_(0.2)O₉ 205 6.9 2.6Ca_(2.7)Zn_(0.3)Co_(3.8)Cu_(0.2)O₉ 198 7 2.4Ca_(2.7)Zn_(0.3)Co_(3.9)Ag_(0.1)O₉ 201 8.2 2.3

TABLE 12 Ca_(2.7)Zn_(0.3)Co_(3.9)Mo_(0.1)O₉ 201 7.5 2.2Ca_(2.7)Zn_(0.3)Co_(3.9)W_(0.1)O₉ 196 6.9 2.2Ca_(2.7)Zn_(0.3)Co_(3.9)Nb_(0.1)O₉ 202 8.1 2.4Ca_(2.7)Zn_(0.3)Co_(3.9)Ta_(0.1)O₉ 203 7.6 2.6Ca_(2.7)Pb_(0.3)Co_(3.8)Ti_(0.2)O₉ 198 5.8 3Ca_(2.7)Pb_(0.3)Co_(3.8)V_(0.2)O₉ 199 7.2 2.6Ca_(2.7)Pb_(0.3)Co_(3.8)Cr_(0.2)O₉ 201 8.2 2.9Ca_(2.7)Pb_(0.3)Co_(3.8)Mn_(0.2)O₉ 207 7.1 1.9Ca_(2.7)Pb_(0.3)Co_(3.8)Fe_(0.2)O₉ 190 6.5 2.2Ca_(2.7)Pb_(0.3)Co_(3.8)Ni_(0.2)O₉ 198 6.9 2.6Ca_(2.7)Pb_(0.3)Co_(3.8)Cu_(0.2)O₉ 199 7.2 2.5Ca_(2.7)Pb_(0.3)Co_(3.9)Ag_(0.1)O₉ 201 8.1 3Ca_(2.7)Pb_(0.3)Co_(3.9)Mo_(0.1)O₉ 200 6.9 1.9Ca_(2.7)Pb_(0.3)Co_(3.9)W_(0.1)O₉ 206 5.7 2Ca_(2.7)Pb_(0.3)Co_(3.9)Nb_(0.1)O₉ 207 6.2 2.2Ca_(2.7)Pb_(0.3)Co_(3.9)Ta_(0.1)O₉ 198 6.8 2.3Ca_(2.7)Sr_(0.3)Co_(3.8)Ti_(0.2)O₉ 210 7.9 3.1Ca_(2.7)Sr_(0.3)Co_(3.8)V_(0.2)O₉ 202 6.9 2.6Ca_(2.7)Sr_(0.3)Co_(3.8)Cr_(0.2)O₉ 204 5.9 2.7Ca_(2.7)Sr_(0.3)Co_(3.8)Mn_(0.2)O₉ 197 7.8 2.4Ca_(2.7)Sr_(0.3)Co_(3.8)Fe_(0.2)O₉ 205 6.3 1.9Ca_(2.7)Sr_(0.3)Co_(3.8)Ni_(0.2)O₉ 201 6.5 3Ca_(2.7)Sr_(0.3)Co_(3.8)Cu_(0.2)O₉ 196 6.4 2.1Ca_(2.7)Sr_(0.3)Co_(3.9)Ag_(0.1)O₉ 202 8.2 2.2Ca_(2.7)Sr_(0.3)Co_(3.9)Mo_(0.1)O₉ 203 7.5 2.6Ca_(2.7)Sr_(0.3)Co_(3.9)W_(0.1)O₉ 208 6.9 2.7Ca_(2.7)Sr_(0.3)Co_(3.9)Nb_(0.1)O₉ 198 8.1 2.5Ca_(2.7)Sr_(0.3)Co_(3.9)Ta_(0.1)O₉ 199 7.6 1.9Ca_(2.7)Ba_(0.3)Co_(3.8)Ti_(0.2)O₉ 201 5.9 2.9Ca_(2.7)Ba_(0.3)Co_(3.8)V_(0.2)O₉ 207 5.8 2.4Ca_(2.7)Ba_(0.3)Co_(3.8)Cr_(0.2)O₉ 190 7.2 2.6Ca_(2.7)Ba_(0.3)Co_(3.8)Mn_(0.2)O₉ 198 8.2 2.7Ca_(2.7)Ba_(0.3)Co_(3.8)Fe_(0.2)O₉ 199 7.1 1.9Ca_(2.7)Ba_(0.3)Co_(3.8)Ni_(0.2)O₉ 201 6.5 3Ca_(2.7)Ba_(0.3)Co_(3.8)Cu_(0.2)O₉ 200 6.9 2.7

TABLE 13 Ca_(2.7)Ba_(0.3)Co_(3.9)Ag_(0.1)O₉ 206 7 2.7Ca_(2.7)Ba_(0.3)Co_(3.9)Mo_(0.1)O₉ 205 7.2 2.8Ca_(2.7)Ba_(0.3)Co_(3.9)W_(0.1)O₉ 198 6.8 2.2Ca_(2.7)Ba_(0.3)Co_(3.9)Nb_(0.1)O₉ 201 6.4 2.5Ca_(2.7)Ba_(0.3)Co_(3.9)Ta_(0.1)O₉ 196 8.2 2.7Ca_(2.7)Al_(0.3)Co_(3.8)Ti_(0.2)O₉ 203 6.9 2Ca_(2.7)Al_(0.3)Co_(3.8)V_(0.2)O₉ 205 8.1 1.9Ca_(2.7)Al_(0.3)Co_(3.8)Cr_(0.2)O₉ 198 7.6 2.3Ca_(2.7)Al_(0.3)Co_(3.8)Mn_(0.2)O₉ 195 5.9 2.5Ca_(2.7)Al_(0.3)Co_(3.8)Fe_(0.2)O₉ 200 5.8 2.7Ca_(2.7)Al_(0.3)Co_(3.8)Ni_(0.2)O₉ 205 7.2 2.5Ca_(2.7)Al_(0.3)Co_(3.8)Cu_(0.2)O₉ 198 8.2 2.6Ca_(2.7)Al_(0.3)Co_(3.9)Ag_(0.1)O₉ 199 7.1 2.5Ca_(2.7)Al_(0.3)Co_(3.9)Mo_(0.1)O₉ 210 6.5 2.7Ca_(2.7)Al_(0.3)Co_(3.9)W_(0.1)O₉ 202 6.9 2.5Ca_(2.7)Al_(0.3)Co_(3.9)Nb_(0.1)O₉ 204 7 2.6Ca_(2.7)Al_(0.3)Co_(3.9)Ta_(0.1)O₉ 197 7.2 2.4Ca_(2.7)Bi_(0.3)Co_(3.8)Ti_(0.2)O₉ 201 4.2 2.2Ca_(2.7)Bi_(0.3)Co_(3.8)V_(0.2)O₉ 196 6 2.2Ca_(2.7)Bi_(0.3)Co_(3.8)Cr_(0.2)O₉ 202 7.2 2.4Ca_(2.7)Bi_(0.3)Co_(3.8)Mn_(0.2)O₉ 203 6.8 2.6Ca_(2.7)Bi_(0.3)Co_(3.8)Fe_(0.2)O₉ 208 5.7 2.5Ca_(2.7)Bii_(0.3)Co_(3.8)Ni_(0.2)O₉ 198 6.2 3Ca_(2.7)Bi_(0.3)Co_(3.8)Cu_(0.2)O₉ 199 6.8 2.6Ca_(2.7)Bi_(0.3)Co_(3.9)Ag_(0.1)O₉ 201 8 2.9Ca_(2.7)Bi_(0.3)Co_(3.9)Mo_(0.1)O₉ 207 7.9 1.9Ca_(2.7)Bi_(0.3)Co_(3.9)W_(0.1)O₉ 190 6.9 2.2Ca_(2.7)Bi_(0.3)Co_(3.9)Nb_(0.1)O₉ 198 5.9 2.6Ca_(2.7)Bi_(0.3)Co_(3.9)Ta_(0.1)O₉ 199 7.8 2.5Ca_(2.7)Y_(0.3)Co_(3.8)Ti_(0.2)O₉ 200 6.9 1.9Ca_(2.7)Y_(0.3)Co_(3.8)V_(0.2)O₉ 206 7.2 2Ca_(2.7)Y_(0.3)Co_(3.8)Cr_(0.2)O₉ 205 8.1 2.2Ca_(2.7)Y_(0.3)Co_(3.8)Mn_(0.2)O₉ 198 6.9 2.3Ca_(2.7)Y_(0.3)Co_(3.8)Fe_(0.2)O₉ 201 5.7 1.9

TABLE 14 Ca_(2.7)Y_(0.3)Co_(3.8)Ni_(0.2)O₉ 196 6.2 3.1Ca_(2.7)Y_(0.3)Co_(3.8)Cu_(0.2)O₉ 202 6.8 2.6Ca_(2.7)Y_(0.3)Co_(3.9)Ag_(0.1)O₉ 203 8 2.7Ca_(2.7)Y_(0.3)Co_(3.9)Mo_(0.1)O₉ 205 7.9 2.4Ca_(2.7)Y_(0.3)Co_(3.9)W_(0.1)O₉ 198 6.9 1.9Ca_(2.7)Y_(0.3)Co_(3.9)Nb_(0.1)O₉ 195 5.9 3Ca_(2.7)Y_(0.3)Co_(3.9)Ta_(0.1)O₉ 200 7.8 2.1Ca_(2.7)La_(0.3)Co_(3.8)Ti_(0.2)O₉ 198 6.5 2.6Ca_(2.7)La_(0.3)Co_(3.8)V_(0.2)O₉ 199 6.4 2.7Ca_(2.7)La_(0.3)Co_(3.8)Cr_(0.2)O₉ 210 8.2 2.5Ca_(2.7)La_(0.3)Co_(3.8)Mn_(0.2)O₉ 202 7.5 1.9Ca_(2.7)La_(0.3)Co_(3.8)Fe_(0.2)O₉ 204 6.9 2.6Ca_(2.7)La_(0.3)Co_(3.8)Ni_(0.2)O₉ 197 8.1 2.4Ca_(2.7)La_(0.3)Co_(3.8)Cu_(0.2)O₉ 205 7.6 2.3Ca_(2.7)La_(0.3)Co_(3.9)Ag_(0.1)O₉ 201 5.9 2.2Ca_(2.7)La_(0.3)Co_(3.9)Mo_(0.1)O₉ 196 5.8 2.7Ca_(2.7)La_(0.3)Co_(3.9)W_(0.1)O₉ 202 7.2 2.6Ca_(2.7)La_(0.3)Co_(3.9)Nb_(0.1)O₉ 203 8.2 2Ca_(2.7)La_(0.3)Co_(3.9)Ta_(0.1)O₉ 208 7.1 1.9Ca_(2.7)Ce_(0.3)Co_(3.8)Ti_(0.2)O₉ 199 6.9 2.5Ca_(2.7)Ce_(0.3)Co_(3.8)V_(0.2)O₉ 199 7 2.7Ca_(2.7)Ce_(0.3)Co_(3.8)Cr_(0.2)O₉ 210 7.2 2.5Ca_(2.7)Ce_(0.3)Co_(3.8)Mn_(0.2)O₉ 202 6.8 1.9Ca_(2.7)Ce_(0.3)Co_(3.8)Fe_(0.2)O₉ 204 6.4 2.3Ca_(2.7)Ce_(0.3)Co_(3.8)Ni_(0.2)O₉ 197 8.2 2.5Ca_(2.7)Ce_(0.3)Co_(3.8)Cu_(0.2)O₉ 205 7.5 2.7Ca_(2.7)Ce_(0.3)Co_(3.9)Ag_(0.1)O₉ 201 6.9 2.5Ca_(2.7)Ce_(0.3)Co_(3.9)Mo_(0.1)O₉ 196 8.1 2.6Ca_(2.7)Ce_(0.3)Co_(3.9)W_(0.1)O₉ 202 7.6 2.4Ca_(2.7)Ce_(0.3)Co_(3.9)Nb_(0.1)O₉ 203 5.9 2.3Ca_(2.7)Ce_(0.3)Co_(3.9)Ta_(0.1)O₉ 208 5.8 2.2Ca_(2.7)Pr_(0.3)Co_(3.8)Ti_(0.2)O₉ 199 8.2 2.4Ca_(2.7)Pr_(0.3)Co_(3.8)V_(0.2)O₉ 201 7.1 2.3Ca_(2.7)Pr_(0.3)Co_(3.8)Cr_(0.2)O₉ 207 6.5 2.2

TABLE 15 Ca_(2.7)Pr_(0.3)Co_(3.8)Mn_(0.2)O₉ 190 6.9 2.2Ca_(2.7)Pr_(0.3)Co_(3.8)Fe_(0.2)O₉ 198 7 2.4Ca_(2.7)Pr_(0.3)Co_(3.8)Ni_(0.2)O₉ 199 6.9 2.6Ca_(2.7)Pr_(0.3)Co_(3.8)Cu_(0.2)O₉ 201 8.1 2.5Ca_(2.7)Pr_(0.3)Co_(3.9)Ag_(0.1)O₉ 207 7.6 3Ca_(2.7)Pr_(0.3)Co_(3.9)Mo_(0.1)O₉ 190 5.9 2.6Ca_(2.7)Pr_(0.3)Co_(3.9)W_(0.1)O₉ 198 5.8 2.9Ca_(2.7)Pr_(0.3)Co_(3.9)Nb_(0.1)O₉ 199 7.2 1.9Ca_(2.7)Pr_(0.3)Co_(3.9)Ta_(0.1)O₉ 201 8.2 2.2Ca_(2.7)Nd_(0.3)Co_(3.8)Ti_(0.2)O₉ 206 6.5 2.5Ca_(2.7)Nd_(0.3)Co_(3.8)V_(0.2)O₉ 205 6.9 3Ca_(2.7)Nd_(0.3)Co_(3.8)Cr_(0.2)O₉ 198 7 1.9Ca_(2.7)Nd_(0.3)Co_(3.8)Mn_(0.2)O₉ 195 7.2 2Ca_(2.7)Nd_(0.3)Co_(3.8)Fe_(0.2)O₉ 200 6.8 2.2Ca_(2.7)Nd_(0.3)Co_(3.8)Ni_(0.2)O₉ 203 6.4 2.3Ca_(2.7)Nd_(0.3)Co_(3.8)Cu_(0.2)O₉ 201 8.2 1.9Ca_(2.7)Nd_(0.3)Co_(3.9)Ag_(0.1)O₉ 208 7.5 3.1Ca_(2.7)Nd_(0.3)Co_(3.9)Mo_(0.1)O₉ 198 6.9 2.6Ca_(2.7)Nd_(0.3)Co_(3.9)W_(0.1)O₉ 199 8.1 2.7Ca_(2.7)Nd_(0.3)Co_(3.9)Nb_(0.1)O₉ 207 7.6 2.4Ca_(2.7)Nd_(0.3)Co_(3.9)Ta_(0.1)O₉ 198 5.9 1.9Ca_(2.7)Sm_(0.3)Co_(3.8)Ti_(0.2)O₉ 200 7.2 2.1Ca_(2.7)Sm_(0.3)Co_(3.8)V_(0.2)O₉ 198 8.2 2.2Ca_(2.7)Sm_(0.3)Co_(3.8)Cr_(0.2)O₉ 205 7.1 2.6Ca_(2.7)Sm_(0.3)Co_(3.8)Mn_(0.2)O₉ 196 6.5 2.7Ca_(2.7)Sm_(0.3)Co_(3.8)Fe_(0.2)O₉ 205 6.9 2.5Ca_(2.7)Sm_(0.3)Co_(3.8)Ni_(0.2)O₉ 198 6.8 1.9Ca_(2.7)Sm_(0.3)Co_(3.8)Cu_(0.2)O₉ 195 7.2 2.6Ca_(2.7)Sm_(0.3)Co_(3.9)Ag_(0.1)O₉ 200 5.9 2.4Ca_(2.7)Sm_(0.3)Co_(3.9)Mo_(0.1)O₉ 205 8.1 2.3Ca_(2.7)Sm_(0.3)Co_(3.9)W_(0.1)O₉ 198 7.2 2.2Ca_(2.7)Sm_(0.3)Co_(3.9)Nb_(0.1)O₉ 199 6.4 2.7Ca_(2.7)Sm_(0.3)Co_(3.9)Ta_(0.1)O₉ 210 5.9 2.6Ca_(2.7)Eu_(0.3)Co_(3.8)Ti_(0.2)O₉ 207 5.9 1.9

TABLE 16 Ca_(2.7)Eu_(0.3)Co_(3.8)V_(0.2)O₉ 198 7.2 2.3Ca_(2.7)Eu_(0.3)Co_(3.8)Cr_(0.2)O₉ 196 8.1 2.5Ca_(2.7)Eu_(0.3)Co_(3.8)Mn_(0.2)O₉ 200 6.9 2.6Ca_(2.7)Eu_(0.3)Co_(3.8)Fe_(0.2)O₉ 198 5.7 2.9Ca_(2.7)Eu_(0.3)Co_(3.8)Ni_(0.2)O₉ 205 6.2 1.9Ca_(2.7)Eu_(0.3)Co_(3.8)Cu_(0.2)O₉ 196 6.8 2.2Ca_(2.7)Eu_(0.3)Co_(3.9)Ag_(0.1)O₉ 205 8 2.6Ca_(2.7)Eu_(0.3)Co_(3.9)Mo_(0.1)O₉ 198 7.9 2.5Ca_(2.7)Eu_(0.3)Co_(3.9)W_(0.1)O₉ 198 6.9 3Ca_(2.7)Eu_(0.3)Co_(3.9)Nb_(0.1)O₉ 195 5.9 1.9Ca_(2.7)Eu_(0.3)Co_(3.9)Ta_(0.1)O₉ 200 7.8 2Ca_(2.7)Gd_(0.3)Co_(3.8)Ti_(0.2)O₉ 201 6.5 2.3Ca_(2.7)Gd_(0.3)Co_(3.8)V_(0.2)O₉ 208 6.4 1.9Ca_(2.7)Gd_(0.3)Co_(3.8)Cr_(0.2)O₉ 198 8.2 3.1Ca_(2.7)Gd_(0.3)Co_(3.8)Mn_(0.2)O₉ 199 7.5 2.6Ca_(2.7)Gd_(0.3)Co_(3.8)Fe_(0.2)O₉ 207 6.9 2.7Ca_(2.7)Gd_(0.3)Co_(3.8)Ni_(0.2)O₉ 198 8.1 2.4Ca_(2.7)Gd_(0.3)Co_(3.8)Cu_(0.2)O₉ 199 7.6 1.9Ca_(2.7)Gd_(0.3)Co_(3.9)Ag_(0.1)O₉ 210 5.9 3Ca_(2.7)Gd_(0.3)Co_(3.9)Mo_(0.1)O₉ 202 5.8 2.1Ca_(2.7)Gd_(0.3)Co_(3.9)W_(0.1)O₉ 204 7.2 2.2Ca_(2.7)Gd_(0.3)Co_(3.9)Nb_(0.1)O₉ 197 8.2 2.4Ca_(2.7)Gd_(0.3)Co_(3.9)Ta_(0.1)O₉ 205 7.1 2.6Ca_(2.7)Dy_(0.3)Co_(3.8)Ti_(0.2)O₉ 196 6.9 3Ca_(2.7)Dy_(0.3)Co_(3.8)V_(0.2)O₉ 202 7 2.6Ca_(2.7)Dy_(0.3)Co_(3.8)Cr_(0.2)O₉ 203 7.2 2.9Ca_(2.7)Dy_(0.3)Co_(3.8)Mn_(0.2)O₉ 208 6.8 1.9Ca_(2.7)Dy_(0.3)Co_(3.8)Fe_(0.2)O₉ 198 7.2 2.2Ca_(2.7)Dy_(0.3)Co_(3.8)Ni_(0.2)O₉ 199 5.9 2.6Ca_(2.7)Dy_(0.3)Co_(3.8)Cu_(0.2)O₉ 201 6.2 2.5Ca_(2.7)Dy_(0.3)Co_(3.9)Ag_(0.1)O₉ 207 6.8 3Ca_(2.7)Dy_(0.3)Co_(3.9)Mo_(0.1)O₉ 190 8 1.9Ca_(2.7)Dy_(0.3)Co_(3.9)W_(0.1)O₉ 198 7.9 2Ca_(2.7)Dy_(0.3)Co_(3.9)Nb_(0.1)O₉ 199 6.9 2.2Ca_(2.7)Dy_(0.3)Co_(3.9)Ta_(0.1)O₉ 201 5.9 2.3

TABLE 17 Ca_(2.7)Ho_(0.3)Co_(3.8)Ti_(0.2)O₉ 206 7.8 1.9Ca_(2.7)Ho_(0.3)Co_(3.8)V_(0.2)O₉ 205 6.3 3.1Ca_(2.7)Ho_(0.3)Co_(3.8)Cr_(0.2)O₉ 198 6.5 2.6Ca_(2.7)Ho_(0.3)Co_(3.8)Mn_(0.2)O₉ 201 6.4 2.7Ca_(2.7)Ho_(0.3)Co_(3.8)Fe_(0.2)O₉ 196 8.2 2.4Ca_(2.7)Ho_(0.3)Co_(3.8)Ni_(0.2)O₉ 202 7.5 1.9Ca_(2.7)Ho_(0.3)Co_(3.8)Cu_(0.2)O₉ 203 6.9 3Ca_(2.7)Ho_(0.3)Co_(3.9)Ag_(0.1)O₉ 208 8.1 2.1Ca_(2.7)Ho_(0.3)Co_(3.9)Mo_(0.1)O₉ 198 7.6 2.2Ca_(2.7)Ho_(0.3)Co_(3.9)W_(0.1)O₉ 199 5.9 2.6Ca_(2.7)Ho_(0.3)Co_(3.9)Nb_(0.1)O₉ 201 5.8 2.7Ca_(2.7)Ho_(0.3)Co_(3.9)Ta_(0.1)O₉ 207 7 2.5Ca_(2.7)Er_(0.3)Co_(3.8)Ti_(0.2)O₉ 205 6.8 2.6Ca_(2.7)Er_(0.3)Co_(3.8)V_(0.2)O₉ 198 6.4 2.4Ca_(2.7)Er_(0.3)Co_(3.8)Cr_(0.2)O₉ 195 8.2 2.3Ca_(2.7)Er_(0.3)Co_(3.8)Mn_(0.2)O₉ 200 7.5 2.2Ca_(2.7)Er_(0.3)Co_(3.8)Fe_(0.2)O₉ 205 6.9 2.7Ca_(2.7)Er_(0.3)Co_(3.8)Ni_(0.2)O₉ 198 8.1 2.6Ca_(2.7)Er_(0.3)Co_(3.8)Cu_(0.2)O₉ 199 7.6 2Ca_(2.7)Er_(0.3)Co_(3.9)Ag_(0.1)O₉ 210 5.9 1.9Ca_(2.7)Er_(0.3)Co_(3.9)Mo_(0.1)O₉ 202 5.8 2.3Ca_(2.7)Er_(0.3)Co_(3.9)W_(0.1)O₉ 198 7.2 2.6Ca_(2.7)Er_(0.3)Co_(3.9)Nb_(0.1)O₉ 201 8.2 2.9Ca_(2.7)Er_(0.3)Co_(3.9)Ta_(0.1)O₉ 196 7.1 1.9Ca_(2.7)Yb_(0.3)Co_(3.8)Ti_(0.2)O₉ 203 6.9 2.6Ca_(2.7)Yb_(0.3)Co_(3.8)V_(0.2)O₉ 208 7 2.5Ca_(2.7)Yb_(0.3)Co_(3.8)Cr_(0.2)O₉ 198 7.2 3Ca_(2.7)Yb_(0.3)Co_(3.8)Mn_(0.2)O₉ 199 6.8 1.9Ca_(2.7)Yb_(0.3)Co_(3.8)Fe_(0.2)O₉ 201 4.2 2Ca_(2.7)Yb_(0.3)Co_(3.8)Ni_(0.2)O₉ 207 6 2.6Ca_(2.7)Yb_(0.3)Co_(3.8)Cu_(0.2)O₉ 203 7.2 2.7Ca_(2.7)Yb_(0.3)Co_(3.9)Ag_(0.1)O₉ 205 6.8 2.4Ca_(2.7)Yb_(0.3)Co_(3.9)Mo_(0.1)O₉ 198 5.7 1.9Ca_(2.7)Yb_(0.3)Co_(3.9)W_(0.1)O₉ 201 6.2 3Ca_(2.7)Yb_(0.3)Co_(3.9)Nb_(0.1)O₉ 196 6.8 2.1Ca_(2.7)Yb_(0.3)Co_(3.9)Ta_(0.1)O₉ 202 8.0 2.2

TABLE 18 Seebeck Electrical Thermal Coefficient Resistivity ConductivityComposition μV/K mΩcm W/mK Bi_(f)Pb_(g)M¹ _(h)Co_(i)M_(j) ²O_(k) (700°C.) (700° C.) (700° C.) Bi₂Sr₂Co₂O₉ 210 6.2 1.2 Bi₂Sr_(1.8)Na_(0.2)Co₂O₉205 5.9 1 Bi₂Sr_(1.8)K_(0.2)Co₂O₉ 195 6.7 1.3 Bi₂Sr_(1.8)Li_(0.2)Co₂O₉208 8 1 Bi₂Sr_(1.8)Ti_(0.2)Co₂O₉ 220 8.1 0.9 Bi₂Sr_(1.8)V_(0.2)Co₂O₉ 1988 1.1 Bi₂Sr_(1.8)Cr_(0.2)Co₂O₉ 201 7.8 1 Bi₂Sr_(1.8)Mn_(0.2)Co₂O₉ 2077.2 1.2 Bi₂Sr_(1.8)Fe_(0.2)Co₂O₉ 190 9 1.1 Bi₂Sr_(1.8)Ni_(0.2)Co₂O₉ 1987.8 0.9 Bi₂Sr_(1.8)Cu_(0.2)Co₂O₉ 199 7.5 0.8 Bi₂Sr_(1.8)Zn_(0.2)Co₂O₉201 8.6 1 Bi₂Sr_(1.8)Pb_(0.2)Co₂O₉ 200 8.2 1.3 Bi₂Sr_(1.8)Ca_(0.2)Co₂O₉206 7.9 1.2 Bi₂Sr_(1.8)Ba_(0.2)Co₂O₉ 205 6.9 0.7Bi₂Sr_(1.8)Al_(0.2)Co₂O₉ 198 8.1 1.3 Bi₂Sr_(1.8)Y_(0.2)Co₂O₉ 201 9 1.4Bi₂Sr_(1.8)La_(0.2)Co₂O₉ 196 8.2 1.1 Bi₂Sr_(1.8)Ce_(0.2)Co₂O₉ 202 7.9 1Bi₂Sr_(1.8)Pr_(0.2)Co₂O₉ 203 8.6 1.3 Bi₂Sr_(1.8)Nd_(0.2)Co₂O₉ 205 9.10.9 Bi₂Sr_(1.8)Sm_(0.2)Co₂O₉ 198 6.9 1.1 Bi₂Sr_(1.8)Eu_(0.2)Co₂O₉ 1957.4 1.4 Bi₂Sr_(1.8)Gd_(0.2)Co₂O₉ 200 7.8 1.2 Bi₂Sr_(1.8)Dy_(0.2)Co₂O₉205 7.7 0.9 Bi₂Sr_(1.8)Ho_(0.2)Co₂O₉ 198 8 1.1 Bi₂Sr_(1.8)Er_(0.2)Co₂O₉199 8.2 1.2 Bi₂Sr_(1.8)Yb_(0.2)Co₂O₉ 210 7.9 0.9 Bi₂Pb_(0.2)Sr₂Co₂O₉ 2048.4 1.2 Bi₂Pb_(0.2)Sr_(1.8)Na_(0.2)Co₂O₉ 197 8.6 1.4Bi₂Pb_(0.2)Sr_(1.8)K_(0.2)Co₂O₉ 190 7.8 0.8Bi₂Pb_(0.2)Sr_(1.8)Li_(0.2)Co₂O₉ 198 9 1.3Bi₂Pb_(0.2)Sr_(1.8)Ti_(0.2)Co₂O₉ 199 8.2 1.2Bi₂Pb_(0.2)Sr_(1.8)V_(0.2)Co₂O₉ 201 8.3 1.1

TABLE 19 Bi₂Pb_(0.2)Sr_(1.8)Cr_(0.2)Co₂O₉ 207 8.6 0.8Bi₂Pb_(0.2)Sr_(1.8)Mn_(0.2)Co₂O₉ 190 8.7 1.3Bi₂Pb_(0.2)Sr_(1.8)Fe_(0.2)Co₂O₉ 198 8.3 1.4Bi₂Pb_(0.2)Sr_(1.8)Ni_(0.2)Co₂O₉ 199 9 1.1Bi₂Pb_(0.2)Sr_(1.8)Cu_(0.2)Co₂O₉ 201 7.9 1Bi₂Pb_(0.2)Sr_(1.8)Zn_(0.2)Co₂O₉ 210 8.1 1.3Bi₂Pb_(0.2)Sr_(1.8)Pb_(0.2)Co₂O₉ 206 8 0.9Bi₂Pb_(0.2)Sr_(1.8)Ca_(0.2)Co₂O₉ 205 7.8 1.1Bi₂Pb_(0.2)Sr_(1.8)Ba_(0.2)Co₂O₉ 198 7.2 1.4Bi₂Pb_(0.2)Sr_(1.8)Al_(0.2)Co₂O₉ 195 9 1.2Bi₂Pb_(0.2)Sr_(1.8)Y_(0.2)Co₂O₉ 200 7.8 0.9Bi₂Pb_(0.2)Sr_(1.8)La_(0.2)Co₂O₉ 203 7.5 1.1Bi₂Pb_(0.2)Sr_(1.8)Ce_(0.2)Co₂O₉ 201 8.6 1.2Bi₂Pb_(0.2)Sr_(1.8)Pr_(0.2)Co₂O₉ 208 8.2 0.9Bi₂Pb_(0.2)Sr_(1.8)Nd_(0.2)Co₂O₉ 198 7.9 1.1Bi₂Pb_(0.2)Sr_(1.8)Sm_(0.2)Co₂O₉ 199 6.9 1.2Bi₂Pb_(0.2)Sr_(1.8)Eu_(0.2)Co₂O₉ 207 8.1 1.4Bi₂Pb_(0.2)Sr_(1.8)Gd_(0.2)Co₂O₉ 198 9 0.8Bi₂Pb_(0.2)Sr_(1.8)Dy_(0.2)Co₂O₉ 201 8.2 1.3Bi₂Pb_(0.2)Sr_(1.8)Ho_(0.2)Co₂O₉ 200 7.9 1.2Bi₂Pb_(0.2)Sr_(1.8)Er_(0.2)Co₂O₉ 198 8.6 1.1Bi₂Pb_(0.2)Sr_(1.8)Yb_(0.2)Co₂O₉ 205 9.1 1 Bi₂Ca₂Co₂O₉ 205 7.4 1.1Bi₂Ca_(1.8)Na_(0.2)Co₂O₉ 198 7.8 0.9 Bi₂Ca_(1.8)K_(0.2)Co₂O₉ 195 7.7 0.8Bi₂Ca_(1.8)Li_(0.2)Co₂O₉ 200 8 1 Bi₂Ca_(1.8)Ti_(0.2)Co₂O₉ 205 8.2 1.3Bi₂Ca_(1.8)V_(0.2)Co₂O₉ 198 7.9 1.2 Bi₂Ca_(1.8)Cr_(0.2)Co₂O₉ 199 9.1 0.7Bi₂Ca_(1.8)Mn_(0.2)Co₂O₉ 210 8.4 1.3 Bi₂Ca_(1.8)Fe_(0.2)Co₂O₉ 200 8.61.4 Bi₂Ca_(1.8)Ni_(0.2)Co₂O₉ 207 8.2 1.1 Bi₂Ca_(1.8)Cu_(0.2)Co₂O₉ 1987.9 1 Bi₂Ca_(1.8)Zn_(0.2)Co₂O₉ 196 8.6 1.3 Bi₂Ca_(1.8)Pb_(0.2)Co₂O₉ 2009.1 0.9 Bi₂Ca_(1.8)Sr_(0.2)Co₂O₉ 198 6.9 1.1

TABLE 20 Bi₂Ca_(1.8)Ba_(0.2)Co₂O₉ 205 7.4 1.4 Bi₂Ca_(1.8)Al_(0.2)Co₂O₉196 7.8 1.2 Bi₂Ca_(1.8)Y_(0.2)Co₂O₉ 205 7.7 0.9 Bi₂Ca_(1.8)La_(0.2)Co₂O₉198 8 1.1 Bi₂Ca_(1.8)Ce_(0.2)Co₂O₉ 198 8.2 1.2 Bi₂Ca_(1.8)Pr_(0.2)Co₂O₉195 7.9 0.9 Bi₂Ca_(1.8)Nd_(0.2)Co₂O₉ 200 9.1 1.1Bi₂Ca_(1.8)Sm_(0.2)Co₂O₉ 210 8.4 1.2 Bi₂Ca_(1.8)Eu_(0.2)Co₂O₉ 201 8.61.4 Bi₂Ca_(1.8)Gd_(0.2)Co₂O₉ 208 7.8 0.8 Bi₂Ca_(1.8)Dy_(0.2)Co₂O₉ 198 91.3 Bi₂Ca_(1.8)Ho_(0.2)Co₂O₉ 199 8.2 1.2 Bi₂Ca_(1.8)Er_(0.2)Co₂O₉ 2078.3 1.1 Bi₂Ca_(1.8)Yb_(0.2)Co₂O₉ 198 8.6 0.8 Bi₂Pb_(0.2)Ca₂Co₂O₉ 210 8.31.4 Bi₂Pb_(0.2)Ca_(1.8)Na_(0.2)Co₂O₉ 202 9 1.1Bi₂Pb_(0.2)Ca_(1.8)K_(0.2)Co₂O₉ 204 7.9 1Bi₂Pb_(0.2)Ca_(1.8)Li_(0.2)Co₂O₉ 197 8.1 1.3Bi₂Pb_(0.2)Ca_(1.8)Ti_(0.2)Co₂O₉ 205 8 0.9Bi₂Pb_(0.2)Ca_(1.8)V_(0.2)Co₂O₉ 208 7.8 1.1Bi₂Pb_(0.2)Ca_(1.8)Cr_(0.2)Co₂O₉ 196 7.2 1.4Bi₂Pb_(0.2)Ca_(1.8)Mn_(0.2)Co₂O₉ 202 9 1.2Bi₂Pb_(0.2)Ca_(1.8)Fe_(0.2)Co₂O₉ 203 7.8 0.9Bi₂Pb_(0.2)Ca_(1.8)Ni_(0.2)Co₂O₉ 208 7.5 1.1Bi₂Pb_(0.2)Ca_(1.8)Cu_(0.2)Co₂O₉ 198 8.6 1.2Bi₂Pb_(0.2)Ca_(1.8)Zn_(0.2)Co₂O₉ 199 8.2 0.9Bi₂Pb_(0.2)Ca_(1.8)Pb_(0.2)Co₂O₉ 201 7.9 1.1Bi₂Pb_(0.2)Ca_(1.8)Sr_(0.2)Co₂O₉ 207 6.9 1.2Bi₂Pb_(0.2)Ca_(1.8)Ba_(0.2)Co₂O₉ 190 8.1 1Bi₂Pb_(0.2)Ca_(1.8)Al_(0.2)Co₂O₉ 198 9 1.3Bi₂Pb_(0.2)Ca_(1.8)Y_(0.2)Co₂O₉ 199 8.2 1Bi₂Pb_(0.2)Ca_(1.8)La_(0.2)Co₂O₉ 201 7.9 0.9Bi₂Pb_(0.2)Ca_(1.8)Ce_(0.2)Co₂O₉ 190 8.6 1.1Bi₂Pb_(0.2)Ca_(1.8)Pr_(0.2)Co₂O₉ 198 9.1 1Bi₂Pb_(0.2)Ca_(1.8)Nd_(0.2)Co₂O₉ 199 8 1.2Bi₂Pb_(0.2)Ca_(1.8)Sm_(0.2)Co₂O₉ 201 8.2 1.1

TABLE 21 Bi₂Pb_(0.2)Ca_(1.8)Eu_(0.2)Co₂O₉ 200 7.9 0.9Bi₂Pb_(0.2)Ca_(1.8)Gd_(0.2)Co₂O₉ 206 9.1 0.8Bi₂Pb_(0.2)Ca_(1.8)Dy_(0.2)Co₂O₉ 205 8.4 1Bi₂Pb_(0.2)Ca_(1.8)Ho_(0.2)Co₂O₉ 198 8.6 1.3Bi₂Pb_(0.2)Ca_(1.8)Er_(0.2)Co₂O₉ 201 7.8 1.2Bi₂Pb_(0.2)Ca_(1.8)Yb_(0.2)Co₂O₉ 196 9 0.7 Bi₂Ba₂Co₂O₉ 203 8.3 1.4Bi₂Ba_(1.8)Na_(0.2)Co₂O₉ 205 8.6 1.1 Bi₂Ba_(1.8)K_(0.2)Co₂O₉ 198 8.7 1Bi₂Ba_(1.8)Li_(0.2)Co₂O₉ 195 8.3 1.3 Bi₂Ba_(1.8)Ti_(0.2)Co₂O₉ 200 9 0.9Bi₂Ba_(1.8)V_(0.2)Co₂O₉ 205 7.9 1.1 Bi₂Ba_(1.8)Cr_(0.2)Co₂O₉ 198 8.1 1.4Bi₂Ba_(1.8)Mn_(0.2)Co₂O₉ 199 8 1.2 Bi₂Ba_(1.8)Fe_(0.2)Co₂O₉ 210 7.8 0.9Bi₂Ba_(1.8)Ni_(0.2)Co₂O₉ 202 7.2 1.1 Bi₂Ba_(1.8)Cu_(0.2)Co₂O₉ 204 9 1.2Bi₂Ba_(1.8)Zn_(0.2)Co₂O₉ 197 7.8 0.9 Bi₂Ba_(1.8)Pb_(0.2)Co₂O₉ 190 7.51.1 Bi₂Ba_(1.8)Ca_(0.2)Co₂O₉ 198 8.6 1.2 Bi₂Ba_(1.8)Sr_(0.2)Co₂O₉ 1998.2 1.4 Bi₂Ba_(1.8)Al_(0.2)Co₂O₉ 201 7.9 0.8 Bi₂Ba_(1.8)Y_(0.2)Co₂O₉ 2076.9 1.3 Bi₂Ba_(1.8)La_(0.2)Co₂O₉ 190 8.1 1.2 Bi₂Ba_(1.8)Ce_(0.2)Co₂O₉198 9 1.1 Bi₂Ba_(1.8)Pr_(0.2)Co₂O₉ 199 8.2 0.8 Bi₂Ba_(1.8)Nd_(0.2)Co₂O₉201 7.9 1.3 Bi₂Ba_(1.8)Sm_(0.2)Co₂O₉ 210 8.6 1.4Bi₂Ba_(1.8)Eu_(0.2)Co₂O₉ 206 9.1 1.1 Bi₂Ba_(1.8)Gd_(0.2)Co₂O₉ 205 6.9 1Bi₂Ba_(1.8)Dy_(0.2)Co₂O₉ 198 7.4 1.3 Bi₂Ba_(1.8)Ho_(0.2)Co₂O₉ 195 7.80.9 Bi₂Ba_(1.8)Er_(0.2)Co₂O₉ 200 7.7 1.1 Bi₂Ba_(1.8)Yb_(0.2)Co₂O₉ 2038.0 1.4 Bi₂Pb_(0.2)Ba₂Co₂O₉ 208 7.9 0.9

TABLE 22 Bi₂Pb_(0.2)Ba_(1.8)Na_(0.2)Co₂O₉ 198 8.0 1.1Bi₂Pb_(0.2)Ba_(1.8)K_(0.2)Co₂O₉ 199 8.1 1.2Bi₂Pb_(0.2)Ba_(1.8)Li_(0.2)Co₂O₉ 200 8 0.9Bi₂Pb_(0.2)Ba_(1.8)Ti_(0.2)Co₂O₉ 206 7.8 1.1Bi₂Pb_(0.2)Ba_(1.8)V_(0.2)Co₂O₉ 205 7.2 1.2Bi₂Pb_(0.2)Ba_(1.8)Cr_(0.2)Co₂O₉ 198 9 1.4Bi₂Pb_(0.2)Ba_(1.8)Mn_(0.2)Co₂O₉ 201 7.8 0.8Bi₂Pb_(0.2)Ba_(1.8)Fe_(0.2)Co₂O₉ 196 7.5 1.3Bi₂Pb_(0.2)Ba_(1.8)Ni_(0.2)Co₂O₉ 202 8.6 1.2Bi₂Pb_(0.2)Ba_(1.8)Cu_(0.2)Co₂O₉ 203 8.2 1.1Bi₂Pb_(0.2)Ba_(1.8)Zn_(0.2)Co₂O₉ 205 7.9 0.8Bi₂Pb_(0.2)Ba_(1.8)Pb_(0.2)Co₂O₉ 198 6.9 1Bi₂Pb_(0.2)Ba_(1.8)Ca_(0.2)Co₂O₉ 195 8.1 1.3Bi₂Pb_(0.2)Ba_(1.8)Sr_(0.2)Co₂O₉ 200 9 1.2Bi₂Pb_(0.2)Ba_(1.8)Al_(0.2)Co₂O₉ 205 8.2 0.7Bi₂Pb_(0.2)Ba_(1.8)Y_(0.2)Co₂O₉ 198 7.9 1.3Bi₂Pb_(0.2)Ba_(1.8)La_(0.2)Co₂O₉ 199 8.6 1.4Bi₂Pb_(0.2)Ba_(1.8)Ce_(0.2)Co₂O₉ 210 9.1 1.1Bi₂Pb_(0.2)Ba_(1.8)Pr_(0.2)Co₂O₉ 202 6.9 1Bi₂Pb_(0.2)Ba_(1.8)Nd_(0.2)Co₂O₉ 207 7.4 1.3Bi₂Pb_(0.2)Ba_(1.8)Sm_(0.2)Co₂O₉ 198 7.8 0.9Bi₂Pb_(0.2)Ba_(1.8)Eu_(0.2)Co₂O₉ 199 7.7 1.1Bi₂Pb_(0.2)Ba_(1.8)Gd_(0.2)Co₂O₉ 210 8 1.4Bi₂Pb_(0.2)Ba_(1.8)Dy_(0.2)Co₂O₉ 202 8.2 1.2Bi₂Pb_(0.2)Ba_(1.8)Ho_(0.2)Co₂O₉ 204 7.9 0.9Bi₂Pb_(0.2)Ba_(1.8)Er_(0.2)Co₂O₉ 197 9.1 1.1Bi₂Pb_(0.2)Ba_(1.8)Yb_(0.2)Co₂O₉ 205 8.4 1.2 Bi₂Sr₂Co_(1.9)Ti_(0.1)O₉196 7.8 1.1 Bi₂Sr_(1.8)Na_(0.2)Co_(1.9)Ti_(0.1)O₉ 202 9 1.2Bi₂Sr_(1.8)K_(0.2)Co_(1.9)Ti_(0.1)O₉ 203 8.2 1.4Bi₂Sr_(1.8)Li_(0.2)Co_(1.9)Ti_(0.1)O₉ 208 8.3 0.8Bi₂Sr_(1.8)Ti_(0.2)Co_(1.9)Ti_(0.1)O₉ 198 8.6 1.3Bi₂Sr_(1.8)V_(0.2)Co_(1.9)Ti_(0.1)O₉ 199 8.7 1.2Bi₂Sr_(1.8)Cr_(0.2)Co_(1.9)Ti_(0.1)O₉ 201 8.3 1.1Bi₂Sr_(1.8)Mn_(0.2)Co_(1.9)Ti_(0.1)O₉ 207 9 0.8Bi₂Sr_(1.8)Fe_(0.2)Co_(1.9)Ti_(0.1)O₉ 190 7.9 1.3

TABLE 23 Bi₂Sr_(1.8)Ni_(0.2)Co_(1.9)Ti_(0.1)O₉ 198 8.1 1.4Bi₂Sr_(1.8)Cu_(0.2)Co_(1.9)Ti_(0.1)O₉ 199 8 1.1Bi₂Sr_(1.8)Zn_(0.2)Co_(1.9)Ti_(0.1)O₉ 201 7.8 1Bi₂Sr_(1.8)Pb_(0.2)Co_(1.9)Ti_(0.1)O₉ 190 7.2 1.3Bi₂Sr_(1.8)Ca_(0.2)Co_(1.9)Ti_(0.1)O₉ 198 9 0.9Bi₂Sr_(1.8)Ba_(0.2)Co_(1.9)Ti_(0.1)O₉ 199 7.8 1.1Bi₂Sr_(1.8)Al_(0.2)Co_(1.9)Ti_(0.1)O₉ 201 7.5 1.4Bi₂Sr_(1.8)Y_(0.2)Co_(1.9)Ti_(0.1)O₉ 200 8.6 1.2Bi₂Sr_(1.8)La_(0.2)Co_(1.9)Ti_(0.1)O₉ 206 8.2 0.9Bi₂Sr_(1.8)Ce_(0.2)Co_(1.9)Ti_(0.1)O₉ 205 7.9 1.1Bi₂Sr_(1.8)Pr_(0.2)Co_(1.9)Ti_(0.1)O₉ 198 6.9 1.2Bi₂Sr_(1.8)Nd_(0.2)Co_(1.9)Ti_(0.1)O₉ 201 8.1 0.9Bi₂Sr_(1.8)Sm_(0.2)Co_(1.9)Ti_(0.1)O₉ 196 9 1.1Bi₂Sr_(1.8)Eu_(0.2)Co_(1.9)Ti_(0.1)O₉ 202 8.2 1.2Bi₂Sr_(1.8)Gd_(0.2)Co_(1.9)Ti_(0.1)O₉ 203 7.9 1.4Bi₂Sr_(1.8)Dy_(0.2)Co_(1.9)Ti_(0.1)O₉ 205 8.6 0.8Bi₂Sr_(1.8)Ho_(0.2)Co_(1.9)Ti_(0.1)O₉ 198 9.1 1.3Bi₂Sr_(1.8)Er_(0.2)Co_(1.9)Ti_(0.1)O₉ 195 6.9 1.2Bi₂Sr_(1.8)Yb_(0.2)Co_(1.9)Ti_(0.1)O₉ 200 7.4 1.1Bi₂Pb_(0.2)Sr₂Co_(1.9)Ti_(0.1)O₉ 198 7.7 1.2Bi₂Pb_(0.2)Sr_(1.8)Na_(0.2)Co_(1.9)Ti_(0.1)O₉ 199 8 0.9Bi₂Pb_(0.2)Sr_(1.8)K_(0.2)Co_(1.9)Ti_(0.1)O₉ 210 8.2 1.1Bi₂Pb_(0.2)Sr_(1.8)Li_(0.2)Co_(1.9)Ti_(0.1)O₉ 202 7.9 1.2Bi₂Pb_(0.2)Sr_(1.8)Ti_(0.2)Co_(1.9)Ti_(0.1)O₉ 204 9.1 0.9Bi₂Pb_(0.2)Sr_(1.8)V_(0.2)Co_(1.9)Ti_(0.1)O₉ 197 8.4 1.1Bi₂Pb_(0.2)Sr_(1.8)Cr_(0.2)Co_(1.9)Ti_(0.1)O₉ 190 8.6 1.2Bi₂Pb_(0.2)Sr_(1.8)Mn_(0.2)Co_(1.9)Ti_(0.1)O₉ 198 8.2 1.4Bi₂Pb_(0.2)Sr_(1.8)Fe_(0.2)Co_(1.9)Ti_(0.1)O₉ 199 7.9 0.8Bi₂Pb_(0.2)Sr_(1.8)Ni_(0.2)Co_(1.9)Ti_(0.1)O₉ 201 8.6 1.3Bi₂Pb_(0.2)Sr_(1.8)Cu_(0.2)Co_(1.9)Ti_(0.1)O₉ 207 9.1 1.2Bi₂Pb_(0.2)Sr_(1.8)Zn_(0.2)Co_(1.9)Ti_(0.1)O₉ 190 6.9 1.1Bi₂Pb_(0.2)Sr_(1.8)Pb_(0.2)Co_(1.9)Ti_(0.1)O₉ 198 7.4 0.8Bi₂Pb_(0.2)Sr_(1.8)Ca_(0.2)Co_(1.9)Ti_(0.1)O₉ 199 7.8 1.3Bi₂Pb_(0.2)Sr_(1.8)Ba_(0.2)Co_(1.9)Ti_(0.1)O₉ 201 7.7 1.4Bi₂Pb_(0.2)Sr_(1.8)Al_(0.2)Co_(1.9)Ti_(0.1)O₉ 210 8 1.1Bi₂Pb_(0.2)Sr_(1.8)Y_(0.2)Co_(1.9)Ti_(0.1)O₉ 206 8.2 1

TABLE 24 Bi₂Pb_(0.2)Sr_(1.8)La_(0.2)Co_(1.9)Ti_(0.1)O₉ 205 7.9 1.3Bi₂Pb_(0.2)Sr_(1.8)Ce_(0.2)Co_(1.9)Ti_(0.1)O₉ 198 9.1 0.9Bi₂Pb_(0.2)Sr_(1.8)Pr_(0.2)Co_(1.9)Ti_(0.1)O₉ 195 8.4 1.1Bi₂Pb_(0.2)Sr_(1.8)Nd_(0.2)Co_(1.9)Ti_(0.1)O₉ 200 8.6 1.4Bi₂Pb_(0.2)Sr_(1.8)Sm_(0.2)Co_(1.9)Ti_(0.1)O₉ 203 7.8 1.2Bi₂Pb_(0.2)Sr_(1.8)Eu_(0.2)Co_(1.9)Ti_(0.1)O₉ 201 9 0.9Bi₂Pb_(0.2)Sr_(1.8)Gd_(0.2)Co_(1.9)Ti_(0.1)O₉ 208 8.2 1.1Bi₂Pb_(0.2)Sr_(1.8)Dy_(0.2)Co_(1.9)Ti_(0.1)O₉ 201 8.3 1.2Bi₂Pb_(0.2)Sr_(1.8)Ho_(0.2)Co_(1.9)Ti_(0.1)O₉ 190 8.6 0.9Bi₂Pb_(0.2)Sr_(1.8)Er_(0.2)Co_(1.9)Ti_(0.1)O₉ 198 8.7 1.1Bi₂Pb_(0.2)Sr_(1.8)Yb_(0.2)Co_(1.9)Ti_(0.1)O₉ 199 8.3 1.2Bi₂Ca₂Co_(1.9)Ti_(0.1)O₉ 200 7.9 1.3Bi₂Ca_(1.8)Na_(0.2)Co_(1.9)Ti_(0.1)O₉ 206 8.1 1Bi₂Ca_(1.8)K_(0.2)Co_(1.9)Ti_(0.1)O₉ 205 8 0.9Bi₂Ca_(1.8)Li_(0.2)Co_(1.9)Ti_(0.1)O₉ 198 7.8 1.1Bi₂Ca_(1.8)Ti_(0.2)Co_(1.9)Ti_(0.1)O₉ 201 7.2 1Bi₂Ca_(1.8)V_(0.2)Co_(1.9)Ti_(0.1)O₉ 196 9 1.2Bi₂Ca_(1.8)Cr_(0.2)Co_(1.9)Ti_(0.1)O₉ 202 7.8 1.1Bi₂Ca_(1.8)Mn_(0.2)Co_(1.9)Ti_(0.1)O₉ 203 7.5 0.9Bi₂Ca_(1.8)Fe_(0.2)Co_(1.9)Ti_(0.1)O₉ 205 8.6 0.8Bi₂Ca_(1.8)Ni_(0.2)Co_(1.9)Ti_(0.1)O₉ 198 8.2 1Bi₂Ca_(1.8)Cu_(0.2)Co_(1.9)Ti_(0.1)O₉ 195 7.9 1.3Bi₂Ca_(1.8)Zn_(0.2)Co_(1.9)Ti_(0.1)O₉ 200 6.9 1.2Bi₂Ca_(1.8)Pb_(0.2)Co_(1.9)Ti_(0.1)O₉ 205 8.1 0.7Bi₂Ca_(1.8)Sr_(0.2)Co_(1.9)Ti_(0.1)O₉ 198 7.5 1.3Bi₂Ca_(1.8)Ba_(0.2)Co_(1.9)Ti_(0.1)O₉ 199 8.6 1.4Bi₂Ca_(1.8)Al_(0.2)Co_(1.9)Ti_(0.1)O₉ 210 8.2 1.1Bi₂Ca_(1.8)Y_(0.2)Co_(1.9)Ti_(0.1)O₉ 202 7.9 1Bi₂Ca_(1.8)La_(0.2)Co_(1.9)Ti_(0.1)O₉ 204 6.9 1.3Bi₂Ca_(1.8)Ce_(0.2)Co_(1.9)Ti_(0.1)O₉ 197 8.1 0.9Bi₂Ca_(1.8)Pr_(0.2)Co_(1.9)Ti_(0.1)O₉ 190 9 1.1Bi₂Ca_(1.8)Nd_(0.2)Co_(1.9)Ti_(0.1)O₉ 198 8.2 1.4Bi₂Ca_(1.8)Sm_(0.2)Co_(1.9)Ti_(0.1)O₉ 199 7.9 1.2Bi₂Ca_(1.8)Eu_(0.2)Co_(1.9)Ti_(0.1)O₉ 201 8.6 0.9Bi₂Ca_(1.8)Gd_(0.2)Co_(1.9)Ti_(0.1)O₉ 207 9.1 1.1Bi₂Ca_(1.8)Dy_(0.2)Co_(1.9)Ti_(0.1)O₉ 190 6.9 1.2

TABLE 25 Bi₂Ca_(1.8)Ho_(0.2)Co_(1.9)Ti_(0.1)O₉ 198 7.4 0.9Bi₂Ca_(1.8)Er_(0.2)Co_(1.9)Ti_(0.1)O₉ 199 7.8 1.1Bi₂Ca_(1.8)Yb_(0.2)Co_(1.9)Ti_(0.1)O₉ 201 7.7 1.2Bi₂Pb_(0.2)Ca₂Co_(1.9)Ti_(0.1)O₉ 206 8.2 0.8Bi₂Pb_(0.2)Ca_(1.8)Na_(0.2)Co_(1.9)Ti_(0.1)O₉ 205 7.9 1.3Bi₂Pb_(0.2)Ca_(1.8)K_(0.2)Co_(1.9)Ti_(0.1)O₉ 198 8 1.2Bi₂Pb_(0.2)Ca_(1.8)Li_(0.2)Co_(1.9)Ti_(0.1)O₉ 195 8.1 1.1Bi₂Pb_(0.2)Ca_(1.8)Ti_(0.2)Co_(1.9)Ti_(0.1)O₉ 200 7.5 0.8Bi₂Pb_(0.2)Ca_(1.8)V_(0.2)Co_(1.9)Ti_(0.1)O₉ 203 8.6 1.3Bi₂Pb_(0.2)Ca_(1.8)Cr_(0.2)Co_(1.9)Ti_(0.1)O₉ 201 8.2 1.4Bi₂Pb_(0.2)Ca_(1.8)Mn_(0.2)Co_(1.9)Ti_(0.1)O₉ 208 7.9 1.1Bi₂Pb_(0.2)Ca_(1.8)Fe_(0.2)Co_(1.9)Ti_(0.1)O₉ 198 6.9 1Bi₂Pb_(0.2)Ca_(1.8)Ni_(0.2)Co_(1.9)Ti_(0.1)O₉ 199 8.1 1.3Bi₂Pb_(0.2)Ca_(1.8)Cu_(0.2)Co_(1.9)Ti_(0.1)O₉ 200 9 0.9Bi₂Pb_(0.2)Ca_(1.8)Zn_(0.2)Co_(1.9)Ti_(0.1)O₉ 206 8.2 1.1Bi₂Pb_(0.2)Ca_(1.8)Pb_(0.2)Co_(1.9)Ti_(0.1)O₉ 205 7.9 1.4Bi₂Pb_(0.2)Ca_(1.8)Sr_(0.2)Co_(1.9)Ti_(0.1)O₉ 198 8.6 1.2Bi₂Pb_(0.2)Ca_(1.8)Ba_(0.2)Co_(1.9)Ti_(0.1)O₉ 201 9.1 0.9Bi₂Pb_(0.2)Ca_(1.8)Al_(0.2)Co_(1.9)Ti_(0.1)O₉ 196 6.9 1.1Bi₂Pb_(0.2)Ca_(1.8)Y_(0.2)Co_(1.9)Ti_(0.1)O₉ 202 7.4 1.2Bi₂Pb_(0.2)Ca_(1.8)La_(0.2)Co_(1.9)Ti_(0.1)O₉ 203 7.8 0.9Bi₂Pb_(0.2)Ca_(1.8)Ce_(0.2)Co_(1.9)Ti_(0.1)O₉ 202 7.7 1.1Bi₂Pb_(0.2)Ca_(1.8)Pr_(0.2)Co_(1.9)Ti_(0.1)O₉ 203 8 1.2Bi₂Pb_(0.2)Ca_(1.8)Nd_(0.2)Co_(1.9)Ti_(0.1)O₉ 208 8.2 1.4Bi₂Pb_(0.2)Ca_(1.8)Sm_(0.2)Co_(1.9)Ti_(0.1)O₉ 198 7.9 0.8Bi₂Pb_(0.2)Ca_(1.8)Eu_(0.2)Co_(1.9)Ti_(0.1)O₉ 199 9.1 1.3Bi₂Pb_(0.2)Ca_(1.8)Gd_(0.2)Co_(1.9)Ti_(0.1)O₉ 201 8.4 1.2Bi₂Pb_(0.2)Ca_(1.8)Dy_(0.2)Co_(1.9)Ti_(0.1)O₉ 207 8.6 1.1Bi₂Pb_(0.2)Ca_(1.8)Ho_(0.2)Co_(1.9)Ti_(0.1)O₉ 190 7.8 0.8Bi₂Pb_(0.2)Ca_(1.8)Er_(0.2)Co_(1.9)Ti_(0.1)O₉ 198 9 0.7Bi₂Pb_(0.2)Ca_(1.8)Yb_(0.2)Co_(1.9)Ti_(0.1)O₉ 199 8.2 1.3Bi₂Ba₂Co_(1.9)Ti_(0.1)O₉ 190 8.6 1.1Bi₂Ba_(1.8)Na_(0.2)Co_(1.9)Ti_(0.1)O₉ 198 8.7 1Bi₂Ba_(1.8)K_(0.2)Co_(1.9)Ti_(0.1)O₉ 199 8.3 1.3Bi₂Ba_(1.8)Li_(0.2)Co_(1.9)Ti_(0.1)O₉ 201 9 0.9

TABLE 26 Bi₂Ba_(1.8)Ti_(0.2)Co_(1.9)Ti_(0.1)O₉ 200 7.9 1.1Bi₂Ba_(1.8)V_(0.2)Co_(1.9)Ti_(0.1)O₉ 206 8.1 1.4Bi₂Ba_(1.8)Cr_(0.2)Co_(1.9)Ti_(0.1)O₉ 205 8 1.2Bi₂Ba_(1.8)Mn_(0.2)Co_(1.9)Ti_(0.1)O₉ 198 7.8 0.9Bi₂Ba_(1.8)Fe_(0.2)Co_(1.9)Ti_(0.1)O₉ 201 7.2 1.1Bi₂Ba_(1.8)Ni_(0.2)Co_(1.9)Ti_(0.1)O₉ 196 9 1.2Bi₂Ba_(1.8)Cu_(0.2)Co_(1.9)Ti_(0.1)O₉ 202 7.8 0.9Bi₂Ba_(1.8)Zn_(0.2)Co_(1.9)Ti_(0.1)O₉ 203 7.5 1.1Bi₂Ba_(1.8)Pb_(0.2)Co_(1.9)Ti_(0.1)O₉ 205 8.6 1.2Bi₂Ba_(1.8)Ca_(0.2)Co_(1.9)Ti_(0.1)O₉ 198 8.2 1.4Bi₂Ba_(1.8)Sr_(0.2)Co_(1.9)Ti_(0.1)O₉ 195 7.9 0.8Bi₂Ba_(1.8)Al_(0.2)Co_(1.9)Ti_(0.1)O₉ 200 6.9 1.3Bi₂Ba_(1.8)Y_(0.2)Co_(1.9)Ti_(0.1)O₉ 205 8.1 1.2Bi₂Ba_(1.8)La_(0.2)Co_(1.9)Ti_(0.1)O₉ 198 9 1.1Bi₂Ba_(1.8)Ce_(0.2)Co_(1.9)Ti_(0.1)O₉ 199 8.2 0.8Bi₂Ba_(1.8)Pr_(0.2)Co_(1.9)Ti_(0.1)O₉ 210 7.9 1.3Bi₂Ba_(1.8)Nd_(0.2)Co_(1.9)Ti_(0.1)O₉ 202 8.6 1.4Bi₂Ba_(1.8)Sm_(0.2)Co_(1.9)Ti_(0.1)O₉ 204 9.1 1.1Bi₂Ba_(1.8)Eu_(0.2)Co_(1.9)Ti_(0.1)O₉ 197 6.9 1Bi₂Ba_(1.8)Gd_(0.2)Co_(1.9)Ti_(0.1)O₉ 190 7.4 1.3Bi₂Ba_(1.8)Dy_(0.2)Co_(1.9)Ti_(0.1)O₉ 198 7.8 0.9Bi₂Ba_(1.8)Ho_(0.2)Co_(1.9)Ti_(0.1)O₉ 199 7.7 1.1Bi₂Ba_(1.8)Er_(0.2)Co_(1.9)Ti_(0.1)O₉ 201 8 1.4Bi₂Ba_(1.8)Yb_(0.2)Co_(1.9)Ti_(0.1)O₉ 207 8.2 1.2Bi₂Pb_(0.2)Ba₂Co_(1.9)Ti_(0.1)O₉ 198 9.1 1.1Bi₂Pb_(0.2)Ba_(1.8)Na_(0.2)Co_(1.9)Ti_(0.1)O₉ 199 8.4 1.2Bi₂Pb_(0.2)Ba_(1.8)K_(0.2)Co_(1.9)Ti_(0.1)O₉ 201 8.6 0.9Bi₂Pb_(0.2)Ba_(1.8)Li_(0.2)Co_(1.9)Ti_(0.1)O₉ 210 8.2 1.1Bi₂Pb_(0.2)Ba_(1.8)Ti_(0.2)Co_(1.9)Ti_(0.1)O₉ 206 7.9 1.2Bi₂Pb_(0.2)Ba_(1.8)V_(0.2)Co_(1.9)Ti_(0.1)O₉ 205 8.6 1.4Bi₂Pb_(0.2)Ba_(1.8)Cr_(0.2)Co_(1.9)Ti_(0.1)O₉ 198 9.1 0.8Bi₂Pb_(0.2)Ba_(1.8)Mn_(0.2)Co_(1.9)Ti_(0.1)O₉ 195 6.9 1.3Bi₂Pb_(0.2)Ba_(1.8)Fe_(0.2)Co_(1.9)Ti_(0.1)O₉ 200 7.4 1.2Bi₂Pb_(0.2)Ba_(1.8)Ni_(0.2)Co_(1.9)Ti_(0.1)O₉ 203 7.8 1.1Bi₂Pb_(0.2)Ba_(1.8)Cu_(0.2)Co_(1.9)Ti_(0.1)O₉ 201 7.7 1.4Bi₂Pb_(0.2)Ba_(1.8)Zn_(0.2)Co_(1.9)Ti_(0.1)O₉ 208 8 1.2

TABLE 27 Bi₂Pb_(0.2)Ba_(1.8)Pb_(0.2)Co_(1.9)Ti_(0.1)O₉ 205 8.2 0.9Bi₂Pb_(0.2)Ba_(1.8)Ca_(0.2)Co_(1.9)Ti_(0.1)O₉ 198 7.9 1.1Bi₂Pb_(0.2)Ba_(1.8)Sr_(0.2)Co_(1.9)Ti_(0.1)O₉ 201 9.1 1.2Bi₂Pb_(0.2)Ba_(1.8)Al_(0.2)Co_(1.9)Ti_(0.1)O₉ 196 8.4 0.9Bi₂Pb_(0.2)Ba_(1.8)Y_(0.2)Co_(1.9)Ti_(0.1)O₉ 202 8.6 1.1Bi₂Pb_(0.2)Ba_(1.8)La_(0.2)Co_(1.9)Ti_(0.1)O₉ 203 7.8 1.2Bi₂Pb_(0.2)Ba_(1.8)Ce_(0.2)Co_(1.9)Ti_(0.1)O₉ 205 9 1.4Bi₂Pb_(0.2)Ba_(1.8)Pr_(0.2)Co_(1.9)Ti_(0.1)O₉ 198 8.2 0.8Bi₂Pb_(0.2)Ba_(1.8)Nd_(0.2)Co_(1.9)Ti_(0.1)O₉ 195 8.3 1.3Bi₂Pb_(0.2)Ba_(1.8)Sm_(0.2)Co_(1.9)Ti_(0.1)O₉ 200 8.6 1.2Bi₂Pb_(0.2)Ba_(1.8)Eu_(0.2)Co_(1.9)Ti_(0.1)O₉ 205 8.7 1.1Bi₂Pb_(0.2)Ba_(1.8)Gd_(0.2)Co_(1.9)Ti_(0.1)O₉ 198 8.3 0.8Bi₂Pb_(0.2)Ba_(1.8)Dy_(0.2)Co_(1.9)Ti_(0.1)O₉ 199 9 1.3Bi₂Pb_(0.2)Ba_(1.8)Ho_(0.2)Co_(1.9)Ti_(0.1)O₉ 210 7.9 1.4Bi₂Pb_(0.2)Ba_(1.8)Er_(0.2)Co_(1.9)Ti_(0.1)O₉ 202 8.1 1.1Bi₂Pb_(0.2)Ba_(1.8)Yb_(0.2)Co_(1.9)Ti_(0.1)O₉ 204 8 1Bi₂Sr₂Co_(1.9)V_(0.1)O₉ 190 7.2 0.9 Bi₂Sr_(1.8)Na_(0.2)Co_(1.9)V_(0.1)O₉198 9 1.1 Bi₂Sr_(1.8)K_(0.2)Co_(1.9)V_(0.1)O₉ 199 7.8 1.4Bi₂Sr_(1.8)Li_(0.2)Co_(1.9)V_(0.1)O₉ 201 7.5 1.2Bi₂Sr_(1.8)Ti_(0.2)Co_(1.9)V_(0.1)O₉ 207 8.6 0.9Bi₂Sr_(1.8)V_(0.2)Co_(1.9)V_(0.1)O₉ 190 8.2 1.1Bi₂Sr_(1.8)Cr_(0.2)Co_(1.9)V_(0.1)O₉ 198 7.9 1.2Bi₂Sr_(1.8)Mn_(0.2)Co_(1.9)V_(0.1)O₉ 199 6.9 0.9Bi₂Sr_(1.8)Fe_(0.2)Co_(1.9)V_(0.1)O₉ 201 8.1 1.1Bi₂Sr_(1.8)Ni_(0.2)Co_(1.9)V_(0.1)O₉ 210 6.9 1.2Bi₂Sr_(1.8)Cu_(0.2)Co_(1.9)V_(0.1)O₉ 206 7.4 1Bi₂Sr_(1.8)Zn_(0.2)Co_(1.9)V_(0.1)O₉ 205 7.8 1.3Bi₂Sr_(1.8)Pb_(0.2)Co_(1.9)V_(0.1)O₉ 198 7.7 1Bi₂Sr_(1.8)Ca_(0.2)Co_(1.9)V_(0.1)O₉ 195 8 0.9Bi₂Sr_(1.8)Ba_(0.2)Co_(1.9)V_(0.1)O₉ 200 8.2 1.1Bi₂Sr_(1.8)Al_(0.2)Co_(1.9)V_(0.1)O₉ 203 7.9 1Bi₂Sr_(1.8)Y_(0.2)Co_(1.9)V_(0.1)O₉ 201 9.1 1.2Bi₂Sr_(1.8)La_(0.2)Co_(1.9)V_(0.1)O₉ 208 8.4 1.1Bi₂Sr_(1.8)Ce_(0.2)Co_(1.9)V_(0.1)O₉ 201 8.6 0.9Bi₂Sr_(1.8)Pr_(0.2)Co_(1.9)V_(0.1)O₉ 190 8.2 0.8

TABLE 28 Bi₂Sr_(1.8)Nd_(0.2)Co_(1.9)V_(0.1)O₉ 198 7.9 1Bi₂Sr_(1.8)Sm_(0.2)Co_(1.9)V_(0.1)O₉ 199 8.6 1.3Bi₂Sr_(1.8)Eu_(0.2)Co_(1.9)V_(0.1)O₉ 201 9.1 1.2Bi₂Sr_(1.8)Gd_(0.2)Co_(1.9)V_(0.1)O₉ 200 6.9 1.3Bi₂Sr_(1.8)Dy_(0.2)Co_(1.9)V_(0.1)O₉ 206 7.4 0.9Bi₂Sr_(1.8)Ho_(0.2)Co_(1.9)V_(0.1)O₉ 205 7.8 1.1Bi₂Sr_(1.8)Er_(0.2)Co_(1.9)V_(0.1)O₉ 198 7.7 1.4Bi₂Sr_(1.8)Yb_(0.2)Co_(1.9)V_(0.1)O₉ 201 8 1.2Bi₂Pb_(0.2)Sr₂Co_(1.9)V_(0.1)O₉ 202 7.9 1.1Bi₂Pb_(0.2)Sr_(1.8)Na_(0.2)Co_(1.9)V_(0.1)O₉ 203 9.1 1.2Bi₂Pb_(0.2)Sr_(1.8)K_(0.2)Co_(1.9)V_(0.1)O₉ 205 8.4 0.9Bi₂Pb_(0.2)Sr_(1.8)Li_(0.2)Co_(1.9)V_(0.1)O₉ 198 8.6 1.1Bi₂Pb_(0.2)Sr_(1.8)Ti_(0.2)Co_(1.9)V_(0.1)O₉ 195 7.8 1.2Bi₂Pb_(0.2)Sr_(1.8)V_(0.2)Co_(1.9)V_(0.1)O₉ 200 9 1Bi₂Pb_(0.2)Sr_(1.8)Cr_(0.2)Co_(1.9)V_(0.1)O₉ 205 8.2 1.3Bi₂Pb_(0.2)Sr_(1.8)Mn_(0.2)Co_(1.9)V_(0.1)O₉ 198 8.3 1Bi₂Pb_(0.2)Sr_(1.8)Fe_(0.2)Co_(1.9)V_(0.1)O₉ 199 8.6 0.9Bi₂Pb_(0.2)Sr_(1.8)Ni_(0.2)Co_(1.9)V_(0.1)O₉ 210 8.7 1.1Bi₂Pb_(0.2)Sr_(1.8)Cu_(0.2)Co_(1.9)V_(0.1)O₉ 202 8.3 1Bi₂Pb_(0.2)Sr_(1.8)Zn_(0.2)Co_(1.9)V_(0.1)O₉ 204 9 1.2Bi₂Pb_(0.2)Sr_(1.8)Pb_(0.2)Co_(1.9)V_(0.1)O₉ 197 7.9 1.1Bi₂Pb_(0.2)Sr_(1.8)Ca_(0.2)Co_(1.9)V_(0.1)O₉ 190 8.1 0.9Bi₂Pb_(0.2)Sr_(1.8)Ba_(0.2)Co_(1.9)V_(0.1)O₉ 198 8 0.8Bi₂Pb_(0.2)Sr_(1.8)Al_(0.2)Co_(1.9)V_(0.1)O₉ 199 7.8 1Bi₂Pb_(0.2)Sr_(1.8)Y_(0.2)Co_(1.9)V_(0.1)O₉ 201 7.2 1.3Bi₂Pb_(0.2)Sr_(1.8)La_(0.2)Co_(1.9)V_(0.1)O₉ 207 9 1.2Bi₂Pb_(0.2)Sr_(1.8)Ce_(0.2)Co_(1.9)V_(0.1)O₉ 190 7.8 0.7Bi₂Pb_(0.2)Sr_(1.8)Pr_(0.2)Co_(1.9)V_(0.1)O₉ 198 7.5 1.3Bi₂Pb_(0.2)Sr_(1.8)Nd_(0.2)Co_(1.9)V_(0.1)O₉ 199 8.6 1.4Bi₂Pb_(0.2)Sr_(1.8)Sm_(0.2)Co_(1.9)V_(0.1)O₉ 201 8.2 1.1Bi₂Pb_(0.2)Sr_(1.8)Eu_(0.2)Co_(1.9)V_(0.1)O₉ 210 7.9 1Bi₂Pb_(0.2)Sr_(1.8)Gd_(0.2)Co_(1.9)V_(0.1)O₉ 206 6.9 1.3Bi₂Pb_(0.2)Sr_(1.8)Dy_(0.2)Co_(1.9)V_(0.1)O₉ 205 8.1 0.9Bi₂Pb_(0.2)Sr_(1.8)Ho_(0.2)Co_(1.9)V_(0.1)O₉ 198 7.5 1.1Bi₂Pb_(0.2)Sr_(1.8)Er_(0.2)Co_(1.9)V_(0.1)O₉ 195 8.6 1.4Bi₂Pb_(0.2)Sr_(1.8)Yb_(0.2)Co_(1.9)V_(0.1)O₉ 200 8.2 1.2

TABLE 29 Bi₂Ca₂Co_(1.9)V_(0.1)O₉ 203 7.9 0.9Bi₂Ca_(1.8)Na_(0.2)Co_(1.9)V_(0.1)O₉ 201 6.9 1.1Bi₂Ca_(1.8)K_(0.2)Co_(1.9)V_(0.1)O₉ 208 8.1 1.2Bi₂Ca_(1.8)Li_(0.2)Co_(1.9)V_(0.1)O₉ 198 9 0.9Bi₂Ca_(1.8)Ti_(0.2)Co_(1.9)V_(0.1)O₉ 199 8.2 1.1Bi₂Ca_(1.8)V_(0.2)Co_(1.9)V_(0.1)O₉ 200 7.9 1.2Bi₂Ca_(1.8)Cr_(0.2)Co_(1.9)V_(0.1)O₉ 206 8.6 1.4Bi₂Ca_(1.8)Mn_(0.2)Co_(1.9)V_(0.1)O₉ 205 9.1 0.8Bi₂Ca_(1.8)Fe_(0.2)Co_(1.9)V_(0.1)O₉ 198 6.9 1.3Bi₂Ca_(1.8)Ni_(0.2)Co_(1.9)V_(0.1)O₉ 206 7.4 1.2Bi₂Ca_(1.8)Cu_(0.2)Co_(1.9)V_(0.1)O₉ 205 7.8 1.1Bi₂Ca_(1.8)Zn_(0.2)Co_(1.9)V_(0.1)O₉ 198 7.7 0.8Bi₂Ca_(1.8)Pb_(0.2)Co_(1.9)V_(0.1)O₉ 195 8 1.3Bi₂Ca_(1.8)Sr_(0.2)Co_(1.9)V_(0.1)O₉ 200 8.2 1.4Bi₂Ca_(1.8)Ba_(0.2)Co_(1.9)V_(0.1)O₉ 203 8 1.1Bi₂Ca_(1.8)Al_(0.2)Co_(1.9)V_(0.1)O₉ 201 7.4 1Bi₂Ca_(1.8)Y_(0.2)Co_(1.9)V_(0.1)O₉ 208 7.8 1.3Bi₂Ca_(1.8)La_(0.2)Co_(1.9)V_(0.1)O₉ 201 7.7 0.9Bi₂Ca_(1.8)Ce_(0.2)Co_(1.9)V_(0.1)O₉ 190 8 1.1Bi₂Ca_(1.8)Pr_(0.2)Co_(1.9)V_(0.1)O₉ 198 8.2 1.4Bi₂Ca_(1.8)Nd_(0.2)Co_(1.9)V_(0.1)O₉ 199 7.9 1.2Bi₂Ca_(1.8)Sm_(0.2)Co_(1.9)V_(0.1)O₉ 201 9.1 0.9Bi₂Ca_(1.8)Eu_(0.2)Co_(1.9)V_(0.1)O₉ 200 8.4 1.1Bi₂Ca_(1.8)Gd_(0.2)Co_(1.9)V_(0.1)O₉ 206 8.6 1.2Bi₂Ca_(1.8)Dy_(0.2)Co_(1.9)V_(0.1)O₉ 205 8.2 0.9Bi₂Ca_(1.8)Ho_(0.2)Co_(1.9)V_(0.1)O₉ 198 7.9 1.1Bi₂Ca_(1.8)Er_(0.2)Co_(1.9)V_(0.1)O₉ 201 8.6 1.2Bi₂Ca_(1.8)Yb_(0.2)Co_(1.9)V_(0.1)O₉ 196 9.1 1.4Bi₂Pb_(0.2)Ca₂Co_(1.9)V_(0.1)O₉ 203 7.4 1.3Bi₂Pb_(0.2)Ca_(1.8)Na_(0.2)Co_(1.9)V_(0.1)O₉ 205 7.8 1.2Bi₂Pb_(0.2)Ca_(1.8)K_(0.2)Co_(1.9)V_(0.1)O₉ 198 7.7 1.1Bi₂Pb_(0.2)Ca_(1.8)Li_(0.2)Co_(1.9)V_(0.1)O₉ 195 8.3 0.8Bi₂Pb_(0.2)Ca_(1.8)Ti_(0.2)Co_(1.9)V_(0.1)O₉ 200 8.6 0.7Bi₂Pb_(0.2)Ca_(1.8)V_(0.2)Co_(1.9)V_(0.1)O₉ 205 8.7 1.3Bi₂Pb_(0.2)Ca_(1.8)Cr_(0.2)Co_(1.9)V_(0.1)O₉ 198 8.3 0.8Bi₂Pb_(0.2)Ca_(1.8)Mn_(0.2)Co_(1.9)V_(0.1)O₉ 199 9 1.3

TABLE 30 Bi₂Pb_(0.2)Ca_(1.8)Fe_(0.2)Co_(1.9)V_(0.1)O₉ 210 7.9 1.2Bi₂Pb_(0.2)Ca_(1.8)Ni_(0.2)Co_(1.9)V_(0.1)O₉ 202 8.1 1.1Bi₂Pb_(0.2)Ca_(1.8)Cu_(0.2)Co_(1.9)V_(0.1)O₉ 204 8 0.8Bi₂Pb_(0.2)Ca_(1.8)Zn_(0.2)Co_(1.9)V_(0.1)O₉ 197 7.8 1.3Bi₂Pb_(0.2)Ca_(1.8)Pb_(0.2)Co_(1.9)V_(0.1)O₉ 190 7.2 1.4Bi₂Pb_(0.2)Ca_(1.8)Sr_(0.2)Co_(1.9)V_(0.1)O₉ 198 9 1.1Bi₂Pb_(0.2)Ca_(1.8)Ba_(0.2)Co_(1.9)V_(0.1)O₉ 199 7.8 1Bi₂Pb_(0.2)Ca_(1.8)Al_(0.2)Co_(1.9)V_(0.1)O₉ 201 7.5 1.3Bi₂Pb_(0.2)Ca_(1.8)Y_(0.2)Co_(1.9)V_(0.1)O₉ 207 8.6 0.9Bi₂Pb_(0.2)Ca_(1.8)La_(0.2)Co_(1.9)V_(0.1)O₉ 190 8.2 1.1Bi₂Pb_(0.2)Ca_(1.8)Ce_(0.2)Co_(1.9)V_(0.1)O₉ 198 7.9 1.4Bi₂Pb_(0.2)Ca_(1.8)Pr_(0.2)Co_(1.9)V_(0.1)O₉ 199 6.9 1.2Bi₂Pb_(0.2)Ca_(1.8)Nd_(0.2)Co_(1.9)V_(0.1)O₉ 201 8.1 0.9Bi₂Pb_(0.2)Ca_(1.8)Sm_(0.2)Co_(1.9)V_(0.1)O₉ 210 9 1.1Bi₂Pb_(0.2)Ca_(1.8)Eu_(0.2)Co_(1.9)V_(0.1)O₉ 206 8.2 1.2Bi₂Pb_(0.2)Ca_(1.8)Gd_(0.2)Co_(1.9)V_(0.1)O₉ 205 7.9 0.9Bi₂Pb_(0.2)Ca_(1.8)Dy_(0.2)Co_(1.9)V_(0.1)O₉ 198 8.6 1.1Bi₂Pb_(0.2)Ca_(1.8)Ho_(0.2)Co_(1.9)V_(0.1)O₉ 195 9.1 1.2Bi₂Pb_(0.2)Ca_(1.8)Er_(0.2)Co_(1.9)V_(0.1)O₉ 200 6.9 1.4Bi₂Pb_(0.2)Ca_(1.8)Yb_(0.2)Co_(1.9)V_(0.1)O₉ 203 7.4 0.8Bi₂Ba₂Co_(1.9)V_(0.1)O₉ 208 7.7 1.2 Bi₂Ba_(1.8)Na_(0.2)Co_(1.9)V_(0.1)O₉198 8 1.1 Bi₂Ba_(1.8)K_(0.2)Co_(1.9)V_(0.1)O₉ 199 8.2 1.4Bi₂Ba_(1.8)Li_(0.2)Co_(1.9)V_(0.1)O₉ 200 7.9 1.2Bi₂Ba_(1.8)Ti_(0.2)Co_(1.9)V_(0.1)O₉ 199 9.1 0.9Bi₂Ba_(1.8)V_(0.2)Co_(1.9)V_(0.1)O₉ 210 8.4 1.1Bi₂Ba_(1.8)Cr_(0.2)Co_(1.9)V_(0.1)O₉ 202 8.6 1.2Bi₂Ba_(1.8)Mn_(0.2)Co_(1.9)V_(0.1)O₉ 204 8.2 0.9Bi₂Ba_(1.8)Fe_(0.2)Co_(1.9)V_(0.1)O₉ 197 7.9 1.1Bi₂Ba_(1.8)Ni_(0.2)Co_(1.9)V_(0.1)O₉ 190 8.6 1.2Bi₂Ba_(1.8)Cu_(0.2)Co_(1.9)V_(0.1)O₉ 198 9.1 1.4Bi₂Ba_(1.8)Zn_(0.2)Co_(1.9)V_(0.1)O₉ 199 6.9 0.8Bi₂Ba_(1.8)Pb_(0.2)Co_(1.9)V_(0.1)O₉ 201 7.4 1.3Bi₂Ba_(1.8)Ca_(0.2)Co_(1.9)V_(0.1)O₉ 207 7.8 1.2Bi₂Ba_(1.8)Sr_(0.2)Co_(1.9)V_(0.1)O₉ 190 7.7 1.1Bi₂Ba_(1.8)Al_(0.2)Co_(1.9)V_(0.1)O₉ 198 8 0.8

TABLE 31 Bi₂Ba_(1.8)Y_(0.2)Co_(1.9)V_(0.1)O₉ 199 8.2 1.3Bi₂Ba_(1.8)La_(0.2)Co_(1.9)V_(0.1)O₉ 201 7.9 1.4Bi₂Ba_(1.8)Ce_(0.2)Co_(1.9)V_(0.1)O₉ 210 9.1 1.1Bi₂Ba_(1.8)Pr_(0.2)Co_(1.9)V_(0.1)O₉ 206 8.4 1Bi₂Ba_(1.8)Nd_(0.2)Co_(1.9)V_(0.1)O₉ 205 8.6 1.3Bi₂Ba_(1.8)Sm_(0.2)Co_(1.9)V_(0.1)O₉ 198 7.8 0.9Bi₂Ba_(1.8)Eu_(0.2)Co_(1.9)V_(0.1)O₉ 195 9 1.1Bi₂Ba_(1.8)Gd_(0.2)Co_(1.9)V_(0.1)O₉ 200 8.2 1.4Bi₂Ba_(1.8)Dy_(0.2)Co_(1.9)V_(0.1)O₉ 203 8.3 1.2Bi₂Ba_(1.8)Ho_(0.2)Co_(1.9)V_(0.1)O₉ 201 8.6 0.9Bi₂Ba_(1.8)Er_(0.2)Co_(1.9)V_(0.1)O₉ 208 8.7 1.1Bi₂Ba_(1.8)Yb_(0.2)Co_(1.9)V_(0.1)O₉ 201 8.3 1.2Bi₂Pb_(0.2)Ba₂Co_(1.9)V_(0.1)O₉ 198 7.9 1.1Bi₂Pb_(0.2)Ba_(1.8)Na_(0.2)Co_(1.9)V_(0.1)O₉ 199 8.1 1.2Bi₂Pb_(0.2)Ba_(1.8)K_(0.2)Co_(1.9)V_(0.1)O₉ 201 8 1Bi₂Pb_(0.2)Ba_(1.8)Li_(0.2)Co_(1.9)V_(0.1)O₉ 200 7.8 1.3Bi₂Pb_(0.2)Ba_(1.8)Ti_(0.2)Co_(1.9)V_(0.1)O₉ 206 7.2 1Bi₂Pb_(0.2)Ba_(1.8)V_(0.2)Co_(1.9)V_(0.1)O₉ 205 9 0.9Bi₂Pb_(0.2)Ba_(1.8)Cr_(0.2)Co_(1.9)V_(0.1)O₉ 198 7.8 1.1Bi₂Pb_(0.2)Ba_(1.8)Mn_(0.2)Co_(1.9)V_(0.1)O₉ 201 7.5 1Bi₂Pb_(0.2)Ba_(1.8)Fe_(0.2)Co_(1.9)V_(0.1)O₉ 196 8.6 1.2Bi₂Pb_(0.2)Ba_(1.8)Ni_(0.2)Co_(1.9)V_(0.1)O₉ 202 8.2 1.1Bi₂Pb_(0.2)Ba_(1.8)Cu_(0.2)Co_(1.9)V_(0.1)O₉ 203 7.9 0.9Bi₂Pb_(0.2)Ba_(1.8)Zn_(0.2)Co_(1.9)V_(0.1)O₉ 205 6.9 0.8Bi₂Pb_(0.2)Ba_(1.8)Pb_(0.2)Co_(1.9)V_(0.1)O₉ 198 8.1 1Bi₂Pb_(0.2)Ba_(1.8)Ca_(0.2)Co_(1.9)V_(0.1)O₉ 195 6.9 1.3Bi₂Pb_(0.2)Ba_(1.8)Sr_(0.2)Co_(1.9)V_(0.1)O₉ 200 7.4 1.2Bi₂Pb_(0.2)Ba_(1.8)Al_(0.2)Co_(1.9)V_(0.1)O₉ 205 7.8 1.3Bi₂Pb_(0.2)Ba_(1.8)Y_(0.2)Co_(1.9)V_(0.1)O₉ 198 7.7 1Bi₂Pb_(0.2)Ba_(1.8)La_(0.2)Co_(1.9)V_(0.1)O₉ 199 8 1.3Bi₂Pb_(0.2)Ba_(1.8)Ce_(0.2)Co_(1.9)V_(0.1)O₉ 210 8.2 0.9Bi₂Pb_(0.2)Ba_(1.8)Pr_(0.2)Co_(1.9)V_(0.1)O₉ 202 7.9 1.1Bi₂Pb_(0.2)Ba_(1.8)Nd_(0.2)Co_(1.9)V_(0.1)O₉ 204 9.1 1.4Bi₂Pb_(0.2)Ba_(1.8)Sm_(0.2)Co_(1.9)V_(0.1)O₉ 197 8.4 1.2Bi₂Pb_(0.2)Ba_(1.8)Eu_(0.2)Co_(1.9)V_(0.1)O₉ 190 8.6 0.9Bi₂Pb_(0.2)Ba_(1.8)Gd_(0.2)Co_(1.9)V_(0.1)O₉ 198 8.2 1.1

TABLE 32 Bi₂Pb_(0.2)Ba_(1.8)Dy_(0.2)Co_(1.9)V_(0.1)O₉ 199 7.9 1.2Bi₂Pb_(0.2)Ba_(1.8)Ho_(0.2)Co_(1.9)V_(0.1)O₉ 201 8.6 0.9Bi₂Pb_(0.2)Ba_(1.8)Er_(0.2)Co_(1.9)V_(0.1)O₉ 207 9.1 1.1Bi₂Pb_(0.2)Ba_(1.8)Yb_(0.2)Co_(1.9)V_(0.1)O₉ 190 6.9 1.2Bi₂Sr₂Co_(1.9)Mn_(0.1)O₉ 199 7.8 0.8Bi₂Sr_(1.8)Na_(0.2)Co_(1.9)Mn_(0.1)O₉ 201 7.7 1.3Bi₂Sr_(1.8)K_(0.2)Co_(1.9)Mn_(0.1)O₉ 210 8 1.2Bi₂Sr_(1.8)Li_(0.2)Co_(1.9)Mn_(0.1)O₉ 206 8.2 1.1Bi₂Sr_(1.8)Ti_(0.2)Co_(1.9)Mn_(0.1)O₉ 205 7.9 0.8Bi₂Sr_(1.8)V_(0.2)Co_(1.9)Mn_(0.1)O₉ 198 9.1 0.7Bi₂Sr_(1.8)Cr_(0.2)Co_(1.9)Mn_(0.1)O₉ 195 8.4 1.3Bi₂Sr_(1.8)Mn_(0.2)Co_(1.9)Mn_(0.1)O₉ 200 8.6 0.8Bi₂Sr_(1.8)Fe_(0.2)Co_(1.9)Mn_(0.1)O₉ 203 7.8 1.1Bi₂Sr_(1.8)Ni_(0.2)Co_(1.9)Mn_(0.1)O₉ 201 9 1.4Bi₂Sr_(1.8)Cu_(0.2)Co_(1.9)Mn_(0.1)O₉ 208 8.2 1.2Bi₂Sr_(1.8)Zn_(0.2)Co_(1.9)Mn_(0.1)O₉ 198 8.3 0.9Bi₂Sr_(1.8)Pb_(0.2)Co_(1.9)Mn_(0.1)O₉ 199 8.6 1.1Bi₂Sr_(1.8)Ca_(0.2)Co_(1.9)Mn_(0.1)O₉ 200 8.7 1.2Bi₂Sr_(1.8)Ba_(0.2)Co_(1.9)Mn_(0.1)O₉ 206 8.3 0.9Bi₂Sr_(1.8)Al_(0.2)Co_(1.9)Mn_(0.1)O₉ 205 9 1.1Bi₂Sr_(1.8)Y_(0.2)Co_(1.9)Mn_(0.1)O₉ 198 7.9 1.2Bi₂Sr_(1.8)La_(0.2)Co_(1.9)Mn_(0.1)O₉ 206 8.1 1.4Bi₂Sr_(1.8)Ce_(0.2)Co_(1.9)Mn_(0.1)O₉ 198 8 0.8Bi₂Sr_(1.8)Pr_(0.2)Co_(1.9)MN_(0.1)O₉ 195 7.8 1.3Bi₂Sr_(1.8)Nd_(0.2)Co_(1.9)Mn_(0.1)O₉ 200 7.2 1.2Bi₂Sr_(1.8)Sm_(0.2)Co_(1.9)Mn_(0.1)O₉ 203 9 1.1Bi₂Sr_(1.8)Eu_(0.2)Co_(1.9)Mn_(0.1)O₉ 201 7.8 0.8Bi₂Sr_(1.8)Gd_(0.2)Co_(1.9)Mn_(0.1)O₉ 208 7.5 1.3Bi₂Sr_(1.8)Dy_(0.2)Co_(1.9)Mn_(0.1)O₉ 198 8.6 1.4Bi₂Sr_(1.8)Ho_(0.2)Co_(1.9)Mn_(0.1)O₉ 199 8.2 1.1Bi₂Sr_(1.8)Er_(0.2)Co_(1.9)Mn_(0.1)O₉ 200 7.9 1Bi₂Sr_(1.8)Yb_(0.2)Co_(1.9)Mn_(0.1)O₉ 199 6.9 1.3Bi₂Pb_(0.2)Sr₂Co_(1.9)Mn_(0.1)O₉ 202 7.5 1.1Bi₂Pb_(0.2)Sr_(1.8)Na_(0.2)Co_(1.9)Mn_(0.1)O₉ 204 8.6 1.4Bi₂Pb_(0.2)Sr_(1.8)K_(0.2)Co_(1.9)Mn_(0.1)O₉ 197 8.2 1.2

TABLE 33 Bi₂Pb_(0.2)Sr_(1.8)Li_(0.2)Co_(1.9)Mn_(0.1)O₉ 190 7.9 0.9Bi₂Pb_(0.2)Sr_(1.8)Ti_(0.2)Co_(1.9)Mn_(0.1)O₉ 198 6.9 1.1Bi₂Pb_(0.2)Sr_(1.8)V_(0.2)Co_(1.9)Mn_(0.1)O₉ 199 8.1 1.2Bi₂Pb_(0.2)Sr_(1.8)Cr_(0.2)Co_(1.9)Mn_(0.1)O₉ 201 9 0.9Bi₂Pb_(0.2)Sr_(1.8)Mn_(0.2)Co_(1.9)Mn_(0.1)O₉ 207 8.2 1.1Bi₂Pb_(0.2)Sr_(1.8)Fe_(0.2)Co_(1.9)Mn_(0.1)O₉ 190 7.9 1.2Bi₂Pb_(0.2)Sr_(1.8)Ni_(0.2)Co_(1.9)Mn_(0.1)O₉ 198 8.6 1.4Bi₂Pb_(0.2)Sr_(1.8)Cu_(0.2)Co_(1.9)Mn_(0.1)O₉ 200 9.1 0.8Bi₂Pb_(0.2)Sr_(1.8)Zn_(0.2)Co_(1.9)Mn_(0.1)O₉ 203 6.9 1.3Bi₂Pb_(0.2)Sr_(1.8)Pb_(0.2)Co_(1.9)Mn_(0.1)O₉ 201 7.4 1.2Bi₂Pb_(0.2)Sr_(1.8)Ca_(0.2)Co_(1.9)Mn_(0.1)O₉ 208 7.8 1.1Bi₂Pb_(0.2)Sr_(1.8)Ba_(0.2)Co_(1.9)Mn_(0.1)O₉ 198 7.7 1.4Bi₂Pb_(0.2)Sr_(1.8)Al_(0.2)Co_(1.9)Mn_(0.1)O₉ 199 8 1.2Bi₂Pb_(0.2)Sr_(1.8)Y_(0.2)Co_(1.9)Mn_(0.1)O₉ 200 8.2 0.9Bi₂Pb_(0.2)Sr_(1.8)La_(0.2)Co_(1.9)Mn_(0.1)O₉ 199 8 1.1Bi₂Pb_(0.2)Sr_(1.8)Ce_(0.2)Co_(1.9)Mn_(0.1)O₉ 210 7.7 1.2Bi₂Pb_(0.2)Sr_(1.8)Pr_(0.2)Co_(1.9)Mn_(0.1)O₉ 202 8.3 0.9Bi₂Pb_(0.2)Sr_(1.8)Nd_(0.2)Co_(1.9)Mn_(0.1)O₉ 204 8.6 1.1Bi₂Pb_(0.2)Sr_(1.8)Sm_(0.2)Co_(1.9)Mn_(0.1)O₉ 197 8.7 1.2Bi₂Pb_(0.2)Sr_(1.8)Eu_(0.2)Co_(1.9)Mn_(0.1)O₉ 190 8.3 1.4Bi₂Pb_(0.2)Sr_(1.8)Gd_(0.2)Co_(1.9)Mn_(0.1)O₉ 198 9 0.8Bi₂Pb_(0.2)Sr_(1.8)Dy_(0.2)Co_(1.9)Mn_(0.1)O₉ 199 7.9 1.3Bi₂Pb_(0.2)Sr_(1.8)Ho_(0.2)Co_(1.9)Mn_(0.1)O₉ 201 8.1 1.2Bi₂Pb_(0.2)Sr_(1.8)Er_(0.2)Co_(1.9)Mn_(0.1)O₉ 207 8 1.1Bi₂Pb_(0.2)Sr_(1.8)Yb_(0.2)Co_(1.9)Mn_(0.1)O₉ 190 7.8 0.8Bi₂Ca₂Co_(1.9)Mn_(0.1)O₉ 199 9 1.4 Bi₂Ca_(1.8)Na_(0.2)Co_(1.9)Mn_(0.1)O₉201 7.8 1.1 Bi₂Ca_(1.8)K_(0.2)Co_(1.9)Mn_(0.1)O₉ 210 7.5 1Bi₂Ca_(1.8)Li_(0.2)Co_(1.9)Mn_(0.1)O₉ 206 8.6 1.3Bi₂Ca_(1.8)Ti_(0.2)Co_(1.9)Mn_(0.1)O₉ 205 8.2 0.9Bi₂Ca_(1.8)V_(0.2)Co_(1.9)Mn_(0.1)O₉ 198 7.9 1.1Bi₂Ca_(1.8)Cr_(0.2)Co_(1.9)Mn_(0.1)O₉ 195 6.9 1.4Bi₂Ca_(1.8)Mn_(0.2)Co_(1.9)Mn_(0.1)O₉ 200 8.1 1.2Bi₂Ca_(1.8)Fe_(0.2)Co_(1.9)Mn_(0.1)O₉ 203 9 0.9Bi₂Ca_(1.8)Ni_(0.2)Co_(1.9)Mn_(0.1)O₉ 201 8.2 1.1Bi₂Ca_(1.8)Cu_(0.2)Co_(1.9)Mn_(0.1)O₉ 208 7.9 1.2

TABLE 34 Bi₂Ca_(1.8)Zn_(0.2)Co_(1.9)Mn_(0.1)O₉ 201 8.6 0.9Bi₂Ca_(1.8)Pb_(0.2)Co_(1.9)Mn_(0.1)O₉ 190 9.1 1.1Bi₂Ca_(1.8)Sr_(0.2)Co_(1.9)Mn_(0.1)O₉ 198 6.9 1.2Bi₂Ca_(1.8)Ba_(0.2)Co_(1.9)Mn_(0.1)O₉ 199 7.4 1Bi₂Ca_(1.8)Al_(0.2)Co_(1.9)Mn_(0.1)O₉ 201 7.8 1.3Bi₂Ca_(1.8)Y_(0.2)Co_(1.9)Mn_(0.1)O₉ 200 7.7 1Bi₂Ca_(1.8)La_(0.2)Co_(1.9)Mn_(0.1)O₉ 206 8 0.9Bi₂Ca_(1.8)Ce_(0.2)Co_(1.9)Mn_(0.1)O₉ 205 8.2 1.1Bi₂Ca_(1.8)Pr_(0.2)Co_(1.9)Mn_(0.1)O₉ 198 7.9 1Bi₂Ca_(1.8)Nd_(0.2)Co_(1.9)Mn_(0.1)O₉ 201 9.1 1.2Bi₂Ca_(1.8)Sm_(0.2)Co_(1.9)Mn_(0.1)O₉ 196 8.4 1.1Bi₂Ca_(1.8)Eu_(0.2)Co_(1.9)Mn_(0.1)O₉ 202 8.6 0.9Bi₂Ca_(1.8)Gd_(0.2)Co_(1.9)Mn_(0.1)O₉ 203 8.2 0.8Bi₂Ca_(1.8)Dy_(0.2)Co_(1.9)Mn_(0.1)O₉ 205 7.9 1Bi₂Ca_(1.8)Ho_(0.2)Co_(1.9)Mn_(0.1)O₉ 198 8.6 1.3Bi₂Ca_(1.8)Er_(0.2)Co_(1.9)Mn_(0.1)O₉ 195 9.1 1.2Bi₂Ca_(1.8)Yb_(0.2)Co_(1.9)Mn_(0.1)O₉ 200 6.9 1.3Bi₂Pb_(0.2)Ca₂Co_(1.9)Mn_(0.1)O₉ 198 7.8 1.1Bi₂Pb_(0.2)Ca_(1.8)Na_(0.2)Co_(1.9)Mn_(0.1)O₉ 199 7.7 1.4Bi₂Pb_(0.2)Ca_(1.8)K_(0.2)Co_(1.9)Mn_(0.1)O₉ 210 8 1.2Bi₂Pb_(0.2)Ca_(1.8)Li_(0.2)Co_(1.9)Mn_(0.1)O₉ 202 8.2 0.9Bi₂Pb_(0.2)Ca_(1.8)Ti_(0.2)Co_(1.9)Mn_(0.1)O₉ 204 7.9 1.1Bi₂Pb_(0.2)Ca_(1.8)V_(0.2)Co_(1.9)Mn_(0.1)O₉ 197 9.1 1.2Bi₂Pb_(0.2)Ca_(1.8)Cr_(0.2)Co_(1.9)Mn_(0.1)O₉ 190 6.9 0.9Bi₂Pb_(0.2)Ca_(1.8)Mn_(0.2)Co_(1.9)Mn_(0.1)O₉ 198 9.1 1.1Bi₂Pb_(0.2)Ca_(1.8)Fe_(0.2)Co_(1.9)Mn_(0.1)O₉ 199 8.4 1.2Bi₂Pb_(0.2)Ca_(1.8)Ni_(0.2)Co_(1.9)Mn_(0.1)O₉ 201 8.6 1Bi₂Pb_(0.2)Ca_(1.8)Cu_(0.2)Co_(1.9)Mn_(0.1)O₉ 207 8.2 1.3Bi₂Pb_(0.2)Ca_(1.8)Zn_(0.2)Co_(1.9)Mn_(0.1)O₉ 190 7.9 1Bi₂Pb_(0.2)Ca_(1.8)Pb_(0.2)Co_(1.9)Mn_(0.1)O₉ 198 8.6 0.9Bi₂Pb_(0.2)Ca_(1.8)Sr_(0.2)Co_(1.9)Mn_(0.1)O₉ 199 9.1 1.1Bi₂Pb_(0.2)Ca_(1.8)Ba_(0.2)Co_(1.9)Mn_(0.1)O₉ 201 6.9 1Bi₂Pb_(0.2)Ca_(1.8)Al_(0.2)Co_(1.9)Mn_(0.1)O₉ 210 7.4 1.2Bi₂Pb_(0.2)Ca_(1.8)Y_(0.2)Co_(1.9)Mn_(0.1)O₉ 206 7.8 1.1Bi₂Pb_(0.2)Ca_(1.8)La_(0.2)Co_(1.9)Mn_(0.1)O₉ 205 7.7 0.9Bi₂Pb_(0.2)Ca_(1.8)Ce_(0.2)Co_(1.9)Mn_(0.1)O₉ 198 8.0 0.8

TABLE 35 Bi₂Pb_(0.2)Ca_(1.8)Pr_(0.2)Co_(1.9)Mn_(0.1)O₉ 195 8.2 1Bi₂Pb_(0.2)Ca_(1.8)Nd_(0.2)Co_(1.9)Mn_(0.1)O₉ 200 7.9 1.3Bi₂Pb_(0.2)Ca_(1.8)Sm_(0.2)Co_(1.9)Mn_(0.1)O₉ 203 7.9 1.2Bi₂Pb_(0.2)Ca_(1.8)Eu_(0.2)Co_(1.9)Mn_(0.1)O₉ 201 8.1 0.7Bi₂Pb_(0.2)Ca_(1.8)Gd_(0.2)Co_(1.9)Mn_(0.1)O₉ 208 8 1.3Bi₂Pb_(0.2)Ca_(1.8)Dy_(0.2)Co_(1.9)Mn_(1.0)O₉ 198 7.8 1.4Bi₂Pb_(0.2)Ca_(1.8)Ho_(0.2)Co_(1.9)Mn_(0.1)O₉ 199 7.2 1.1Bi₂Pb_(0.2)Ca_(1.8)Er_(0.2)Co_(1.9)Mn_(0.1)O₉ 200 9 1Bi₂Pb_(0.2)Ca_(1.8)Yb_(0.2)Co_(1.9)Mn_(0.1)O₉ 206 7.8 1.3Bi₂Ba₂Co_(1.9)Mn_(0.1)O₉ 198 8.6 1.1Bi₂Ba_(1.8)Na_(0.2)Co_(1.9)Mn_(0.1)O₉ 206 8.2 1.4Bi₂Ba_(1.8)K_(0.2)Co_(1.9)Mn_(0.1)O₉ 198 7.9 1.2Bi₂Ba_(1.8)Li_(0.2)Co_(1.9)Mn_(0.1)O₉ 207 6.9 0.9Bi₂Ba_(1.8)Ti_(0.2)Co_(1.9)Mn_(0.1)O₉ 190 8.1 1.1Bi₂Ba_(1.8)V_(0.2)Co_(1.9)Mn_(0.1)O₉ 198 6.9 1.2Bi₂Ba_(1.8)Cr_(0.2)Co_(1.9)Mn_(0.1)O₉ 199 7.4 0.9Bi₂Ba_(1.8)Mn_(0.2)Co_(1.9)Mn_(0.1)O₉ 201 7.8 1.1Bi₂Ba_(1.8)Fe_(0.2)Co_(1.9)Mn_(0.1)O₉ 210 7.7 1.2Bi₂Ba_(1.8)Ni_(0.2)Co_(1.9)Mn_(0.1)O₉ 206 8 1.4Bi₂Ba_(1.8)Cu_(0.2)Co_(1.9)Mn_(0.1)O₉ 205 8.2 0.8Bi₂Ba_(1.8)Zn_(0.2)Co_(1.9)Mn_(0.1)O₉ 198 7.9 1.3Bi₂Ba_(1.8)Pb_(0.2)Co_(1.9)Mn_(0.1)O₉ 195 9.1 1.2Bi₂Ba_(1.8)Ca_(0.2)Co_(1.9)Mn_(0.1)O₉ 200 8.4 1.1Bi₂Ba_(1.8)Sr_(0.2)Co_(1.9)Mn_(0.1)O₉ 203 8.6 0.8Bi₂Ba_(1.8)Al_(0.2)Co_(1.9)Mn_(0.1)O₉ 201 8.2 1.3Bi₂Ba_(1.8)Y_(0.2)Co_(1.9)Mn_(0.1)O₉ 208 7.9 1.4Bi₂Ba_(1.8)La_(0.2)Co_(1.9)Mn_(0.1)O₉ 198 8.6 1.1Bi₂Ba_(1.8)Ce_(0.2)Co_(1.9)Mn_(0.1)O₉ 199 9.1 1Bi₂Ba_(1.8)Pr_(0.2)Co_(1.9)Mn_(0.1)O₉ 200 6.9 1.3Bi₂Ba_(1.8)Nd_(0.2)Co_(1.9)Mn_(0.1)O₉ 206 7.4 0.9Bi₂Ba_(1.8)Sm_(0.2)Co_(1.9)Mn_(0.1)O₉ 205 7.8 1.1Bi₂Ba_(1.8)Eu_(0.2)Co_(1.9)Mn_(0.1)O₉ 198 7.7 1.4Bi₂Ba_(1.8)Gd_(0.2)Co_(1.9)Mn_(0.1)O₉ 206 8 1.2Bi₂Ba_(1.8)Dy_(0.2)Co_(1.9)Mn_(0.1)O₉ 198 8.2 0.9Bi₂Ba_(1.8)Ho_(0.2)Co_(1.9)Mn_(0.1)O₉ 195 7.9 1.1Bi₂Ba_(1.8)Er_(0.2)Co_(1.9)Mn_(0.1)O₉ 200 9.1 1.2

TABLE 36 Bi₂Ba_(1.8)Yb_(0.2)Co_(1.9)Mn_(0.1)O₉ 203 8.4 0.9Bi₂Pb_(0.2)Ba₂Co_(1.9)Mn_(0.1)O₉ 208 7.8 1.2Bi₂Pb_(0.2)Ba_(1.8)Na_(0.2)Co_(1.9)Mn_(0.1)O₉ 198 9 1.4Bi₂Pb_(0.2)Ba_(1.8)K_(0.2)Co_(1.9)Mn_(0.1)O₉ 199 8.2 0.8Bi₂Pb_(0.2)Ba_(1.8)Li_(0.2)Co_(1.9)Mn_(0.1)O₉ 200 8.3 1.3Bi₂Pb_(0.2)Ba_(1.8)Ti_(0.2)Co_(1.9)Mn_(0.1)O₉ 199 8.6 1.2Bi₂Pb_(0.2)Ba_(1.8)V_(0.2)Co_(1.9)Mn_(0.1)O₉ 210 8.7 1.1Bi₂Pb_(0.2)Ba_(1.8)Cr_(0.2)Co_(1.9)Mn_(0.1)O₉ 202 8.3 0.8Bi₂Pb_(0.2)Ba_(1.8)Mn_(0.2)Co_(1.9)Mn_(0.1)O₉ 204 9 0.7Bi₂Pb_(0.2)Ba_(1.8)Fe_(0.2)Co_(1.9)Mn_(0.1)O₉ 197 7.9 1.3Bi₂Pb_(0.2)Ba_(1.8)Ni_(0.2)Co_(1.9)Mn_(0.1)O₉ 190 8.1 0.8Bi₂Pb_(0.2)Ba_(1.8)Cu_(0.2)Co_(1.9)Mn_(0.1)O₉ 198 8 1.3Bi₂Pb_(0.2)Ba_(1.8)Zn_(0.2)Co_(1.9)Mn_(0.1)O₉ 199 7.8 1.2Bi₂Pb_(0.2)Ba_(1.8)Pb_(0.2)Co_(1.9)Mn_(0.1)O₉ 201 7.2 1.1Bi₂Pb_(0.2)Ba_(1.8)Ca_(0.2)Co_(1.9)Mn_(0.1)O₉ 207 9 0.8Bi₂Pb_(0.2)Ba_(1.8)Sr_(0.2)Co_(1.9)Mn_(0.1)O₉ 190 7.8 1.3Bi₂Pb_(0.2)Ba_(1.8)Al_(0.2)Co_(1.9)Mn_(0.1)O₉ 198 7.5 1.4Bi₂Pb_(0.2)Ba_(1.8)Y_(0.2)Co_(1.9)Mn_(0.1)O₉ 198 8.6 1.1Bi₂Pb_(0.2)Ba_(1.8)La_(0.2)Co_(1.9)Mn_(0.1)O₉ 201 8.2 1Bi₂Pb_(0.2)Ba_(1.8)Ce_(0.2)Co_(1.9)Mn_(0.1)O₉ 196 7.9 1.3Bi₂Pb_(0.2)Ba_(1.8)Pr_(0.2)Co_(1.9)Mn_(0.1)O₉ 202 6.9 0.9Bi₂Pb_(0.2)Ba_(1.8)Nd_(0.2)Co_(1.9)Mn_(0.1)O₉ 203 9 1.1Bi₂Pb_(0.2)Ba_(1.8)Sm_(0.2)Co_(1.9)Mn_(0.1)O₉ 205 7.8 1.4Bi₂Pb_(0.2)Ba_(1.8)Eu_(0.2)Co_(1.9)Mn_(0.1)O₉ 198 7.5 1.2Bi₂Pb_(0.2)Ba_(1.8)Gd_(0.2)Co_(1.9)Mn_(0.1)O₉ 195 8.6 0.9Bi₂Pb_(0.2)Ba_(1.8)Dy_(0.2)Co_(1.9)Mn_(0.1)O₉ 200 8.2 1.1Bi₂Pb_(0.2)Ba_(1.8)Ho_(0.2)Co_(1.9)Mn_(0.1)O₉ 205 7.9 1.2Bi₂Pb_(0.2)Ba_(1.8)Er_(0.2)Co_(1.9)Mn_(0.1)O₉ 198 6.9 0.9Bi₂Pb_(0.2)Ba_(1.8)Yb_(0.2)Co_(1.9)Mn_(0.1)O₉ 199 8.1 1.1Bi₂Sr₂Co_(1.9)Fe_(0.1)O₉ 202 7.4 1.4Bi₂Sr_(1.8)Na_(0.2)Co_(1.9)Fe_(0.1)O₉ 204 7.8 0.8Bi₂Sr_(1.8)K_(0.2)Co_(1.9)Fe_(0.1)O₉ 197 7.7 1.3Bi₂Sr_(1.8)Li_(0.2)Co_(1.9)Fe_(0.1)O₉ 190 8 1.2Bi₂Sr_(1.8)Ti_(0.2)Co_(1.9)Fe_(0.1)O₉ 198 8.2 1.1Bi₂Sr_(1.8)V_(0.2)Co_(1.9)Fe_(0.1)O₉ 199 7.9 1.4

TABLE 37 Bi₂Sr_(1.8)Cr_(0.2)Co_(1.9)Fe_(0.1)O₉ 201 9.1 1.2Bi₂Sr_(1.8)Mn_(0.2)Co_(1.9)Fe_(0.1)O₉ 207 8.4 0.9Bi₂Sr_(1.8)Fe_(0.2)Co_(1.9)Fe_(0.1)O₉ 190 8.6 1.1Bi₂Sr_(1.8)Ni_(0.2)Co_(1.9)Fe_(0.1)O₉ 198 8.2 1.2Bi₂Sr_(1.8)Cu_(0.2)Co_(1.9)Fe_(0.1)O₉ 199 7.9 0.9Bi₂Sr_(1.8)Zn_(0.2)Co_(1.9)Fe_(0.1)O₉ 201 8.6 1.1Bi₂Sr_(1.8)Pb_(0.2)Co_(1.9)Fe_(0.1)O₉ 210 9.1 1.2Bi₂Sr_(1.8)Ca_(0.2)Co_(1.9)Fe_(0.1)O₉ 206 6.9 1.4Bi₂Sr_(1.8)Ba_(0.2)Co_(1.9)Fe_(0.1)O₉ 205 7.4 0.8Bi₂Sr_(1.8)Al_(0.2)Co_(1.9)Fe_(0.1)O₉ 198 7.8 1.3Bi₂Sr_(1.8)Y_(0.2)Co_(1.9)Fe_(0.1)O₉ 195 7.7 1.2Bi₂Sr_(1.8)La_(0.2)Co_(1.9)Fe_(0.1)O₉ 200 8 1.1Bi₂Sr_(1.8)Ce_(0.2)Co_(1.9)Fe_(0.1)O₉ 203 8.2 0.8Bi₂Sr_(1.8)Pr_(0.2)Co_(1.9)Fe_(0.1)O₉ 201 7.9 1.3Bi₂Sr_(1.8)Nd_(0.2)Co_(1.9)Fe_(0.1)O₉ 208 9.1 1.4Bi₂Sr_(1.8)Sm_(0.2)Co_(1.9)Fe_(0.1)O₉ 198 8.4 1.1Bi₂Sr_(1.8)Eu_(0.2)Co_(1.9)Fe_(0.1)O₉ 199 8.6 1Bi₂Sr_(1.8)Gd_(0.2)Co_(1.9)Fe_(0.1)O₉ 200 7.8 1.3Bi₂Sr_(1.8)Dy_(0.2)Co_(1.9)Fe_(0.1)O₉ 206 9 0.9Bi₂Sr_(1.8)Ho_(0.2)Co_(1.9)Fe_(0.1)O₉ 205 8.2 1.1Bi₂Sr_(1.8)Er_(0.2)Co_(1.9)Fe_(0.1)O₉ 198 8.3 1.4Bi₂Sr_(1.8)Yb_(0.2)Co_(1.9)Fe_(0.1)O₉ 206 8.6 1.2Bi₂Pb_(0.2)Sr₂Co_(1.9)Fe_(0.1)O₉ 207 8.3 1.1Bi₂Pb_(0.2)Sr_(1.8)Na_(0.2)Co_(1.9)Fe_(0.1)O₉ 190 9 1.2Bi₂Pb_(0.2)Sr_(1.8)K_(0.2)Co_(1.9)Fe_(0.1)O₉ 198 7.9 0.9Bi₂Pb_(0.2)Sr_(1.8)Li_(0.2)Co_(1.9)Fe_(0.1)O₉ 199 8.1 1.1Bi₂Pb_(0.2)Sr_(1.8)Ti_(0.2)Co_(1.9)Fe_(0.1)O₉ 201 8 1.2Bi₂Pb_(0.2)Sr_(1.8)V_(0.2)Co_(1.9)Fe_(0.1)O₉ 210 7.8 1Bi₂Pb_(0.2)Sr_(1.8)Cr_(0.2)Co_(1.9)Fe_(0.1)O₉ 206 7.2 1.3Bi₂Pb_(0.2)Sr_(1.8)Mn_(0.2)Co_(1.9)Fe_(0.1)O₉ 205 9 1Bi₂Pb_(0.2)Sr_(1.8)Fe_(0.2)Co_(1.9)Fe_(0.1)O₉ 198 8.2 0.9Bi₂Pb_(0.2)Sr_(1.8)Ni_(0.2)Co_(1.9)Fe_(0.1)O₉ 195 7.9 1.1Bi₂Pb_(0.2)Sr_(1.8)Cu_(0.2)Co_(1.9)Fe_(0.1)O₉ 200 6.9 1Bi₂Pb_(0.2)Sr_(1.8)Zn_(0.2)Co_(1.9)Fe_(0.1)O₉ 203 8.1 1.2Bi₂Pb_(0.2)Sr_(1.8)Pb_(0.2)Co_(1.9)Fe_(0.1)O₉ 201 6.9 1.1Bi₂Pb_(0.2)Sr_(1.8)Ca_(0.2)Co_(1.9)Fe_(0.1)O₉ 208 7.4 0.9

TABLE 38 Bi₂Pb_(0.2)Sr_(1.8)Ba_(0.2)Co_(1.9)Fe_(0.1)O₉ 198 7.8 0.8Bi₂Pb_(0.2)Sr_(1.8)Al_(0.2)Co_(1.9)Fe_(0.1)O₉ 199 7.7 1Bi₂Pb_(0.2)Sr_(1.8)Y_(0.2)Co_(1.9)Fe_(0.1)O₉ 200 8 1.3Bi₂Pb_(0.2)Sr_(1.8)La_(0.2)Co_(1.9)Fe_(0.1)O₉ 206 8.2 1.2Bi₂Pb_(0.2)Sr_(1.8)Ce_(0.2)Co_(1.9)Fe_(0.1)O₉ 205 7.9 1.3Bi₂Pb_(0.2)Sr_(1.8)Pr_(0.2)Co_(1.9)Fe_(0.1)O₉ 198 9.1 1Bi₂Pb_(0.2)Sr_(1.8)Nd_(0.2)Co_(1.9)Fe_(0.1)O₉ 206 8.4 0.8Bi₂Pb_(0.2)Sr_(1.8)Sm_(0.2)Co_(1.9)Fe_(0.1)O₉ 198 8.6 1.3Bi₂Pb_(0.2)Sr_(1.8)Eu_(0.2)Co_(1.9)Fe_(0.1)O₉ 195 8.2 1.2Bi₂Pb_(0.2)Sr_(1.8)Gd_(0.2)Co_(1.9)Fe_(0.1)O₉ 200 7.9 1.1Bi₂Pb_(0.2)Sr_(1.8)Dy_(0.2)Co_(1.9)Fe_(0.1)O₉ 203 8.6 0.8Bi₂Pb_(0.2)Sr_(1.8)Ho_(0.2)Co_(1.9)Fe_(0.1)O₉ 201 9.1 1.3Bi₂Pb_(0.2)Sr_(1.8)Er_(0.2)Co_(1.9)Fe_(0.1)O₉ 208 6.9 1.4Bi₂Pb_(0.2)Sr_(1.8)Yb_(0.2)Co_(1.9)Fe_(0.1)O₉ 198 7.4 1.1Bi₂Ca₂Co_(1.9)Fe_(0.1)O₉ 200 7.7 1.3Bi₂Ca_(1.8)Na_(0.2)Co_(1.9)Fe_(0.1)O₉ 199 8 0.9Bi₂Ca_(1.8)K_(0.2)Co_(1.9)Fe_(0.1)O₉ 210 8.2 1.1Bi₂Ca_(1.8)Li_(0.2)Co_(1.9)Fe_(0.1)O₉ 202 7.9 1.4Bi₂Ca_(1.8)Ti_(0.2)Co_(1.9)Fe_(0.1)O₉ 204 9.1 1.2Bi₂Ca_(1.8)V_(0.2)Co_(1.9)Fe_(0.1)O₉ 197 8.4 0.9Bi₂Ca_(1.8)Cr_(0.2)Co_(1.9)Fe_(0.1)O₉ 190 8.6 1.1Bi₂Ca_(1.8)Mn_(0.2)Co_(1.9)Fe_(0.1)O₉ 198 7.8 1.2Bi₂Ca_(1.8)Fe_(0.2)Co_(1.9)Fe_(0.1)O₉ 199 9 0.9Bi₂Ca_(1.8)Ni_(0.2)Co_(1.9)Fe_(0.1)O₉ 201 8.2 1.1Bi₂Ca_(1.8)Cu_(0.2)Co_(1.9)Fe_(0.1)O₉ 207 8.3 1.2Bi₂Ca_(1.8)Zn_(0.2)Co_(1.9)Fe_(0.1)O₉ 190 8.6 1.4Bi₂Ca_(1.8)Pb_(0.2)Co_(1.9)Fe_(0.1)O₉ 201 8.7 0.8Bi₂Ca_(1.8)Sr_(0.2)Co_(1.9)Fe_(0.1)O₉ 208 8.3 1.3Bi₂Ca_(1.8)Ba_(0.2)Co_(1.9)Fe_(0.1)O₉ 198 9 1.2Bi₂Ca_(1.8)Al_(0.2)Co_(1.9)Fe_(0.1)O₉ 199 7.9 1.1Bi₂Ca_(1.8)Y_(0.2)Co_(1.9)Fe_(0.1)O₉ 200 8.1 1.4Bi₂Ca_(1.8)La_(0.2)Co_(1.9)Fe_(0.1)O₉ 199 8 1.2Bi₂Ca_(1.8)Ce_(0.2)Co_(1.9)Fe_(0.1)O₉ 210 7.8 0.9Bi₂Ca_(1.8)Pr_(0.2)Co_(1.9)Fe_(0.1)O₉ 202 7.2 1.1Bi₂Ca_(1.8)Nd_(0.2)Co_(1.9)Fe_(0.1)O₉ 204 9 1.2Bi₂Ca_(1.8)Sm_(0.2)Co_(1.9)Fe_(0.1)O₉ 197 7.8 0.9

TABLE 39 Bi₂Ca_(1.8)Eu_(0.2)Co_(1.9)Fe_(0.1)O₉ 190 7.5 1.1Bi₂Ca_(1.8)Gd_(0.2)Co_(1.9)Fe_(0.1)O₉ 198 8.6 1.2Bi₂Ca_(1.8)Dy_(0.2)Co_(1.9)Fe_(0.1)O₉ 199 8.2 1.4Bi₂Ca_(1.8)Ho_(0.2)Co_(1.9)Fe_(0.1)O₉ 201 7.9 0.8Bi₂Ca_(1.8)Er_(0.2)Co_(1.9)Fe_(0.1)O₉ 207 6.9 1.3Bi₂Ca_(1.8)Yb_(0.2)Co_(1.9)Fe_(0.1)O₉ 190 9 1.2Bi₂Pb_(0.2)Ca₂Co_(1.9)Fe_(0.1)O₉ 200 7.5 0.8Bi₂Pb_(0.2)Ca_(1.8)Na_(0.2)Co_(1.9)Fe_(0.1)O₉ 203 8.6 1.3Bi₂Pb_(0.2)Ca_(1.8)K_(0.2)Co_(1.9)Fe_(0.1)O₉ 201 8.2 1.4Bi₂Pb_(0.2)Ca_(1.8)Li_(0.2)Co_(1.9)Fe_(0.1)O₉ 208 7.9 1.1Bi₂Pb_(0.2)Ca_(1.8)Ti_(0.2)Co_(1.9)Fe_(0.1)O₉ 198 6.9 1Bi₂Pb_(0.2)Ca_(1.8)V_(0.2)Co_(1.9)Fe_(0.1)O₉ 199 8.1 1.3Bi₂Pb_(0.2)Ca_(1.8)Cr_(0.2)Co_(1.9)Fe_(0.1)O₉ 200 6.9 0.9Bi₂Pb_(0.2)Ca_(1.8)Mn_(0.2)Co_(1.9)Fe_(0.1)O₉ 199 7.4 1.1Bi₂Pb_(0.2)Ca_(1.8)Fe_(0.2)Co_(1.9)Fe_(0.1)O₉ 210 7.8 1.4Bi₂Pb_(0.2)Ca_(1.8)Ni_(0.2)Co_(1.9)Fe_(0.1)O₉ 202 7.7 1.2Bi₂Pb_(0.2)Ca_(1.8)Cu_(0.2)Co_(1.9)Fe_(0.1)O₉ 204 8 0.9Bi₂Pb_(0.2)Ca_(1.8)Zn_(0.2)Co_(1.9)Fe_(0.1)O₉ 197 8.2 1.1Bi₂Pb_(0.2)Ca_(1.8)Pb_(0.2)Co_(1.9)Fe_(0.1)O₉ 190 7.9 1.2Bi₂Pb_(0.2)Ca_(1.8)Sr_(0.2)Co_(1.9)Fe_(0.1)O₉ 198 9.1 0.9Bi₂Pb_(0.2)Ca_(1.8)Ba_(0.2)Co_(1.9)Fe_(0.1)O₉ 199 8.4 1.1Bi₂Pb_(0.2)Ca_(1.8)Al_(0.2)Co_(1.9)Fe_(0.1)O₉ 201 8.6 1.2Bi₂Pb_(0.2)Ca_(1.8)Y_(0.2)Co_(1.9)Fe_(0.1)O₉ 207 8.2 1Bi₂Pb_(0.2)Ca_(1.8)La_(0.2)Co_(1.9)Fe_(0.1)O₉ 190 7.9 1.3Bi₂Pb_(0.2)Ca_(1.8)Ce_(0.2)Co_(1.9)Fe_(0.1)O₉ 198 8.6 1Bi₂Pb_(0.2)Ca_(1.8)Pr_(0.2)Co_(1.9)Fe_(0.1)O₉ 199 9.1 0.9Bi₂Pb_(0.2)Ca_(1.8)Nd_(0.2)Co_(1.9)Fe_(0.1)O₉ 201 6.9 1.1Bi₂Pb_(0.2)Ca_(1.8)Sm_(0.2)Co_(1.9)Fe_(0.1)O₉ 210 7.4 1Bi₂Pb_(0.2)Ca_(1.8)Eu_(0.2)Co_(1.9)Fe_(0.1)O₉ 206 7.8 1.2Bi₂Pb_(0.2)Ca_(1.8)Gd_(0.2)Co_(1.9)Fe_(0.1)O₉ 205 7.7 1.1Bi₂Pb_(0.2)Ca_(1.8)Dy_(0.2)Co_(1.9)Fe_(0.1)O₉ 198 8 0.9Bi₂Pb_(0.2)Ca_(1.8)Ho_(0.2)Co_(1.9)Fe_(0.1)O₉ 195 8.2 0.8Bi₂Pb_(0.2)Ca_(1.8)Er_(0.2)Co_(1.9)Fe_(0.1)O₉ 200 7.9 1Bi₂Pb_(0.2)Ca_(1.8)Yb_(0.2)Co_(1.9)Fe_(0.1)O₉ 203 9.1 1.3Bi₂Ba₂Co_(1.9)Fe_(0.1)O₉ 208 8.6 1.3

TABLE 40 Bi₂Ba_(1.8)Na_(0.2)Co_(1.9)Fe_(0.1)O₉ 201 7.8 0.9Bi₂Ba_(1.8)K_(0.2)Co_(1.9)Fe_(0.1)O₉ 190 9 1.1Bi₂Ba_(1.8)Li_(0.2)Co_(1.9)Fe_(0.1)O₉ 198 8.2 1.4Bi₂Ba_(1.8)Ti_(0.2)Co_(1.9)Fe_(0.1)O₉ 199 9.1 1.2Bi₂Ba_(1.8)V_(0.2)Co_(1.9)Fe_(0.1)O₉ 201 8.4 0.9Bi₂Ba_(1.8)Cr_(0.2)Co_(1.9)Fe_(0.1)O₉ 200 8.6 1.1Bi₂Ba_(1.8)Mn_(0.2)Co_(1.9)Fe_(0.1)O₉ 206 7.8 1.2Bi₂Ba_(1.8)Fe_(0.2)Co_(1.9)Fe_(0.1)O₉ 205 9 0.9Bi₂Ba_(1.8)Ni_(0.2)Co_(1.9)Fe_(0.1)O₉ 198 8.2 1.1Bi₂Ba_(1.8)Cu_(0.2)Co_(1.9)Fe_(0.1)O₉ 201 8.3 1.2Bi₂Ba_(1.8)Zn_(0.2)Co_(1.9)Fe_(0.1)O₉ 196 8.6 1Bi₂Ba_(1.8)Pb_(0.2)Co_(1.9)Fe_(0.1)O₉ 202 8.7 1.3Bi₂Ba_(1.8)Ca_(0.2)Co_(1.9)Fe_(0.1)O₉ 203 8.3 1Bi₂Ba_(1.8)Sr_(0.2)Co_(1.9)Fe_(0.1)O₉ 205 9 0.9Bi₂Ba_(1.8)Al_(0.2)Co_(1.9)Fe_(0.1)O₉ 198 7.9 1.1Bi₂Ba_(1.8)Y_(0.2)Co_(1.9)Fe_(0.1)O₉ 195 8.1 1Bi₂Ba_(1.8)La_(0.2)Co_(1.9)Fe_(0.1)O₉ 200 8 0.9Bi₂Ba_(1.8)Ce_(0.2)Co_(1.9)Fe_(0.1)O₉ 205 7.8 1.1Bi₂Ba_(1.8)Pr_(0.2)Co_(1.9)Fe_(0.1)O₉ 198 7.2 1.4Bi₂Ba_(1.8)Nd_(0.2)Co_(1.9)Fe_(0.1)O₉ 199 9 1.2Bi₂Ba_(1.8)Sm_(0.2)Co_(1.9)Fe_(0.1)O₉ 210 8.2 0.9Bi₂Ba_(1.8)Eu_(0.2)Co_(1.9)Fe_(0.1)O₉ 202 7.9 1.1Bi₂Ba_(1.8)Gd_(0.2)Co_(1.9)Fe_(0.1)O₉ 204 6.9 1.2Bi₂Ba_(1.8)Dy_(0.2)Co_(1.9)Fe_(0.1)O₉ 197 8.1 0.9Bi₂Ba_(1.8)Ho_(0.2)Co_(1.9)Fe_(0.1)O₉ 190 6.9 1.1Bi₂Ba_(1.8)Er_(0.2)Co_(1.9)Fe_(0.1)O₉ 198 7.4 1.2Bi₂Ba_(1.8)Yb_(0.2)Co_(1.9)Fe_(0.1)O₉ 199 7.8 1.4Bi₂Pb_(0.2)Ba₂Co_(1.9)Fe_(0.1)O₉ 207 8 1.3Bi₂Pb_(0.2)Ba_(1.8)Na_(0.2)Co_(1.9)Fe_(0.1)O₉ 190 8.2 1.2Bi₂Pb_(0.2)Ba_(1.8)K_(0.2)Co_(1.9)Fe_(0.1)O₉ 198 7.9 1.1Bi₂Pb_(0.2)Ba_(1.8)Li_(0.2)Co_(1.9)Fe_(0.1)O₉ 199 9.1 1.4Bi₂Pb_(0.2)Ba_(1.8)Ti_(0.2)Co_(1.9)Fe_(0.1)O₉ 201 8.4 1.2Bi₂Pb_(0.2)Ba_(1.8)V_(0.2)Co_(1.9)Fe_(0.1)O₉ 210 8.6 0.9Bi₂Pb_(0.2)Ba_(1.8)Cr_(0.2)Co_(1.9)Fe_(0.1)O₉ 206 8.2 1.1Bi₂Pb_(0.2)Ba_(1.8)Mn_(0.2)Co_(1.9)Fe_(0.1)O₉ 205 7.9 1.2Bi₂Pb_(0.2)Ba_(1.8)Fe_(0.2)Co_(1.9)Fe_(0.1)O₉ 198 8.6 0.9

TABLE 41 Bi₂Pb_(0.2)Ba_(1.8)Ni_(0.2)Co_(1.9)Fe_(0.1)O₉ 195 9.1 1.1Bi₂Pb_(0.2)Ba_(1.8)Cu_(0.2)Co_(1.9)Fe_(0.1)O₉ 200 6.9 1.2Bi₂Pb_(0.2)Ba_(1.8)Zn_(0.2)Co_(1.9)Fe_(0.1)O₉ 203 7.4 1.4Bi₂Pb_(0.2)Ba_(1.8)Pb_(0.2)Co_(1.9)Fe_(0.1)O₉ 201 7.8 0.8Bi₂Pb_(0.2)Ba_(1.8)Ca_(0.2)Co_(1.9)Fe_(0.1)O₉ 208 7.7 1.3Bi₂Pb_(0.2)Ba_(1.8)Sr_(0.2)Co_(1.9)Fe_(0.1)O₉ 198 8 1.2Bi₂Pb_(0.2)Ba_(1.8)Al_(0.2)Co_(1.9)Fe_(0.1)O₉ 199 8.2 1.1Bi₂Pb_(0.2)Ba_(1.8)Y_(0.2)Co_(1.9)Fe_(0.1)O₉ 200 7.9 0.8Bi₂Pb_(0.2)Ba_(1.8)La_(0.2)Co_(1.9)Fe_(0.1)O₉ 206 9.1 1.3Bi₂Pb_(0.2)Ba_(1.8)Ce_(0.2)Co_(1.9)Fe_(0.1)O₉ 205 8.4 1.4Bi₂Pb_(0.2)Ba_(1.8)Pr_(0.2)Co_(1.9)Fe_(0.1)O₉ 198 8.6 1.1Bi₂Pb_(0.2)Ba_(1.8)Nd_(0.2)Co_(1.9)Fe_(0.1)O₉ 206 7.8 1Bi₂Pb_(0.2)Ba_(1.8)Sm_(0.2)Co_(1.9)Fe_(0.1)O₉ 198 9 1.3Bi₂Pb_(0.2)Ba_(1.8)Eu_(0.2)Co_(1.9)Fe_(0.1)O₉ 207 8.2 0.9Bi₂Pb_(0.2)Ba_(1.8)Gd_(0.2)Co_(1.9)Fe_(0.1)O₉ 190 8.3 1.1Bi₂Pb_(0.2)Ba_(1.8)Dy_(0.2)Co_(1.9)Fe_(0.1)O₉ 198 8.4 1.4Bi₂Pb_(0.2)Ba_(1.8)Ho_(0.2)Co_(1.9)Fe_(0.1)O₉ 199 8.6 1.2Bi₂Pb_(0.2)Ba_(1.8)Er_(0.2)Co_(1.9)Fe_(0.1)O₉ 201 8.2 0.9Bi₂Pb_(0.2)Ba_(1.8)Yb_(0.2)Co_(1.9)Fe_(0.1)O₉ 210 7.9 1.1Bi₂Sr₂Co_(1.9)Ni_(0.1)O₉ 205 9.1 0.9Bi₂Sr_(1.8)Na_(0.2)Co_(1.9)Ni_(0.1)O₉ 198 6.9 1.1Bi₂Sr_(1.8)K_(0.2)Co_(1.9)Ni_(0.1)O₉ 195 7.4 1.2Bi₂Sr_(1.8)Li_(0.2)Co_(1.9)Ni_(0.1)O₉ 200 7.8 1Bi₂Sr_(1.8)Ti_(0.2)Co_(1.9)Ni_(0.1)O₉ 203 7.7 1.3Bi₂Sr_(1.8)V_(0.2)Co_(1.9)Ni_(0.1)O₉ 201 8 1Bi₂Sr_(1.8)Cr_(0.2)Co_(1.9)Ni_(0.1)O₉ 208 8.2 0.9Bi₂Sr_(1.8)Mn_(0.2)Co_(1.9)Ni_(0.1)O₉ 198 7.9 1.1Bi₂Sr_(1.8)Fe_(0.2)Co_(1.9)Ni_(0.1)O₉ 199 9.1 1Bi₂Sr_(1.8)Ni_(0.2)Co_(1.9)Ni_(0.1)O₉ 200 8.4 1.2Bi₂Sr_(1.8)Cu_(0.2)Co_(1.9)Ni_(0.1)O₉ 206 8.6 1.1Bi₂Sr_(1.8)Zn_(0.2)Co_(1.9)Ni_(0.1)O₉ 205 7.8 0.9Bi₂Sr_(1.8)Pb_(0.2)Co_(1.9)Ni_(0.1)O₉ 198 9 0.8Bi₂Sr_(1.8)Ca_(0.2)Co_(1.9)Ni_(0.1)O₉ 206 8.2 1Bi₂Sr_(1.8)Ba_(0.2)Co_(1.9)Ni_(0.1)O₉ 198 8.3 1.3Bi₂Sr_(1.8)Al_(0.2)Co_(1.9)Ni_(0.1)O₉ 195 8.6 1.2Bi₂Sr_(1.8)Y_(0.2)Co_(1.9)Ni_(0.1)O₉ 200 8.7 1.3

TABLE 42 Bi₂Sr_(1.8)La_(0.2)Co_(1.9)Ni_(0.1)O₉ 203 8.3 1Bi₂Sr_(1.8)Ce_(0.2)Co_(1.9)Ni_(0.1)O₉ 201 9 1.3Bi₂Sr_(1.8)Pr_(0.2)Co_(1.9)Ni_(0.1)O₉ 208 7.9 0.9Bi₂Sr_(1.8)Nd_(0.2)Co_(1.9)Ni_(0.1)O₉ 198 8.1 1.1Bi₂Sr_(1.8)Sm_(0.2)Co_(1.9)Ni_(0.1)O₉ 199 8 1.4Bi₂Sr_(1.8)Eu_(0.2)Co_(1.9)Ni_(0.1)O₉ 200 7.8 1.2Bi₂Sr_(1.8)Gd_(0.2)Co_(1.9)Ni_(0.1)O₉ 199 7.2 0.9Bi₂Sr_(1.8)Dy_(0.2)Co_(1.9)Ni_(0.1)O₉ 210 9 1.1Bi₂Sr_(1.8)Ho_(0.2)Co_(1.9)Ni_(0.1)O₉ 202 8.2 1.2Bi₂Sr_(1.8)Er_(0.2)Co_(1.9)Ni_(0.1)O₉ 204 7.9 0.9Bi₂Sr_(1.8)Yb_(0.2)Co_(1.9)Ni_(0.1)O₉ 197 6.9 1.1Bi₂Pb_(0.2)Sr₂Co_(1.9)Ni_(0.1)O₉ 208 6.9 1.4Bi₂Pb_(0.2)Sr_(1.8)Na_(0.2)Co_(1.9)Ni_(0.1)O₉ 198 7.4 0.8Bi₂Pb_(0.2)Sr_(1.8)K_(0.2)Co_(1.9)Ni_(0.1)O₉ 199 7.8 1.3Bi₂Pb_(0.2)Sr_(1.8)Li_(0.2)Co_(1.9)Ni_(0.1)O₉ 200 7.7 1.2Bi₂Pb_(0.2)Sr_(1.8)Ti_(0.2)Co_(1.9)Ni_(0.1)O₉ 199 8 1.1Bi₂Pb_(0.2)Sr_(1.8)V_(0.2)Co_(1.9)Ni_(0.1)O₉ 210 8.2 0.8Bi₂Pb_(0.2)Sr_(1.8)Cr_(0.2)Co_(1.9)Ni_(0.1)O₉ 202 7.9 0.7Bi₂Pb_(0.2)Sr_(1.8)Mn_(0.2)Co_(1.9)Ni_(0.1)O₉ 204 9.1 1.3Bi₂Pb_(0.2)Sr_(1.8)Fe_(0.2)Co_(1.9)Ni_(0.1)O₉ 197 8.4 0.8Bi₂Pb_(0.2)Sr_(1.8)Ni_(0.2)Co_(1.9)Ni_(0.1)O₉ 190 8.6 1.1Bi₂Pb_(0.2)Sr_(1.8)Cu_(0.2)Co_(1.9)Ni_(0.1)O₉ 198 8.2 1.4Bi₂Pb_(0.2)Sr_(1.8)Zn_(0.2)Co_(1.9)Ni_(0.1)O₉ 199 7.9 1.2Bi₂Pb_(0.2)Sr_(1.8)Pb_(0.2)Co_(1.9)Ni_(0.1)O₉ 201 8.6 0.9Bi₂Pb_(0.2)Sr_(1.8)Ca_(0.2)Co_(1.9)Ni_(0.1)O₉ 207 9.1 1.1Bi₂Pb_(0.2)Sr_(1.8)Ba_(0.2)Co_(1.9)Ni_(0.1)O₉ 190 6.9 1.2Bi₂Pb_(0.2)Sr_(1.8)Al_(0.2)Co_(1.9)Ni_(0.1)O₉ 198 7.4 0.9Bi₂Pb_(0.2)Sr_(1.8)Y_(0.2)Co_(1.9)Ni_(0.1)O₉ 199 7.8 1.1Bi₂Pb_(0.2)Sr_(1.8)La_(0.2)Co_(1.9)Ni_(0.1)O₉ 201 7.7 1.2Bi₂Pb_(0.2)Sr_(1.8)Ce_(0.2)Co_(1.9)Ni_(0.1)O₉ 210 8 1.4Bi₂Pb_(0.2)Sr_(1.8)Pr_(0.2)Co_(1.9)Ni_(0.1)O₉ 206 8.2 0.8Bi₂Pb_(0.2)Sr_(1.8)Nd_(0.2)Co_(1.9)Ni_(0.1)O₉ 205 7.9 1.3Bi₂Pb_(0.2)Sr_(1.8)Sm_(0.2)Co_(1.9)Ni_(0.1)O₉ 198 9.1 1.2Bi₂Pb_(0.2)Sr_(1.8)Eu_(0.2)Co_(1.9)Ni_(0.1)O₉ 195 8.4 1.1Bi₂Pb_(0.2)Sr_(1.8)Gd_(0.2)Co_(1.9)Ni_(0.1)O₉ 200 8.6 0.8Bi₂Pb_(0.2)Sr_(1.8)Dy_(0.2)Co_(1.9)Ni_(0.1)O₉ 203 7.8 1.3

TABLE 43 Bi₂Pb_(0.2)Sr_(1.8)Ho_(0.2)Co_(1.9)Ni_(0.1)O₉ 201 9 1.4Bi₂Pb_(0.2)Sr_(1.8)Er_(0.2)Co_(1.9)Ni_(0.1)O₉ 208 8.2 1.1Bi₂Pb_(0.2)Sr_(1.8)Yb_(0.2)Co_(1.9)Ni_(0.1)O₉ 201 8.3 1Bi₂Ca₂Co_(1.9)Ni_(0.1)O₉ 198 8.7 0.9Bi₂Ca_(1.8)Na_(0.2)Co_(1.9)Ni_(0.1)O₉ 199 8.3 1.1Bi₂Ca_(1.8)K_(0.2)Co_(1.9)Ni_(0.1)O₉ 201 9 1.4Bi₂Ca_(1.8)Li_(0.2)Co_(1.9)Ni_(0.1)O₉ 200 7.9 1.2Bi₂Ca_(1.8)Ti_(0.2)Co_(1.9)Ni_(0.1)O₉ 206 8.1 0.9Bi₂Ca_(1.8)V_(0.2)Co_(1.9)Ni_(0.1)O₉ 205 8 1.1Bi₂Ca_(1.8)Cr_(0.2)Co_(1.9)Ni_(0.1)O₉ 198 7.8 1.2Bi₂Ca_(1.8)Mn_(0.2)Co_(1.9)Ni_(0.1)O₉ 201 7.2 0.9Bi₂Ca_(1.8)Fe_(0.2)Co_(1.9)Ni_(0.1)O₉ 196 9 1.1Bi₂Ca_(1.8)Ni_(0.2)Co_(1.9)Ni_(0.1)O₉ 202 7.8 1.2Bi₂Ca_(1.8)Cu_(0.2)Co_(1.9)Ni_(0.1)O₉ 203 7.5 1.4Bi₂Ca_(1.8)Zn_(0.2)Co_(1.9)Ni_(0.1)O₉ 205 8.6 0.8Bi₂Ca_(1.8)Pb_(0.2)Co_(1.9)Ni_(0.1)O₉ 198 8.2 1.3Bi₂Ca_(1.8)Sr_(0.2)Co_(1.9)Ni_(0.1)O₉ 195 7.9 1.2Bi₂Ca_(1.8)Ba_(0.2)Co_(1.9)Ni_(0.1)O₉ 200 6.9 1.1Bi₂Ca_(1.8)Al_(0.2)Co_(1.9)Ni_(0.1)O₉ 205 9 1.4Bi₂Ca_(1.8)Y_(0.2)Co_(1.9)Ni_(0.1)O₉ 198 7.8 1.2Bi₂Ca_(1.8)La_(0.2)Co_(1.9)Ni_(0.1)O₉ 199 7.5 0.9Bi₂Ca_(1.8)Ce_(0.2)Co_(1.9)Ni_(0.1)O₉ 210 8.6 1.1Bi₂Ca_(1.8)Pr_(0.2)Co_(1.9)Ni_(0.1)O₉ 202 8.2 1.2Bi₂Ca_(1.8)Nd_(0.2)Co_(1.9)Ni_(0.1)O₉ 204 7.9 0.9Bi₂Ca_(1.8)Sm_(0.2)Co_(1.9)Ni_(0.1)O₉ 197 6.9 1.1Bi₂Ca_(1.8)Eu_(0.2)Co_(1.9)Ni_(0.1)O₉ 190 8.1 1.2Bi₂Ca_(1.8)Gd_(0.2)Co_(1.9)Ni_(0.1)O₉ 198 6.9 1.4Bi₂Ca_(1.8)Dy_(0.2)Co_(1.9)Ni_(0.1)O₉ 199 7.4 0.8Bi₂Ca_(1.8)Ho_(0.2)Co_(1.9)Ni_(0.1)O₉ 201 7.8 1.3Bi₂Ca_(1.8)Er_(0.2)Co_(1.9)Ni_(0.1)O₉ 207 7.7 1.2Bi₂Ca_(1.8)Yb_(0.2)Co_(1.9)Ni_(0.1)O₉ 190 8 1.1Bi₂Pb_(0.2)Ca₂Co_(1.9)Ni_(0.1)O₉ 199 7.9 1.3Bi₂Pb_(0.2)Ca_(1.8)Na_(0.2)Co_(1.9)Ni_(0.1)O₉ 201 9.1 1.4Bi₂Pb_(0.2)Ca_(1.8)K_(0.2)Co_(1.9)Ni_(0.1)O₉ 210 8.4 1.1Bi₂Pb_(0.2)Ca_(1.8)Li_(0.2)Co_(1.9)Ni_(0.1)O₉ 206 8.6 1

TABLE 44 Bi₂Pb_(0.2)Ca_(1.8)Ti_(0.2)Co_(1.9)Ni_(0.1)O₉ 205 8.2 1.3Bi₂Pb_(0.2)Ca_(1.8)V_(0.2)Co_(1.9)Ni_(0.1)O₉ 198 7.9 0.9Bi₂Pb_(0.2)Ca_(1.8)Cr_(0.2)Co_(1.9)Ni_(0.1)O₉ 195 8.6 1.1Bi₂Pb_(0.2)Ca_(1.8)Mn_(0.2)Co_(1.9)Ni_(0.1)O₉ 200 9.1 1.4Bi₂Pb_(0.2)Ca_(1.8)Fe_(0.2)Co_(1.9)Ni_(0.1)O₉ 203 6.9 1.2Bi₂Pb_(0.2)Ca_(1.8)Ni_(0.2)Co_(1.9)Ni_(0.1)O₉ 201 7.4 0.9Bi₂Pb_(0.2)Ca_(1.8)Cu_(0.2)Co_(1.9)Ni_(0.1)O₉ 208 7.8 1.1Bi₂Pb_(0.2)Ca_(1.8)Zn_(0.2)Co_(1.9)Ni_(0.1)O₉ 198 7.7 1.2Bi₂Pb_(0.2)Ca_(1.8)Pb_(0.2)Co_(1.9)Ni_(0.1)O₉ 199 8 0.9Bi₂Pb_(0.2)Ca_(1.8)Sr_(0.2)Co_(1.9)Ni_(0.1)O₉ 200 8.2 1.1Bi₂Pb_(0.2)Ca_(1.8)Ba_(0.2)Co_(1.9)Ni_(0.1)O₉ 206 7.9 1.2Bi₂Pb_(0.2)Ca_(1.8)Al_(0.2)Co_(1.9)Ni_(0.1)O₉ 205 9.1 1Bi₂Pb_(0.2)Ca_(1.8)Y_(0.2)Co_(1.9)Ni_(0.1)O₉ 198 8.4 1.3Bi₂Pb_(0.2)Ca_(1.8)La_(0.2)Co_(1.9)Ni_(0.1)O₉ 206 8.6 1Bi₂Pb_(0.2)Ca_(1.8)Ce_(0.2)Co_(1.9)Ni_(0.1)O₉ 198 7.8 0.9Bi₂Pb_(0.2)Ca_(1.8)Pr_(0.2)Co_(1.9)Ni_(0.1)O₉ 207 9 1.1Bi₂Pb_(0.2)Ca_(1.8)Nd_(0.2)Co_(1.9)Ni_(0.1)O₉ 190 8.2 1Bi₂Pb_(0.2)Ca_(1.8)Sm_(0.2)Co_(1.9)Ni_(0.1)O₉ 198 9.1 1.2Bi₂Pb_(0.2)Ca_(1.8)Eu_(0.2)Co_(1.9)Ni_(0.1)O₉ 199 8.4 1.1Bi₂Pb_(0.2)Ca_(1.8)Gd_(0.2)Co_(1.9)Ni_(0.1)O₉ 201 8.6 0.9Bi₂Pb_(0.2)Ca_(1.8)Dy_(0.2)Co_(1.9)Ni_(0.1)O₉ 210 7.8 0.8Bi₂Pb_(0.2)Ca_(1.8)Ho_(0.2)Co_(1.9)Ni_(0.1)O₉ 206 9 1Bi₂Pb_(0.2)Ca_(1.8)Er_(0.2)Co_(1.9)Ni_(0.1)O₉ 205 8.4 1.3Bi₂Pb_(0.2)Ca_(1.8)Yb_(0.2)Co_(1.9)Ni_(0.1)O₉ 198 8.6 1.2Bi₂Ba₂Co_(1.9)Ni_(0.1)O₉ 200 9 0.9 Bi₂Ba_(1.8)Na_(0.2)Co_(1.9)Ni_(0.1)O₉203 8.2 1.1 Bi₂Ba_(1.8)K_(0.2)Co_(1.9)Ni_(0.1)O₉ 201 8.3 1.4Bi₂Ba_(1.8)Li_(0.2)Co_(1.9)Ni_(0.1)O₉ 208 8.6 1.2Bi₂Ba_(1.8)Ti_(0.2)Co_(1.9)Ni_(0.1)O₉ 198 8.7 0.9Bi₂Ba_(1.8)V_(0.2)Co_(1.9)Ni_(0.1)O₉ 199 8.3 1.1Bi₂Ba_(1.8)Cr_(0.2)Co_(1.9)Ni_(0.1)O₉ 200 9 1.2Bi₂Ba_(1.8)Mn_(0.2)Co_(1.9)Ni_(0.1)O₉ 206 7.9 0.9Bi₂Ba_(1.8)Fe_(0.2)Co_(1.9)Ni_(0.1)O₉ 205 8.1 1.1Bi₂Ba_(1.8)Ni_(0.2)Co_(1.9)Ni_(0.1)O₉ 198 8 1.2Bi₂Ba_(1.8)Cu_(0.2)Co_(1.9)Ni_(0.1)O₉ 199 7.8 1Bi₂Ba_(1.8)Zn_(0.2)Co_(1.9)Ni_(0.1)O₉ 200 7.2 1.3

TABLE 45 Bi₂Ba_(1.8)Pb_(0.2)Co_(1.9)Ni_(0.1)O₉ 199 9 1Bi₂Ba_(1.8)Ca_(0.2)Co_(1.9)Ni_(0.1)O₉ 210 7.8 0.9Bi₂Ba_(1.8)Sr_(0.2)Co_(1.9)Ni_(0.1)O₉ 202 7.5 1.1Bi₂Ba_(1.8)Al_(0.2)Co_(1.9)Ni_(0.1)O₉ 204 8.6 1Bi₂Ba_(1.8)Y_(0.2)Co_(1.9)Ni_(0.1)O₉ 197 8.2 1.2Bi₂Ba_(1.8)La_(0.2)Co_(1.9)Ni_(0.1)O₉ 190 7.9 1.1Bi₂Ba_(1.8)Ce_(0.2)Co_(1.9)Ni_(0.1)O₉ 198 6.9 0.9Bi₂Ba_(1.8)Pr_(0.2)Co_(1.9)Ni_(0.1)O₉ 199 9 0.8Bi₂Ba_(1.8)Nd_(0.2)Co_(1.9)Ni_(0.1)O₉ 201 7.8 1Bi₂Ba_(1.8)Sm_(0.2)Co_(1.9)Ni_(0.1)O₉ 207 7.5 1.3Bi₂Ba_(1.8)Eu_(0.2)Co_(1.9)Ni_(0.1)O₉ 190 8.6 1.2Bi₂Ba_(1.8)Gd_(0.2)Co_(1.9)Ni_(0.1)O₉ 198 8.2 0.7Bi₂Ba_(1.8)Dy_(0.2)Co_(1.9)Ni_(0.1)O₉ 199 7.9 1.3Bi₂Ba_(1.8)Ho_(0.2)Co_(1.9)Ni_(0.1)O₉ 201 6.9 1.4Bi₂Ba_(1.8)Er_(0.2)Co_(1.9)Ni_(0.1)O₉ 210 8.1 1.1Bi₂Ba_(1.8)Yb_(0.2)Co_(1.9)Ni_(0.1)O₉ 206 6.9 1Bi₂Pb_(0.2)Ba₂Co_(1.9)Ni_(0.1)O₉ 198 7.8 0.9Bi₂Pb_(0.2)Ba_(1.8)Na_(0.2)Co_(1.9)Ni_(0.1)O₉ 195 7.7 1.1Bi₂Pb_(0.2)Ba_(1.8)K_(0.2)Co_(1.9)Ni_(0.1)O₉ 200 8 1.4Bi₂Pb_(0.2)Ba_(1.8)Li_(0.2)Co_(1.9)Ni_(0.1)O₉ 203 8.2 1.2Bi₂Pb_(0.2)Ba_(1.8)Ti_(0.2)Co_(1.9)Ni_(0.1)O₉ 201 7.9 0.9Bi₂Pb_(0.2)Ba_(1.8)V_(0.2)Co_(1.9)Ni_(0.1)O₉ 196 9.1 1.1Bi₂Pb_(0.2)Ba_(1.8)Cr_(0.2)Co_(1.9)Ni_(0.1)O₉ 202 8.4 1.2Bi₂Pb_(0.2)Ba_(1.8)Mn_(0.2)Co_(1.9)Ni_(0.1)O₉ 203 8.6 0.9Bi₂Pb_(0.2)Ba_(1.8)Fe_(0.2)Co_(1.9)Ni_(0.1)O₉ 205 8.2 1.1Bi₂Pb_(0.2)Ba_(1.8)Ni_(0.2)Co_(1.9)Ni_(0.1)O₉ 198 7.9 1.2Bi₂Pb_(0.2)Ba_(1.8)Cu_(0.2)Co_(1.9)Ni_(0.1)O₉ 195 8.6 1.4Bi₂Pb_(0.2)Ba_(1.8)Zn_(0.2)Co_(1.9)Ni_(0.1)O₉ 200 9.1 0.8Bi₂Pb_(0.2)Ba_(1.8)Pb_(0.2)Co_(1.9)Ni_(0.1)O₉ 205 6.9 1.3Bi₂Pb_(0.2)Ba_(1.8)Ca_(0.2)Co_(1.9)Ni_(0.1)O₉ 198 7.4 1.2Bi₂Pb_(0.2)Ba_(1.8)Sr_(0.2)Co_(1.9)Ni_(0.1)O₉ 199 7.8 1.1Bi₂Pb_(0.2)Ba_(1.8)Al_(0.2)Co_(1.9)Ni_(0.1)O₉ 210 7.7 0.8Bi₂Pb_(0.2)Ba_(1.8)Y_(0.2)Co_(1.9)Ni_(0.1)O₉ 202 8 1.3Bi₂Pb_(0.2)Ba_(1.8)La_(0.2)Co_(1.9)Ni_(0.1)O₉ 204 8.2 1.4Bi₂Pb_(0.2)Ba_(1.8)Ce_(0.2)Co_(1.9)Ni_(0.1)O₉ 197 7.9 1.1Bi₂Pb_(0.2)Ba_(1.8)Pr_(0.2)Co_(1.9)Ni_(0.1)O₉ 190 9.1 1

TABLE 46 Bi₂Pb_(0.2)Ba_(1.8)Nd_(0.2)Co_(1.9)Ni_(0.1)O₉ 198 8.4 1.3Bi₂Pb_(0.2)Ba_(1.8)Sm_(0.2)Co_(1.9)Ni_(0.1)O₉ 199 8.6 0.9Bi₂Pb_(0.2)Ba_(1.8)Eu_(0.2)Co_(1.9)Ni_(0.1)O₉ 201 7.8 1.1Bi₂Pb_(0.2)Ba_(1.8)Gd_(0.2)Co_(1.9)Ni_(0.1)O₉ 207 9 1.4Bi₂Pb_(0.2)Ba_(1.8)Dy_(0.2)Co_(1.9)Ni_(0.1)O₉ 190 8.2 1.2Bi₂Pb_(0.2)Ba_(1.8)Ho_(0.2)Co_(1.9)Ni_(0.1)O₉ 198 8.3 0.9Bi₂Pb_(0.2)Ba_(1.8)Er_(0.2)Co_(1.9)Ni_(0.1)O₉ 199 8.6 1.1Bi₂Pb_(0.2)Ba_(1.8)Yb_(0.2)Co_(1.9)Ni_(0.1)O₉ 201 8.7 1.2Bi₂Sr₂Co_(1.9)Cu_(0.1)O₉ 206 9 1.1 Bi₂Sr_(1.8)Na_(0.2)Co_(1.9)Cu_(0.1)O₉205 7.9 1.2 Bi₂Sr_(1.8)K_(0.2)Co_(1.9)Cu_(0.1)O₉ 198 8.1 1.4Bi₂Sr_(1.8)Li_(0.2)Co_(1.9)Cu_(0.1)O₉ 195 8 0.8Bi₂Sr_(1.8)Ti_(0.2)Co_(1.9)Cu_(0.1)O₉ 200 7.8 1.3Bi₂Sr_(1.8)V_(0.2)Co_(1.9)Cu_(0.1)O₉ 203 7.2 1.2Bi₂Sr_(1.8)Cr_(0.2)Co_(1.9)Cu_(0.1)O₉ 201 9 1.1Bi₂Sr_(1.8)Mn_(0.2)Co_(1.9)Cu_(0.1)O₉ 208 8.2 0.8Bi₂Sr_(1.8)Fe_(0.2)Co_(1.9)Cu_(0.1)O₉ 198 7.9 0.7Bi₂Sr_(1.8)Ni_(0.2)Co_(1.9)Cu_(0.1)O₉ 199 6.9 1.3Bi₂Sr_(1.8)Cu_(0.2)Co_(1.9)Cu_(0.1)O₉ 200 8.1 0.8Bi₂Sr_(1.8)Zn_(0.2)Co_(1.9)Cu_(0.1)O₉ 206 6.9 1.3Bi₂Sr_(1.8)Pb_(0.2)Co_(1.9)Cu_(0.1)O₉ 205 7.4 1.2Bi₂Sr_(1.8)Ca_(0.2)Co_(1.9)Cu_(0.1)O₉ 198 7.8 1.1Bi₂Sr_(1.8)Ba_(0.2)Co_(1.9)Cu_(0.1)O₉ 206 7.7 0.8Bi₂Sr_(1.8)Al_(0.2)Co_(1.9)Cu_(0.1)O₉ 198 8 1.3Bi₂Sr_(1.8)Y_(0.2)Co_(1.9)Cu_(0.1)O₉ 207 8.2 1.4Bi₂Sr_(1.8)La_(0.2)Co_(1.9)Cu_(0.1)O₉ 190 7.9 1.1Bi₂Sr_(1.8)Ce_(0.2)Co_(1.9)Cu_(0.1)O₉ 198 9.1 1Bi₂Sr_(1.8)Pr_(0.2)Co_(1.9)Cu_(0.1)O₉ 199 8.4 1.3Bi₂Sr_(1.8)Nd_(0.2)Co_(1.9)Cu_(0.1)O₉ 201 8.6 0.9Bi₂Sr_(1.8)Sm_(0.2)Co_(1.9)Cu_(0.1)O₉ 210 8.2 1.1Bi₂Sr_(1.8)Eu_(0.2)Co_(1.9)Cu_(0.1)O₉ 206 7.9 1.4Bi₂Sr_(1.8)Gd_(0.2)Co_(1.9)Cu_(0.1)O₉ 205 8.6 1.2Bi₂Sr_(1.8)Dy_(0.2)Co_(1.9)Cu_(0.1)O₉ 198 9.1 0.9Bi₂Sr_(1.8)Ho_(0.2)Co_(1.9)Cu_(0.1)O₉ 195 6.9 1.1Bi₂Sr_(1.8)Er_(0.2)Co_(1.9)Cu_(0.1)O₉ 200 7.4 1.2Bi₂Sr_(1.8)Yb_(0.2)Co_(1.9)Cu_(0.1)O₉ 203 7.8 0.9

TABLE 47 Bi₂Pb_(0.2)Sr₂Co_(1.9)Cu_(0.1)O₉ 208 8.0 1.2Bi₂Pb_(0.2)Sr_(1.8)Na_(0.2)Co_(1.9)Cu_(0.1)O₉ 198 8.2 1.4Bi₂Pb_(0.2)Sr_(1.8)K_(0.2)Co_(1.9)Cu_(0.1)O₉ 199 7.9 0.8Bi₂Pb_(0.2)Sr_(1.8)Li_(0.2)Co_(1.9)Cu_(0.1)O₉ 200 9.1 1.3Bi₂Pb_(0.2)Sr_(1.8)Ti_(0.2)Co_(1.9)Cu_(0.1)O₉ 206 8.4 1.2Bi₂Pb_(0.2)Sr_(1.8)V_(0.2)Co_(1.9)Cu_(0.1)O₉ 206 8.6 1.1Bi₂Pb_(0.2)Sr_(1.8)Cr_(0.2)Co_(1.9)Cu_(0.1)O₉ 205 7.8 1.4Bi₂Pb_(0.2)Sr_(1.8)Mn_(0.2)Co_(1.9)Cu_(0.1)O₉ 198 9 1.2Bi₂Pb_(0.2)Sr_(1.8)Fe_(0.2)Co_(1.9)Cu_(0.1)O₉ 195 8.2 0.9Bi₂Pb_(0.2)Sr_(1.8)Ni_(0.2)Co_(1.9)Cu_(0.1)O₉ 200 8.3 1.1Bi₂Pb_(0.2)Sr_(1.8)Cu_(0.2)Co_(1.9)Cu_(0.1)O₉ 203 8.6 1.2Bi₂Pb_(0.2)Sr_(1.8)Zn_(0.2)Co_(1.9)Cu_(0.1)O₉ 201 8.7 0.9Bi₂Pb_(0.2)Sr_(1.8)Pb_(0.2)Co_(1.9)Cu_(0.1)O₉ 208 8.3 1.1Bi₂Pb_(0.2)Sr_(1.8)Ca_(0.2)Co_(1.9)Cu_(0.1)O₉ 198 9 1.2Bi₂Pb_(0.2)Sr_(1.8)Ba_(0.2)Co_(1.9)Cu_(0.1)O₉ 199 7.9 1.4Bi₂Pb_(0.2)Sr_(1.8)Al_(0.2)Co_(1.9)Cu_(0.1)O₉ 200 8.1 0.8Bi₂Pb_(0.2)Sr_(1.8)Y_(0.2)Co_(1.9)Cu_(0.1)O₉ 206 8 1.3Bi₂Pb_(0.2)Sr_(1.8)La_(0.2)Co_(1.9)Cu_(0.1)O₉ 205 7.8 1.2Bi₂Pb_(0.2)Sr_(1.8)Ce_(0.2)Co_(1.9)Cu_(0.1)O₉ 198 7.2 1.1Bi₂Pb_(0.2)Sr_(1.8)Pr_(0.2)Co_(1.9)Cu_(0.1)O₉ 206 9 0.8Bi₂Pb_(0.2)Sr_(1.8)Nd_(0.2)Co_(1.9)Cu_(0.1)O₉ 198 7.8 1.3Bi₂Pb_(0.2)Sr_(1.8)Sm_(0.2)Co_(1.9)Cu_(0.1)O₉ 207 7.5 1.4Bi₂Pb_(0.2)Sr_(1.8)Eu_(0.2)Co_(1.9)Cu_(0.1)O₉ 190 8.6 1.1Bi₂Pb_(0.2)Sr_(1.8)Gd_(0.2)Co_(1.9)Cu_(0.1)O₉ 198 8.2 1Bi₂Pb_(0.2)Sr_(1.8)Dy_(0.2)Co_(1.9)Cu_(0.1)O₉ 199 7.9 1.3Bi₂Pb_(0.2)Sr_(1.8)Ho_(0.2)Co_(1.9)Cu_(0.1)O₉ 201 6.9 0.9Bi₂Pb_(0.2)Sr_(1.8)Er_(0.2)Co_(1.9)Cu_(0.1)O₉ 210 9 1.1Bi₂Pb_(0.2)Sr_(1.8)Yb_(0.2)Co_(1.9)Cu_(0.1)O₉ 206 7.8 1.4Bi₂Ca₂Co_(1.9)Cu_(0.1)O₉ 198 8.6 0.9Bi₂Ca_(1.8)Na_(0.2)Co_(1.9)Cu_(0.1)O₉ 195 8.2 1.1Bi₂Ca_(1.8)K_(0.2)Co_(1.9)Cu_(0.1)O₉ 200 7.9 1.2Bi₂Ca_(1.8)Li_(0.2)Co_(1.9)Cu_(0.1)O₉ 203 6.9 0.9Bi₂Ca_(1.8)Ti_(0.2)Co_(1.9)Cu_(0.1)O₉ 201 8.1 1.1Bi₂Ca_(1.8)V_(0.2)Co_(1.9)Cu_(0.1)O₉ 208 6.9 1.2Bi₂Ca_(1.8)Cr_(0.2)Co_(1.9)Cu_(0.1)O₉ 198 7.4 1

TABLE 48 Bi₂Ca_(1.8)Mn_(0.2)Co_(1.9)Cu_(0.1)O₉ 199 7.8 1.3Bi₂Ca_(1.8)Fe_(0.2)Co_(1.9)Cu_(0.1)O₉ 200 7.7 1Bi₂Ca_(1.8)Ni_(0.2)Co_(1.9)Cu_(0.1)O₉ 206 8 0.9Bi₂Ca_(1.8)Cu_(0.2)Co_(1.9)Cu_(0.1)O₉ 205 8.2 1.1Bi₂Ca_(1.8)Zn_(0.2)Co_(1.9)Cu_(0.1)O₉ 198 7.9 1Bi₂Ca_(1.8)Pb_(0.2)Co_(1.9)Cu_(0.1)O₉ 199 9.1 1.2Bi₂Ca_(1.8)Sr_(0.2)Co_(1.9)Cu_(0.1)O₉ 200 8.4 1.1Bi₂Ca_(1.8)Ba_(0.2)Co_(1.9)Cu_(0.1)O₉ 199 8.6 0.9Bi₂Ca_(1.8)Al_(0.2)Co_(1.9)Cu_(0.1)O₉ 210 8.2 0.8Bi₂Ca_(1.8)Y_(0.2)Co_(1.9)Cu_(0.1)O₉ 202 7.9 1Bi₂Ca_(1.8)La_(0.2)Co_(1.9)Cu_(0.1)O₉ 204 8.6 1.3Bi₂Ca_(1.8)Ce_(0.2)Co_(1.9)Cu_(0.1)O₉ 197 9.1 1.2Bi₂Ca_(1.8)Pr_(0.2)Co_(1.9)Cu_(0.1)O₉ 190 6.9 1.3Bi₂Ca_(1.8)Nd_(0.2)Co_(1.9)Cu_(0.1)O₉ 198 7.4 1Bi₂Ca_(1.8)Sm_(0.2)Co_(1.9)Cu_(0.1)O₉ 199 7.8 0.8Bi₂Ca_(1.8)Eu_(0.2)Co_(1.9)Cu_(0.1)O₉ 201 7.7 1.1Bi₂Ca_(1.8)Gd_(0.2)Co_(1.9)Cu_(0.1)O₉ 207 8 1.2Bi₂Ca_(1.8)Dy_(0.2)Co_(1.9)Cu_(0.1)O₉ 190 8.2 0.9Bi₂Ca_(1.8)Ho_(0.2)Co_(1.9)Cu_(0.1)O₉ 198 7.9 1.1Bi₂Ca_(1.8)Er_(0.2)Co_(1.9)Cu_(0.1)O₉ 199 9.1 1.2Bi₂Ca_(1.8)Yb_(0.2)Co_(1.9)Cu_(0.1)O₉ 201 8.4 1.4Bi₂Pb_(0.2)Ca₂Co_(1.9)Cu_(0.1)O₉ 206 7.8 1.3Bi₂Pb_(0.2)Ca_(1.8)Na_(0.2)Co_(1.9)Cu_(0.1)O₉ 205 9 1.2Bi₂Pb_(0.2)Ca_(1.8)K_(0.2)Co_(1.9)Cu_(0.1)O₉ 198 8.2 1.1Bi₂Pb_(0.2)Ca_(1.8)Li_(0.2)Co_(1.9)Cu_(0.1)O₉ 195 9.1 0.8Bi₂Pb_(0.2)Ca_(1.8)Ti_(0.2)Co_(1.9)Cu_(0.1)O₉ 200 8.4 1.3Bi₂Pb_(0.2)Ca_(1.8)V_(0.2)Co_(1.9)Cu_(0.1)O₉ 203 8.6 1.4Bi₂Pb_(0.2)Ca_(1.8)Cr_(0.2)Co_(1.9)Cu_(0.1)O₉ 200 7.8 1.1Bi₂Pb_(0.2)Ca_(1.8)Mn_(0.2)Co_(1.9)Cu_(0.1)O₉ 203 9 1Bi₂Pb_(0.2)Ca_(1.8)Fe_(0.2)Co_(1.9)Cu_(0.1)O₉ 201 8.2 1.3Bi₂Pb_(0.2)Ca_(1.8)Ni_(0.2)Co_(1.9)Cu_(0.1)O₉ 208 8.3 0.9Bi₂Pb_(0.2)Ca_(1.8)Cu_(0.2)Co_(1.9)Cu_(0.1)O₉ 198 8.6 1.1Bi₂Pb_(0.2)Ca_(1.8)Zn_(0.2)Co_(1.9)Cu_(0.1)O₉ 199 8.7 1.4Bi₂Pb_(0.2)Ca_(1.8)Pb_(0.2)Co_(1.9)Cu_(0.1)O₉ 200 8.3 1.2Bi₂Pb_(0.2)Ca_(1.8)Sr_(0.2)Co_(1.9)Cu_(0.1)O₉ 206 9 0.9Bi₂Pb_(0.2)Ca_(1.8)Ba_(0.2)Co_(1.9)Cu_(0.1)O₉ 205 7.9 1.1

TABLE 49 Bi₂Pb_(0.2)Ca_(1.8)Al_(0.2)Co_(1.9)Cu_(0.1)O₉ 198 8.1 1.2Bi₂Pb_(0.2)Ca_(1.8)Y_(0.2)Co_(1.9)Cu_(0.1)O₉ 206 8 0.9Bi₂Pb_(0.2)Ca_(1.8)La_(0.2)Co_(1.9)Cu_(0.1)O₉ 198 7.8 1.1Bi₂Pb_(0.2)Ca_(1.8)Ce_(0.2)Co_(1.9)Cu_(0.1)O₉ 207 7.2 1.2Bi₂Pb_(0.2)Ca_(1.8)Pr_(0.2)Co_(1.9)Cu_(0.1)O₉ 190 9 1.4Bi₂Pb_(0.2)Ca_(1.8)Nd_(0.2)Co_(1.9)Cu_(0.1)O₉ 198 8.2 0.8Bi₂Pb_(0.2)Ca_(1.8)Sm_(0.2)Co_(1.9)Cu_(0.1)O₉ 199 7.9 1.3Bi₂Pb_(0.2)Ca_(1.8)Eu_(0.2)Co_(1.9)Cu_(0.1)O₉ 201 6.9 1.2Bi₂Pb_(0.2)Ca_(1.8)Gd_(0.2)Co_(1.9)Cu_(0.1)O₉ 210 8.1 1.1Bi₂Pb_(0.2)Ca_(1.8)Dy_(0.2)Co_(1.9)Cu_(0.1)O₉ 206 6.9 1.4Bi₂Pb_(0.2)Ca_(1.8)Ho_(0.2)Co_(1.9)Cu_(0.1)O₉ 205 7.4 1.2Bi₂Pb_(0.2)Ca_(1.8)Er_(0.2)Co_(1.9)Cu_(0.1)O₉ 198 7.8 0.9Bi₂Pb_(0.2)Ca_(1.8)Yb_(0.2)Co_(1.9)Cu_(0.1)O₉ 195 7.7 1.1Bi₂Ba₂Co_(1.9)Cu_(0.1)O₉ 203 8.2 0.9Bi₂Ba_(1.8)Na_(0.2)Co_(1.9)Cu_(0.1)O₉ 201 7.9 1.1Bi₂Ba_(1.8)K_(0.2)Co_(1.9)Cu_(0.1)O₉ 208 9.1 1.2Bi₂Ba_(1.8)Li_(0.2)Co_(1.9)Cu_(0.1)O₉ 198 8.4 1.4Bi₂Ba_(1.8)Ti_(0.2)Co_(1.9)Cu_(0.1)O₉ 199 8.6 0.8Bi₂Ba_(1.8)V_(0.2)Co_(1.9)Cu_(0.1)O₉ 200 8.2 1.3Bi₂Ba_(1.8)Cr_(0.2)Co_(1.9)Cu_(0.1)O₉ 206 7.9 1.2Bi₂Ba_(1.8)Mn_(0.2)Co_(1.9)Cu_(0.1)O₉ 206 8.6 1.1Bi₂Ba_(1.8)Fe_(0.2)Co_(1.9)Cu_(0.1)O₉ 198 9.1 0.8Bi₂Ba_(1.8)Ni_(0.2)Co_(1.9)Cu_(0.1)O₉ 199 6.9 1.3Bi₂Ba_(1.8)Cu_(0.2)Co_(1.9)Cu_(0.1)O₉ 200 7.4 1.4Bi₂Ba_(1.8)Zn_(0.2)Co_(1.9)Cu_(0.1)O₉ 206 7.8 1.1Bi₂Ba_(1.8)Pb_(0.2)Co_(1.9)Cu_(0.1)O₉ 205 7.7 1Bi₂Ba_(1.8)Ca_(0.2)Co_(1.9)Cu_(0.1)O₉ 198 8 1.3Bi₂Ba_(1.8)Sr_(0.2)Co_(1.9)Cu_(0.1)O₉ 199 8.2 0.9Bi₂Ba_(1.8)Al_(0.2)Co_(1.9)Cu_(0.1)O₉ 200 7.9 1.1Bi₂Ba_(1.8)Y_(0.2)Co_(1.9)Cu_(0.1)O₉ 199 9.1 1.4Bi₂Ba_(1.8)La_(0.2)Co_(1.9)Cu_(0.1)O₉ 210 8.4 1.2Bi₂Ba_(1.8)Ce_(0.2)Co_(1.9)Cu_(0.1)O₉ 202 8.6 0.9Bi₂Ba_(1.8)Pr_(0.2)Co_(1.9)Cu_(0.1)O₉ 204 7.8 1.1Bi₂Ba_(1.8)Nd_(0.2)Co_(1.9)Cu_(0.1)O₉ 197 9 1.2Bi₂Ba_(1.8)Sm_(0.2)Co_(1.9)Cu_(0.1)O₉ 190 8.2 0.9Bi₂Ba_(1.8)Eu_(0.2)Co_(1.9)Cu_(0.1)O₉ 198 8.3 1.1

TABLE 50 Bi₂Ba_(1.8)Gd_(0.2)Co_(1.9)Cu_(0.1)O₉ 199 8.4 1.2Bi₂Ba_(1.8)Dy_(0.2)Co_(1.9)Cu_(0.1)O₉ 201 6.9 1Bi₂Ba_(1.8)Ho_(0.2)Co_(1.9)Cu_(0.1)O₉ 207 8.1 1.3Bi₂Ba_(1.8)Er_(0.2)Co_(1.9)Cu_(0.1)O₉ 190 6.9 1Bi₂Ba_(1.8)Yb_(0.2)Co_(1.9)Cu_(0.1)O₉ 198 7.4 0.9Bi₂Pb_(0.2)Ba₂Co_(1.9)Cu_(0.1)O₉ 201 7.7 1Bi₂Pb_(0.2)Ba_(1.8)Na_(0.2)Co_(1.9)Cu_(0.1)O₉ 210 8 1.2Bi₂Pb_(0.2)Ba_(1.8)K_(0.2)Co_(1.9)Cu_(0.1)O₉ 206 8.2 1.1Bi₂Pb_(0.2)Ba_(1.8)Li_(0.2)Co_(1.9)Cu_(0.1)O₉ 205 7.9 0.9Bi₂Pb_(0.2)Ba_(1.8)Ti_(0.2)Co_(1.9)Cu_(0.1)O₉ 198 9.1 0.8Bi₂Pb_(0.2)Ba_(1.8)V_(0.2)Co_(1.9)Cu_(0.1)O₉ 195 8.4 1Bi₂Pb_(0.2)Ba_(1.8)Cr_(0.2)Co_(1.9)Cu_(0.1)O₉ 200 8.6 1.3Bi₂Pb_(0.2)Ba_(1.8)Mn_(0.2)Co_(1.9)Cu_(0.1)O₉ 203 8.2 1.2Bi₂Pb_(0.2)Ba_(1.8)Fe_(0.2)Co_(1.9)Cu_(0.1)O₉ 200 7.9 1.3Bi₂Pb_(0.2)Ba_(1.8)Ni_(0.2)Co_(1.9)Cu_(0.1)O₉ 203 8.6 0.9Bi₂Pb_(0.2)Ba_(1.8)Cu_(0.2)Co_(1.9)Cu_(0.1)O₉ 201 9.1 1.1Bi₂Pb_(0.2)Ba_(1.8)Zn_(0.2)Co_(1.9)Cu_(0.1)O₉ 208 6.9 1.4Bi₂Pb_(0.2)Ba_(1.8)Pb_(0.2)Co_(1.9)Cu_(0.1)O₉ 198 7.4 1.2Bi₂Pb_(0.2)Ba_(1.8)Ca_(0.2)Co_(1.9)Cu_(0.1)O₉ 199 7.8 0.9Bi₂Pb_(0.2)Ba_(1.8)Sr_(0.2)Co_(1.9)Cu_(0.1)O₉ 200 7.7 1.1Bi₂Pb_(0.2)Ba_(1.8)Al_(0.2)Co_(1.9)Cu_(0.1)O₉ 206 8 1.2Bi₂Pb_(0.2)Ba_(1.8)Y_(0.2)Co_(1.9)Cu_(0.1)O₉ 205 8.2 0.9Bi₂Pb_(0.2)Ba_(1.8)La_(0.2)Co_(1.9)Cu_(0.1)O₉ 198 7.9 1.1Bi₂Pb_(0.2)Ba_(1.8)Ce_(0.2)Co_(1.9)Cu_(0.1)O₉ 206 9.1 1.2Bi₂Pb_(0.2)Ba_(1.8)Pr_(0.2)Co_(1.9)Cu_(0.1)O₉ 198 8.4 1Bi₂Pb_(0.2)Ba_(1.8)Nd_(0.2)Co_(1.9)Cu_(0.1)O₉ 207 8.6 1.3Bi₂Pb_(0.2)Ba_(1.8)Sm_(0.2)Co_(1.9)Cu_(0.1)O₉ 190 7.8 1Bi₂Pb_(0.2)Ba_(1.8)Eu_(0.2)Co_(1.9)Cu_(0.1)O₉ 198 9 0.9Bi₂Pb_(0.2)Ba_(1.8)Gd_(0.2)Co_(1.9)Cu_(0.1)O₉ 199 8.2 1.1Bi₂Pb_(0.2)Ba_(1.8)Dy_(0.2)Co_(1.9)Cu_(0.1)O₉ 201 9.1 1Bi₂Pb_(0.2)Ba_(1.8)Ho_(0.2)Co_(1.9)Cu_(0.1)O₉ 210 8.4 1.2Bi₂Pb_(0.2)Ba_(1.8)Er_(0.2)Co_(1.9)Cu_(0.1)O₉ 206 8.6 1.1Bi₂Pb_(0.2)Ba_(1.8)Yb_(0.2)Co_(1.9)Cu_(0.1)O₉ 205 7.8 0.9Bi₂Sr₂Co_(1.9)Ag_(0.1)O₉ 195 8.2 1 Bi₂Sr_(1.8)Na_(0.2)Co_(1.9)Ag_(0.1)O₉200 8.3 1.3

TABLE 51 Bi₂Sr_(1.8)K_(0.2)Co_(1.9)Ag_(0.1)O₉ 203 8.6 1.2Bi₂Sr_(1.8)Li_(0.2)Co_(1.9)Ag_(0.1)O₉ 201 8.7 0.7Bi₂Sr_(1.8)Ti_(0.2)Co_(1.9)Ag_(0.1)O₉ 208 8.3 1.3Bi₂Sr_(1.8)V_(0.2)Co_(1.9)Ag_(0.1)O₉ 198 9 1.4Bi₂Sr_(1.8)Cr_(0.2)Co_(1.9)Ag_(0.1)O₉ 206 7.9 1.1Bi₂Sr_(1.8)Mn_(0.2)Co_(1.9)Ag_(0.1)O₉ 198 8.1 1Bi₂Sr_(1.8)Fe_(0.2)Co_(1.9)Ag_(0.1)O₉ 207 8 1.3Bi₂Sr_(1.8)Ni_(0.2)Co_(1.9)Ag_(0.1)O₉ 190 7.8 0.9Bi₂Sr_(1.8)Cu_(0.2)Co_(1.9)Ag_(0.1)O₉ 198 7.2 1.1Bi₂Sr_(1.8)Zn_(0.2)Co_(1.9)Ag_(0.1)O₉ 199 9 1.4Bi₂Sr_(1.8)Pb_(0.2)Co_(1.9)Ag_(0.1)O₉ 201 8.2 1.2Bi₂Sr_(1.8)Ca_(0.2)Co_(1.9)Ag_(0.1)O₉ 210 7.9 0.9Bi₂Sr_(1.8)Ba_(0.2)Co_(1.9)Ag_(0.1)O₉ 206 6.9 1.1Bi₂Sr_(1.8)Al_(0.2)Co_(1.9)Ag_(0.1)O₉ 205 8.1 1.2Bi₂Sr_(1.8)Y_(0.2)Co_(1.9)Ag_(0.1)O₉ 198 6.9 0.9Bi₂Sr_(1.8)La_(0.2)Co_(1.9)Ag_(0.1)O₉ 195 7.4 1.1Bi₂Sr_(1.8)Ce_(0.2)Co_(1.9)Ag_(0.1)O₉ 200 7.8 1.2Bi₂Sr_(1.8)Pr_(0.2)Co_(1.9)Ag_(0.1)O₉ 203 7.7 1.4Bi₂Sr_(1.8)Nd_(0.2)Co_(1.9)Ag_(0.1)O₉ 201 8 0.8Bi₂Sr_(1.8)Sm_(0.2)Co_(1.9)Ag_(0.1)O₉ 208 8.2 1.3Bi₂Sr_(1.8)Eu_(0.2)Co_(1.9)Ag_(0.1)O₉ 198 7.9 1.2Bi₂Sr_(1.8)Gd_(0.2)Co_(1.9)Ag_(0.1)O₉ 199 9.1 1.1Bi₂Sr_(1.8)Dy_(0.2)Co_(1.9)Ag_(0.1)O₉ 200 8.4 0.8Bi₂Sr_(1.8)Ho_(0.2)Co_(1.9)Ag_(0.1)O₉ 206 8.6 1.3Bi₂Sr_(1.8)Er_(0.2)Co_(1.9)Ag_(0.1)O₉ 206 8.2 1.4Bi₂Sr_(1.8)Yb_(0.2)Co_(1.9)Ag_(0.1)O₉ 198 7.9 1.1Bi₂Pb_(0.2)Sr₂Co_(1.9)Ag_(0.1)O₉ 200 9.1 1.3Bi₂Pb_(0.2)Sr_(1.8)Na_(0.2)Co_(1.9)Ag_(0.1)O₉ 206 6.9 0.9Bi₂Pb_(0.2)Sr_(1.8)K_(0.2)Co_(1.9)Ag_(0.1)O₉ 205 7.4 1.1Bi₂Pb_(0.2)Sr_(1.8)Li_(0.2)Co_(1.9)Ag_(0.1)O₉ 198 7.8 1.4Bi₂Pb_(0.2)Sr_(1.8)Ti_(0.2)Co_(1.9)Ag_(0.1)O₉ 199 7.7 1.2Bi₂Pb_(0.2)Sr_(1.8)V_(0.2)Co_(1.9)Ag_(0.1)O₉ 200 8 0.9Bi₂Pb_(0.2)Sr_(1.8)Cr_(0.2)Co_(1.9)Ag_(0.1)O₉ 199 8.2 1.1Bi₂Pb_(0.2)Sr_(1.8)Mn_(0.2)Co_(1.9)Ag_(0.1)O₉ 210 7.9 1.2Bi₂Pb_(0.2)Sr_(1.8)Fe_(0.2)Co_(1.9)Ag_(0.1)O₉ 202 9.1 0.9Bi₂Pb_(0.2)Sr_(1.8)Ni_(0.2)Co_(1.9)Ag_(0.1)O₉ 204 8.4 1.1

TABLE 52 Bi₂Pb_(0.2)Sr_(1.8)Cu_(0.2)Co_(1.9)Ag_(0.1)O₉ 197 8.6 1.2i₂Pb_(0.2)Sr_(1.8)Zn_(0.2)Co_(1.9)Ag_(0.1)O₉ 190 7.8 1.4Bi₂Pb_(0.2)Sr_(1.8)Pb_(0.2)Co_(1.9)Ag_(0.1)O₉ 198 9 0.8Bi₂Pb_(0.2)Sr_(1.8)Ca_(0.2)Co_(1.9)Ag_(0.1)O₉ 199 8.2 1.3Bi₂Pb_(0.2)Sr_(1.8)Ba_(0.2)Co_(1.9)Ag_(0.1)O₉ 201 8.3 1.2Bi₂Pb_(0.2)Sr_(1.8)Al_(0.2)Co_(1.9)Ag_(0.1)O₉ 207 8.4 1.1Bi₂Pb_(0.2)Sr_(1.8)Y_(0.2)Co_(1.9)Ag_(0.1)O₉ 190 8.6 0.8Bi₂Pb_(0.2)Sr_(1.8)La_(0.2)Co_(1.9)Ag_(0.1)O₉ 198 8.2 0.7Bi₂Pb_(0.2)Sr_(1.8)Ce_(0.2)Co_(1.9)Ag_(0.1)O₉ 199 7.9 1.3Bi₂Pb_(0.2)Sr_(1.8)Pr_(0.2)Co_(1.9)Ag_(0.1)O₉ 201 8.6 0.8Bi₂Pb_(0.2)Sr_(1.8)Nd_(0.2)Co_(1.9)Ag_(0.1)O₉ 210 9.1 1.3Bi₂Pb_(0.2)Sr_(1.8)Sm_(0.2)Co_(1.9)Ag_(0.1)O₉ 206 6.9 1.2Bi₂Pb_(0.2)Sr_(1.8)Eu_(0.2)Co_(1.9)Ag_(0.1)O₉ 205 7.4 1.1Bi₂Pb_(0.2)Sr_(1.8)Gd_(0.2)Co_(1.9)Ag_(0.1)O₉ 198 7.8 0.8Bi₂Pb_(0.2)Sr_(1.8)Dy_(0.2)Co_(1.9)Ag_(0.1)O₉ 195 7.7 1.3Bi₂Pb_(0.2)Sr_(1.8)Ho_(0.2)Co_(1.9)Ag_(0.1)O₉ 200 8 1.4Bi₂Pb_(0.2)Sr_(1.8)Er_(0.2)Co_(1.9)Ag_(0.1)O₉ 203 8.2 1.1Bi₂Pb_(0.2)Sr_(1.8)Yb_(0.2)Co_(1.9)Ag_(0.1)O₉ 200 7.9 1Bi₂Ca₂Co_(1.9)Ag_(0.1)O₉ 201 8.4 0.9Bi₂Ca_(1.8)Na_(0.2)Co_(1.9)Ag_(0.1)O₉ 208 8.6 1.1Bi₂Ca_(1.8)K_(0.2)Co_(1.9)Ag_(0.1)O₉ 198 7.8 1.4Bi₂Ca_(1.8)Li_(0.2)Co_(1.9)Ag_(0.1)O₉ 199 9 1.2Bi₂Ca_(1.8)Ti_(0.2)Co_(1.9)Ag_(0.1)O₉ 200 8.2 0.9Bi₂Ca_(1.8)V_(0.2)Co_(1.9)Ag_(0.1)O₉ 206 8.3 1.1Bi₂Ca_(1.8)Cr_(0.2)Co_(1.9)Ag_(0.1)O₉ 205 8.6 1.2Bi₂Ca_(1.8)Mn_(0.2)Co_(1.9)Ag_(0.1)O₉ 198 8.7 0.9Bi₂Ca_(1.8)Fe_(0.2)Co_(1.9)Ag_(0.1)O₉ 206 8.3 1.1Bi₂Ca_(1.8)Ni_(0.2)Co_(1.9)Ag_(0.1)O₉ 198 9 1.2Bi₂Ca_(1.8)Cu_(0.2)Co_(1.9)Ag_(0.1)O₉ 207 7.9 1.4Bi₂Ca_(1.8)Zn_(0.2)Co_(1.9)Ag_(0.1)O₉ 190 8.1 0.8Bi₂Ca_(1.8)Pb_(0.2)Co_(1.9)Ag_(0.1)O₉ 198 8 1.3Bi₂Ca_(1.8)Sr_(0.2)Co_(1.9)Ag_(0.1)O₉ 199 7.8 1.2Bi₂Ca_(1.8)Ba_(0.2)Co_(1.9)Ag_(0.1)O₉ 201 7.2 1.1Bi₂Ca_(1.8)Al_(0.2)Co_(1.9)Ag_(0.1)O₉ 210 9 1.4Bi₂Ca_(1.8)Y_(0.2)Co_(1.9)Ag_(0.1)O₉ 206 8.2 1.2Bi₂Ca_(1.8)La_(0.2)Co_(1.9)Ag_(0.1)O₉ 205 7.9 0.9

TABLE 53 Bi₂Ca_(1.8)Ce_(0.2)Co_(1.9)Ag_(0.1)O₉ 198 6.9 1.1Bi₂Ca_(1.8)Pr_(0.2)Co_(1.9)Ag_(0.1)O₉ 195 8.1 1.2Bi₂Ca_(1.8)Nd_(0.2)Co_(1.9)Ag_(0.1)O₉ 200 6.9 0.9Bi₂Ca_(1.8)Sm_(0.2)Co_(1.9)Ag_(0.1)O₉ 203 7.4 1.1Bi₂Ca_(1.8)Eu_(0.2)Co_(1.9)Ag_(0.1)O₉ 201 7.8 1.2Bi₂Ca_(1.8)Gd_(0.2)Co_(1.9)Ag_(0.1)O₉ 208 7.7 1.4Bi₂Ca_(1.8)Dy_(0.2)Co_(1.9)Ag_(0.1)O₉ 198 8 0.8Bi₂Ca_(1.8)Ho_(0.2)Co_(1.9)Ag_(0.1)O₉ 199 8.2 1.3Bi₂Ca_(1.8)Er_(0.2)Co_(1.9)Ag_(0.1)O₉ 200 7.9 1.2Bi₂Ca_(1.8)Yb_(0.2)Co_(1.9)Ag_(0.1)O₉ 206 9.1 1.1Bi₂Pb_(0.2)Ca₂Co_(1.9)Ag_(0.1)O₉ 198 8.6 1.3Bi₂Pb_(0.2)Ca_(1.8)Na_(0.2)Co_(1.9)Ag_(0.1)O₉ 199 8.2 1.4Bi₂Pb_(0.2)Ca_(1.8)K_(0.2)Co_(1.9)Ag_(0.1)O₉ 200 7.9 1.1Bi₂Pb_(0.2)Ca_(1.8)Li_(0.2)Co_(1.9)Ag_(0.1)O₉ 206 8.6 1Bi₂Pb_(0.2)Ca_(1.8)Ti_(0.2)Co_(1.9)Ag_(0.1)O₉ 205 9.1 1.3Bi₂Pb_(0.2)Ca_(1.8)V_(0.2)Co_(1.9)Ag_(0.1)O₉ 198 6.9 0.9Bi₂Pb_(0.2)Ca_(1.8)Cr_(0.2)Co_(1.9)Ag_(0.1)O₉ 199 7.4 1.1Bi₂Pb_(0.2)Ca_(1.8)Mn_(0.2)Co_(1.9)Ag_(0.1)O₉ 200 7.8 1.4Bi₂Pb_(0.2)Ca_(1.8)Fe_(0.2)Co_(1.9)Ag_(0.1)O₉ 199 7.7 1.2Bi₂Pb_(0.2)Ca_(1.8)Ni_(0.2)Co_(1.9)Ag_(0.1)O₉ 210 8 0.9Bi₂Pb_(0.2)Ca_(1.8)Cu_(0.2)Co_(1.9)Ag_(0.1)O₉ 202 8.2 1.1Bi₂Pb_(0.2)Ca_(1.8)Zn_(0.2)Co_(1.9)Ag_(0.1)O₉ 204 7.9 1.2Bi₂Pb_(0.2)Ca_(1.8)Pb_(0.2)Co_(1.9)Ag_(0.1)O₉ 197 9.1 0.9Bi₂Pb_(0.2)Ca_(1.8)Sr_(0.2)Co_(1.9)Ag_(0.1)O₉ 190 8.4 1.1Bi₂Pb_(0.2)Ca_(1.8)Ba_(0.2)Co_(1.9)Ag_(0.1)O₉ 198 8.6 1.2Bi₂Pb_(0.2)Ca_(1.8)Al_(0.2)Co_(1.9)Ag_(0.1)O₉ 199 7.8 1Bi₂Pb_(0.2)Ca_(1.8)Y_(0.2)Co_(1.9)Ag_(0.1)O₉ 201 9 1.3Bi₂Pb_(0.2)Ca_(1.8)La_(0.2)Co_(1.9)Ag_(0.1)O₉ 207 8.2 1Bi₂Pb_(0.2)Ca_(1.8)Ce_(0.2)Co_(1.9)Ag_(0.1)O₉ 190 8.3 0.9Bi₂Pb_(0.2)Ca_(1.8)Pr_(0.2)Co_(1.9)Ag_(0.1)O₉ 198 8.6 1.1Bi₂Pb_(0.2)Ca_(1.8)Nd_(0.2)Co_(1.9)Ag_(0.1)O₉ 199 8.7 1Bi₂Pb_(0.2)Ca_(1.8)Sm_(0.2)Co_(1.9)Ag_(0.1)O₉ 201 8.3 1.2Bi₂Pb_(0.2)Ca_(1.8)Eu_(0.2)Co_(1.9)Ag_(0.1)O₉ 210 9 1.1Bi₂Pb_(0.2)Ca_(1.8)Gd_(0.2)Co_(1.9)Ag_(0.1)O₉ 206 7.9 0.9Bi₂Pb_(0.2)Ca_(1.8)Dy_(0.2)Co_(1.9)Ag_(0.1)O₉ 205 8.1 0.8Bi₂Pb_(0.2)Ca_(1.8)Ho_(0.2)Co_(1.9)Ag_(0.1)O₉ 198 8 1

TABLE 54 Bi₂Pb_(0.2)Ca_(1.8)Er_(0.2)Co_(1.9)Ag_(0.1)O₉ 195 7.8 1.3Bi₂Pb_(0.2)Ca_(1.8)Yb_(0.2)Co_(1.9)Ag_(0.1)O₉ 200 7.2 1.2Bi₂Ba₂Co_(1.9)Ag_(0.1)O₉ 200 7.8 1 Bi₂Ba_(1.8)Na_(0.2)Co_(1.9)Ag_(0.1)O₉203 7.5 1.3 Bi₂Ba_(1.8)K_(0.2)Co_(1.9)Ag_(0.1)O₉ 201 8.6 0.9Bi₂Ba_(1.8)Li_(0.2)Co_(1.9)Ag_(0.1)O₉ 208 8.2 1.1Bi₂Ba_(1.8)Ti_(0.2)Co_(1.9)Ag_(0.1)O₉ 198 7.9 1.4Bi₂Ba_(1.8)V_(0.2)Co_(1.9)Ag_(0.1)O₉ 199 6.9 1.2Bi₂Ba_(1.8)Cr_(0.2)Co_(1.9)Ag_(0.1)O₉ 200 9 0.9Bi₂Ba_(1.8)Mn_(0.2)Co_(1.9)Ag_(0.1)O₉ 206 7.8 1.1Bi₂Ba_(1.8)Fe_(0.2)Co_(1.9)Ag_(0.1)O₉ 205 7.5 1.2Bi₂Ba_(1.8)Ni_(0.2)Co_(1.9)Ag_(0.1)O₉ 198 8.6 0.9Bi₂Ba_(1.8)Cu_(0.2)Co_(1.9)Ag_(0.1)O₉ 206 8.2 1.1Bi₂Ba_(1.8)Zn_(0.2)Co_(1.9)Ag_(0.1)O₉ 198 7.9 1.2Bi₂Ba_(1.8)Pb_(0.2)Co_(1.9)Ag_(0.1)O₉ 207 6.9 1Bi₂Ba_(1.8)Ca_(0.2)Co_(1.9)Ag_(0.1)O₉ 190 8.1 1.3Bi₂Ba_(1.8)Sr_(0.2)Co_(1.9)Ag_(0.1)O₉ 190 6.9 1Bi₂Ba_(1.8)Al_(0.2)Co_(1.9)Ag_(0.1)O₉ 198 7.4 0.9Bi₂Ba_(1.8)Y_(0.2)Co_(1.9)Ag_(0.1)O₉ 199 7.8 1.1Bi₂Ba_(1.8)La_(0.2)Co_(1.9)Ag_(0.1)O₉ 201 7.7 1Bi₂Ba_(1.8)Ce_(0.2)Co_(1.9)Ag_(0.1)O₉ 210 8 1.2Bi₂Ba_(1.8)Pr_(0.2)Co_(1.9)Ag_(0.1)O₉ 206 8.2 1.1Bi₂Ba_(1.8)Nd_(0.2)Co_(1.9)Ag_(0.1)O₉ 205 7.9 0.9Bi₂Ba_(1.8)Sm_(0.2)Co_(1.9)Ag_(0.1)O₉ 198 9.1 0.8Bi₂Ba_(1.8)Eu_(0.2)Co_(1.9)Ag_(0.1)O₉ 195 8.4 1Bi₂Ba_(1.8)Gd_(0.2)Co_(1.9)Ag_(0.1)O₉ 200 8.6 1.3Bi₂Ba_(1.8)Dy_(0.2)Co_(1.9)Ag_(0.1)O₉ 203 8.2 1.2Bi₂Ba_(1.8)Ho_(0.2)Co_(1.9)Ag_(0.1)O₉ 201 7.9 1.3Bi₂Ba_(1.8)Er_(0.2)Co_(1.9)Ag_(0.1)O₉ 208 8.6 1Bi₂Ba_(1.8)Yb_(0.2)Co_(1.9)Ag_(0.1)O₉ 198 9.1 0.8Bi₂Pb_(0.2)Ba₂Co_(1.9)Ag_(0.1)O₉ 200 7.4 1.2Bi₂Pb_(0.2)Ba_(1.8)Na_(0.2)Co_(1.9)Ag_(0.1)O₉ 206 7.8 0.9Bi₂Pb_(0.2)Ba_(1.8)K_(0.2)Co_(1.9)Ag_(0.1)O₉ 206 7.7 1.1Bi₂Pb_(0.2)Ba_(1.8)Li_(0.2)Co_(1.9)Ag_(0.1)O₉ 198 8 1.2Bi₂Pb_(0.2)Ba_(1.8)Ti_(0.2)Co_(1.9)Ag_(0.1)O₉ 199 8.2 1.4

TABLE 55 Bi₂Pb_(0.2)Ba_(1.8)V_(0.2)Co_(1.9)Ag_(0.1)O₉ 200 7.9 0.8Bi₂Pb_(0.2)Ba_(1.8)Cr_(0.2)Co_(1.9)Ag_(0.1)O₉ 206 9.1 1.3Bi₂Pb_(0.2)Ba_(1.8)Mn_(0.2)Co_(1.9)Ag_(0.1)O₉ 205 8.4 1.2Bi₂Pb_(0.2)Ba_(1.8)Fe_(0.2)Co_(1.9)Ag_(0.1)O₉ 198 8.6 1.1Bi₂Pb_(0.2)Ba_(1.8)Ni_(0.2)Co_(1.9)Ag_(0.1)O₉ 199 7.8 0.8Bi₂Pb_(0.2)Ba_(1.8)Cu_(0.2)Co_(1.9)Ag_(0.1)O₉ 200 9 1.3Bi₂Pb_(0.2)Ba_(1.8)Zn_(0.2)Co_(1.9)Ag_(0.1)O₉ 199 8.2 1.4Bi₂Pb_(0.2)Ba_(1.8)Pb_(0.2)Co_(1.9)Ag_(0.1)O₉ 210 9.1 1.1Bi₂Pb_(0.2)Ba_(1.8)Ca_(0.2)Co_(1.9)Ag_(0.1)O₉ 202 8.4 1Bi₂Pb_(0.2)Ba_(1.8)Sr_(0.2)Co_(1.9)Ag_(0.1)O₉ 204 8.6 1.3Bi₂Pb_(0.2)Ba_(1.8)Al_(0.2)Co_(1.9)Ag_(0.1)O₉ 197 7.8 0.9Bi₂Pb_(0.2)Ba_(1.8)Y_(0.2)Co_(1.9)Ag_(0.1)O₉ 190 9 1.1Bi₂Pb_(0.2)Ba_(1.8)La_(0.2)Co_(1.9)Ag_(0.1)O₉ 198 8.4 1.4Bi₂Pb_(0.2)Ba_(1.8)Ce_(0.2)Co_(1.9)Ag_(0.1)O₉ 199 7.8 1.2Bi₂Pb_(0.2)Ba_(1.8)Pr_(0.2)Co_(1.9)Ag_(0.1)O₉ 201 9 0.9Bi₂Pb_(0.2)Ba_(1.8)Nd_(0.2)Co_(1.9)Ag_(0.1)O₉ 207 8.2 1.1Bi₂Pb_(0.2)Ba_(1.8)Sm_(0.2)Co_(1.9)Ag_(0.1)O₉ 190 8.3 1.2Bi₂Pb_(0.2)Ba_(1.8)Eu_(0.2)Co_(1.9)Ag_(0.1)O₉ 198 8.6 0.9Bi₂Pb_(0.2)Ba_(1.8)Gd_(0.2)Co_(1.9)Ag_(0.1)O₉ 199 8.7 1.1Bi₂Pb_(0.2)Ba_(1.8)Dy_(0.2)Co_(1.9)Ag_(0.1)O₉ 201 8.3 1.2Bi₂Pb_(0.2)Ba_(1.8)Ho_(0.2)Co_(1.9)Ag_(0.1)O₉ 210 9 1.4Bi₂Pb_(0.2)Ba_(1.8)Er_(0.2)Co_(1.9)Ag_(0.1)O₉ 206 7.9 0.8Bi₂Pb_(0.2)Ba_(1.8)Yb_(0.2)Co_(1.9)Ag_(0.1)O₉ 205 8.1 1.3Bi₂Sr₂Co_(1.9)Mo_(0.1)O₉ 195 7.8 1.1Bi₂Sr_(1.8)Na_(0.2)Co_(1.9)Mo_(0.1)O₉ 200 7.2 1.4Bi₂Sr_(1.8)K_(0.2)Co_(1.9)Mo_(0.1)O₉ 203 9 1.2Bi₂Sr_(1.8)Li_(0.2)Co_(1.9)Mo_(0.1)O₉ 200 8.2 0.9Bi₂Sr_(1.8)Ti_(0.2)Co_(1.9)Mo_(0.1)O₉ 203 7.9 1.1Bi₂Sr_(1.8)V_(0.2)Co_(1.9)Mo_(0.1)O₉ 201 6.9 1.2Bi₂Sr_(1.8)Cr_(0.2)Co_(1.9)Mo_(0.1)O₉ 208 8.1 0.9Bi₂Sr_(1.8)Mn_(0.2)Co_(1.9)Mo_(0.1)O₉ 198 6.9 1.1Bi₂Sr_(1.8)Fe_(0.2)Co_(1.9)Mo_(0.1)O₉ 199 7.4 1.2Bi₂Sr_(1.8)Ni_(0.2)Co_(1.9)Mo_(0.1)O₉ 200 7.8 1.4Bi₂Sr_(1.8)Cu_(0.2)Co_(1.9)Mo_(0.1)O₉ 199 7.7 0.8Bi₂Sr_(1.8)Zn_(0.2)Co_(1.9)Mo_(0.1)O₉ 200 8 1.3Bi₂Sr_(1.8)Pb_(0.2)Co_(1.9)Mo_(0.1)O₉ 206 8.2 1.2

TABLE 56 Bi₂Sr_(1.8)Ca_(0.2)Co_(1.9)Mo_(0.1)O₉ 206 7.9 1.1Bi₂Sr_(1.8)Ba_(0.2)Co_(1.9)Mo_(0.1)O₉ 198 9.1 0.8Bi₂Sr_(1.8)Al_(0.2)Co_(1.9)Mo_(0.1)O₉ 199 8.4 1.3Bi₂Sr_(1.8)Y_(0.2)Co_(1.9)Mo_(0.1)O₉ 200 8.6 1.4Bi₂Sr_(1.8)La_(0.2)Co_(1.9)Mo_(0.1)O₉ 206 8.2 1.1Bi₂Sr_(1.8)Ce_(0.2)Co_(1.9)Mo_(0.1)O₉ 205 7.9 1Bi₂Sr_(1.8)Pr_(0.2)Co_(1.9)Mo_(0.1)O₉ 198 8.6 1.3Bi₂Sr_(1.8)Nd_(0.2)Co_(1.9)Mo_(0.1)O₉ 199 9.1 0.9Bi₂Sr_(1.8)Sm_(0.2)Co_(1.9)Mo_(0.1)O₉ 200 6.9 1.1Bi₂Sr_(1.8)Eu_(0.2)Co_(1.9)Mo_(0.1)O₉ 199 7.4 1.4Bi₂Sr_(1.8)Gd_(0.2)Co_(1.9)Mo_(0.1)O₉ 210 7.8 1.2Bi₂Sr_(1.8)Dy_(0.2)Co_(1.9)Mo_(0.1)O₉ 202 7.7 0.9Bi₂Sr_(1.8)Ho_(0.2)Co_(1.9)Mo_(0.1)O₉ 204 8 1.1Bi₂Sr_(1.8)Er_(0.2)Co_(1.9)Mo_(0.1)O₉ 197 8.2 1.2Bi₂Sr_(1.8)Yb_(0.2)Co_(1.9)Mo_(0.1)O₉ 190 7.9 0.9Bi₂Pb_(0.2)Sr₂Co_(1.9)Mo_(0.1)O₉ 199 8.4 1.2Bi₂Pb_(0.2)Sr_(1.8)Na_(0.2)Co_(1.9)Mo_(0.1)O₉ 201 8.6 1Bi₂Pb_(0.2)Sr_(1.8)K_(0.2)Co_(1.9)Mo_(0.1)O₉ 207 7.8 1.3Bi₂Pb_(0.2)Sr_(1.8)Li_(0.2)Co_(1.9)Mo_(0.1)O₉ 190 9 1Bi₂Pb_(0.2)Sr_(1.8)Ti_(0.2)Co_(1.9)Mo_(0.1)O₉ 198 8.2 0.9Bi₂Pb_(0.2)Sr_(1.8)V_(0.2)Co_(1.9)Mo_(0.1)O₉ 199 8.3 1.1Bi₂Pb_(0.2)Sr_(1.8)Cr_(0.2)Co_(1.9)Mo_(0.1)O₉ 201 8.4 1Bi₂Pb_(0.2)Sr_(1.8)Mn_(0.2)Co_(1.9)Mo_(0.1)O₉ 210 8.6 1.2Bi₂Pb_(0.2)Sr_(1.8)Fe_(0.2)Co_(1.9)Mo_(0.1)O₉ 206 8.2 1.1Bi₂Pb_(0.2)Sr_(1.8)Ni_(0.2)Co_(1.9)Mo_(0.1)O₉ 205 7.9 0.9Bi₂Pb_(0.2)Sr_(1.8)Cu_(0.2)Co_(1.9)Mo_(0.1)O₉ 198 8.6 0.8Bi₂Pb_(0.2)Sr_(1.8)Zn_(0.2)Co_(1.9)Mo_(0.1)O₉ 195 9.1 1Bi₂Pb_(0.2)Sr_(1.8)Pb_(0.2)Co_(1.9)Mo_(0.1)O₉ 200 6.9 1.3Bi₂Pb_(0.2)Sr_(1.8)Ca_(0.2)Co_(1.9)Mo_(0.1)O₉ 203 7.4 1.2Bi₂Pb_(0.2)Sr_(1.8)Ba_(0.2)Co_(1.9)Mo_(0.1)O₉ 200 7.8 1.3Bi₂Pb_(0.2)Sr_(1.8)Al_(0.2)Co_(1.9)Mo_(0.1)O₉ 203 7.7 0.9Bi₂Pb_(0.2)Sr_(1.8)Y_(0.2)Co_(1.9)Mo_(0.1)O₉ 201 8 1.1Bi₂Pb_(0.2)Sr_(1.8)La_(0.2)Co_(1.9)Mo_(0.1)O₉ 208 8.2 1.4Bi₂Pb_(0.2)Sr_(1.8)Ce_(0.2)Co_(1.9)Mo_(0.1)O₉ 198 7.9 1.2Bi₂Pb_(0.2)Sr_(1.8)Pr_(0.2)Co_(1.9)Mo_(0.1)O₉ 199 9.1 0.9Bi₂Pb_(0.2)Sr_(1.8)Nd_(0.2)Co_(1.9)Mo_(0.1)O₉ 200 8.4 1.1

TABLE 57 Bi₂Pb_(0.2)Sr_(1.8)Sm_(0.2)Co_(1.9)Mo_(0.1)O₉ 203 8.6 1.2Bi₂Pb_(0.2)Sr_(1.8)Eu_(0.2)Co_(1.9)Mo_(0.1)O₉ 200 7.8 0.9Bi₂Pb_(0.2)Sr_(1.8)Gd_(0.2)Co_(1.9)Mo_(0.1)O₉ 203 9 1.1Bi₂Pb_(0.2)Sr_(1.8)Dy_(0.2)Co_(1.9)Mo_(0.1)O₉ 201 8.2 1.2Bi₂Pb_(0.2)Sr_(1.8)Ho_(0.2)Co_(1.9)Mo_(0.1)O₉ 208 8.3 1Bi₂Pb_(0.2)Sr_(1.8)Er_(0.2)Co_(1.9)Mo_(0.1)O₉ 198 8.6 1.3Bi₂Pb_(0.2)Sr_(1.8)Yb_(0.2)Co_(1.9)Mo_(0.1)O₉ 199 8.7 1Bi₂Ca₂Co_(1.9)Mo_(0.1)O₉ 199 9 1.1 Bi₂Ca_(1.8)Na_(0.2)Co_(1.9)Mo_(0.1)O₉200 7.9 1 Bi₂Ca_(1.8)K_(0.2)Co_(1.9)Mo_(0.1)O₉ 206 8.1 1.2Bi₂Ca_(1.8)Li_(0.2)Co_(1.9)Mo_(0.1)O₉ 206 8 1.1Bi₂Ca_(1.8)Ti_(0.2)Co_(1.9)Mo_(0.1)O₉ 198 7.8 0.9Bi₂Ca_(1.8)V_(0.2)Co_(1.9)Mo_(0.1)O₉ 199 7.2 0.8Bi₂Ca_(1.8)Cr_(0.2)Co_(1.9)Mo_(0.1)O₉ 200 9 1Bi₂Ca_(1.8)Mn_(0.2)Co_(1.9)Mo_(0.1)O₉ 206 8.2 1.3Bi₂Ca_(1.8)Fe_(0.2)Co_(1.9)Mo_(0.1)O₉ 205 7.9 1.2Bi₂Ca_(1.8)Ni_(0.2)Co_(1.9)Mo_(0.1)O₉ 198 6.9 0.7Bi₂Ca_(1.8)Cu_(0.2)Co_(1.9)Mo_(0.1)O₉ 199 8.1 1.3Bi₂Ca_(1.8)Zn_(0.2)Co_(1.9)Mo_(0.1)O₉ 200 6.9 1.4Bi₂Ca_(1.8)Pb_(0.2)Co_(1.9)Mo_(0.1)O₉ 199 7.4 1.1Bi₂Ca_(1.8)Sr_(0.2)Co_(1.9)Mo_(0.1)O₉ 210 7.8 1Bi₂Ca_(1.8)Ba_(0.2)Co_(1.9)Mo_(0.1)O₉ 202 7.7 1.3Bi₂Ca_(1.8)Al_(0.2)Co_(1.9)Mo_(0.1)O₉ 204 8 0.9Bi₂Ca_(1.8)Y_(0.2)Co_(1.9)Mo_(0.1)O₉ 197 8.2 1.1Bi₂Ca_(1.8)La_(0.2)Co_(1.9)Mo_(0.1)O₉ 190 7.9 1.4Bi₂Ca_(1.8)Ce_(0.2)Co_(1.9)Mo_(0.1)O₉ 198 9.1 1.2Bi₂Ca_(1.8)Pr_(0.2)Co_(1.9)Mo_(0.1)O₉ 199 8.4 0.9Bi₂Ca_(1.8)Nd_(0.2)Co_(1.9)Mo_(0.1)O₉ 201 8.6 1.1Bi₂Ca_(1.8)Sm_(0.2)Co_(1.9)Mo_(0.1)O₉ 207 8.2 1.2Bi₂Ca_(1.8)Eu_(0.2)Co_(1.9)Mo_(0.1)O₉ 190 7.9 0.9Bi₂Ca_(1.8)Gd_(0.2)Co_(1.9)Mo_(0.1)O₉ 198 8.6 1.1Bi₂Ca_(1.8)Dy_(0.2)Co_(1.9)Mo_(0.1)O₉ 199 9.1 1.2Bi₂Ca_(1.8)Ho_(0.2)Co_(1.9)Mo_(0.1)O₉ 201 6.9 1.4Bi₂Ca_(1.8)Er_(0.2)Co_(1.9)Mo_(0.1)O₉ 210 7.4 0.8Bi₂Ca_(1.8)Yb_(0.2)Co_(1.9)Mo_(0.1)O₉ 198 7.8 1.3

TABLE 58 Bi₂Pb_(0.2)Ca₂Co_(1.9)Mo_(0.1)O₉ 201 8.0 1.1Bi₂Pb_(0.2)Ca_(1.8)Na_(0.2)Co_(1.9)Mo_(0.1)O₉ 207 8.2 0.8Bi₂Pb_(0.2)Ca_(1.8)K_(0.2)Co_(1.9)Mo_(0.1)O₉ 190 7.9 1.3Bi₂Pb_(0.2)Ca_(1.8)Li_(0.2)Co_(1.9)Mo_(0.1)O₉ 198 9.1 1.4Bi₂Pb_(0.2)Ca_(1.8)Ti_(0.2)Co_(1.9)Mo_(0.1)O₉ 199 8.4 1.1Bi₂Pb_(0.2)Ca_(1.8)V_(0.2)Co_(1.9)Mo_(0.1)O₉ 201 8.6 1Bi₂Pb_(0.2)Ca_(1.8)Cr_(0.2)Co_(1.9)Mo_(0.1)O₉ 210 7.8 1.3Bi₂Pb_(0.2)Ca_(1.8)Mn_(0.2)Co_(1.9)Mo_(0.1)O₉ 206 9 0.9Bi₂Pb_(0.2)Ca_(1.8)Fe_(0.2)Co_(1.9)Mo_(0.1)O₉ 205 8.2 1.1Bi₂Pb_(0.2)Ca_(1.8)Ni_(0.2)Co_(1.9)Mo_(0.1)O₉ 198 8.3 1.4Bi₂Pb_(0.2)Ca_(1.8)Cu_(0.2)Co_(1.9)Mo_(0.1)O₉ 195 8.6 1.2Bi₂Pb_(0.2)Ca_(1.8)Zn_(0.2)Co_(1.9)Mo_(0.1)O₉ 200 8.7 0.9Bi₂Pb_(0.2)Ca_(1.8)Pb_(0.2)Co_(1.9)Mo_(0.1)O₉ 203 8.3 1.1Bi₂Pb_(0.2)Ca_(1.8)Sr_(0.2)Co_(1.9)Mo_(0.1)O₉ 200 9 1.2Bi₂Pb_(0.2)Ca_(1.8)Ba_(0.2)Co_(1.9)Mo_(0.1)O₉ 203 7.9 0.9Bi₂Pb_(0.2)Ca_(1.8)Al_(0.2)Co_(1.9)Mo_(0.1)O₉ 201 8.1 1.1Bi₂Pb_(0.2)Ca_(1.8)Y_(0.2)Co_(1.9)Mo_(0.1)O₉ 208 8 1.2Bi₂Pb_(0.2)Ca_(1.8)La_(0.2)Co_(1.9)Mo_(0.1)O₉ 198 7.8 1.4Bi₂Pb_(0.2)Ca_(1.8)Ce_(0.2)Co_(1.9)Mo_(0.1)O₉ 199 7.2 0.8Bi₂Pb_(0.2)Ca_(1.8)Pr_(0.2)Co_(1.9)Mo_(0.1)O₉ 200 9 1.3Bi₂Pb_(0.2)Ca_(1.8)Nd_(0.2)Co_(1.9)Mo_(0.1)O₉ 206 7.8 1.2Bi₂Pb_(0.2)Ca_(1.8)Sm_(0.2)Co_(1.9)Mo_(0.1)O₉ 205 7.5 1.1Bi₂Pb_(0.2)Ca_(1.8)Eu_(0.2)Co_(1.9)Mo_(0.1)O₉ 198 8.6 0.8Bi₂Pb_(0.2)Ca_(1.8)Gd_(0.2)Co_(1.9)Mo_(0.1)O₉ 206 8.2 0.7Bi₂Pb_(0.2)Ca_(1.8)Dy_(0.2)Co_(1.9)Mo_(0.1)O₉ 198 7.9 1.3Bi₂Pb_(0.2)Ca_(1.8)Ho_(0.2)Co_(1.9)Mo_(0.1)O₉ 207 6.9 0.8Bi₂Pb_(0.2)Ca_(1.8)Er_(0.2)Co_(1.9)Mo_(0.1)O₉ 190 9 1.3Bi₂Pb_(0.2)Ca_(1.8)Yb_(0.2)Co_(1.9)Mo_(0.1)O₉ 190 7.8 1.2Bi₂Ba₂Co_(1.9)Mo_(0.1)O₉ 199 8.6 0.8Bi₂Ba_(1.8)Na_(0.2)Co_(1.9)Mo_(0.1)O₉ 201 8.2 1.3Bi₂Ba_(1.8)K_(0.2)Co_(1.9)Mo_(0.1)O₉ 210 7.9 1.4Bi₂Ba_(1.8)Li_(0.2)Co_(1.9)Mo_(0.1)O₉ 206 6.9 1.1Bi₂Ba_(1.8)Ti_(0.2)Co_(1.9)Mo_(0.1)O₉ 205 8.1 1Bi₂Ba_(1.8)V_(0.2)Co_(1.9)Mo_(0.1)O₉ 198 6.9 1.3Bi₂Ba_(1.8)Cr_(0.2)Co_(1.9)Mo_(0.1)O₉ 195 7.4 0.9Bi₂Ba_(1.8)Mn_(0.2)Co_(1.9)Mo_(0.1)O₉ 200 7.8 1.1

TABLE 59 Bi₂Ba_(1.8)Fe_(0.2)Co_(1.9)Mo_(0.1)O₉ 203 7.7 1.4Bi₂Ba_(1.8)Ni_(0.2)Co_(1.9)Mo_(0.1)O₉ 201 8 1.2Bi₂Ba_(1.8)Cu_(0.2)Co_(1.9)Mo_(0.1)O₉ 208 8.2 0.9Bi₂Ba_(1.8)Zn_(0.2)Co_(1.9)Mo_(0.1)O₉ 198 7.9 1.1Bi₂Ba_(1.8)Pb_(0.2)Co_(1.9)Mo_(0.1)O₉ 199 9.1 1.2Bi₂Ba_(1.8)Ca_(0.2)Co_(1.9)Mo_(0.1)O₉ 200 8.4 0.9Bi₂Ba_(1.8)Sr_(0.2)Co_(1.9)Mo_(0.1)O₉ 206 8.6 1.1Bi₂Ba_(1.8)Al_(0.2)Co_(1.9)Mo_(0.1)O₉ 206 8.2 1.2Bi₂Ba_(1.8)Y_(0.2)Co_(1.9)Mo_(0.1)O₉ 198 7.9 1.4Bi₂Ba_(1.8)La_(0.2)Co_(1.9)Mo_(0.1)O₉ 199 8.6 0.8Bi₂Ba_(1.8)Ce_(0.2)Co_(1.9)Mo_(0.1)O₉ 200 9.1 1.3Bi₂Ba_(1.8)Pr_(0.2)Co_(1.9)Mo_(0.1)O₉ 206 6.9 1.2Bi₂Ba_(1.8)Nd_(0.2)Co_(1.9)Mo_(0.1)O₉ 205 7.4 1.1Bi₂Ba_(1.8)Sm_(0.2)Co_(1.9)Mo_(0.1)O₉ 198 7.8 1.4Bi₂Ba_(1.8)Eu_(0.2)Co_(1.9)Mo_(0.1)O₉ 199 7.7 1.2Bi₂Ba_(1.8)Gd_(0.2)Co_(1.9)Mo_(0.1)O₉ 200 8 0.9Bi₂Ba_(1.8)Dy_(0.2)Co_(1.9)Mo_(0.1)O₉ 199 8.2 1.1Bi₂Ba_(1.8)Ho_(0.2)Co_(1.9)Mo_(0.1)O₉ 210 7.9 1.2Bi₂Ba_(1.8)Er_(0.2)Co_(1.9)Mo_(0.1)O₉ 202 9.1 0.9Bi₂Ba_(1.8)Yb_(0.2)Co_(1.9)Mo_(0.1)O₉ 204 8.4 1.1Bi₂Pb_(0.2)Ba₂Co_(1.9)Mo_(0.1)O₉ 190 7.8 1.4Bi₂Pb_(0.2)Ba_(1.8)Na_(0.2)Co_(1.9)Mo_(0.1)O₉ 198 9 0.8Bi₂Pb_(0.2)Ba_(1.8)K_(0.2)Co_(1.9)Mo_(0.1)O₉ 199 8.2 1.3Bi₂Pb_(0.2)Ba_(1.8)Li_(0.2)Co_(1.9)Mo_(0.1)O₉ 201 9.1 1.2Bi₂Pb_(0.2)Ba_(1.8)Ti_(0.2)Co_(1.9)Mo_(0.1)O₉ 207 8.4 1.1Bi₂Pb_(0.2)Ba_(1.8)V_(0.2)Co_(1.9)Mo_(0.1)O₉ 190 8.6 0.8Bi₂Pb_(0.2)Ba_(1.8)Cr_(0.2)Co_(1.9)Mo_(0.1)O₉ 198 7.8 1.3Bi₂Pb_(0.2)Ba_(1.8)Mn_(0.2)Co_(1.9)Mo_(0.1)O₉ 199 9 1.4Bi₂Pb_(0.2)Ba_(1.8)Fe_(0.2)Co_(1.9)Mo_(0.1)O₉ 201 8.4 1.1Bi₂Pb_(0.2)Ba_(1.8)Ni_(0.2)Co_(1.9)Mo_(0.1)O₉ 210 8.2 1Bi₂Pb_(0.2)Ba_(1.8)Cu_(0.2)Co_(1.9)Mo_(0.1)O₉ 206 9.1 1.3Bi₂Pb_(0.2)Ba_(1.8)Zn_(0.2)Co_(1.9)Mo_(0.1)O₉ 205 8.4 0.9Bi₂Pb_(0.2)Ba_(1.8)Pb_(0.2)Co_(1.9)Mo_(0.1)O₉ 198 8.6 1.1Bi₂Pb_(0.2)Ba_(1.8)Ca_(0.2)Co_(1.9)Mo_(0.1)O₉ 195 7.8 1.4Bi₂Pb_(0.2)Ba_(1.8)Sr_(0.2)Co_(1.9)Mo_(0.1)O₉ 200 9 1.2Bi₂Pb_(0.2)Ba_(1.8)Al_(0.2)Co_(1.9)Mo_(0.1)O₉ 203 8.2 0.9

TABLE 60 Bi₂Pb_(0.2)Ba_(1.8)Y_(0.2)Co_(1.9)Mo_(0.1)O₉ 200 8.3 1.1Bi₂Pb_(0.2)Ba_(1.8)La_(0.2)Co_(1.9)Mo_(0.1)O₉ 203 8.6 1.2Bi₂Pb_(0.2)Ba_(1.8)Ce_(0.2)Co_(1.9)Mo_(0.1)O₉ 201 8.7 0.9Bi₂Pb_(0.2)Ba_(1.8)Pr_(0.2)Co_(1.9)Mo_(0.1)O₉ 208 8.3 1.1Bi₂Pb_(0.2)Ba_(1.8)Nd_(0.2)Co_(1.9)Mo_(0.1)O₉ 198 9 1.2Bi₂Pb_(0.2)Ba_(1.8)Sm_(0.2)Co_(1.9)Mo_(0.1)O₉ 199 7.9 1Bi₂Pb_(0.2)Ba_(1.8)Eu_(0.2)Co_(1.9)Mo_(0.1)O₉ 200 8.1 1.3Bi₂Pb_(0.2)Ba_(1.8)Gd_(0.2)Co_(1.9)Mo_(0.1)O₉ 199 8 1Bi₂Pb_(0.2)Ba_(1.8)Dy_(0.2)Co_(1.9)Mo_(0.1)O₉ 200 7.8 0.9Bi₂Pb_(0.2)Ba_(1.8)Ho_(0.2)Co_(1.9)Mo_(0.1)O₉ 206 7.2 1.1Bi₂Pb_(0.2)Ba_(1.8)Er_(0.2)Co_(1.9)Mo_(0.1)O₉ 206 9 1Bi₂Pb_(0.2)Ba_(1.8)Yb_(0.2)Co_(1.9)Mo_(0.1)O₉ 198 8.2 1.2Bi₂Sr₂Co_(1.9)W_(0.1)O₉ 200 6.9 0.9 Bi₂Sr_(1.8)Na_(0.2)Co_(1.9)W_(0.1)O₉206 8.1 0.8 Bi₂Sr_(1.8)K_(0.2)Co_(1.9)W_(0.1)O₉ 205 6.9 0.8Bi₂Sr_(1.8)Li_(0.2)Co_(1.9)W_(0.1)O₉ 198 7.4 1.3Bi₂Sr_(1.8)Ti_(0.2)Co_(1.9)W_(0.1)O₉ 199 7.8 1.2Bi₂Sr_(1.8)V_(0.2)Co_(1.9)W_(0.1)O₉ 200 7.7 1.1Bi₂Sr_(1.8)Cr_(0.2)Co_(1.9)W_(0.1)O₉ 199 8 1.4Bi₂Sr_(1.8)Mn_(0.2)Co_(1.9)W_(0.1)O₉ 210 8.2 1.2Bi₂Sr_(1.8)Fe_(0.2)Co_(1.9)W_(0.1)O₉ 202 7.9 0.9Bi₂Sr_(1.8)Ni_(0.2)Co_(1.9)W_(0.1)O₉ 204 9.1 1.1Bi₂Sr_(1.8)Cu_(0.2)Co_(1.9)W_(0.1)O₉ 197 8.4 1.2Bi₂Sr_(1.8)Zn_(0.2)Co_(1.9)W_(0.1)O₉ 190 8.6 0.9Bi₂Sr_(1.8)Pb_(0.2)Co_(1.9)W_(0.1)O₉ 198 8.2 1.1Bi₂Sr_(1.8)Ca_(0.2)Co_(1.9)W_(0.1)O₉ 199 7.9 1.2Bi₂Sr_(1.8)Ba_(0.2)Co_(1.9)W_(0.1)O₉ 201 8.6 1.4Bi₂Sr_(1.8)Al_(0.2)Co_(1.9)W_(0.1)O₉ 207 9.1 0.8Bi₂Sr_(1.8)Y_(0.2)Co_(1.9)W_(0.1)O₉ 190 6.9 1.3Bi₂Sr_(1.8)La_(0.2)Co_(1.9)W_(0.1)O₉ 198 7.4 1.2Bi₂Sr_(1.8)Ce_(0.2)Co_(1.9)W_(0.1)O₉ 199 7.8 1.1Bi₂Sr_(1.8)Pr_(0.2)Co_(1.9)W_(0.1)O₉ 201 7.7 0.8Bi₂Sr_(1.8)Nd_(0.2)Co_(1.9)W_(0.1)O₉ 210 8 1.3Bi₂Sr_(1.8)Sm_(0.2)Co_(1.9)W_(0.1)O₉ 206 8.2 1.4Bi₂Sr_(1.8)Eu_(0.2)Co_(1.9)W_(0.1)O₉ 205 7.9 1.1Bi₂Sr_(1.8)Gd_(0.2)Co_(1.9)W_(0.1)O₉ 198 9.1 1

TABLE 61 Bi₂Sr_(1.8)Dy_(0.2)Co_(1.9)W_(0.1)O₉ 195 8.4 1.3Bi₂Sr_(1.8)Ho_(0.2)Co_(1.9)W_(0.1)O₉ 200 8.6 0.9Bi₂Sr_(1.8)Er_(0.2)Co_(1.9)W_(0.1)O₉ 203 7.8 1.1Bi₂Sr_(1.8)Yb_(0.2)Co_(1.9)W_(0.1)O₉ 200 9 1.4Bi₂Pb_(0.2)Sr₂Co_(1.9)W_(0.1)O₉ 201 8.3 0.9Bi₂Pb_(0.2)Sr_(1.8)Na_(0.2)Co_(1.9)W_(0.1)O₉ 208 8.4 1.1Bi₂Pb_(0.2)Sr_(1.8)K_(0.2)Co_(1.9)W_(0.1)O₉ 198 8.6 1.2Bi₂Pb_(0.2)Sr_(1.8)Li_(0.2)Co_(1.9)W_(0.1)O₉ 199 8.2 0.9Bi₂Pb_(0.2)Sr_(1.8)Ti_(0.2)Co_(1.9)W_(0.1)O₉ 200 7.9 1.1Bi₂Pb_(0.2)Sr_(1.8)V_(0.2)Co_(1.9)W_(0.1)O₉ 203 8.6 1.2Bi₂Pb_(0.2)Sr_(1.8)Cr_(0.2)Co_(1.9)W_(0.1)O₉ 200 9.1 1Bi₂Pb_(0.2)Sr_(1.8)Mn_(0.2)Co_(1.9)W_(0.1)O₉ 203 6.9 1.3Bi₂Pb_(0.2)Sr_(1.8)Fe_(0.2)Co_(1.9)W_(0.1)O₉ 201 7.4 1Bi₂Pb_(0.2)Sr_(1.8)Ni_(0.2)Co_(1.9)W_(0.1)O₉ 208 7.8 0.9Bi₂Pb_(0.2)Sr_(1.8)Cu_(0.2)Co_(1.9)W_(0.1)O₉ 198 7.7 1.1Bi₂Pb_(0.2)Sr_(1.8)Zn_(0.2)Co_(1.9)W_(0.1)O₉ 199 8 1Bi₂Pb_(0.2)Sr_(1.8)Pb_(0.2)Co_(1.9)W_(0.1)O₉ 200 8.2 1.2Bi₂Pb_(0.2)Sr_(1.8)Ca_(0.2)Co_(1.9)W_(0.1)O₉ 199 7.9 1.1Bi₂Pb_(0.2)Sr_(1.8)Ba_(0.2)Co_(1.9)W_(0.1)O₉ 200 9.1 0.9Bi₂Pb_(0.2)Sr_(1.8)Al_(0.2)Co_(1.9)W_(0.1)O₉ 206 8.4 0.8Bi₂Pb_(0.2)Sr_(1.8)Y_(0.2)Co_(1.9)W_(0.1)O₉ 206 8.6 1Bi₂Pb_(0.2)Sr_(1.8)La_(0.2)Co_(1.9)W_(0.1)O₉ 198 7.8 1.3Bi₂Pb_(0.2)Sr_(1.8)Ce_(0.2)Co_(1.9)W_(0.1)O₉ 199 9 1.2Bi₂Pb_(0.2)Sr_(1.8)Pr_(0.2)Co_(1.9)W_(0.1)O₉ 200 8.2 1.3Bi₂Pb_(0.2)Sr_(1.8)Nd_(0.2)Co_(1.9)W_(0.1)O₉ 206 8.3 1Bi₂Pb_(0.2)Sr_(1.8)Sm_(0.2)Co_(1.9)W_(0.1)O₉ 205 8.6 1.3Bi₂Pb_(0.2)Sr_(1.8)Eu_(0.2)Co_(1.9)W_(0.1)O₉ 198 8.7 0.9Bi₂Pb_(0.2)Sr_(1.8)Gd_(0.2)Co_(1.9)W_(0.1)O₉ 199 8.3 1.1Bi₂Pb_(0.2)Sr_(1.8)Dy_(0.2)Co_(1.9)W_(0.1)O₉ 200 9 1.4Bi₂Pb_(0.2)Sr_(1.8)Ho_(0.2)Co_(1.9)W_(0.1)O₉ 199 7.9 1.2Bi₂Pb_(0.2)Sr_(1.8)Er_(0.2)Co_(1.9)W_(0.1)O₉ 210 8.1 0.9Bi₂Pb_(0.2)Sr_(1.8)Yb_(0.2)Co_(1.9)W_(0.1)O₉ 202 8 1.1Bi₂Ca₂Co_(1.9)W_(0.1)O₉ 197 7.2 0.9 Bi₂Ca_(1.8)Na_(0.2)Co_(1.9)W_(0.1)O₉190 9 1.1 Bi₂Ca_(1.8)K_(0.2)Co_(1.9)W_(0.1)O₉ 198 8.2 1.2

TABLE 62 Bi₂Ca_(1.8)Li_(0.2)Co_(1.9)W_(0.1)O₉ 199 7.9 1Bi₂Ca_(1.8)Ti_(0.2)Co_(1.9)W_(0.1)O₉ 201 6.9 1.3Bi₂Ca_(1.8)V_(0.2)Co_(1.9)W_(0.1)O₉ 207 8.1 1Bi₂Ca_(1.8)Cr_(0.2)Co_(1.9)W_(0.1)O₉ 208 6.9 0.9Bi₂Ca_(1.8)Mn_(0.2)Co_(1.9)W_(0.1)O₉ 198 7.4 1.1Bi₂Ca_(1.8)Fe_(0.2)Co_(1.9)W_(0.1)O₉ 199 7.8 1Bi₂Ca_(1.8)Ni_(0.2)Co_(1.9)W_(0.1)O₉ 200 7.7 1.2Bi₂Ca_(1.8)Cu_(0.2)Co_(1.9)W_(0.1)O₉ 206 8 1.1Bi₂Ca_(1.8)Zn_(0.2)Co_(1.9)W_(0.1)O₉ 205 8.2 0.9Bi₂Ca_(1.8)Pb_(0.2)Co_(1.9)W_(0.1)O₉ 198 7.9 0.8Bi₂Ca_(1.8)Sr_(0.2)Co_(1.9)W_(0.1)O₉ 206 9.1 1Bi₂Ca_(1.8)Ba_(0.2)Co_(1.9)W_(0.1)O₉ 198 8.4 1.3Bi₂Ca_(1.8)Al_(0.2)Co_(1.9)W_(0.1)O₉ 207 8.6 1.2Bi₂Ca_(1.8)Y_(0.2)Co_(1.9)W_(0.1)O₉ 190 8.2 1.3Bi₂Ca_(1.8)La_(0.2)Co_(1.9)W_(0.1)O₉ 198 7.9 1Bi₂Ca_(1.8)Ce_(0.2)Co_(1.9)W_(0.1)O₉ 199 8.6 0.8Bi₂Ca_(1.8)Pr_(0.2)Co_(1.9)W_(0.1)O₉ 201 9.1 1.1Bi₂Ca_(1.8)Nd_(0.2)Co_(1.9)W_(0.1)O₉ 210 6.9 1.2Bi₂Ca_(1.8)Sm_(0.2)Co_(1.9)W_(0.1)O₉ 206 7.4 0.9Bi₂Ca_(1.8)Eu_(0.2)Co_(1.9)W_(0.1)O₉ 205 7.8 1.1Bi₂Ca_(1.8)Gd_(0.2)Co_(1.9)W_(0.1)O₉ 198 7.7 1.2Bi₂Ca_(1.8)Dy_(0.2)Co_(1.9)W_(0.1)O₉ 195 8 1.4Bi₂Ca_(1.8)Ho_(0.2)Co_(1.9)W_(0.1)O₉ 200 8.2 0.8Bi₂Ca_(1.8)Er_(0.2)Co_(1.9)W_(0.1)O₉ 203 7.9 1.3Bi₂Ca_(1.8)Yb_(0.2)Co_(1.9)W_(0.1)O₉ 201 9.1 1.2Bi₂Pb_(0.2)Ca₂Co_(1.9)W_(0.1)O₉ 198 8.6 0.8Bi₂Pb_(0.2)Ca_(1.8)Na_(0.2)Co_(1.9)W_(0.1)O₉ 199 7.8 1.3Bi₂Pb_(0.2)Ca_(1.8)K_(0.2)Co_(1.9)W_(0.1)O₉ 200 9 1.4Bi₂Pb_(0.2)Ca_(1.8)Li_(0.2)Co_(1.9)W_(0.1)O₉ 206 8.2 1.1Bi₂Pb_(0.2)Ca_(1.8)Ti_(0.2)Co_(1.9)W_(0.1)O₉ 206 8.3 1Bi₂Pb_(0.2)Ca_(1.8)V_(0.2)Co_(1.9)W_(0.1)O₉ 198 8.6 1.3Bi₂Pb_(0.2)Ca_(1.8)Cr_(0.2)Co_(1.9)W_(0.1)O₉ 199 8.7 0.9Bi₂Pb_(0.2)Ca_(1.8)Mn_(0.2)Co_(1.9)W_(0.1)O₉ 200 8.3 1.1Bi₂Pb_(0.2)Ca_(1.8)Fe_(0.2)Co_(1.9)W_(0.1)O₉ 206 9 1.4Bi₂Pb_(0.2)Ca_(1.8)Ni_(0.2)Co_(1.9)W_(0.1)O₉ 205 7.9 1.2Bi₂Pb_(0.2)Ca_(1.8)Cu_(0.2)Co_(1.9)W_(0.1)O₉ 198 8.1 0.9

TABLE 63 Bi₂Pb_(0.2)Ca_(1.8)Zn_(0.2)Co_(1.9)W_(0.1)O₉ 199 8.0 1.1Bi₂Pb_(0.2)Ca_(1.8)Pb_(0.2)Co_(1.9)W_(0.1)O₉ 200 7.8 1.2Bi₂Pb_(0.2)Ca_(1.8)Sr_(0.2)Co_(1.9)W_(0.1)O₉ 199 7.2 0.9Bi₂Pb_(0.2)Ca_(1.8)Ba_(0.2)Co_(1.9)W_(0.1)O₉ 210 9.0 1.1Bi₂Pb_(0.2)Ca_(1.8)Al_(0.2)Co_(1.9)W_(0.1)O₉ 202 7.8 1.2Bi₂Pb_(0.2)Ca_(1.8)Y_(0.2)Co_(1.9)W_(0.1)O₉ 204 7.5 1.4Bi₂Pb_(0.2)Ca_(1.8)La_(0.2)Co_(1.9)W_(0.1)O₉ 197 8.6 0.8Bi₂Pb_(0.2)Ca_(1.8)Ce_(0.2)Co_(1.9)W_(0.1)O₉ 190 8.2 1.3Bi₂Pb_(0.2)Ca_(1.8)Pr_(0.2)Co_(1.9)W_(0.1)O₉ 198 7.9 1.2Bi₂Pb_(0.2)Ca_(1.8)Nd_(0.2)Co_(1.9)W_(0.1)O₉ 199 6.9 1.1Bi₂Pb_(0.2)Ca_(1.8)Sm_(0.2)Co_(1.9)W_(0.1)O₉ 201 9 1.4Bi₂Pb_(0.2)Ca_(1.8)Eu_(0.2)Co_(1.9)W_(0.1)O₉ 207 7.8 1.2Bi₂Pb_(0.2)Ca_(1.8)Gd_(0.2)Co_(1.9)W_(0.1)O₉ 190 7.5 0.9Bi₂Pb_(0.2)Ca_(1.8)Dy_(0.2)Co_(1.9)W_(0.1)O₉ 198 8.6 1.1Bi₂Pb_(0.2)Ca_(1.8)Ho_(0.2)Co_(1.9)W_(0.1)O₉ 199 8.2 1.2Bi₂Pb_(0.2)Ca_(1.8)Er_(0.2)Co_(1.9)W_(0.1)O₉ 201 7.9 0.9Bi₂Pb_(0.2)Ca_(1.8)Yb_(0.2)Co_(1.9)W_(0.1)O₉ 210 6.9 1.1Bi₂Ba₂Co_(1.9)W_(0.1)O₉ 205 6.9 1.4 Bi₂Ba_(1.8)Na_(0.2)Co_(1.9)W_(0.1)O₉198 7.4 0.8 Bi₂Ba_(1.8)K_(0.2)Co_(1.9)W_(0.1)O₉ 195 7.8 1.3Bi₂Ba_(1.8)Li_(0.2)Co_(1.9)W_(0.1)O₉ 200 7.7 1.2Bi₂Ba_(1.8)Ti_(0.2)Co_(1.9)W_(0.1)O₉ 203 8 1.1Bi₂Ba_(1.8)V_(0.2)Co_(1.9)W_(0.1)O₉ 200 8.2 0.8Bi₂Ba_(1.8)Cr_(0.2)Co_(1.9)W_(0.1)O₉ 203 7.9 1.3Bi₂Ba_(1.8)Mn_(0.2)Co_(1.9)W_(0.1)O₉ 201 9.1 1.4Bi₂Ba_(1.8)Fe_(0.2)Co_(1.9)W_(0.1)O₉ 208 8.4 1.1Bi₂Ba_(1.8)Ni_(0.2)Co_(1.9)W_(0.1)O₉ 198 8.6 1Bi₂Ba_(1.8)Cu_(0.2)Co_(1.9)W_(0.1)O₉ 199 8.2 1.3Bi₂Ba_(1.8)Zn_(0.2)Co_(1.9)W_(0.1)O₉ 200 7.9 0.9Bi₂Ba_(1.8)Pb_(0.2)Co_(1.9)W_(0.1)O₉ 206 8.6 1.1Bi₂Ba_(1.8)Ca_(0.2)Co_(1.9)W_(0.1)O₉ 205 9.1 1.4Bi₂Ba_(1.8)Sr_(0.2)Co_(1.9)W_(0.1)O₉ 198 6.9 1.2Bi₂Ba_(1.8)Al_(0.2)Co_(1.9)W_(0.1)O₉ 206 7.4 0.9Bi₂Ba_(1.8)Y_(0.2)Co_(1.9)W_(0.1)O₉ 198 7.8 1.1Bi₂Ba_(1.8)La_(0.2)Co_(1.9)W_(0.1)O₉ 207 7.7 1.2Bi₂Ba_(1.8)Ce_(0.2)Co_(1.9)W_(0.1)O₉ 190 8.0 0.9

TABLE 64 Bi₂Ba_(1.8)Pr_(0.2)Co_(1.9)W_(0.1)O₉ 190 8.2 1.1Bi₂Ba_(1.8)Nd_(0.2)Co_(1.9)W_(0.1)O₉ 198 7.9 1.2Bi₂Ba_(1.8)Sm_(0.2)Co_(1.9)W_(0.1)O₉ 199 9.1 1Bi₂Ba_(1.8)Eu_(0.2)Co_(1.9)W_(0.1)O₉ 201 8.4 1.3Bi₂Ba_(1.8)Gd_(0.2)Co_(1.9)W_(0.1)O₉ 210 8.6 1Bi₂Ba_(1.8)Dy_(0.2)Co_(1.9)W_(0.1)O₉ 206 7.8 0.9Bi₂Ba_(1.8)Ho_(0.2)Co_(1.9)W_(0.1)O₉ 205 9 1.1Bi₂Ba_(1.8)Er_(0.2)Co_(1.9)W_(0.1)O₉ 198 8.2 1Bi₂Ba_(1.8)Yb_(0.2)Co_(1.9)W_(0.1)O₉ 195 9.1 1.2Bi₂Pb_(0.2)Ba₂Co_(1.9)W_(0.1)O₉ 203 8.6 0.9Bi₂Pb_(0.2)Ba_(1.8)Na_(0.2)Co_(1.9)W_(0.1)O₉ 201 7.8 0.8Bi₂Pb_(0.2)Ba_(1.8)K_(0.2)Co_(1.9)W_(0.1)O₉ 208 9 1Bi₂Pb_(0.2)Ba_(1.8)Li_(0.2)Co_(1.9)W_(0.1)O₉ 198 8.4 1.3Bi₂Pb_(0.2)Ba_(1.8)Ti_(0.2)Co_(1.9)W_(0.1)O₉ 199 7.8 1.2Bi₂Pb_(0.2)Ba_(1.8)V_(0.2)Co_(1.9)W_(0.1)O₉ 200 8 1.3Bi₂Pb_(0.2)Ba_(1.8)Cr_(0.2)Co_(1.9)W_(0.1)O₉ 206 7.8 0.9Bi₂Pb_(0.2)Ba_(1.8)Mn_(0.2)Co_(1.9)W_(0.1)O₉ 206 7.2 1.1Bi₂Pb_(0.2)Ba_(1.8)Fe_(0.2)Co_(1.9)W_(0.1)O₉ 198 9 1.4Bi₂Pb_(0.2)Ba_(1.8)Ni_(0.2)Co_(1.9)W_(0.1)O₉ 199 7.8 1.2Bi₂Pb_(0.2)Ba_(1.8)Cu_(0.2)Co_(1.9)W_(0.1)O₉ 200 7.5 0.9Bi₂Pb_(0.2)Ba_(1.8)Zn_(0.2)Co_(1.9)W_(0.1)O₉ 206 8.6 1.1Bi₂Pb_(0.2)Ba_(1.8)Pb_(0.2)Co_(1.9)W_(0.1)O₉ 205 8.2 1.2Bi₂Pb_(0.2)Ba_(1.8)Ca_(0.2)Co_(1.9)W_(0.1)O₉ 198 7.9 0.9Bi₂Pb_(0.2)Ba_(1.8)Sr_(0.2)Co_(1.9)W_(0.1)O₉ 199 6.9 1.1Bi₂Pb_(0.2)Ba_(1.8)Al_(0.2)Co_(1.9)W_(0.1)O₉ 200 9 1.2Bi₂Pb_(0.2)Ba_(1.8)Y_(0.2)Co_(1.9)W_(0.1)O₉ 199 7.8 1Bi₂Pb_(0.2)Ba_(1.8)La_(0.2)Co_(1.9)W_(0.1)O₉ 210 7.5 1.3Bi₂Pb_(0.2)Ba_(1.8)Ce_(0.2)Co_(1.9)W_(0.1)O₉ 202 8.6 1Bi₂Pb_(0.2)Ba_(1.8)Pr_(0.2)Co_(1.9)W_(0.1)O₉ 204 8.2 0.9Bi₂Pb_(0.2)Ba_(1.8)Nd_(0.2)Co_(1.9)W_(0.1)O₉ 197 7.9 1.1Bi₂Pb_(0.2)Ba_(1.8)Sm_(0.2)Co_(1.9)W_(0.1)O₉ 190 6.9 1Bi₂Pb_(0.2)Ba_(1.8)Eu_(0.2)Co_(1.9)W_(0.1)O₉ 198 8.1 1.2Bi₂Pb_(0.2)Ba_(1.8)Gd_(0.2)Co_(1.9)W_(0.1)O₉ 199 6.9 1.1Bi₂Pb_(0.2)Ba_(1.8)Dy_(0.2)Co_(1.9)W_(0.1)O₉ 201 7.4 0.9Bi₂Pb_(0.2)Ba_(1.8)Ho_(0.2)Co_(1.9)W_(0.1)O₉ 207 7.8 0.8Bi₂Pb_(0.2)Ba_(1.8)Er_(0.2)Co_(1.9)W_(0.1)O₉ 190 7.7 1

TABLE 65 Bi₂Pb_(0.2)Ba_(1.8)Yb_(0.2)Co_(1.9)W_(0.1)O₉ 198 8 1.3Bi₂Sr₂Co_(1.9)Nb_(0.1)O₉ 201 7.9 0.7Bi₂Sr_(1.8)Na_(0.2)Co_(1.9)Nb_(0.1)O₉ 210 9.1 1.3Bi₂Sr_(1.8)K_(0.2)Co_(1.9)Nb_(0.1)O₉ 206 8.4 1.4Bi₂Sr_(1.8)Li_(0.2)Co_(1.9)Nb_(0.1)O₉ 205 8.6 1.1Bi₂Sr_(1.8)Ti_(0.2)Co_(1.9)Nb_(0.1)O₉ 198 8.2 1Bi₂Sr_(1.8)V_(0.2)Co_(1.9)Nb_(0.1)O₉ 195 7.9 1.3Bi₂Sr_(1.8)Cr_(0.2)Co_(1.9)Nb_(0.1)O₉ 200 8.6 0.9Bi₂Sr_(1.8)Mn_(0.2)Co_(1.9)Nb_(0.1)O₉ 203 9.1 1.1Bi₂Sr_(1.8)Fe_(0.2)Co_(1.9)Nb_(0.1)O₉ 200 6.9 1.4Bi₂Sr_(1.8)Ni_(0.2)Co_(1.9)Nb_(0.1)O₉ 203 7.4 1.2Bi₂Sr_(1.8)Cu_(0.2)Co_(1.9)Nb_(0.1)O₉ 201 7.8 0.9Bi₂Sr_(1.8)Zn_(0.2)Co_(1.9)Nb_(0.1)O₉ 208 7.7 1.1Bi₂Sr_(1.8)Pb_(0.2)Co_(1.9)Nb_(0.1)O₉ 198 8 1.2Bi₂Sr_(1.8)Ca_(0.2)Co_(1.9)Nb_(0.1)O₉ 199 8.2 0.9Bi₂Sr_(1.8)Ba_(0.2)Co_(1.9)Nb_(0.1)O₉ 200 7.9 1.1Bi₂Sr_(1.8)Al_(0.2)Co_(1.9)Nb_(0.1)O₉ 199 9.1 1.2Bi₂Sr_(1.8)Y_(0.2)Co_(1.9)Nb_(0.1)O₉ 200 8.4 1.4Bi₂Sr_(1.8)La_(0.2)Co_(1.9)Nb_(0.1)O₉ 206 8.6 0.8Bi₂Sr_(1.8)Ce_(0.2)Co_(1.9)Nb_(0.1)O₉ 206 7.8 1.3Bi₂Sr_(1.8)Pr_(0.2)Co_(1.9)Nb_(0.1)O₉ 198 9 1.2Bi₂Sr_(1.8)Nd_(0.2)Co_(1.9)Nb_(0.1)O₉ 199 8.2 1.1Bi₂Sr_(1.8)Sm_(0.2)Co_(1.9)Nb_(0.1)O₉ 200 9.1 0.8Bi₂Sr_(1.8)Eu_(0.2)Co_(1.9)Nb_(0.1)O₉ 206 8.4 1.3Bi₂Sr_(1.8)Gd_(0.2)Co_(1.9)Nb_(0.1)O₉ 205 8.6 1.4Bi₂Sr_(1.8)Dy_(0.2)Co_(1.9)Nb_(0.1)O₉ 198 7.8 1.1Bi₂Sr_(1.8)Ho_(0.2)Co_(1.9)Nb_(0.1)O₉ 199 9 1Bi₂Sr_(1.8)Er_(0.2)Co_(1.9)Nb_(0.1)O₉ 200 8.4 1.3Bi₂Sr_(1.8)Yb_(0.2)Co_(1.9)Nb_(0.1)O₉ 199 7.8 0.9Bi₂Pb_(0.2)Sr₂Co_(1.9)Nb_(0.1)O₉ 202 8.2 1.4Bi₂Pb_(0.2)Sr_(1.8)Na_(0.2)Co_(1.9)Nb_(0.1)O₉ 204 8.3 1.2Bi₂Pb_(0.2)Sr_(1.8)K_(0.2)Co_(1.9)Nb_(0.1)O₉ 197 8.6 0.9Bi₂Pb_(0.2)Sr_(1.8)Li_(0.2)Co_(1.9)Nb_(0.1)O₉ 190 8.7 1.1Bi₂Pb_(0.2)Sr_(1.8)Ti_(0.2)Co_(1.9)Nb_(0.1)O₉ 198 8.3 1.2Bi₂Pb_(0.2)Sr_(1.8)V_(0.2)Co_(1.9)Nb_(0.1)O₉ 199 9 0.9

TABLE 66 Bi₂Pb_(0.2)Sr_(1.8)Cr_(0.2)Co_(1.9)Nb_(0.1)O₉ 201 7.9 1.1Bi₂Pb_(0.2)Sr_(1.8)Mn_(0.2)Co_(1.9)Nb_(0.1)O₉ 207 8.1 1.2Bi₂Pb_(0.2)Sr_(1.8)Fe_(0.2)Co_(1.9)Nb_(0.1)O₉ 190 8 1.4Bi₂Pb_(0.2)Sr_(1.8)Ni_(0.2)Co_(1.9)Nb_(0.1)O₉ 198 7.8 0.8Bi₂Pb_(0.2)Sr_(1.8)Cu_(0.2)Co_(1.9)Nb_(0.1)O₉ 199 7.2 1.3Bi₂Pb_(0.2)Sr_(1.8)Zn_(0.2)Co_(1.9)Nb_(0.1)O₉ 201 9 1.2Bi₂Pb_(0.2)Sr_(1.8)Pb_(0.2)Co_(1.9)Nb_(0.1)O₉ 210 8.2 1.1Bi₂Pb_(0.2)Sr_(1.8)Ca_(0.2)Co_(1.9)Nb_(0.1)O₉ 206 7.9 0.8Bi₂Pb_(0.2)Sr_(1.8)Ba_(0.2)Co_(1.9)Nb_(0.1)O₉ 205 6.9 0.7Bi₂Pb_(0.2)Sr_(1.8)Al_(0.2)Co_(1.9)Nb_(0.1)O₉ 198 8.1 1.3Bi₂Pb_(0.2)Sr_(1.8)Y_(0.2)Co_(1.9)Nb_(0.1)O₉ 195 6.9 0.8Bi₂Pb_(0.2)Sr_(1.8)La_(0.2)Co_(1.9)Nb_(0.1)O₉ 200 7.4 1.3Bi₂Pb_(0.2)Sr_(1.8)Ce_(0.2)Co_(1.9)Nb_(0.1)O₉ 203 7.8 1.2Bi₂Pb_(0.2)Sr_(1.8)Pr_(0.2)Co_(1.9)Nb_(0.1)O₉ 200 7.7 1.1Bi₂Pb_(0.2)Sr_(1.8)Nd_(0.2)Co_(1.9)Nb_(0.1)O₉ 203 8 0.8Bi₂Pb_(0.2)Sr_(1.8)Sm_(0.2)Co_(1.9)Nb_(0.1)O₉ 201 8.2 1.3Bi₂Pb_(0.2)Sr_(1.8)Eu_(0.2)Co_(1.9)Nb_(0.1)O₉ 208 7.9 1.4Bi₂Pb_(0.2)Sr_(1.8)Gd_(0.2)Co_(1.9)Nb_(0.1)O₉ 198 9.1 1.1Bi₂Pb_(0.2)Sr_(1.8)Dy_(0.2)Co_(1.9)Nb_(0.1)O₉ 199 8.4 1Bi₂Pb_(0.2)Sr_(1.8)Ho_(0.2)Co_(1.9)Nb_(0.1)O₉ 200 8.6 1.3Bi₂Pb_(0.2)Sr_(1.8)Er_(0.2)Co_(1.9)Nb_(0.1)O₉ 203 8.2 0.9Bi₂Pb_(0.2)Sr_(1.8)Yb_(0.2)Co_(1.9)Nb_(0.1)O₉ 200 7.9 1.1Bi₂Ca₂Co_(1.9)Nb_(0.1)O₉ 201 9.1 1.2Bi₂Ca_(1.8)Na_(0.2)Co_(1.9)Nb_(0.1)O₉ 208 6.9 0.9Bi₂Ca_(1.8)K_(0.2)Co_(1.9)Nb_(0.1)O₉ 198 7.4 1.1Bi₂Ca_(1.8)Li_(0.2)Co_(1.9)Nb_(0.1)O₉ 199 7.8 1.2Bi₂Ca_(1.8)Ti_(0.2)Co_(1.9)Nb_(0.1)O₉ 200 7.7 0.9Bi₂Ca_(1.8)V_(0.2)Co_(1.9)Nb_(0.1)O₉ 199 8 1.1Bi₂Ca_(1.8)Cr_(0.2)Co_(1.9)Nb_(0.1)O₉ 200 8.2 1.2Bi₂Ca_(1.8)Mn_(0.2)Co_(1.9)Nb_(0.1)O₉ 206 7.9 1.4Bi₂Ca_(1.8)Fe_(0.2)Co_(1.9)Nb_(0.1)O₉ 206 9.1 0.8Bi₂Ca_(1.8)Ni_(0.2)Co_(1.9)Nb_(0.1)O₉ 198 8.4 1.3Bi₂Ca_(1.8)Cu_(0.2)Co_(1.9)Nb_(0.1)O₉ 199 8.6 1.2Bi₂Ca_(1.8)Zn_(0.2)Co_(1.9)Nb_(0.1)O₉ 200 7.8 1.1Bi₂Ca_(1.8)Pb_(0.2)Co_(1.9)Nb_(0.1)O₉ 206 9 1.4Bi₂Ca_(1.8)Sr_(0.2)Co_(1.9)Nb_(0.1)O₉ 205 8.2 1.2

TABLE 67 Bi₂Ca_(1.8)Ba_(0.2)Co_(1.9)Nb_(0.1)O₉ 198 8.3 0.9Bi₂Ca_(1.8)Al_(0.2)Co_(1.9)Nb_(0.1)O₉ 199 8.4 1.1Bi₂Ca_(1.8)Y_(0.2)Co_(1.9)Nb_(0.1)O₉ 200 8.6 1.2Bi₂Ca_(1.8)La_(0.2)Co_(1.9)Nb_(0.1)O₉ 199 8.2 0.9Bi₂Ca_(1.8)Ce_(0.2)Co_(1.9)Nb_(0.1)O₉ 210 7.9 1.1Bi₂Ca_(1.8)Pr_(0.2)Co_(1.9)Nb_(0.1)O₉ 202 8.6 1.2Bi₂Ca_(1.8)Nd_(0.2)Co_(1.9)Nb_(0.1)O₉ 204 9.1 1.4Bi₂Ca_(1.8)Sm_(0.2)Co_(1.9)Nb_(0.1)O₉ 197 6.9 0.8Bi₂Ca_(1.8)Eu_(0.2)Co_(1.9)Nb_(0.1)O₉ 190 7.4 1.3Bi₂Ca_(1.8)Gd_(0.2)Co_(1.9)Nb_(0.1)O₉ 198 7.8 1.2Bi₂Ca_(1.8)Dy_(0.2)Co_(1.9)Nb_(0.1)O₉ 199 7.7 1.1Bi₂Ca_(1.8)Ho_(0.2)Co_(1.9)Nb_(0.1)O₉ 201 8 0.8Bi₂Ca_(1.8)Er_(0.2)Co_(1.9)Nb_(0.1)O₉ 207 8.2 1.3Bi₂Ca_(1.8)Yb_(0.2)Co_(1.9)Nb_(0.1)O₉ 190 7.9 1.4Bi₂Pb_(0.2)Ca₂Co_(1.9)Nb_(0.1)O₉ 199 8.4 1Bi₂Pb_(0.2)Ca_(1.8)Na_(0.2)Co_(1.9)Nb_(0.1)O₉ 201 8.6 1.3Bi₂Pb_(0.2)Ca_(1.8)K_(0.2)Co_(1.9)Nb_(0.1)O₉ 210 7.8 0.9Bi₂Pb_(0.2)Ca_(1.8)Li_(0.2)Co_(1.9)Nb_(0.1)O₉ 198 9 1.1Bi₂Pb_(0.2)Ca_(1.8)Ti_(0.2)Co_(1.9)Nb_(0.1)O₉ 200 8.2 1.4Bi₂Pb_(0.2)Ca_(1.8)V_(0.2)Co_(1.9)Nb_(0.1)O₉ 203 8.3 1.2Bi₂Pb_(0.2)Ca_(1.8)Cr_(0.2)Co_(1.9)Nb_(0.1)O₉ 201 8.6 0.9Bi₂Pb_(0.2)Ca_(1.8)Mn_(0.2)Co_(1.9)Nb_(0.1)O₉ 208 8.7 1.1Bi₂Pb_(0.2)Ca_(1.8)Fe_(0.2)Co_(1.9)Nb_(0.1)O₉ 198 8.3 1.2Bi₂Pb_(0.2)Ca_(1.8)Ni_(0.2)Co_(1.9)Nb_(0.1)O₉ 199 9 0.9Bi₂Pb_(0.2)Ca_(1.8)Cu_(0.2)Co_(1.9)Nb_(0.1)O₉ 200 7.9 1.1Bi₂Pb_(0.2)Ca_(1.8)Zn_(0.2)Co_(1.9)Nb_(0.1)O₉ 206 8.1 1.2Bi₂Pb_(0.2)Ca_(1.8)Pb_(0.2)Co_(1.9)Nb_(0.1)O₉ 206 8 1Bi₂Pb_(0.2)Ca_(1.8)Sr_(0.2)Co_(1.9)Nb_(0.1)O₉ 198 7.8 1.3Bi₂Pb_(0.2)Ca_(1.8)Ba_(0.2)Co_(1.9)Nb_(0.1)O₉ 199 7.2 1Bi₂Pb_(0.2)Ca_(1.8)Al_(0.2)Co_(1.9)Nb_(0.1)O₉ 200 9 0.9Bi₂Pb_(0.2)Ca_(1.8)Y_(0.2)Co_(1.9)Nb_(0.1)O₉ 206 8.2 1.1Bi₂Pb_(0.2)Ca_(1.8)La_(0.2)Co_(1.9)Nb_(0.1)O₉ 205 7.9 1Bi₂Pb_(0.2)Ca_(1.8)Ce_(0.2)Co_(1.9)Nb_(0.1)O₉ 198 6.9 1.2Bi₂Pb_(0.2)Ca_(1.8)Pr_(0.2)Co_(1.9)Nb_(0.1)O₉ 199 8.1 1.1Bi₂Pb_(0.2)Ca_(1.8)Nd_(0.2)Co_(1.9)Nb_(0.1)O₉ 200 6.9 1Bi₂Pb_(0.2)Ca_(1.8)Sm_(0.2)Co_(1.9)Nb_(0.1)O₉ 199 7.4 0.9

TABLE 68 Bi₂Pb_(0.2)Ca_(1.8)Eu_(0.2)Co_(1.9)Nb_(0.1)O₉ 210 7.8 1.1Bi₂Pb_(0.2)Ca_(1.8)Gd_(0.2)Co_(1.9)Nb_(0.1)O₉ 202 7.7 1Bi₂Pb_(0.2)Ca_(1.8)Dy_(0.2)Co_(1.9)Nb_(0.1)O₉ 204 8 1.2Bi₂Pb_(0.2)Ca_(1.8)Ho_(0.2)Co_(1.9)Nb_(0.1)O₉ 197 8.2 1.1Bi₂Pb_(0.2)Ca_(1.8)Er_(0.2)Co_(1.9)Nb_(0.1)O₉ 190 7.9 0.9Bi₂Pb_(0.2)Ca_(1.8)Yb_(0.2)Co_(1.9)Nb_(0.1)O₉ 198 9.1 0.8Bi₂Ba₂Co_(1.9)Nb_(0.1)O₉ 201 8.6 1.3Bi₂Ba_(1.8)Na_(0.2)Co_(1.9)Nb_(0.1)O₉ 207 8.2 1.2Bi₂Ba_(1.8)K_(0.2)Co_(1.9)Nb_(0.1)O₉ 190 7.9 1.3Bi₂Ba_(1.8)Li_(0.2)Co_(1.9)Nb_(0.1)O₉ 198 8.6 1Bi₂Ba_(1.8)Ti_(0.2)Co_(1.9)Nb_(0.1)O₉ 199 9.1 0.8Bi₂Ba_(1.8)V_(0.2)Co_(1.9)Nb_(0.1)O₉ 201 6.9 1.1Bi₂Ba_(1.8)Cr_(0.2)Co_(1.9)Nb_(0.1)O₉ 210 7.4 1.2Bi₂Ba_(1.8)Mn_(0.2)Co_(1.9)Nb_(0.1)O₉ 206 7.8 0.9Bi₂Ba_(1.8)Fe_(0.2)Co_(1.9)Nb_(0.1)O₉ 205 7.7 1.1Bi₂Ba_(1.8)Ni_(0.2)Co_(1.9)Nb_(0.1)O₉ 198 8 1.2Bi₂Ba_(1.8)Cu_(0.2)Co_(1.9)Nb_(0.1)O₉ 195 8.2 1.4Bi₂Ba_(1.8)Zn_(0.2)Co_(1.9)Nb_(0.1)O₉ 200 7.9 0.8Bi₂Ba_(1.8)Pb_(0.2)Co_(1.9)Nb_(0.1)O₉ 203 9.1 1.3Bi₂Ba_(1.8)Ca_(0.2)Co_(1.9)Nb_(0.1)O₉ 200 8.4 1.2Bi₂Ba_(1.8)Sr_(0.2)Co_(1.9)Nb_(0.1)O₉ 203 8.6 1.1Bi₂Ba_(1.8)Al_(0.2)Co_(1.9)Nb_(0.1)O₉ 201 7.8 0.8Bi₂Ba_(1.8)Y_(0.2)Co_(1.9)Nb_(0.1)O₉ 208 9 1.3Bi₂Ba_(1.8)La_(0.2)Co_(1.9)Nb_(0.1)O₉ 198 8.2 1.4Bi₂Ba_(1.8)Ce_(0.2)Co_(1.9)Nb_(0.1)O₉ 199 8.3 1.1Bi₂Ba_(1.8)Pr_(0.2)Co_(1.9)Nb_(0.1)O₉ 200 8.6 1Bi₂Ba_(1.8)Nd_(0.2)Co_(1.9)Nb_(0.1)O₉ 199 8.7 1.3Bi₂Ba_(1.8)Sm_(0.2)Co_(1.9)Nb_(0.1)O₉ 200 8.3 0.9Bi₂Ba_(1.8)Eu_(0.2)Co_(1.9)Nb_(0.1)O₉ 206 9 1.1Bi₂Ba_(1.8)Gd_(0.2)Co_(1.9)Nb_(0.1)O₉ 206 7.9 1.4Bi₂Ba_(1.8)Dy_(0.2)Co_(1.9)Nb_(0.1)O₉ 198 8.1 1.2Bi₂Ba_(1.8)Ho_(0.2)Co_(1.9)Nb_(0.1)O₉ 199 8 0.9Bi₂Ba_(1.8)Er_(0.2)Co_(1.9)Nb_(0.1)O₉ 200 7.8 1.1Bi₂Ba_(1.8)Yb_(0.2)Co_(1.9)Nb_(0.1)O₉ 206 7.2 1.2Bi₂Pb_(0.2)Ba_(0.2)Co_(1.9)Nb_(0.1)O₉ 198 7.8 1.1

TABLE 69 Bi₂Pb_(0.2)Ba_(1.8)Na_(0.2)Co_(1.9)Nb_(0.1)O₉ 199 7.5 1.2Bi₂Pb_(0.2)Ba_(1.8)K_(0.2)Co_(1.9)Nb_(0.1)O₉ 200 8.6 1.4Bi₂Pb_(0.2)Ba_(1.8)Li_(0.2)Co_(1.9)Nb_(0.1)O₉ 199 8.2 0.8Bi₂Pb_(0.2)Ba_(1.8)Ti_(0.2)Co_(1.9)Nb_(0.1)O₉ 210 7.9 1.3Bi₂Pb_(0.2)Ba_(1.8)V_(0.2)Co_(1.9)Nb_(0.1)O₉ 202 6.9 1.2Bi₂Pb_(0.2)Ba_(1.8)Cr_(0.2)Co_(1.9)Nb_(0.1)O₉ 204 9 1.1Bi₂Pb_(0.2)Ba_(1.8)Mn_(0.2)Co_(1.9)Nb_(0.1)O₉ 197 7.8 1.4Bi₂Pb_(0.2)Ba_(1.8)Fe_(0.2)Co_(1.9)Nb_(0.1)O₉ 190 7.5 1.2Bi₂Pb_(0.2)Ba_(1.8)Ni_(0.2)Co_(1.9)Nb_(0.1)O₉ 198 8.6 0.9Bi₂Pb_(0.2)Ba_(1.8)Cu_(0.2)Co_(1.9)Nb_(0.1)O₉ 199 8.2 1.1Bi₂Pb_(0.2)Ba_(1.8)Zn_(0.2)Co_(1.9)Nb_(0.1)O₉ 201 7.9 1.2Bi₂Pb_(0.2)Ba_(1.8)Pb_(0.2)Co_(1.9)Nb_(0.1)O₉ 207 6.9 0.9Bi₂Pb_(0.2)Ba_(1.8)Ca_(0.2)Co_(1.9)Nb_(0.1)O₉ 190 8.1 1.1Bi₂Pb_(0.2)Ba_(1.8)Sr_(0.2)Co_(1.9)Nb_(0.1)O₉ 198 6.9 1.2Bi₂Pb_(0.2)Ba_(1.8)Al_(0.2)Co_(1.9)Nb_(0.1)O₉ 199 7.4 1.4Bi₂Pb_(0.2)Ba_(1.8)Y_(0.2)Co_(1.9)Nb_(0.1)O₉ 201 7.8 0.8Bi₂Pb_(0.2)Ba_(1.8)La_(0.2)Co_(1.9)Nb_(0.1)O₉ 210 7.7 1.3Bi₂Pb_(0.2)Ba_(1.8)Ce_(0.2)Co_(1.9)Nb_(0.1)O₉ 206 8 1.2Bi₂Pb_(0.2)Ba_(1.8)Pr_(0.2)Co_(1.9)Nb_(0.1)O₉ 205 8.2 1.1Bi₂Pb_(0.2)Ba_(1.8)Nd_(0.2)Co_(1.9)Nb_(0.1)O₉ 198 7.9 0.8Bi₂Pb_(0.2)Ba_(1.8)Sm_(0.2)Co_(1.9)Nb_(0.1)O₉ 195 9.1 1.3Bi₂Pb_(0.2)Ba_(1.8)Eu_(0.2)Co_(1.9)Nb_(0.1)O₉ 200 8.4 1.4Bi₂Pb_(0.2)Ba_(1.8)Gd_(0.2)Co_(1.9)Nb_(0.1)O₉ 203 8.6 1.1Bi₂Pb_(0.2)Ba_(1.8)Dy_(0.2)Co_(1.9)Nb_(0.1)O₉ 200 8.2 1Bi₂Pb_(0.2)Ba_(1.8)Ho_(0.2)Co_(1.9)Nb_(0.1)O₉ 203 7.9 1.3Bi₂Pb_(0.2)Ba_(1.8)Er_(0.2)Co_(1.9)Nb_(0.1)O₉ 201 8.6 0.9Bi₂Pb_(0.2)Ba_(1.8)Yb_(0.2)Co_(1.9)Nb_(0.1)O₉ 208 9.1 1.1Bi₂Sr₂Co_(1.9)Ta_(0.1)O₉ 199 7.4 1.2Bi₂Sr_(1.8)Na_(0.2)Co_(1.9)Ta_(0.1)O₉ 200 7.8 0.9Bi₂Sr_(1.8)K_(0.2)Co_(1.9)Ta_(0.1)O₉ 203 7.7 1.1Bi₂Sr_(1.8)Li_(0.2)Co_(1.9)Ta_(0.1)O₉ 200 8 1.2Bi₂Sr_(1.8)Ti_(0.2)Co_(1.9)Ta_(0.1)O₉ 203 8.2 0.9Bi₂Sr_(1.8)V_(0.2)Co_(1.9)Ta_(0.1)O₉ 201 7.9 1.1Bi₂Sr_(1.8)Cr_(0.2)Co_(1.9)Ta_(0.1)O₉ 208 9.1 1.2Bi₂Sr_(1.8)Mn_(0.2)Co_(1.9)Ta_(0.1)O₉ 198 8.4 1Bi₂Sr_(1.8)Fe_(0.2)Co_(1.9)Ta_(0.1)O₉ 199 8.6 1.3

TABLE 70 Bi₂Sr_(1.8)Ni_(0.2)Co_(1.9)Ta_(0.1)O₉ 200 7.8 1Bi₂Sr_(1.8)Cu_(0.2)Co_(1.9)Ta_(0.1)O₉ 199 9 0.9Bi₂Sr_(1.8)Zn_(0.2)Co_(1.9)Ta_(0.1)O₉ 200 8.2 1.1Bi₂Sr_(1.8)Pb_(0.2)Co_(1.9)Ta_(0.1)O₉ 206 9.1 1Bi₂Sr_(1.8)Ca_(0.2)Co_(1.9)Ta_(0.1)O₉ 206 8.4 1.2Bi₂Sr_(1.8)Ba_(0.2)Co_(1.9)Ta_(0.1)O₉ 198 8.6 1.1Bi₂Sr_(1.8)Al_(0.2)Co_(1.9)Ta_(0.1)O₉ 199 7.2 0.9Bi₂Sr_(1.8)Y_(0.2)Co_(1.9)Ta_(0.1)O₉ 200 9 0.8Bi₂Sr_(1.8)La_(0.2)Co_(1.9)Ta_(0.1)O₉ 206 8.2 1Bi₂Sr_(1.8)Ce_(0.2)Co_(1.9)Ta_(0.1)O₉ 205 7.9 1.3Bi₂Sr_(1.8)Pr_(0.2)Co_(1.9)Ta_(0.1)O₉ 198 6.9 1.2Bi₂Sr_(1.8)Nd_(0.2)Co_(1.9)Ta_(0.1)O₉ 199 8.1 1.3Bi₂Sr_(1.8)Sm_(0.2)Co_(1.9)Ta_(0.1)O₉ 200 6.9 0.9Bi₂Sr_(1.8)Eu_(0.2)Co_(1.9)Ta_(0.1)O₉ 199 7.4 1.1Bi₂Sr_(1.8)Gd_(0.2)Co_(1.9)Ta_(0.1)O₉ 210 7.8 1.4Bi₂Sr_(1.8)Dy_(0.2)Co_(1.9)Ta_(0.1)O₉ 202 7.7 1.2Bi₂Sr_(1.8)Ho_(0.2)Co_(1.9)Ta_(0.1)O₉ 204 8 0.9Bi₂Sr_(1.8)Er_(0.2)Co_(1.9)Ta_(0.1)O₉ 197 8.2 1.1Bi₂Sr_(1.8)Yb_(0.2)Co_(1.9)Ta_(0.1)O₉ 190 7.9 1.2Bi₂Pb_(0.2)Sr₂Co_(1.9)Ta_(0.1)O₉ 199 8.4 1.1Bi₂Pb_(0.2)Sr_(1.8)Na_(0.2)Co_(1.9)Ta_(0.1)O₉ 201 8.6 1.2Bi₂Pb_(0.2)Sr_(1.8)K_(0.2)Co_(1.9)Ta_(0.1)O₉ 207 8.2 1Bi₂Pb_(0.2)Sr_(1.8)Li_(0.2)Co_(1.9)Ta_(0.1)O₉ 190 7.9 1.3Bi₂Pb_(0.2)Sr_(1.8)Ti_(0.2)Co_(1.9)Ta_(0.1)O₉ 198 8.6 1Bi₂Pb_(0.2)Sr_(1.8)V_(0.2)Co_(1.9)Ta_(0.1)O₉ 199 9.1 0.9Bi₂Pb_(0.2)Sr_(1.8)Cr_(0.2)Co_(1.9)Ta_(0.1)O₉ 201 6.9 1.1Bi₂Pb_(0.2)Sr_(1.8)Mn_(0.2)Co_(1.9)Ta_(0.1)O₉ 210 7.4 1Bi₂Pb_(0.2)Sr_(1.8)Fe_(0.2)Co_(1.9)Ta_(0.1)O₉ 200 7.8 1.2Bi₂Pb_(0.2)Sr_(1.8)Ni_(0.2)Co_(1.9)Ta_(0.1)O₉ 206 7.7 1.1Bi₂Pb_(0.2)Sr_(1.8)Cu_(0.2)Co_(1.9)Ta_(0.1)O₉ 206 8.0 0.9Bi₂Pb_(0.2)Sr_(1.8)Zn_(0.2)Co_(1.9)Ta_(0.1)O₉ 198 8.2 0.8Bi₂Pb_(0.2)Sr_(1.8)Pb_(0.2)Co_(1.9)Ta_(0.1)O₉ 199 7.9 1Bi₂Pb_(0.2)Sr_(1.8)Ca_(0.2)Co_(1.9)Ta_(0.1)O₉ 200 9.1 1.3Bi₂Pb_(0.2)Sr_(1.8)Ba_(0.2)Co_(1.9)Ta_(0.1)O₉ 206 8.4 1.2Bi₂Pb_(0.2)Sr_(1.8)Al_(0.2)Co_(1.9)Ta_(0.1)O₉ 205 8.6 0.7Bi₂Pb_(0.2)Sr_(1.8)Y_(0.2)Co_(1.9)Ta_(0.1)O₉ 198 7.8 1.3

TABLE 71 Bi₂Pb_(0.2)Sr_(1.8)La_(0.2)Co_(1.9)Ta_(0.1)O₉ 199 9.0 1.4Bi₂Pb_(0.2)Sr_(1.8)Ce_(0.2)Co_(1.9)Ta_(0.1)O₉ 200 8.2 1.1Bi₂Pb_(0.2)Sr_(1.8)Pr_(0.2)Co_(1.9)Ta_(0.1)O₉ 199 8.3 1Bi₂Pb_(0.2)Sr_(1.8)Nd_(0.2)Co_(1.9)Ta_(0.1)O₉ 210 8.4 1.3Bi₂Pb_(0.2)Sr_(1.8)Sm_(0.2)Co_(1.9)Ta_(0.1)O₉ 202 8.6 0.9Bi₂Pb_(0.2)Sr_(1.8)Eu_(0.2)Co_(1.9)Ta_(0.1)O₉ 204 8.2 1.1Bi₂Pb_(0.2)Sr_(1.8)Gd_(0.2)Co_(1.9)Ta_(0.1)O₉ 197 7.9 1.4Bi₂Pb_(0.2)Sr_(1.8)Dy_(0.2)Co_(1.9)Ta_(0.1)O₉ 190 8.6 1.2Bi₂Pb_(0.2)Sr_(1.8)Ho_(0.2)Co_(1.9)Ta_(0.1)O₉ 198 9.1 0.9Bi₂Pb_(0.2)Sr_(1.8)Er_(0.2)Co_(1.9)Ta_(0.1)O₉ 199 6.9 1.1Bi₂Pb_(0.2)Sr_(1.8)Yb_(0.2)Co_(1.9)Ta_(0.1)O₉ 201 7.4 1.2Bi₂Ca₂Co_(1.9)Ta_(0.1)O₉ 190 7.7 1.1Bi₂Ca_(1.8)Na_(0.2)Co_(1.9)Ta_(0.1)O₉ 198 8 1.2Bi₂Ca_(1.8)K_(0.2)Co_(1.9)Ta_(0.1)O₉ 199 8.2 1.4Bi₂Ca_(1.8)Li_(0.2)Co_(1.9)Ta_(0.1)O₉ 201 7.9 0.8Bi₂Ca_(1.8)Ti_(0.2)Co_(1.9)Ta_(0.1)O₉ 210 9.1 1.3Bi₂Ca_(1.8)V_(0.2)Co_(1.9)Ta_(0.1)O₉ 206 8.4 1.2Bi₂Ca_(1.8)Cr_(0.2)Co_(1.9)Ta_(0.1)O₉ 205 8.6 1.1Bi₂Ca_(1.8)Mn_(0.2)Co_(1.9)Ta_(0.1)O₉ 198 7.8 0.8Bi₂Ca_(1.8)Fe_(0.2)Co_(1.9)Ta_(0.1)O₉ 195 9 1.3Bi₂Ca_(1.8)Ni_(0.2)Co_(1.9)Ta_(0.1)O₉ 200 8.2 1.4Bi₂Ca_(1.8)Cu_(0.2)Co_(1.9)Ta_(0.1)O₉ 203 8.3 1.1Bi₂Ca_(1.8)Zn_(0.2)Co_(1.9)Ta_(0.1)O₉ 200 8.6 1Bi₂Ca_(1.8)Pb_(0.2)Co_(1.9)Ta_(0.1)O₉ 203 8.7 1.3Bi₂Ca_(1.8)Sr_(0.2)Co_(1.9)Ta_(0.1)O₉ 201 8.3 0.9Bi₂Ca_(1.8)Ba_(0.2)Co_(1.9)Ta_(0.1)O₉ 208 9 1.1Bi₂Ca_(1.8)Al_(0.2)Co_(1.9)Ta_(0.1)O₉ 198 7.9 1.4Bi₂Ca_(1.8)Y_(0.2)Co_(1.9)Ta_(0.1)O₉ 199 8.1 1.2Bi₂Ca_(1.8)La_(0.2)Co_(1.9)Ta_(0.1)O₉ 200 8 0.9Bi₂Ca_(1.8)Ce_(0.2)Co_(1.9)Ta_(0.1)O₉ 199 7.8 1.1Bi₂Ca_(1.8)Pr_(0.2)Co_(1.9)Ta_(0.1)O₉ 200 7.2 1.2Bi₂Ca_(1.8)Nd_(0.2)Co_(1.9)Ta_(0.1)O₉ 206 9 0.9Bi₂Ca_(1.8)Sm_(0.2)Co_(1.9)Ta_(0.1)O₉ 206 8.2 1.3Bi₂Ca_(1.8)Eu_(0.2)Co_(1.9)Ta_(0.1)O₉ 198 7.9 1.4Bi₂Ca_(1.8)Gd_(0.2)Co_(1.9)Ta_(0.1)O₉ 199 6.9 1.1Bi₂Ca_(1.8)Dy_(0.2)Co_(1.9)Ta_(0.1)O₉ 200 8.1 1.0

TABLE 72 Bi₂Ca_(1.8)Ho_(0.2)Co_(1.9)Ta_(0.1)O₉ 206 6.9 1.3Bi₂Ca_(1.8)Er_(0.2)Co_(1.9)Ta_(0.1)O₉ 205 7.4 0.9Bi₂Ca_(1.8)Yb_(0.2)Co_(1.9)Ta_(0.1)O₉ 198 7.8 1.1Bi₂Pb_(0.2)Ca₂Co_(1.9)Ta_(0.1)O₉ 200 8 1.2Bi₂Pb_(0.2)Ca_(1.8)Na_(0.2)Co_(1.9)Ta_(0.1)O₉ 199 8.2 0.9Bi₂Pb_(0.2)Ca_(1.8)K_(0.2)Co_(1.9)Ta_(0.1)O₉ 210 7.9 1.1Bi₂Pb_(0.2)Ca_(1.8)Li_(0.2)Co_(1.9)Ta_(0.1)O₉ 202 9.1 1.2Bi₂Pb_(0.2)Ca_(1.8)Ti_(0.2)Co_(1.9)Ta_(0.1)O₉ 204 8.4 0.9Bi₂Pb_(0.2)Ca_(1.8)V_(0.2)Co_(1.9)Ta_(0.1)O₉ 197 8.6 1.1Bi₂Pb_(0.2)Ca_(1.8)Cr_(0.2)Co_(1.9)Ta_(0.1)O₉ 190 8.2 1.2Bi₂Pb_(0.2)Ca_(1.8)Mn_(0.2)Co_(1.9)Ta_(0.1)O₉ 198 7.9 1.4Bi₂Pb_(0.2)Ca_(1.8)Fe_(0.2)Co_(1.9)Ta_(0.1)O₉ 199 8.6 0.8Bi₂Pb_(0.2)Ca_(1.8)Ni_(0.2)Co_(1.9)Ta_(0.1)O₉ 201 9.1 1.3Bi₂Pb_(0.2)Ca_(1.8)Cu_(0.2)Co_(1.9)Ta_(0.1)O₉ 207 6.9 1.2Bi₂Pb_(0.2)Ca_(1.8)Zn_(0.2)Co_(1.9)Ta_(0.1)O₉ 190 7.4 1.1Bi₂Pb_(0.2)Ca_(1.8)Pb_(0.2)Co_(1.9)Ta_(0.1)O₉ 198 7.8 0.8Bi₂Pb_(0.2)Ca_(1.8)Sr_(0.2)Co_(1.9)Ta_(0.1)O₉ 199 7.7 1.3Bi₂Pb_(0.2)Ca_(1.8)Ba_(0.2)Co_(1.9)Ta_(0.1)O₉ 201 8 1.4Bi₂Pb_(0.2)Ca_(1.8)Al_(0.2)Co_(1.9)Ta_(0.1)O₉ 210 8.2 1.1Bi₂Pb_(0.2)Ca_(1.8)Y_(0.2)Co_(1.9)Ta_(0.1)O₉ 206 7.9 1Bi₂Pb_(0.2)Ca_(1.8)La_(0.2)Co_(1.9)Ta_(0.1)O₉ 205 9.1 1.3Bi₂Pb_(0.2)Ca_(1.8)Ce_(0.2)Co_(1.9)Ta_(0.1)O₉ 198 8.4 0.9Bi₂Pb_(0.2)Ca_(1.8)Pr_(0.2)Co_(1.9)Ta_(0.1)O₉ 195 8.6 1.1Bi₂Pb_(0.2)Ca_(1.8)Nd_(0.2)Co_(1.9)Ta_(0.1)O₉ 200 7.8 1.4Bi₂Pb_(0.2)Ca_(1.8)Sm_(0.2)Co_(1.9)Ta_(0.1)O₉ 203 9 1.2Bi₂Pb_(0.2)Ca_(1.8)Eu_(0.2)Co_(1.9)Ta_(0.1)O₉ 200 8.2 0.9Bi₂Pb_(0.2)Ca_(1.8)Gd_(0.2)Co_(1.9)Ta_(0.1)O₉ 203 8.3 1.1Bi₂Pb_(0.2)Ca_(1.8)Dy_(0.2)Co_(1.9)Ta_(0.1)O₉ 201 8.6 1.2Bi₂Pb_(0.2)Ca_(1.8)Ho_(0.2)Co_(1.9)Ta_(0.1)O₉ 208 8.7 0.9Bi₂Pb_(0.2)Ca_(1.8)Er_(0.2)Co_(1.9)Ta_(0.1)O₉ 198 8.3 1.1Bi₂Pb_(0.2)Ca_(1.8)Yb_(0.2)Co_(1.9)Ta_(0.1)O₉ 199 9 1.2Bi₂Ba₂Co_(1.9)Ta_(0.1)O₉ 203 8.1 0.8Bi₂Ba_(1.8)Na_(0.2)Co_(1.9)Ta_(0.1)O₉ 200 8 1.3Bi₂Ba_(1.8)K_(0.2)Co_(1.9)Ta_(0.1)O₉ 203 7.8 1.2Bi₂Ba_(1.8)Li_(0.2)Co_(1.9)Ta_(0.1)O₉ 201 7.2 1.1Bi₂Ba_(1.8)Ti_(0.2)Co_(1.9)Ta_(0.1)O₉ 208 9 0.8Bi₂Ba_(1.8)V_(0.2)Co_(1.9)Ta_(0.1)O₉ 198 7.8 0.7

TABLE 73 Bi₂Ba_(1.8)Cr_(0.2)Co_(1.9)Ta_(0.1)O₉ 199 7.5 1.3Bi₂Ba_(1.8)Mn_(0.2)Co_(1.9)Ta_(0.1)O₉ 200 8.6 0.8Bi₂Ba_(1.8)Fe_(0.2)Co_(1.9)Ta_(0.1)O₉ 199 8.2 1.3Bi₂Ba_(1.8)Ni_(0.2)Co_(1.9)Ta_(0.1)O₉ 200 7.9 1.2Bi₂Ba_(1.8)Cu_(0.2)Co_(1.9)Ta_(0.1)O₉ 206 6.9 1.1Bi₂Ba_(1.8)Zn_(0.2)Co_(1.9)Ta_(0.1)O₉ 206 9 0.8Bi₂Ba_(1.8)Pb_(0.2)Co_(1.9)Ta_(0.1)O₉ 198 7.8 1.3Bi₂Ba_(1.8)Ca_(0.2)Co_(1.9)Ta_(0.1)O₉ 199 7.5 1.4Bi₂Ba_(1.8)Sr_(0.2)Co_(1.9)Ta_(0.1)O₉ 200 8.6 1.1Bi₂Ba_(1.8)Al_(0.2)Co_(1.9)Ta_(0.1)O₉ 206 8.2 1Bi₂Ba_(1.8)Y_(0.2)Co_(1.9)Ta_(0.1)O₉ 205 7.9 1.3Bi₂Ba_(1.8)La_(0.2)Co_(1.9)Ta_(0.1)O₉ 198 6.9 0.9Bi₂Ba_(1.8)Ce_(0.2)Co_(1.9)Ta_(0.1)O₉ 199 8.1 1.1Bi₂Ba_(1.8)Pr_(0.2)Co_(1.9)Ta_(0.1)O₉ 200 6.9 1.4Bi₂Ba_(1.8)Nd_(0.2)Co_(1.9)Ta_(0.1)O₉ 199 7.4 1.2Bi₂Ba_(1.8)Sm_(0.2)Co_(1.9)Ta_(0.1)O₉ 210 7.8 0.9Bi₂Ba_(1.8)Eu_(0.2)Co_(1.9)Ta_(0.1)O₉ 202 7.7 1.1Bi₂Ba_(1.8)Gd_(0.2)Co_(1.9)Ta_(0.1)O₉ 204 8 1.2Bi₂Ba_(1.8)Dy_(0.2)Co_(1.9)Ta_(0.1)O₉ 197 8.2 0.9Bi₂Ba_(1.8)Ho_(0.2)Co_(1.9)Ta_(0.1)O₉ 190 7.9 1.1Bi₂Ba_(1.8)Er_(0.2)Co_(1.9)Ta_(0.1)O₉ 198 9.1 1.2Bi₂Ba_(1.8)Yb_(0.2)Co_(1.9)Ta_(0.1)O₉ 199 8.4 1.4Bi₂Pb_(0.2)Ba₂Co_(1.9)Ta_(0.1)O₉ 207 8.2 1.3Bi₂Pb_(0.2)Ba_(1.8)Na_(0.2)Co_(1.9)Ta_(0.1)O₉ 190 7.9 1.2Bi₂Pb_(0.2)Ba_(1.8)K_(0.2)Co_(1.9)Ta_(0.1)O₉ 198 8.6 1.1Bi₂Pb_(0.2)Ba_(1.8)Li_(0.2)Co_(1.9)Ta_(0.1)O₉ 199 9.1 1.4Bi₂Pb_(0.2)Ba_(1.8)Ti_(0.2)Co_(1.9)Ta_(0.1)O₉ 201 6.9 1.2Bi₂Pb_(0.2)Ba_(1.8)V_(0.2)Co_(1.9)Ta_(0.1)O₉ 210 7.4 0.9Bi₂Pb_(0.2)Ba_(1.8)Cr_(0.2)Co_(1.9)Ta_(0.1)O₉ 198 7.8 1.1Bi₂Pb_(0.2)Ba_(1.8)Mn_(0.2)Co_(1.9)Ta_(0.1)O₉ 200 7.7 1.2Bi₂Pb_(0.2)Ba_(1.8)Fe_(0.2)Co_(1.9)Ta_(0.1)O₉ 203 8 0.9Bi₂Pb_(0.2)Ba_(1.8)Ni_(0.2)Co_(1.9)Ta_(0.1)O₉ 201 8.2 1.1Bi₂Pb_(0.2)Ba_(1.8)Cu_(0.2)Co_(1.9)Ta_(0.1)O₉ 208 7.9 1.2Bi₂Pb_(0.2)Ba_(1.8)Zn_(0.2)Co_(1.9)Ta_(0.1)O₉ 198 9.1 1.4Bi₂Pb_(0.2)Ba_(1.8)Pb_(0.2)Co_(1.9)Ta_(0.1)O₉ 199 8.4 0.8Bi₂Pb_(0.2)Ba_(1.8)Ca_(0.2)Co_(1.9)Ta_(0.1)O₉ 200 8.6 1.3Bi₂Pb_(0.2)Ba_(1.8)Sr_(0.2)Co_(1.9)Ta_(0.1)O₉ 206 7.8 1.2

TABLE 74 Bi₂Pb_(0.2)Ba_(1.8)Al_(0.2)Co_(1.9)Ta_(0.1)O₉ 206 9.0 1.1Bi₂Pb_(0.2)Ba_(1.8)Y_(0.2)Co_(1.9)Ta_(0.1)O₉ 198 8.2 0.8Bi₂Pb_(0.2)Ba_(1.8)La_(0.2)Co_(1.9)Ta_(0.1)O₉ 199 9.1 1.3Bi₂Pb_(0.2)Ba_(1.8)Ce_(0.2)Co_(1.9)Ta_(0.1)O₉ 200 8.4 1.4Bi₂Pb_(0.2)Ba_(1.8)Pr_(0.2)Co_(1.9)Ta_(0.1)O₉ 206 8.6 1.1Bi₂Pb_(0.2)Ba_(1.8)Nd_(0.2)Co_(1.9)Ta_(0.1)O₉ 205 7.8 1Bi₂Pb_(0.2)Ba_(1.8)Sm_(0.2)Co_(1.9)Ta_(0.1)O₉ 198 9 1.3Bi₂Pb_(0.2)Ba_(1.8)Eu_(0.2)Co_(1.9)Ta_(0.1)O₉ 199 7.8 0.9Bi₂Pb_(0.2)Ba_(1.8)Gd_(0.2)Co_(1.9)Ta_(0.1)O₉ 200 7.5 1.1Bi₂Pb_(0.2)Ba_(1.8)Dy_(0.2)Co_(1.9)Ta_(0.1)O₉ 199 8.6 1.4Bi₂Pb_(0.2)Ba_(1.8)Ho_(0.2)Co_(1.9)Ta_(0.1)O₉ 210 8.2 1.2Bi₂Pb_(0.2)Ba_(1.8)Er_(0.2)Co_(1.9)Ta_(0.1)O₉ 202 7.9 0.9Bi₂Pb_(0.2)Ba_(1.8)Yb_(0.2)Co_(1.9)Ta_(0.1)O₉ 204 6.9 1.1Bi₂Sr_(1.9)Na_(0.1)Co₂O₉ 199 8.6 1.2Bi₂Sr_(1.9)Na_(0.1)Co_(1.9)Ti_(0.1)O₉ 201 8.2 1Bi₂Sr_(1.9)Na_(0.1)Co_(1.9)V_(0.1)O₉ 207 7.9 1.3Bi₂Sr_(1.9)Na_(0.1)Co_(1.9)Cr_(0.1)O₉ 190 6.9 1Bi₂Sr_(1.9)Na_(0.1)Co_(1.9)Mn_(0.1)O₉ 198 8.1 0.9Bi₂Sr_(1.9)Na_(0.1)Co_(1.9)Fe_(0.1)O₉ 199 6.9 1.1Bi₂Sr_(1.9)Na_(0.1)Co_(1.9)Cu_(0.1)O₉ 201 7.4 1Bi₂Sr_(1.9)Na_(0.1)Co_(1.9)Ag_(0.1)O₉ 210 7.8 1.2Bi₂Sr_(1.9)Na_(0.1)Co_(1.9)Mo_(0.1)O₉ 206 7.7 1.1Bi₂Sr_(1.9)Na_(0.1)Co_(1.9)W_(0.1)O₉ 205 8 1Bi₂Sr_(1.9)Na_(0.1)Co_(1.9)Nb_(0.1)O₉ 198 8.2 0.9Bi₂Sr_(1.9)Na_(0.1)Co_(1.9)Ta_(0.1)O₉ 195 7.9 1.1Bi₂Sr_(1.9)K_(0.1)Co₂O₉ 203 8.4 1.2 Bi₂Sr_(1.9)K_(0.1)Co_(1.9)Ti_(0.1)O₉200 8.6 1.1 Bi₂Sr_(1.9)K_(0.1)Co_(1.9)V_(0.1)O₉ 203 8.2 0.9Bi₂Sr_(1.9)K_(0.1)Co_(1.9)Cr_(0.1)O₉ 201 7.9 0.8Bi₂Sr_(1.9)K_(0.1)Co_(1.9)Mn_(0.1)O₉ 208 8.6 1Bi₂Sr_(1.9)K_(0.1)Co_(1.9)Fe_(0.1)O₉ 198 9.1 1.3Bi₂Sr_(1.9)K_(0.1)Co_(1.9)Cu_(0.1)O₉ 199 6.9 1.2Bi₂Sr_(1.9)K_(0.1)Co_(1.9)Ag_(0.1)O₉ 200 7.4 1.3Bi₂Sr_(1.9)K_(0.1)Co_(1.9)Mo_(0.1)O₉ 199 7.8 1Bi₂Sr_(1.9)K_(0.1)Co_(1.9)W_(0.1)O₉ 200 7.7 0.8Bi₂Sr_(1.9)K_(0.1)Co_(1.9)Nb_(0.1)O₉ 206 8 1.1Bi₂Sr_(1.9)K_(0.1)Co_(1.9)Ta_(0.1)O₉ 206 8.2 1.2

As is clear from the above results, the complex oxides represented bythe formulae shown in Tables 7 to 74 exhibit excellent properties as ap-type thermoelectric material and have favorable electricalconductivity. Therefore, the complex oxides can possibly demonstrateexcellent thermoelectric generation properties when used in place of thep-type thermoelectric materials of the Examples.

Reference Example 2

A complex oxide having properties of the n-type thermoelectric materialrepresented by the formula Ln_(m)R_(n) ¹Ni_(p)R_(q) ²O_(r) or(Ln_(s)R_(t) ³)₂Ni_(u)R_(v) ⁴O_(w) was prepared by the following method.

As a starting material, nitrates comprising an element of an intendedcomplex oxide were used. The starting materials were completelydissolved in distilled water in such a manner as to yield the atomicratio of each formula shown in Tables 75 to 121. The solution wasthoroughly mixed while stirring in a crucible of alumina, and solidifiedby evaporating the water. The solidified product was calcined at 600° C.in air for 10 hours to decompose the nitrates. The obtained calcinatewas crushed, and then molded under pressure. The molded body was heatedin a 300 mL/min oxygen stream for 20 hours, thereby producing a complexoxide. The heating temperature and heating time varied in the range of700 to 1100° C. in such a manner that an intended oxide is produced.

The complex oxides obtained were measured for the Seebeck coefficient at700° C., electrical resistivity at 700° C. and thermal conductivity at700° C. Tables 75 to 121 show the measurement results.

TABLE 75 n-type Electrical Seebeck Resistivity Thermal CompositionCoefficient mΩcm Conductivity Ln_(m)R¹ _(n)Ni_(p)R² _(q)O_(r) μV/K (700°C.) (700° C.) W/mK (700° C.) LaNiO₃ −22 2.2 4.2 CeNiO₃ −19 1.9 4.1PrNiO₃ −25 1.8 3.9 NdNiO₃ −30 2.9 4 SmNiO₃ −28 3.1 3.8 EuNiO₃ −27 2.23.7 GdNiO₃ −25 2.1 4 DyNiO₃ −18 3 3.9 HoNiO₃ −22 2.8 3.6 ErNiO₃ −10 3.24.1 YbNiO₃ −26 3.1 3.9 La_(0.9)Na_(0.1)NiO₃ −19 2.4 4.3La_(0.9)K_(0.1)NiO₃ −17 2.8 4 La_(0.9)Sr_(0.1)NiO₃ −23 2.9 4.7La_(0.9)Ca_(0.1)NiO₃ −22 3 4.2 La_(0.9)Bi_(0.1)NiO₃ −18 2.8 4.3 −20 3.54.9 Ce_(0.9)Na_(0.1)NiO₃ −21 4 3.9 Ce_(0.9)K_(0.1)NiO₃ −21 3.9 4.2Ce_(0.9)Sr_(0.1)NiO₃ −22 2.1 4 Ce_(0.9)Ca_(0.1)NiO₃ −18 2.6 4.7Ce_(0.9)Bi_(0.1)NiO₃ −25 2.8 4.6 Pr_(0.9)Na_(0.1)NiO₃ −28 3.9 4.2Pr_(0.9)K_(0.1)NiO₃ −19 3.8 4.7 Pr_(0.9)Sr_(0.1)NiO₃ −20 2.7 4.8Pr_(0.9)Ca_(0.1)NiO₃ −26 1.9 4.1 Pr_(0.9)Bi_(0.1)NiO₃ −23 2.8 3.8Nd_(0.9)Na_(0.1)NiO₃ −19 3.4 4.6 Nd_(0.9)K_(0.1)NiO₃ −17 2.8 4.2Nd_(0.9)Sr_(0.1)NiO₃ −20 3 4.5 Nd_(0.9)Ca_(0.1)NiO₃ −22 2.9 4.3

TABLE 76 Nd_(0.9)Bi_(0.1)NiO₃ −20 1.8 4.2 Sm_(0.9)Na_(0.1)NiO₃ −23 3.13.9 Sm_(0.9)K_(0.1)NiO₃ −18 2.2 4 Sm_(0.9)Sr_(0.1)NiO₃ −28 2.1 3.8Sm_(0.9)Ca_(0.1)NiO₃ −19 3 3.7 Sm_(0.9)Bi_(0.1)NiO₃ −24 2.8 4Eu_(0.9)Na_(0.1)NiO₃ −16 3.1 3.6 Eu_(0.9)K_(0.1)NiO₃ −20 3 4.1Eu_(0.9)Sr_(0.1)NiO₃ −22 2.4 3.9 Eu_(0.9)Ca_(0.1)NiO₃ −24 2.8 4.6Eu_(0.9)Bi_(0.1)NiO₃ −23 2.9 4.3 Gd_(0.9)Na_(0.1)NiO₃ −28 2.8 4.7Gd_(0.9)K_(0.1)NiO₃ −19 3.5 4.2 Gd_(0.9)Sr_(0.1)NiO₃ −21 4 4.3Gd_(0.9)Ca_(0.1)NiO₃ −22 3.9 4.9 Gd_(0.9)Bi_(0.1)NiO₃ −24 2.1 3.9Dy_(0.9)Na_(0.1)NiO₃ −29 2.8 4 Dy_(0.9)K_(0.1)NiO₃ −17 2.7 4.7Dy_(0.9)Sr_(0.1)NiO₃ −18 3.9 4.6 Dy_(0.9)Ca_(0.1)NiO₃ −24 3.8 4.5Dy_(0.9)Bi_(0.1)NiO₃ −22 2.7 4.2 Ho_(0.9)Na_(0.1)NiO₃ −27 2.8 4.8Ho_(0.9)K_(0.1)NiO₃ −21 3.7 4.1 Ho_(0.9)Sr_(0.1)NiO₃ −23 3.4 3.8Ho_(0.9)Ca_(0.1)NiO₃ −19 2.8 4 Ho_(0.9)Bi_(0.1)NiO₃ −23 3 4.6Er_(0.9)Na_(0.1)NiO₃ −25 2.2 4.5 Er_(0.9)K_(0.1)NiO₃ −16 1.9 4.3Er_(0.9)Sr_(0.1)NiO₃ −20 1.8 4.1 Er_(0.9)Ca_(0.1)NiO₃ −22 2.9 3.9Er_(0.9)Bi_(0.1)NiO₃ −29 3.1 4

TABLE 77 Yb_(0.9)Na_(0.1)NiO₃ −22 2.2 3.8 Yb_(0.9)K_(0.1)NiO₃ −19 2.13.7 Yb_(0.9)Sr_(0.1)NiO₃ −25 3 4 Yb_(0.9)Ca_(0.1)NiO₃ −30 2.8 3.9Yb_(0.9)Bi_(0.1)NiO₃ −28 3.2 3.6 LaNi_(0.9)Ti_(0.1)O₃ −25 3 3.9LaNi_(0.9)V_(0.1)O₃ −18 2.4 4.6 LaNi_(0.9)Cr_(0.1)O₃ −22 2.8 4.3LaNi_(0.9)Mn_(0.1)O₃ −10 2.9 4 LaNi_(0.9)Fe_(0.1)O₃ −26 3 4.7LaNi_(0.9)Co_(0.1)O₃ −20 2.8 4.2 LaNi_(0.9)Cu_(0.1)O₃ −19 3.5 4.3LaNi_(0.9)Mo_(0.1)O₃ −17 4 4.9 LaNi_(0.9)W_(0.1)O₃ −23 3.9 3.9LaNi_(0.9)Nb_(0.1)O₃ −22 2.1 4.2 LaNi_(0.9)Ta_(0.1)O₃ −18 2.6 4CeNi_(0.9)Ti_(0.1)O₃ −21 2.7 4.6 CeNi_(0.9)V_(0.1)O₃ −21 3.9 4.5CeNi_(0.9)Cr_(0.1)O₃ −22 3.8 4.2 CeNi_(0.9)Mn_(0.1)O₃ −18 2.7 4.7CeNi_(0.9)Fe_(0.1)O₃ −25 1.9 4.8 CeNi_(0.9)Co_(0.1)O₃ −24 2.8 4.1CeNi_(0.9)Cu_(0.1)O₃ −28 3.7 3.8 CeNi_(0.9)Mo_(0.1)O₃ −19 3.4 4CeNi_(0.9)W_(0.1)O₃ −20 2.8 4.6 CeNi_(0.9)Nb_(0.1)O₃ −26 3 4.2CeNi_(0.9)Ta_(0.1)O₃ −23 2.9 4.5 PrNi_(0.9)Ti_(0.1)O₃ −19 2.9 4.2PrNi_(0.9)V_(0.1)O₃ −17 3.1 4.1 PrNi_(0.9)Cr_(0.1)O₃ −20 2.2 3.9PrNi_(0.9)Mn_(0.1)O₃ −22 2.1 4 PrNi_(0.9)Fe_(0.1)O₃ −20 3 3.8PrNi_(0.9)Co_(0.1)O₃ −21 2.8 3.7 PrNi_(0.9)Cu_(0.1)O₃ −23 3.2 4

TABLE 78 PrNi_(0.9)Mo_(0.1)O₃ −18 3.1 3.9 PrNi_(0.9)W_(0.1)O₃ −28 3 3.6PrNi_(0.9)Nb_(0.1)O₃ −19 2.4 4.1 PrNi_(0.9)Ta_(0.1)O₃ −24 2.8 3.9NdNi_(0.9)Ti_(0.1)O₃ −16 3 4.3 NdNi_(0.9)V_(0.1)O₃ −20 2.8 4NdNi_(0.9)Cr_(0.1)O₃ −22 3.5 4.7 NdNi_(0.9)Mn_(0.1)O₃ −24 4 4.2NdNi_(0.9)Fe_(0.1)O₃ −23 3.9 4.3 NdNi_(0.9)Co_(0.1)O₃ −26 2.1 4.9NdNi_(0.9)Cu_(0.1)O₃ −28 2.6 3.9 NdNi_(0.9)Mo_(0.1)O₃ −19 2.2 4.2NdNi_(0.9)W_(0.1)O₃ −21 1.9 4 NdNi_(0.9)Nb_(0.1)O₃ −22 1.8 4.7NdNi_(0.9)Ta_(0.1)O₃ −24 2.9 4.6 SmNi_(0.9)Ti_(0.1)O₃ −29 2.2 4.2SmNi_(0.9)V_(0.1)O₃ −17 2.1 4.7 SmNi_(0.9)Cr_(0.1)O₃ −18 3 4.8SmNi_(0.9)Mn_(0.1)O₃ −24 2.8 4.1 SmNi_(0.9)Fe_(0.1)O₃ −22 3.2 3.8SmNi_(0.9)Co_(0.1)O₃ −21 3.1 4 SmNi_(0.9)Cu_(0.1)O₃ −27 3 4.6SmNi_(0.9)Mo_(0.1)O₃ −25 2.4 4.2 SmNi_(0.9)W_(0.1)O₃ −30 2.8 4.1SmNi_(0.9)Nb_(0.1)O₃ −28 2.9 3.9 SmNi_(0.9)Ta_(0.1)O₃ −27 3 4EuNi_(0.9)Ti_(0.1)O₃ −18 3.5 3.7 EuNi_(0.9)V_(0.1)O₃ −22 4 4EuNi_(0.9)Cr_(0.1)O₃ −10 3.9 3.9 EuNi_(0.9)Mn_(0.1)O₃ −26 2.1 3.6EuNi_(0.9)Fe_(0.1)O₃ −20 2.6 4.1 EuNi_(0.9)Co_(0.1)O₃ −19 2.8 3.9EuNi_(0.9)Cu_(0.1)O₃ −17 2.7 4.6 EuNi_(0.9)Mo_(0.1)O₃ −23 3.9 4.3

TABLE 79 EuNi_(0.9)W_(0.1)O₃ −22 3.8 4 EuNi_(0.9)Nb_(0.1)O₃ −18 2.7 4.7EuNi_(0.9)Ta_(0.1)O₃ −20 1.9 4.2 GdNi_(0.9)Ti_(0.1)O₃ −21 3.7 4.9GdNi_(0.9)V_(0.1)O₃ −22 3.4 3.9 GdNi_(0.9)Cr_(0.1)O₃ −18 2.8 4.2GdNi_(0.9)Mn_(0.1)O₃ −25 3 4 GdNi_(0.9)Fe_(0.1)O₃ −24 2.9 4.7GdNi_(0.9)Co_(0.1)O₃ −28 1.8 4.6 GdNi_(0.9)Cu_(0.1)O₃ −19 2.9 4.5GdNi_(0.9)Mo_(0.1)O₃ −20 3.1 4.2 GdNi_(0.9)W_(0.1)O₃ −26 2.2 4.7GdNi_(0.9)Nb_(0.1)O₃ −23 2.1 4.8 GdNi_(0.9)Ta_(0.1)O₃ −22 3 4.1DyNi_(0.9)Ti_(0.1)O₃ −17 3.2 4 DyNi_(0.9)V_(0.1)O₃ −20 3.1 4.6DyNi_(0.9)Cr_(0.1)O₃ −22 3 4.2 DyNi_(0.9)Mn_(0.1)O₃ −20 2.4 4.5DyNi_(0.9)Fe_(0.1)O₃ −21 2.8 4.3 DyNi_(0.9)Co_(0.1)O₃ −23 2.9 4.2DyNi_(0.9)Cu_(0.1)O₃ −18 3 4.1 DyNi_(0.9)Mo_(0.1)O₃ −28 2.8 3.9DyNi_(0.9)W_(0.1)O₃ −19 3.5 4 DyNi_(0.9)Nb_(0.1)O₃ −24 4 3.8DyNi_(0.9)Ta_(0.1)O₃ −25 3.9 3.7 HoNi_(0.9)Ti_(0.1)O₃ −20 2.6 3.9HoNi_(0.9)V_(0.1)O₃ −22 2.8 3.6 HoNi_(0.9)Cr_(0.1)O₃ −24 2.7 4.1HoNi_(0.9)Mn_(0.1)O₃ −23 3.9 3.9 HoNi_(0.9)Fe_(0.1)O₃ −26 1.8 4.6HoNi_(0.9)Co_(0.1)O₃ −28 2.9 4.3 HoNi_(0.9)Cu_(0.1)O₃ −19 3.1 4HoNi_(0.9)Mo_(0.1)O₃ −21 2.2 4.7 HoNi_(0.9)W_(0.1)O₃ −22 2.1 4.2

TABLE 80 HoNi_(0.9)Nb_(0.1)O₃ −24 3 4.3 HoNi_(0.9)Ta_(0.1)O₃ −21 2.8 4.9ErNi_(0.9)Ti_(0.1)O₃ −17 3.1 4.2 ErNi_(0.9)V_(0.1)O₃ −18 3 4ErNi_(0.9)Cr_(0.1)O₃ −24 2.4 4.7 ErNi_(0.9)Mn_(0.1)O₃ −22 2.8 4.6ErNi_(0.9)Fe_(0.1)O₃ −21 2.9 4.5 ErNi_(0.9)Co_(0.1)O₃ −27 3 4.2ErNi_(0.9)Cu_(0.1)O₃ −21 2.8 4.7 ErNi_(0.9)Mo_(0.1)O₃ −23 3.5 4.8ErNi_(0.9)W_(0.1)O₃ −19 4 4.1 ErNi_(0.9)Nb_(0.1)O₃ −23 3.9 3.8ErNi_(0.9)Ta_(0.1)O₃ −24 2.1 4 YbNi_(0.9)Ti_(0.1)O₃ −16 2.8 4.2YbNi_(0.9)V_(0.1)O₃ −20 2.7 4.5 YbNi_(0.9)Cr_(0.1)O₃ −22 3.9 4.3YbNi_(0.9)Mn_(0.1)O₃ −29 3.8 4.1 YbNi_(0.9)Fe_(0.1)O₃ −28 2.7 3.9YbNi_(0.9)Co_(0.1)O₃ −27 1.9 4 YbNi_(0.9)Cu_(0.1)O₃ −25 2.8 3.8YbNi_(0.9)Mo_(0.1)O₃ −18 3.7 3.7 YbNi_(0.9)W_(0.1)O₃ −22 3.4 4YbNi_(0.9)Nb_(0.1)O₃ −10 2.8 3.9 YbNi_(0.9)Ta_(0.1)O₃ −26 3 3.6La_(0.9)Na_(0.1)Ni_(0.9)Ti_(0.1)O₃ −19 1.8 3.9La_(0.9)Na_(0.1)Ni_(0.9)V_(0.1)O₃ −17 2.9 4.6La_(0.9)Na_(0.1)Ni_(0.9)Cr_(0.1)O₃ −23 3.1 4.3La_(0.9)Na_(0.1)Ni_(0.9)Mn_(0.1)O₃ −22 2.2 4La_(0.9)Na_(0.1)Ni_(0.9)Fe_(0.1)O₃ −18 2.1 4.7La_(0.9)Na_(0.1)Ni_(0.9)Co_(0.1)O₃ −20 3 4.2La_(0.9)Na_(0.1)Ni_(0.9)Cu_(0.1)O₃ −21 2.8 4.3La_(0.9)Na_(0.1)Ni_(0.9)Mo_(0.1)O₃ −21 3.2 4.9La_(0.9)Na_(0.1)Ni_(0.9)W_(0.1)O₃ −22 3.1 3.9La_(0.9)Na_(0.1)Ni_(0.9)Nb_(0.1)O₃ −18 3 4.2

TABLE 81 La_(0.9)Na_(0.1)Ni_(0.9)Ta_(0.1)O₃ −25 2.4 4La_(0.9)K_(0.1)Ni_(0.9)Ti_(0.1)O₃ −28 2.9 4.6La_(0.9)K_(0.1)Ni_(0.9)V_(0.1)O₃ −19 3 4.5La_(0.9)K_(0.1)Ni_(0.9)Cr_(0.1)O₃ −20 2.8 4.2La_(0.9)K_(0.1)Ni_(0.9)Mn_(0.1)O₃ −26 3.5 4.7La_(0.9)K_(0.1)Ni_(0.9)Fe_(0.1)O₃ −23 4 4.8La_(0.9)K_(0.1)Ni_(0.9)Co_(0.1)O₃ −22 3.9 4.1La_(0.9)K_(0.1)Ni_(0.9)Cu_(0.1)O₃ −19 2.1 3.8La_(0.9)K_(0.1)Ni_(0.9)Mo_(0.1)O₃ −17 2.6 4La_(0.9)K_(0.1)Ni_(0.9)W_(0.1)O₃ −20 2.8 4.6La_(0.9)K_(0.1)Ni_(0.9)Nb_(0.1)O₃ −22 2.7 4.2La_(0.9)K_(0.1)Ni_(0.9)Ta_(0.1)O₃ −20 3.9 4.5La_(0.9)Sr_(0.1)Ni_(0.9)Ti_(0.1)O₃ −23 2.7 4.2La_(0.9)Sr_(0.1)Ni_(0.9)V_(0.1)O₃ −18 1.9 4.1La_(0.9)Sr_(0.1)Ni_(0.9)Cr_(0.1)O₃ −28 2.8 3.9La_(0.9)Sr_(0.1)Ni_(0.9)Mn_(0.1)O₃ −19 3.7 4La_(0.9)Sr_(0.1)Ni_(0.9)Fe_(0.1)O₃ −24 3.4 3.8La_(0.9)Sr_(0.1)Ni_(0.9)Co_(0.1)O₃ −25 2.8 3.7La_(0.9)Sr_(0.1)Ni_(0.9)Cu_(0.1)O₃ −16 3 4La_(0.9)Sr_(0.1)Ni_(0.9)Mo_(0.1)O₃ −20 2.9 3.9La_(0.9)Sr_(0.1)Ni_(0.9)W_(0.1)O₃ −22 2.2 3.6La_(0.9)Sr_(0.1)Ni_(0.9)Nb_(0.1)O₃ −24 1.9 4.1La_(0.9)Sr_(0.1)Ni_(0.9)Ta_(0.1)O₃ −23 1.8 3.9La_(0.9)Ca_(0.1)Ni_(0.9)Ti_(0.1)O₃ −28 3.1 4.3La_(0.9)Ca_(0.1)Ni_(0.9)V_(0.1)O₃ −19 2.2 4La_(0.9)Ca_(0.1)Ni_(0.9)Cr_(0.1)O₃ −21 2.1 4.7La_(0.9)Ca_(0.1)Ni_(0.9)Mn_(0.1)O₃ −22 3 4.2La_(0.9)Ca_(0.1)Ni_(0.9)Fe_(0.1)O₃ −24 2.8 4.3La_(0.9)Ca_(0.1)Ni_(0.9)Co_(0.1)O₃ −21 3.2 4.9La_(0.9)Ca_(0.1)Ni_(0.9)Cu_(0.1)O₃ −29 3.1 3.9La_(0.9)Ca_(0.1)Ni_(0.9)Mo_(0.1)O₃ −17 3 4.2La_(0.9)Ca_(0.1)Ni_(0.9)W_(0.1)O₃ −18 2.4 4La_(0.9)Ca_(0.1)Ni_(0.9)Nb_(0.1)O₃ −24 2.8 4.7La_(0.9)Ca_(0.1)Ni_(0.9)Ta_(0.1)O₃ −22 2.9 4.6

TABLE 82 La_(0.9)Bi_(0.1)Ni_(0.9)Ti_(0.1)O₃ −21 3 4.5La_(0.9)Bi_(0.1)Ni_(0.9)V_(0.1)O₃ −27 2.8 4.2La_(0.9)Bi_(0.1)Ni_(0.9)Cr_(0.1)O₃ −21 3.5 4.7La_(0.9)Bi_(0.1)Ni_(0.9)Mn_(0.1)O₃ −23 4 4.8La_(0.9)Bi_(0.1)Ni_(0.9)Fe_(0.1)O₃ −19 3.9 4.1La_(0.9)Bi_(0.1)Ni_(0.9)Co_(0.1)O₃ −23 2.1 3.8La_(0.9)Bi_(0.1)Ni_(0.9)Cu_(0.1)O₃ −24 2.6 4La_(0.9)Bi_(0.1)Ni_(0.9)Mo_(0.1)O₃ −25 2.8 4.6La_(0.9)Bi_(0.1)Ni_(0.9)W_(0.1)O₃ −16 2.7 4La_(0.9)Bi_(0.1)Ni_(0.9)Nb_(0.1)O₃ −20 3.9 4.7La_(0.9)Bi_(0.1)Ni_(0.9)Ta_(0.1)O₃ −22 3.8 4.2Ce_(0.9)Na_(0.1)Ni_(0.9)Ti_(0.1)O₃ −18 1.9 4.9Ce_(0.9)Na_(0.1)Ni_(0.9)V_(0.1)O₃ −22 2.8 3.9Ce_(0.9)Na_(0.1)Ni_(0.9)Cr_(0.1)O₃ −10 3.7 4.2Ce_(0.9)Na_(0.1)Ni_(0.9)Mn_(0.1)O₃ −26 3.4 4Ce_(0.9)Na_(0.1)Ni_(0.9)Fe_(0.1)O₃ −20 2.8 4.7Ce_(0.9)Na_(0.1)Ni_(0.9)Co_(0.1)O₃ −19 3 4.6Ce_(0.9)Na_(0.1)Ni_(0.9)Cu_(0.1)O₃ −17 2.9 4.5Ce_(0.9)Na_(0.1)Ni_(0.9)Mo_(0.1)O₃ −23 1.8 4.2Ce_(0.9)Na_(0.1)Ni_(0.9)W_(0.1)O₃ −22 2.9 4.7Ce_(0.9)Na_(0.1)Ni_(0.9)Nb_(0.1)O₃ −18 3.1 4.8Ce_(0.9)Na_(0.1)Ni_(0.9)Ta_(0.1)O₃ −20 2.2 4.1Ce_(0.9)K_(0.1)Ni_(0.9)Ti_(0.1)O₃ −21 3 4Ce_(0.9)K_(0.1)Ni_(0.9)V_(0.1)O₃ −22 2.8 4.6Ce_(0.9)K_(0.1)Ni_(0.9)Cr_(0.1)O₃ −18 3.2 4.2Ce_(0.9)K_(0.1)Ni_(0.9)Mn_(0.1)O₃ −25 3.1 4.5Ce_(0.9)K_(0.1)Ni_(0.9)Fe_(0.1)O₃ −24 3 4.3Ce_(0.9)K_(0.1)Ni_(0.9)Co_(0.1)O₃ −28 2.4 4.2Ce_(0.9)K_(0.1)Ni_(0.9)Cu_(0.1)O₃ −19 2.8 4.1Ce_(0.9)K_(0.1)Ni_(0.9)Mo_(0.1)O₃ −20 2.9 3.9Ce_(0.9)K_(0.1)Ni_(0.9)W_(0.1)O₃ −26 3 4Ce_(0.9)K_(0.1)Ni_(0.9)Nb_(0.1)O₃ −23 2.8 3.8Ce_(0.9)K_(0.1)Ni_(0.9)Ta_(0.1)O₃ −22 3.5 3.7Ce_(0.9)Sr_(0.1)Ni_(0.9)Ti_(0.1)O₃ −17 3.9 3.9

TABLE 83 Ce_(0.9)Sr_(0.1)Ni_(0.9)V_(0.1)O₃ −20 2.1 3.6Ce_(0.9)Sr_(0.1)Ni_(0.9)Cr_(0.1)O₃ −22 2.6 4.1Ce_(0.9)Sr_(0.1)Ni_(0.9)Mn_(0.1)O₃ −20 2.2 3.9Ce_(0.9)Sr_(0.1)Ni_(0.9)Fe_(0.1)O₃ −21 1.9 4.6Ce_(0.9)Sr_(0.1)Ni_(0.9)Co_(0.1)O₃ −23 1.8 4.3Ce_(0.9)Sr_(0.1)Ni_(0.9)Cu_(0.1)O₃ −18 2.9 4Ce_(0.9)Sr_(0.1)Ni_(0.9)Mo_(0.1)O₃ −28 3.1 4.7Ce_(0.9)Sr_(0.1)Ni_(0.9)W_(0.1)O₃ −19 2.2 4.2Ce_(0.9)Sr_(0.1)Ni_(0.9)Nb_(0.1)O₃ −24 2.1 4.3Ce_(0.9)Sr_(0.1)Ni_(0.9)Ta_(0.1)O₃ −25 3 4.9Ce_(0.9)Ca_(0.1)Ni_(0.9)Ti_(0.1)O₃ −20 3.2 4.2Ce_(0.9)Ca_(0.1)Ni_(0.9)V_(0.1)O₃ −22 3.1 4Ce_(0.9)Ca_(0.1)Ni_(0.9)Cr_(0.1)O₃ −24 3 4.7Ce_(0.9)Ca_(0.1)Ni_(0.9)Mn_(0.1)O₃ −23 2.4 4.6Ce_(0.9)Ca_(0.1)Ni_(0.9)Fe_(0.1)O₃ −26 2.8 4.5Ce_(0.9)Ca_(0.1)Ni_(0.9)Co_(0.1)O₃ −28 2.9 4.2Ce_(0.9)Ca_(0.1)Ni_(0.9)Cu_(0.1)O₃ −19 3 4.7Ce_(0.9)Ca_(0.1)Ni_(0.9)Mo_(0.1)O₃ −21 2.8 4.8Ce_(0.9)Ca_(0.1)Ni_(0.9)W_(0.1)O₃ −22 3.5 4.1Ce_(0.9)Ca_(0.1)Ni_(0.9)Nb_(0.1)O₃ −24 4 3.8Ce_(0.9)Ca_(0.1)Ni_(0.9)Ta_(0.1)O₃ −21 3.9 4Ce_(0.9)Bi_(0.1)Ni_(0.9)Ti_(0.1)O₃ −29 2.1 4.6Ce_(0.9)Bi_(0.1)Ni_(0.9)V_(0.1)O₃ −17 2.6 4.2Ce_(0.9)Bi_(0.1)Ni_(0.9)Cr_(0.1)O₃ −18 2.8 4.5Ce_(0.9)Bi_(0.1)Ni_(0.9)Mn_(0.1)O₃ −24 2.7 4.3Ce_(0.9)Bi_(0.1)Ni_(0.9)Fe_(0.1)O₃ −22 3.9 4.1Ce_(0.9)Bi_(0.1)Ni_(0.9)Co_(0.1)O₃ −21 3.8 3.9Ce_(0.9)Bi_(0.1)Ni_(0.9)Cu_(0.1)O₃ −27 2.7 4Ce_(0.9)Bi_(0.1)Ni_(0.9)Mo_(0.1)O₃ −21 1.9 3.8Ce_(0.9)Bi_(0.1)Ni_(0.9)W_(0.1)O₃ −23 2.8 3.7Ce_(0.9)Bi_(0.1)Ni_(0.9)Nb_(0.1)O₃ −19 3.7 4Ce_(0.9)Bi_(0.1)Ni_(0.9)Ta_(0.1)O₃ −23 3.4 3.9Pr_(0.9)Na_(0.1)Ni_(0.9)Ti_(0.1)O₃ −25 3 4.1Pr_(0.9)Na_(0.1)Ni_(0.9)V_(0.1)O₃ −16 2.9 3.9Pr_(0.9)Na_(0.1)Ni_(0.9)Cr_(0.1)O₃ −20 1.8 4.6

TABLE 84 Pr_(0.9)Na_(0.1)Ni_(0.9)Mn_(0.1)O₃ −22 2.9 4.3Pr_(0.9)Na_(0.1)Ni_(0.9)Fe_(0.1)O₃ −29 3.1 4Pr_(0.9)Na_(0.1)Ni_(0.9)Co_(0.1)O₃ −22 2.2 4.7Pr_(0.9)Na_(0.1)Ni_(0.9)Cu_(0.1)O₃ −19 2.1 4.2Pr_(0.9)Na_(0.1)Ni_(0.9)Mo_(0.1)O₃ −25 3 4.3Pr_(0.9)Na_(0.1)Ni_(0.9)W_(0.1)O₃ −30 2.8 4.9Pr_(0.9)Na_(0.1)Ni_(0.9)Nb_(0.1)O₃ −28 3.2 3.9Pr_(0.9)Na_(0.1)Ni_(0.9)Ta_(0.1)O₃ −27 3.1 4.2Pr_(0.9)K_(0.1)Ni_(0.9)Ti_(0.1)O₃ −18 2.4 4.7Pr_(0.9)K_(0.1)Ni_(0.9)V_(0.1)O₃ −22 2.8 4.6Pr_(0.9)K_(0.1)Ni_(0.9)Cr_(0.1)O₃ −10 2.9 4.5Pr_(0.9)K_(0.1)Ni_(0.9)Mn_(0.1)O₃ −26 3 4.2Pr_(0.9)K_(0.1)Ni_(0.9)Fe_(0.1)O₃ −20 2.8 4.7Pr_(0.9)K_(0.1)Ni_(0.9)Co_(0.1)O₃ −19 3.5 4.8Pr_(0.9)K_(0.1)Ni_(0.9)Cu_(0.1)O₃ −17 4 4.1Pr_(0.9)K_(0.1)Ni_(0.9)Mo_(0.1)O₃ −23 3.9 3.8Pr_(0.9)K_(0.1)Ni_(0.9)W_(0.1)O₃ −22 2.1 4Pr_(0.9)K_(0.1)Ni_(0.9)Nb_(0.1)O₃ −18 2.6 4.6Pr_(0.9)K_(0.1)Ni_(0.9)Ta_(0.1)O₃ −20 2.8 4.2Pr_(0.9)Sr_(0.1)Ni_(0.9)Ti_(0.1)O₃ −21 2.9 4.3Pr_(0.9)Sr_(0.1)Ni_(0.9)V_(0.1)O₃ −22 3.1 4.2Pr_(0.9)Sr_(0.1)Ni_(0.9)Cr_(0.1)O₃ −18 2.2 4.1Pr_(0.9)Sr_(0.1)Ni_(0.9)Mn_(0.1)O₃ −25 2.1 3.9Pr_(0.9)Sr_(0.1)Ni_(0.9)Fe_(0.1)O₃ −24 3 4Pr_(0.9)Sr_(0.1)Ni_(0.9)Co_(0.1)O₃ −28 2.8 3.8Pr_(0.9)Sr_(0.1)Ni_(0.9)Cu_(0.1)O₃ −19 3.2 3.7Pr_(0.9)Sr_(0.1)Ni_(0.9)Mo_(0.1)O₃ −20 3.1 4Pr_(0.9)Sr_(0.1)Ni_(0.9)W_(0.1)O₃ −26 3 3.9Pr_(0.9)Sr_(0.1)Ni_(0.9)Nb_(0.1)O₃ −23 2.4 3.6Pr_(0.9)Sr_(0.1)Ni_(0.9)Ta_(0.1)O₃ −22 2.8 4.1Pr_(0.9)Ca_(0.1)Ni_(0.9)Ti_(0.1)O₃ −17 3 4.6Pr_(0.9)Ca_(0.1)Ni_(0.9)V_(0.1)O₃ −20 2.8 4.3Pr_(0.9)Ca_(0.1)Ni_(0.9)Cr_(0.1)O₃ −22 3.5 4Pr_(0.9)Ca_(0.1)Ni_(0.9)Mn_(0.1)O₃ −20 4 4.7

TABLE 85 Pr_(0.9)Ca_(0.1)Ni_(0.9)Fe_(0.1)O₃ −21 3.9 4.2Pr_(0.9)Ca_(0.1)Ni_(0.9)Co_(0.1)O₃ −23 2.1 4.3Pr_(0.9)Ca_(0.1)Ni_(0.9)Cu_(0.1)O₃ −18 2.6 4.9Pr_(0.9)Ca_(0.1)Ni_(0.9)Mo_(0.1)O₃ −28 2.8 3.9Pr_(0.9)Ca_(0.1)Ni_(0.9)W_(0.1)O₃ −19 2.7 4.2Pr_(0.9)Ca_(0.1)Ni_(0.9)Nb_(0.1)O₃ −24 3.9 4Pr_(0.9)Ca_(0.1)Ni_(0.9)Ta_(0.1)O₃ −25 3.8 4.7Pr_(0.9)Bi_(0.1)Ni_(0.9)Ti_(0.1)O₃ −16 2.7 4.6Pr_(0.9)Bi_(0.1)Ni_(0.9)V_(0.1)O₃ −20 1.9 4.5Pr_(0.9)Bi_(0.1)Ni_(0.9)Cr_(0.1)O₃ −22 2.8 4.2Pr_(0.9)Bi_(0.1)Ni_(0.9)Mn_(0.1)O₃ −24 3.7 4.7Pr_(0.9)Bi_(0.1)Ni_(0.9)Fe_(0.1)O₃ −23 3.4 4.8Pr_(0.9)Bi_(0.1)Ni_(0.9)Co_(0.1)O₃ −26 2.8 4.1Pr_(0.9)Bi_(0.1)Ni_(0.9)Cu_(0.1)O₃ −28 3 3.8Pr_(0.9)Bi_(0.1)Ni_(0.9)Mo_(0.1)O₃ −19 2.9 4.1Pr_(0.9)Bi_(0.1)Ni_(0.9)W_(0.1)O₃ −21 1.8 3.9Pr_(0.9)Bi_(0.1)Ni_(0.9)Nb_(0.1)O₃ −22 2.9 4.6Pr_(0.9)Bi_(0.1)Ni_(0.9)Ta_(0.1)O₃ −24 3.1 4.3Nd_(0.9)Na_(0.1)Ni_(0.9)Ti_(0.1)O₃ −29 2.1 4.7Nd_(0.9)Na_(0.1)Ni_(0.9)V_(0.1)O₃ −17 3 4.2Nd_(0.9)Na_(0.1)Ni_(0.9)Cr_(0.1)O₃ −18 2.8 4.3Nd_(0.9)Na_(0.1)Ni_(0.9)Mn_(0.1)O₃ −24 3.2 4.9Nd_(0.9)Na_(0.1)Ni_(0.9)Fe_(0.1)O₃ −22 3.1 3.9Nd_(0.9)Na_(0.1)Ni_(0.9)Co_(0.1)O₃ −21 3 4.2Nd_(0.9)Na_(0.1)Ni_(0.9)Cu_(0.1)O₃ −27 2.4 4Nd_(0.9)Na_(0.1)Ni_(0.9)Mo_(0.1)O₃ −25 2.8 4.7Nd_(0.9)Na_(0.1)Ni_(0.9)W_(0.1)O₃ −30 2.9 4.6Nd_(0.9)Na_(0.1)Ni_(0.9)Nb_(0.1)O₃ −28 3 4.5Nd_(0.9)Na_(0.1)Ni_(0.9)Ta_(0.1)O₃ −27 2.8 4.2Nd_(0.9)K_(0.1)Ni_(0.9)Ti_(0.1)O₃ −18 4 4.8Nd_(0.9)K_(0.1)Ni_(0.9)V_(0.1)O₃ −22 3.9 4.1Nd_(0.9)K_(0.1)Ni_(0.9)Cr_(0.1)O₃ −10 2.1 3.8Nd_(0.9)K_(0.1)Ni_(0.9)Mn_(0.1)O₃ −26 2.6 4Nd_(0.9)K_(0.1)Ni_(0.9)Fe_(0.1)O₃ −20 2.2 4.6Nd_(0.9)K_(0.1)Ni_(0.9)Co_(0.1)O₃ −19 1.9 4.2

TABLE 86 Nd_(0.9)K_(0.1)Ni_(0.9)Cu_(0.1)O₃ −17 1.8 4.5Nd_(0.9)K_(0.1)Ni_(0.9)Mo_(0.1)O₃ −23 2.9 4.3Nd_(0.9)K_(0.1)Ni_(0.9)W_(0.1)O₃ −22 3.1 4.1Nd_(0.9)K_(0.1)Ni_(0.9)Nb_(0.1)O₃ −18 2.2 3.9Nd_(0.9)K_(0.1)Ni_(0.9)Ta_(0.1)O₃ −20 2.1 4Nd_(0.9)Sr_(0.1)Ni_(0.9)Ti_(0.1)O₃ −21 2.8 3.7Nd_(0.9)Sr_(0.1)Ni_(0.9)V_(0.1)O₃ −22 3.2 4Nd_(0.9)Sr_(0.1)Ni_(0.9)Cr_(0.1)O₃ −18 3.1 3.9Nd_(0.9)Sr_(0.1)Ni_(0.9)Mn_(0.1)O₃ −25 3 3.6Nd_(0.9)Sr_(0.1)Ni_(0.9)Fe_(0.1)O₃ −24 2.4 4.1Nd_(0.9)Sr_(0.1)Ni_(0.9)Co_(0.1)O₃ −28 2.8 3.9Nd_(0.9)Sr_(0.1)Ni_(0.9)Cu_(0.1)O₃ −19 2.9 4.6Nd_(0.9)Sr_(0.1)Ni_(0.9)Mo_(0.1)O₃ −20 3 4.3Nd_(0.9)Sr_(0.1)Ni_(0.9)W_(0.1)O₃ −26 2.8 4Nd_(0.9)Sr_(0.1)Ni_(0.9)Nb_(0.1)O₃ −23 3.5 4.7Nd_(0.9)Sr_(0.1)Ni_(0.9)Ta_(0.1)O₃ −22 4 4.2Nd_(0.9)Ca_(0.1)Ni_(0.9)Ti_(0.1)O₃ −17 2.1 4.9Nd_(0.9)Ca_(0.1)Ni_(0.9)V_(0.1)O₃ −20 2.6 3.9Nd_(0.9)Ca_(0.1)Ni_(0.9)Cr_(0.1)O₃ −22 2.8 4.2Nd_(0.9)Ca_(0.1)Ni_(0.9)Mn_(0.1)O₃ −20 2.7 4Nd_(0.9)Ca_(0.1)Ni_(0.9)Fe_(0.1)O₃ −21 3.9 4.7Nd_(0.9)Ca_(0.1)Ni_(0.9)Co_(0.1)O₃ −23 3.8 4.6Nd_(0.9)Ca_(0.1)Ni_(0.9)Cu_(0.1)O₃ −18 2.7 4.5Nd_(0.9)Ca_(0.1)Ni_(0.9)Mo_(0.1)O₃ −28 1.9 4.2Nd_(0.9)Ca_(0.1)Ni_(0.9)W_(0.1)O₃ −19 2.8 4.7Nd_(0.9)Ca_(0.1)Ni_(0.9)Nb_(0.1)O₃ −24 3.7 4.8Nd_(0.9)Ca_(0.1)Ni_(0.9)Ta_(0.1)O₃ −25 3.4 4.1Nd_(0.9)Bi_(0.1)Ni_(0.9)Ti_(0.1)O₃ −16 2.8 3.8Nd_(0.9)Bi_(0.1)Ni_(0.9)V_(0.1)O₃ −20 3 4Nd_(0.9)Bi_(0.1)Ni_(0.9)Cr_(0.1)O₃ −22 2.9 4.6Nd_(0.9)Bi_(0.1)Ni_(0.9)Mn_(0.1)O₃ −24 1.8 4.2Nd_(0.9)Bi_(0.1)Ni_(0.9)Fe_(0.1)O₃ −23 2.9 4.5Nd_(0.9)Bi_(0.1)Ni_(0.9)Co_(0.1)O₃ −26 3.1 4.3Nd_(0.9)Bi_(0.1)Ni_(0.9)Cu_(0.1)O₃ −28 2.2 4.2Nd_(0.9)Bi_(0.1)Ni_(0.9)Mo_(0.1)O₃ −19 2.1 4.1

TABLE 87 Nd_(0.9)Bi_(0.1)Ni_(0.9)W_(0.1)O₃ −21 3 3.9Nd_(0.9)Bi_(0.1)Ni_(0.9)Nb_(0.1)O₃ −22 2.8 4Nd_(0.9)Bi_(0.1)Ni_(0.9)Ta_(0.1)O₃ −24 3.2 3.8Sm_(0.9)Na_(0.1)Ni_(0.9)Ti_(0.1)O₃ −29 3 4Sm_(0.9)Na_(0.1)Ni_(0.9)V_(0.1)O₃ −17 2.4 3.9Sm_(0.9)Na_(0.1)Ni_(0.9)Cr_(0.1)O₃ −18 2.8 3.6Sm_(0.9)Na_(0.1)Ni_(0.9)Mn_(0.1)O₃ −24 2.9 4.1Sm_(0.9)Na_(0.1)Ni_(0.9)Fe_(0.1)O₃ −22 3 3.9Sm_(0.9)Na_(0.1)Ni_(0.9)Co_(0.1)O₃ −21 2.8 4.6Sm_(0.9)Na_(0.1)Ni_(0.9)Cu_(0.1)O₃ −27 3.5 4.3Sm_(0.9)Na_(0.1)Ni_(0.9)Mo_(0.1)O₃ −21 4 4Sm_(0.9)Na_(0.1)Ni_(0.9)W_(0.1)O₃ −23 3.9 4.7Sm_(0.9)Na_(0.1)Ni_(0.9)Nb_(0.1)O₃ −19 2.1 4.2Sm_(0.9)Na_(0.1)Ni_(0.9)Ta_(0.1)O₃ −23 2.6 4.3Sm_(0.9)K_(0.1)Ni_(0.9)Ti_(0.1)O₃ −25 2.7 3.9Sm_(0.9)K_(0.1)Ni_(0.9)V_(0.1)O₃ −16 3.9 4.2Sm_(0.9)K_(0.1)Ni_(0.9)Cr_(0.1)O₃ −20 1.8 4Sm_(0.9)K_(0.1)Ni_(0.9)Mn_(0.1)O₃ −22 2.9 4.7Sm_(0.9)K_(0.1)Ni_(0.9)Fe_(0.1)O₃ −22 3.1 4.6Sm_(0.9)K_(0.1)Ni_(0.9)Co_(0.1)O₃ −10 2.2 4.5Sm_(0.9)K_(0.1)Ni_(0.9)Cu_(0.1)O₃ −26 2.1 4.2Sm_(0.9)K_(0.1)Ni_(0.9)Mo_(0.1)O₃ −20 3 4.7Sm_(0.9)K_(0.1)Ni_(0.9)W_(0.1)O₃ −19 2.8 4.8Sm_(0.9)K_(0.1)Ni_(0.9)Nb_(0.1)O₃ −17 3.2 4.1Sm_(0.9)K_(0.1)Ni_(0.9)Ta_(0.1)O₃ −23 3.1 3.8Sm_(0.9)Sr_(0.1)Ni_(0.9)Ti_(0.1)O₃ −18 2.4 4Sm_(0.9)Sr_(0.1)Ni_(0.9)V_(0.1)O₃ −20 2.8 4.7Sm_(0.9)Sr_(0.1)Ni_(0.9)Cr_(0.1)O₃ −21 2.9 4.2Sm_(0.9)Sr_(0.1)Ni_(0.9)Mn_(0.1)O₃ −21 3 4.3Sm_(0.9)Sr_(0.1)Ni_(0.9)Fe_(0.1)O₃ −22 2.8 4.9Sm_(0.9)Sr_(0.1)Ni_(0.9)Co_(0.1)O₃ −18 3.5 3.9Sm_(0.9)Sr_(0.1)Ni_(0.9)Cu_(0.1)O₃ −25 4 4.2Sm_(0.9)Sr_(0.1)Ni_(0.9)Mo_(0.1)O₃ −24 3.9 4Sm_(0.9)Sr_(0.1)Ni_(0.9)W_(0.1)O₃ −28 2.1 4.7

TABLE 88 Sm_(0.9)Sr_(0.1)Ni_(0.9)Nb_(0.1)O₃ −19 2.6 4.6Sm_(0.9)Sr_(0.1)Ni_(0.9)Ta_(0.1)O₃ −20 2.8 4.5Sm_(0.9)Ca_(0.1)Ni_(0.9)Ti_(0.1)O₃ −23 3.9 4.7Sm_(0.9)Ca_(0.1)Ni_(0.9)V_(0.1)O₃ −22 3.8 4.8Sm_(0.9)Ca_(0.1)Ni_(0.9)Cr_(0.1)O₃ −19 2.7 4.1Sm_(0.9)Ca_(0.1)Ni_(0.9)Mn_(0.1)O₃ −17 1.9 3.8Sm_(0.9)Ca_(0.1)Ni_(0.9)Fe_(0.1)O₃ −20 2.8 4Sm_(0.9)Ca_(0.1)Ni_(0.9)Co_(0.1)O₃ −22 3.7 4.6Sm_(0.9)Ca_(0.1)Ni_(0.9)Cu_(0.1)O₃ −20 3.4 4.2Sm_(0.9)Ca_(0.1)Ni_(0.9)Mo_(0.1)O₃ −21 2.8 4.5Sm_(0.9)Ca_(0.1)Ni_(0.9)W_(0.1)O₃ −23 3 4.3Sm_(0.9)Ca_(0.1)Ni_(0.9)Nb_(0.1)O₃ −18 2.9 4.2Sm_(0.9)Ca_(0.1)Ni_(0.9)Ta_(0.1)O₃ −28 1.8 4.1Sm_(0.9)Bi_(0.1)Ni_(0.9)Ti_(0.1)O₃ −19 2.9 3.9Sm_(0.9)Bi_(0.1)Ni_(0.9)V_(0.1)O₃ −24 3.1 4Sm_(0.9)Bi_(0.1)Ni_(0.9)Cr_(0.1)O₃ −25 2.2 3.8Sm_(0.9)Bi_(0.1)Ni_(0.9)Mn_(0.1)O₃ −16 2.1 3.7Sm_(0.9)Bi_(0.1)Ni_(0.9)Fe_(0.1)O₃ −20 3 4Sm_(0.9)Bi_(0.1)Ni_(0.9)Co_(0.1)O₃ −22 2.8 3.9Sm_(0.9)Bi_(0.1)Ni_(0.9)Cu_(0.1)O₃ −24 3.2 3.6Sm_(0.9)Bi_(0.1)Ni_(0.9)Mo_(0.1)O₃ −23 3.1 4.1Sm_(0.9)Bi_(0.1)Ni_(0.9)W_(0.1)O₃ −26 3 3.9Sm_(0.9)Bi_(0.1)Ni_(0.9)Nb_(0.1)O₃ −28 2.4 4.6Sm_(0.9)Bi_(0.1)Ni_(0.9)Ta_(0.1)O₃ −19 2.8 4.3Eu_(0.9)Na_(0.1)Ni_(0.9)Ti_(0.1)O₃ −22 3 4.7Eu_(0.9)Na_(0.1)Ni_(0.9)V_(0.1)O₃ −24 2.8 4.2Eu_(0.9)Na_(0.1)Ni_(0.9)Cr_(0.1)O₃ −21 3.5 4.3Eu_(0.9)Na_(0.1)Ni_(0.9)Mn_(0.1)O₃ −29 4 4.9Eu_(0.9)Na_(0.1)Ni_(0.9)Fe_(0.1)O₃ −17 3.9 3.9Eu_(0.9)Na_(0.1)Ni_(0.9)Co_(0.1)O₃ −18 2.1 4.2Eu_(0.9)Na_(0.1)Ni_(0.9)Cu_(0.1)O₃ −24 2.6 4Eu_(0.9)Na_(0.1)Ni_(0.9)Mo_(0.1)O₃ −22 2.8 4.7Eu_(0.9)Na_(0.1)Ni_(0.9)W_(0.1)O₃ −21 2.7 4.6Eu_(0.9)Na_(0.1)Ni_(0.9)Nb_(0.1)O₃ −27 3.9 4.5Eu_(0.9)Na_(0.1)Ni_(0.9)Ta_(0.1)O₃ −21 3.8 4.2

TABLE 89 Eu_(0.9)K_(0.1)Ni_(0.9)Ti_(0.1)O₃ −19 1.9 4.8Eu_(0.9)K_(0.1)Ni_(0.9)V_(0.1)O₃ −23 2.8 4.1Eu_(0.9)K_(0.1)Ni_(0.9)Cr_(0.1)O₃ −24 3.7 3.8Eu_(0.9)K_(0.1)Ni_(0.9)Mn_(0.1)O₃ −25 3.4 4.1Eu_(0.9)K_(0.1)Ni_(0.9)Fe_(0.1)O₃ −16 2.8 3.9Eu_(0.9)K_(0.1)Ni_(0.9)Co_(0.1)O₃ −20 3 4.6Eu_(0.9)K_(0.1)Ni_(0.9)Cu_(0.1)O₃ −22 2.9 4.3Eu_(0.9)K_(0.1)Ni_(0.9)Mo_(0.1)O₃ −29 2.2 4Eu_(0.9)K_(0.1)Ni_(0.9)W_(0.1)O₃ −22 1.9 4.7Eu_(0.9)K_(0.1)Ni_(0.9)Nb_(0.1)O₃ −19 1.8 4.2Eu_(0.9)K_(0.1)Ni_(0.9)Ta_(0.1)O₃ −25 2.9 4.3Eu_(0.9)Sr_(0.1)Ni_(0.9)Ti_(0.1)O₃ −28 2.2 3.9Eu_(0.9)Sr_(0.1)Ni_(0.9)V_(0.1)O₃ −27 2.1 4.2Eu_(0.9)Sr_(0.1)Ni_(0.9)Cr_(0.1)O₃ −25 3 4Eu_(0.9)Sr_(0.1)Ni_(0.9)Mn_(0.1)O₃ −18 2.8 4.7Eu_(0.9)Sr_(0.1)Ni_(0.9)Fe_(0.1)O₃ −22 3.2 4.6Eu_(0.9)Sr_(0.1)Ni_(0.9)Co_(0.1)O₃ −10 3.1 4.5Eu_(0.9)Sr_(0.1)Ni_(0.9)Cu_(0.1)O₃ −26 3 4.2Eu_(0.9)Sr_(0.1)Ni_(0.9)Mo_(0.1)O₃ −20 2.4 4.7Eu_(0.9)Sr_(0.1)Ni_(0.9)W_(0.1)O₃ −19 2.8 4.8Eu_(0.9)Sr_(0.1)Ni_(0.9)Nb_(0.1)O₃ −17 2.9 4.1Eu_(0.9)Sr_(0.1)Ni_(0.9)Ta_(0.1)O₃ −23 3 3.8Eu_(0.9)Ca_(0.1)Ni_(0.9)Ti_(0.1)O₃ −18 3.5 4.6Eu_(0.9)Ca_(0.1)Ni_(0.9)V_(0.1)O₃ −20 4 4.2Eu_(0.9)Ca_(0.1)Ni_(0.9)Cr_(0.1)O₃ −21 3.9 4.5Eu_(0.9)Ca_(0.1)Ni_(0.9)Mn_(0.1)O₃ −21 2.1 4.3Eu_(0.9)Ca_(0.1)Ni_(0.9)Fe_(0.1)O₃ −22 2.6 4.1Eu_(0.9)Ca_(0.1)Ni_(0.9)Co_(0.1)O₃ −18 2.8 3.9Eu_(0.9)Ca_(0.1)Ni_(0.9)Cu_(0.1)O₃ −25 2.7 4Eu_(0.9)Ca_(0.1)Ni_(0.9)Mo_(0.1)O₃ −24 3.9 3.8Eu_(0.9)Ca_(0.1)Ni_(0.9)W_(0.1)O₃ −28 3.8 3.7Eu_(0.9)Ca_(0.1)Ni_(0.9)Nb_(0.1)O₃ −19 2.7 4Eu_(0.9)Ca_(0.1)Ni_(0.9)Ta_(0.1)O₃ −20 1.9 3.9Eu_(0.9)Bi_(0.1)Ni_(0.9)Ti_(0.1)O₃ −26 2.8 3.6

TABLE 90 Eu_(0.9)Bi_(0.1)Ni_(0.9)V_(0.1)O₃ −23 3.7 4.1Eu_(0.9)Bi_(0.1)Ni_(0.9)Cr_(0.1)O₃ −22 3.4 3.9Eu_(0.9)Bi_(0.1)Ni_(0.9)Mn_(0.1)O₃ −19 2.8 4.6Eu_(0.9)Bi_(0.1)Ni_(0.9)Fe_(0.1)O₃ −17 3 4.3Eu_(0.9)Bi_(0.1)Ni_(0.9)Co_(0.1)O₃ −20 2.9 4Eu_(0.9)Bi_(0.1)Ni_(0.9)Cu_(0.1)O₃ −22 1.8 4.7Eu_(0.9)Bi_(0.1)Ni_(0.9)Mo_(0.1)O₃ −20 2.9 4.2Eu_(0.9)Bi_(0.1)Ni_(0.9)W_(0.1)O₃ −21 3.1 4.3Eu_(0.9)Bi_(0.1)Ni_(0.9)Nb_(0.1)O₃ −23 2.2 4.9Eu_(0.9)Bi_(0.1)Ni_(0.9)Ta_(0.1)O₃ −18 2.1 3.9Gd_(0.9)Na_(0.1)Ni_(0.9)Ti_(0.1)O₃ −19 2.8 4Gd_(0.9)Na_(0.1)Ni_(0.9)V_(0.1)O₃ −24 3.2 4.7Gd_(0.9)Na_(0.1)Ni_(0.9)Cr_(0.1)O₃ −25 3.1 4.6Gd_(0.9)Na_(0.1)Ni_(0.9)Mn_(0.1)O₃ −16 3 4.5Gd_(0.9)Na_(0.1)Ni_(0.9)Fe_(0.1)O₃ −20 2.4 4.2Gd_(0.9)Na_(0.1)Ni_(0.9)Co_(0.1)O₃ −22 2.8 4.7Gd_(0.9)Na_(0.1)Ni_(0.9)Cu_(0.1)O₃ −24 2.9 4.8Gd_(0.9)Na_(0.1)Ni_(0.9)Mo_(0.1)O₃ −23 3 4.1Gd_(0.9)Na_(0.1)Ni_(0.9)W_(0.1)O₃ −26 2.8 3.8Gd_(0.9)Na_(0.1)Ni_(0.9)Nb_(0.1)O₃ −28 3.5 4Gd_(0.9)Na_(0.1)Ni_(0.9)Ta_(0.1)O₃ −19 4 4.6Gd_(0.9)K_(0.1)Ni_(0.9)Ti_(0.1)O₃ −22 2.1 4.5Gd_(0.9)K_(0.1)Ni_(0.9)V_(0.1)O₃ −24 2.6 4.3Gd_(0.9)K_(0.1)Ni_(0.9)Cr_(0.1)O₃ −21 2.2 4.2Gd_(0.9)K_(0.1)Ni_(0.9)Mn_(0.1)O₃ −29 1.9 4.1Gd_(0.9)K_(0.1)Ni_(0.9)Fe_(0.1)O₃ −17 1.8 3.9Gd_(0.9)K_(0.1)Ni_(0.9)Co_(0.1)O₃ −18 2.9 4Gd_(0.9)K_(0.1)Ni_(0.9)Cu_(0.1)O₃ −24 3.1 3.8Gd_(0.9)K_(0.1)Ni_(0.9)Mo_(0.1)O₃ −22 2.2 3.7Gd_(0.9)K_(0.1)Ni_(0.9)W_(0.1)O₃ −21 2.1 4Gd_(0.9)K_(0.1)Ni_(0.9)Nb_(0.1)O₃ −27 3 3.9Gd_(0.9)K_(0.1)Ni_(0.9)Ta_(0.1)O₃ −25 2.8 3.6Gd_(0.9)Sr_(0.1)Ni_(0.9)Ti_(0.1)O₃ −28 3.1 3.9Gd_(0.9)Sr_(0.1)Ni_(0.9)V_(0.1)O₃ −27 3 4.6

TABLE 91 Gd_(0.9)Sr_(0.1)Ni_(0.9)Cr_(0.1)O₃ −25 2.4 4.3Gd_(0.9)Sr_(0.1)Ni_(0.9)Mn_(0.1)O₃ −18 2.8 4Gd_(0.9)Sr_(0.1)Ni_(0.9)Fe_(0.1)O₃ −22 2.9 4.7Gd_(0.9)Sr_(0.1)Ni_(0.9)Co_(0.1)O₃ −10 3 4.2Gd_(0.9)Sr_(0.1)Ni_(0.9)Cu_(0.1)O₃ −26 2.8 4.3Gd_(0.9)Sr_(0.1)Ni_(0.9)Mo_(0.1)O₃ −20 3.5 4.9Gd_(0.9)Sr_(0.1)Ni_(0.9)W_(0.1)O₃ −19 4 3.9Gd_(0.9)Sr_(0.1)Ni_(0.9)Nb_(0.1)O₃ −17 3.9 4.2Gd_(0.9)Sr_(0.1)Ni_(0.9)Ta_(0.1)O₃ −23 2.1 4Gd_(0.9)Ca_(0.1)Ni_(0.9)Ti_(0.1)O₃ −18 2.8 4.6Gd_(0.9)Ca_(0.1)Ni_(0.9)V_(0.1)O₃ −20 2.7 4.5Gd_(0.9)Ca_(0.1)Ni_(0.9)Cr_(0.1)O₃ −21 3.9 4.2Gd_(0.9)Ca_(0.1)Ni_(0.9)Mn_(0.1)O₃ −21 3.8 4.7Gd_(0.9)Ca_(0.1)Ni_(0.9)Fe_(0.1)O₃ −22 2.7 4.8Gd_(0.9)Ca_(0.1)Ni_(0.9)Co_(0.1)O₃ −18 1.9 4.1Gd_(0.9)Ca_(0.1)Ni_(0.9)Cu_(0.1)O₃ −25 2.8 3.8Gd_(0.9)Ca_(0.1)Ni_(0.9)Mo_(0.1)O₃ −24 3.7 3.9Gd_(0.9)Ca_(0.1)Ni_(0.9)W_(0.1)O₃ −28 3.4 4.6Gd_(0.9)Ca_(0.1)Ni_(0.9)Nb_(0.1)O₃ −19 2.8 4.3Gd_(0.9)Ca_(0.1)Ni_(0.9)Ta_(0.1)O₃ −20 3 4Gd_(0.9)Bi_(0.1)Ni_(0.9)Ti_(0.1)O₃ −26 2.9 4.7Gd_(0.9)Bi_(0.1)Ni_(0.9)V_(0.1)O₃ −23 1.8 4.2Gd_(0.9)Bi_(0.1)Ni_(0.9)Cr_(0.1)O₃ −22 2.9 4.3Gd_(0.9)Bi_(0.1)Ni_(0.9)Mn_(0.1)O₃ −19 3.1 4.9Gd_(0.9)Bi_(0.1)Ni_(0.9)Fe_(0.1)O₃ −17 2.2 3.9Gd_(0.9)Bi_(0.1)Ni_(0.9)Co_(0.1)O₃ −20 2.1 4.2Gd_(0.9)Bi_(0.1)Ni_(0.9)Cu_(0.1)O₃ −22 3 4Gd_(0.9)Bi_(0.1)Ni_(0.9)Mo_(0.1)O₃ −20 2.8 4.7Gd_(0.9)Bi_(0.1)Ni_(0.9)W_(0.1)O₃ −21 3.2 4.6Gd_(0.9)Bi_(0.1)Ni_(0.9)Nb_(0.1)O₃ −23 3.1 4.5Gd_(0.9)Bi_(0.1)Ni_(0.9)Ta_(0.1)O₃ −18 3 4.2Dy_(0.9)Na_(0.1)Ni_(0.9)Ti_(0.1)O₃ −19 2.8 4.8Dy_(0.9)Na_(0.1)Ni_(0.9)V_(0.1)O₃ −24 2.9 4.1Dy_(0.9)Na_(0.1)Ni_(0.9)Cr_(0.1)O₃ −25 3 3.8Dy_(0.9)Na_(0.1)Ni_(0.9)Mn_(0.1)O₃ −16 2.8 4.3

TABLE 92 Dy_(0.9)Na_(0.1)Ni_(0.9)Fe_(0.1)O₃ −20 3.5 4Dy_(0.9)Na_(0.1)Ni_(0.9)Co_(0.1)O₃ −22 4 4.7Dy_(0.9)Na_(0.1)Ni_(0.9)Cu_(0.1)O₃ −24 3.9 4.2Dy_(0.9)Na_(0.1)Ni_(0.9)Mo_(0.1)O₃ −23 2.1 4.3Dy_(0.9)Na_(0.1)Ni_(0.9)W_(0.1)O₃ −26 2.6 4.9Dy_(0.9)Na_(0.1)Ni_(0.9)Nb_(0.1)O₃ −28 2.8 3.9Dy_(0.9)Na_(0.1)Ni_(0.9)Ta_(0.1)O₃ −19 2.7 4.2Dy_(0.9)K_(0.1)Ni_(0.9)Ti_(0.1)O₃ −22 2.4 4.7Dy_(0.9)K_(0.1)Ni_(0.9)V_(0.1)O₃ −24 2.8 4.6Dy_(0.9)K_(0.1)Ni_(0.9)Cr_(0.1)O₃ −21 2.9 4.5Dy_(0.9)K_(0.1)Ni_(0.9)Mn_(0.1)O₃ −29 3 4.2Dy_(0.9)K_(0.1)Ni_(0.9)Fe_(0.1)O₃ −17 2.8 4.7Dy_(0.9)K_(0.1)Ni_(0.9)Co_(0.1)O₃ −18 3.5 4.8Dy_(0.9)K_(0.1)Ni_(0.9)Cu_(0.1)O₃ −24 4 4.1Dy_(0.9)K_(0.1)Ni_(0.9)Mo_(0.1)O₃ −22 3.9 3.8Dy_(0.9)K_(0.1)Ni_(0.9)W_(0.1)O₃ −21 2.1 4Dy_(0.9)K_(0.1)Ni_(0.9)Nb_(0.1)O₃ −27 2.6 4.6Dy_(0.9)K_(0.1)Ni_(0.9)Ta_(0.1)O₃ −21 2.8 4.2Dy_(0.9)Sr_(0.1)Ni_(0.9)Ti_(0.1)O₃ −19 3.9 4.3Dy_(0.9)Sr_(0.1)Ni_(0.9)V_(0.1)O₃ −23 1.8 4.2Dy_(0.9)Sr_(0.1)Ni_(0.9)Cr_(0.1)O₃ −24 2.9 4.1Dy_(0.9)Sr_(0.1)Ni_(0.9)Mn_(0.1)O₃ −25 3.1 3.9Dy_(0.9)Sr_(0.1)Ni_(0.9)Fe_(0.1)O₃ −16 2.2 4Dy_(0.9)Sr_(0.1)Ni_(0.9)Co_(0.1)O₃ −21 2.1 3.8Dy_(0.9)Sr_(0.1)Ni_(0.9)Cu_(0.1)O₃ −23 3 3.7Dy_(0.9)Sr_(0.1)Ni_(0.9)Mo_(0.1)O₃ −19 2.8 4Dy_(0.9)Sr_(0.1)Ni_(0.9)W_(0.1)O₃ −23 3.2 3.9Dy_(0.9)Sr_(0.1)Ni_(0.9)Nb_(0.1)O₃ −24 3.1 3.6Dy_(0.9)Sr_(0.1)Ni_(0.9)Ta_(0.1)O₃ −25 3 4.1Dy_(0.9)Ca_(0.1)Ni_(0.9)Ti_(0.1)O₃ −20 2.8 4.6Dy_(0.9)Ca_(0.1)Ni_(0.9)V_(0.1)O₃ −22 2.9 4.3Dy_(0.9)Ca_(0.1)Ni_(0.9)Cr_(0.1)O₃ −29 3 4Dy_(0.9)Ca_(0.1)Ni_(0.9)Mn_(0.1)O₃ −22 2.8 4.7Dy_(0.9)Ca_(0.1)Ni_(0.9)Fe_(0.1)O₃ −19 3.5 4.2

TABLE 93 Dy_(0.9)Ca_(0.1)Ni_(0.9)Co_(0.1)O₃ −25 4.0 4.3Dy_(0.9)Ca_(0.1)Ni_(0.9)Cu_(0.1)O₃ −30 3.9 4.9Dy_(0.9)Ca_(0.1)Ni_(0.9)Mo_(0.1)O₃ −28 2.1 3.9Dy_(0.9)Ca_(0.1)Ni_(0.9)W_(0.1)O₃ −27 2.6 4.2Dy_(0.9)Ca_(0.1)Ni_(0.9)Nb_(0.1)O₃ −25 2.8 4Dy_(0.9)Ca_(0.1)Ni_(0.9)Ta_(0.1)O₃ −18 2.7 4.7Dy_(0.9)Bi_(0.1)Ni_(0.9)Ti_(0.1)O₃ −22 3.9 4.6Dy_(0.9)Bi_(0.1)Ni_(0.9)V_(0.1)O₃ −10 3.8 4.5Dy_(0.9)Bi_(0.1)Ni_(0.9)Cr_(0.1)O₃ −26 2.7 4.2Dy_(0.9)Bi_(0.1)Ni_(0.9)Mn_(0.1)O₃ −20 1.9 4.7Dy_(0.9)Bi_(0.1)Ni_(0.9)Fe_(0.1)O₃ −19 2.8 4.8Dy_(0.9)Bi_(0.1)Ni_(0.9)Co_(0.1)O₃ −17 3.7 4.1Dy_(0.9)Bi_(0.1)Ni_(0.9)Cu_(0.1)O₃ −23 3.4 3.8Dy_(0.9)Bi_(0.1)Ni_(0.9)Mo_(0.1)O₃ −22 2.8 4.1Dy_(0.9)Bi_(0.1)Ni_(0.9)W_(0.1)O₃ −18 3 3.9Dy_(0.9)Bi_(0.1)Ni_(0.9)Nb_(0.1)O₃ −20 2.9 4.6Dy_(0.9)Bi_(0.1)Ni_(0.9)Ta_(0.1)O₃ −21 1.8 4.3Ho_(0.9)Na_(0.1)Ni_(0.9)Ti_(0.1)O₃ −22 3.1 4.7Ho_(0.9)Na_(0.1)Ni_(0.9)V_(0.1)O₃ −18 2.2 4.2Ho_(0.9)Na_(0.1)Ni_(0.9)Cr_(0.1)O₃ −25 2.1 4.3Ho_(0.9)Na_(0.1)Ni_(0.9)Mn_(0.1)O₃ −24 3 4.9Ho_(0.9)Na_(0.1)Ni_(0.9)Fe_(0.1)O₃ −28 2.8 3.9Ho_(0.9)Na_(0.1)Ni_(0.9)Co_(0.1)O₃ −19 3.2 4.2Ho_(0.9)Na_(0.1)Ni_(0.9)Cu_(0.1)O₃ −20 3.1 4Ho_(0.9)Na_(0.1)Ni_(0.9)Mo_(0.1)O₃ −26 3 4.7Ho_(0.9)Na_(0.1)Ni_(0.9)W_(0.1)O₃ −23 2.4 4.6Ho_(0.9)Na_(0.1)Ni_(0.9)Nb_(0.1)O₃ −22 2.8 4.5Ho_(0.9)Na_(0.1)Ni_(0.9)Ta_(0.1)O₃ −19 2.9 4.2Ho_(0.9)K_(0.1)Ni_(0.9)Ti_(0.1)O₃ −20 2.8 4.8Ho_(0.9)K_(0.1)Ni_(0.9)V_(0.1)O₃ −22 3.5 4.1Ho_(0.9)K_(0.1)Ni_(0.9)Cr_(0.1)O₃ −20 4 3.8Ho_(0.9)K_(0.1)Ni_(0.9)Mn_(0.1)O₃ −21 3.9 4Ho_(0.9)K_(0.1)Ni_(0.9)Fe_(0.1)O₃ −23 2.1 4.6Ho_(0.9)K_(0.1)Ni_(0.9)Co_(0.1)O₃ −18 2.6 4.2Ho_(0.9)K_(0.1)Ni_(0.9)Cu_(0.1)O₃ −28 2.8 4.5

TABLE 94 Ho_(0.9)K_(0.1)Ni_(0.9)Mo_(0.1)O₃ −19 2.7 4.3Ho_(0.9)K_(0.1)Ni_(0.9)W_(0.1)O₃ −24 3.9 4.1Ho_(0.9)K_(0.1)Ni_(0.9)Nb_(0.1)O₃ −25 3.8 3.9Ho_(0.9)K_(0.1)Ni_(0.9)Ta_(0.1)O₃ −16 2.7 4Ho_(0.9)Sr_(0.1)Ni_(0.9)Ti_(0.1)O₃ −22 2.8 3.7Ho_(0.9)Sr_(0.1)Ni_(0.9)V_(0.1)O₃ −24 3.7 4Ho_(0.9)Sr_(0.1)Ni_(0.9)Cr_(0.1)O₃ −23 3.4 3.9Ho_(0.9)Sr_(0.1)Ni_(0.9)Mn_(0.1)O₃ −26 2.8 3.6Ho_(0.9)Sr_(0.1)Ni_(0.9)Fe_(0.1)O₃ −28 3 4.1Ho_(0.9)Sr_(0.1)Ni_(0.9)Co_(0.1)O₃ −19 2.9 3.9Ho_(0.9)Sr_(0.1)Ni_(0.9)Cu_(0.1)O₃ −21 2.2 4.6Ho_(0.9)Sr_(0.1)Ni_(0.9)Mo_(0.1)O₃ −22 1.9 4.3Ho_(0.9)Sr_(0.1)Ni_(0.9)W_(0.1)O₃ −24 1.8 4Ho_(0.9)Sr_(0.1)Ni_(0.9)Nb_(0.1)O₃ −21 2.9 4.7Ho_(0.9)Sr_(0.1)Ni_(0.9)Ta_(0.1)O₃ −29 3.1 4.2Ho_(0.9)Ca_(0.1)Ni_(0.9)Ti_(0.1)O₃ −18 2.1 4.9Ho_(0.9)Ca_(0.1)Ni_(0.9)V_(0.1)O₃ −24 3 3.9Ho_(0.9)Ca_(0.1)Ni_(0.9)Cr_(0.1)O₃ −22 2.8 4.2Ho_(0.9)Ca_(0.1)Ni_(0.9)Mn_(0.1)O₃ −21 3.2 4Ho_(0.9)Ca_(0.1)Ni_(0.9)Fe_(0.1)O₃ −27 3.1 4.7Ho_(0.9)Ca_(0.1)Ni_(0.9)Co_(0.1)O₃ −25 3 4.6Ho_(0.9)Ca_(0.1)Ni_(0.9)Cu_(0.1)O₃ −30 2.4 4.5Ho_(0.9)Ca_(0.1)Ni_(0.9)Mo_(0.1)O₃ −28 2.8 4.2Ho_(0.9)Ca_(0.1)Ni_(0.9)W_(0.1)O₃ −27 2.9 4.7Ho_(0.9)Ca_(0.1)Ni_(0.9)Nb_(0.1)O₃ −25 3 4.8Ho_(0.9)Ca_(0.1)Ni_(0.9)Ta_(0.1)O₃ −18 2.8 4.1Ho_(0.9)Bi_(0.1)Ni_(0.9)Ti_(0.1)O₃ −22 3.5 3.8Ho_(0.9)Bi_(0.1)Ni_(0.9)V_(0.1)O₃ −10 4 4Ho_(0.9)Bi_(0.1)Ni_(0.9)Cr_(0.1)O₃ −26 3.9 4.6Ho_(0.9)Bi_(0.1)Ni_(0.9)Mn_(0.1)O₃ −20 2.1 4.2Ho_(0.9)Bi_(0.1)Ni_(0.9)Fe_(0.1)O₃ −19 2.6 4.5Ho_(0.9)Bi_(0.1)Ni_(0.9)Co_(0.1)O₃ −17 2.8 4.3Ho_(0.9)Bi_(0.1)Ni_(0.9)Cu_(0.1)O₃ −23 2.7 4.2Ho_(0.9)Bi_(0.1)Ni_(0.9)Mo_(0.1)O₃ −22 3.9 4.1Ho_(0.9)Bi_(0.1)Ni_(0.9)W_(0.1)O₃ −18 3.8 3.9Ho_(0.9)Bi_(0.1)Ni_(0.9)Nb_(0.1)O₃ −20 2.7 4

TABLE 95 Ho_(0.9)Bi_(0.1)Ni_(0.9)Ta_(0.1)O₃ −21 1.9 3.8Er_(0.9)Na_(0.1)Ni_(0.9)Ti_(0.1)O₃ −22 3.7 4Er_(0.9)Na_(0.1)Ni_(0.9)V_(0.1)O₃ −18 3.4 3.9Er_(0.9)Na_(0.1)Ni_(0.9)Cr_(0.1)O₃ −25 2.8 3.6Er_(0.9)Na_(0.1)Ni_(0.9)Mn_(0.1)O₃ −24 3 4.1Er_(0.9)Na_(0.1)Ni_(0.9)Fe_(0.1)O₃ −28 2.9 3.9Er_(0.9)Na_(0.1)Ni_(0.9)Co_(0.1)O₃ −19 1.8 4.6Er_(0.9)Na_(0.1)Ni_(0.9)Cu_(0.1)O₃ −20 2.9 4.3Er_(0.9)Na_(0.1)Ni_(0.9)Mo_(0.1)O₃ −26 3.1 4Er_(0.9)Na_(0.1)Ni_(0.9)W_(0.1)O₃ −23 2.2 4.7Er_(0.9)Na_(0.1)Ni_(0.9)Nb_(0.1)O₃ −22 2.1 4.2Er_(0.9)Na_(0.1)Ni_(0.9)Ta_(0.1)O₃ −19 3 4.3Er_(0.9)K_(0.1)Ni_(0.9)Ti_(0.1)O₃ −20 3.2 3.9Er_(0.9)K_(0.1)Ni_(0.9)V_(0.1)O₃ −22 3.1 4.2Er_(0.9)K_(0.1)Ni_(0.9)Cr_(0.1)O₃ −20 3 4Er_(0.9)K_(0.1)Ni_(0.9)Mn_(0.1)O₃ −21 2.4 4.7Er_(0.9)K_(0.1)Ni_(0.9)Fe_(0.1)O₃ −23 2.8 4.6Er_(0.9)K_(0.1)Ni_(0.9)Co_(0.1)O₃ −18 2.9 4.5Er_(0.9)K_(0.1)Ni_(0.9)Cu_(0.1)O₃ −28 3 4.2Er_(0.9)K_(0.1)Ni_(0.9)Mo_(0.1)O₃ −19 2.8 4.7Er_(0.9)K_(0.1)Ni_(0.9)W_(0.1)O₃ −24 3.5 4.8Er_(0.9)K_(0.1)Ni_(0.9)Nb_(0.1)O₃ −25 4 4.1Er_(0.9)K_(0.1)Ni_(0.9)Ta_(0.1)O₃ −16 3.9 3.8Er_(0.9)Sr_(0.1)Ni_(0.9)Ti_(0.1)O₃ −22 2.6 4.7Er_(0.9)Sr_(0.1)Ni_(0.9)V_(0.1)O₃ −24 2.2 4.6Er_(0.9)Sr_(0.1)Ni_(0.9)Cr_(0.1)O₃ −23 1.9 4.5Er_(0.9)Sr_(0.1)Ni_(0.9)Mn_(0.1)O₃ −26 1.8 4.2Er_(0.9)Sr_(0.1)Ni_(0.9)Fe_(0.1)O₃ −28 2.9 4.7Er_(0.9)Sr_(0.1)Ni_(0.9)Co_(0.1)O₃ −19 3.1 4.8Er_(0.9)Sr_(0.1)Ni_(0.9)Cu_(0.1)O₃ −21 2.2 4.1Er_(0.9)Sr_(0.1)Ni_(0.9)Mo_(0.1)O₃ −22 2.1 3.8Er_(0.9)Sr_(0.1)Ni_(0.9)W_(0.1)O₃ −24 3 4.1Er_(0.9)Sr_(0.1)Ni_(0.9)Nb_(0.1)O₃ −21 2.8 3.9Er_(0.9)Sr_(0.1)Ni_(0.9)Ta_(0.1)O₃ −29 3.2 4.6Er_(0.9)Ca_(0.1)Ni_(0.9)Ti_(0.1)O₃ −18 3 4Er_(0.9)Ca_(0.1)Ni_(0.9)V_(0.1)O₃ −24 2.4 4.7Er_(0.9)Ca_(0.1)Ni_(0.9)Cr_(0.1)O₃ −22 2.8 4.2

TABLE 96 Er_(0.9)Ca_(0.1)Ni_(0.9)Mn_(0.1)O₃ −21 2.9 4.3Er_(0.9)Ca_(0.1)Ni_(0.9)Fe_(0.1)O₃ −27 3 4.9Er_(0.9)Ca_(0.1)Ni_(0.9)Co_(0.1)O₃ −21 2.8 3.9Er_(0.9)Ca_(0.1)Ni_(0.9)Cu_(0.1)O₃ −23 3.5 4.2Er_(0.9)Ca_(0.1)Ni_(0.9)Mo_(0.1)O₃ −19 4 4Er_(0.9)Ca_(0.1)Ni_(0.9)W_(0.1)O₃ −23 3.9 4.7Er_(0.9)Ca_(0.1)Ni_(0.9)Nb_(0.1)O₃ −24 2.1 4.6Er_(0.9)Ca_(0.1)Ni_(0.9)Ta_(0.1)O₃ −25 2.6 4.5Er_(0.9)Bi_(0.1)Ni_(0.9)Ti_(0.1)O₃ −16 2.8 4.2Er_(0.9)Bi_(0.1)Ni_(0.9)V_(0.1)O₃ −20 2.7 4.7Er_(0.9)Bi_(0.1)Ni_(0.9)Cr_(0.1)O₃ −22 3.9 4.8Er_(0.9)Bi_(0.1)Ni_(0.9)Mn_(0.1)O₃ −22 3.8 4.1Er_(0.9)Bi_(0.1)Ni_(0.9)Fe_(0.1)O₃ −10 2.7 3.8Er_(0.9)Bi_(0.1)Ni_(0.9)Co_(0.1)O₃ −26 1.9 4Er_(0.9)Bi_(0.1)Ni_(0.9)Cu_(0.1)O₃ −20 2.8 4.6Er_(0.9)Bi_(0.1)Ni_(0.9)Mo_(0.1)O₃ −19 3.7 4.2Er_(0.9)Bi_(0.1)Ni_(0.9)W_(0.1)O₃ −17 3.4 4.5Er_(0.9)Bi_(0.1)Ni_(0.9)Nb_(0.1)O₃ −23 2.8 4.3Er_(0.9)Bi_(0.1)Ni_(0.9)Ta_(0.1)O₃ −22 3 4.1Yb_(0.9)Na_(0.1)Ni_(0.9)Ti_(0.1)O₃ −20 1.8 4Yb_(0.9)Na_(0.1)Ni_(0.9)V_(0.1)O₃ −21 2.9 3.8Yb_(0.9)Na_(0.1)Ni_(0.9)Cr_(0.1)O₃ −21 3.1 3.7Yb_(0.9)Na_(0.1)Ni_(0.9)Mn_(0.1)O₃ −22 2.2 4Yb_(0.9)Na_(0.1)Ni_(0.9)Fe_(0.1)O₃ −18 2.1 3.9Yb_(0.9)Na_(0.1)Ni_(0.9)Co_(0.1)O₃ −25 3 3.6Yb_(0.9)Na_(0.1)Ni_(0.9)Cu_(0.1)O₃ −24 2.8 4.1Yb_(0.9)Na_(0.1)Ni_(0.9)Mo_(0.1)O₃ −28 3.2 3.9Yb_(0.9)Na_(0.1)Ni_(0.9)W_(0.1)O₃ −19 3.1 4.6Yb_(0.9)Na_(0.1)Ni_(0.9)Nb_(0.1)O₃ −20 3 4.3Yb_(0.9)Na_(0.1)Ni_(0.9)Ta_(0.1)O₃ −26 2.4 4Yb_(0.9)K_(0.1)Ni_(0.9)Ti_(0.1)O₃ −22 2.9 4.2Yb_(0.9)K_(0.1)Ni_(0.9)V_(0.1)O₃ −19 3 4.3Yb_(0.9)K_(0.1)Ni_(0.9)Cr_(0.1)O₃ −17 2.8 4.9Yb_(0.9)K_(0.1)Ni_(0.9)Mn_(0.1)O₃ −20 3.5 3.9Yb_(0.9)K_(0.1)Ni_(0.9)Fe_(0.1)O₃ −22 4 4.2Yb_(0.9)K_(0.1)Ni_(0.9)Co_(0.1)O₃ −20 3.9 4Yb_(0.9)K_(0.1)Ni_(0.9)Cu_(0.1)O₃ −21 2.1 4.7

TABLE 97 Yb_(0.9)K_(0.1)Ni_(0.9)Mo_(0.1)O₃ −23 2.6 4.6Yb_(0.9)K_(0.1)Ni_(0.9)W_(0.1)O₃ −18 2.8 4.5Yb_(0.9)K_(0.1)Ni_(0.9)Nb_(0.1)O₃ −28 2.7 4.2Yb_(0.9)K_(0.1)Ni_(0.9)Ta_(0.1)O₃ −19 3.1 4.7Yb_(0.9)Sr_(0.1)Ni_(0.9)Ti_(0.1)O₃ −25 2.1 4.1Yb_(0.9)Sr_(0.1)Ni_(0.9)V_(0.1)O₃ −16 3 3.8Yb_(0.9)Sr_(0.1)Ni_(0.9)Cr_(0.1)O₃ −20 2.8 4Yb_(0.9)Sr_(0.1)Ni_(0.9)Mn_(0.1)O₃ −22 3.2 4.6Yb_(0.9)Sr_(0.1)Ni_(0.9)Fe_(0.1)O₃ −24 3.1 4.2Yb_(0.9)Sr_(0.1)Ni_(0.9)Co_(0.1)O₃ −23 3 4.5Yb_(0.9)Sr_(0.1)Ni_(0.9)Cu_(0.1)O₃ −26 2.4 4.3Yb_(0.9)Sr_(0.1)Ni_(0.9)Mo_(0.1)O₃ −28 2.8 4.2Yb_(0.9)Sr_(0.1)Ni_(0.9)W_(0.1)O₃ −19 2.9 4.1Yb_(0.9)Sr_(0.1)Ni_(0.9)Nb_(0.1)O₃ −21 3 3.9Yb_(0.9)Sr_(0.1)Ni_(0.9)Ta_(0.1)O₃ −22 2.8 4Yb_(0.9)Ca_(0.1)Ni_(0.9)Ti_(0.1)O₃ −21 4 3.7Yb_(0.9)Ca_(0.1)Ni_(0.9)V_(0.1)O₃ −29 3.9 4Yb_(0.9)Ca_(0.1)Ni_(0.9)Cr_(0.1)O₃ −17 2.1 3.9Yb_(0.9)Ca_(0.1)Ni_(0.9)Mn_(0.1)O₃ −18 2.6 3.6Yb_(0.9)Ca_(0.1)Ni_(0.9)Fe_(0.1)O₃ −24 2.8 4.1Yb_(0.9)Ca_(0.1)Ni_(0.9)Co_(0.1)O₃ −22 2.7 3.9Yb_(0.9)Ca_(0.1)Ni_(0.9)Cu_(0.1)O₃ −21 3.9 4.6Yb_(0.9)Ca_(0.1)Ni_(0.9)Mo_(0.1)O₃ −27 3.8 4.3Yb_(0.9)Ca_(0.1)Ni_(0.9)W_(0.1)O₃ −21 2.7 4Yb_(0.9)Ca_(0.1)Ni_(0.9)Nb_(0.1)O₃ −23 1.9 4.7Yb_(0.9)Ca_(0.1)Ni_(0.9)Ta_(0.1)O₃ −19 2.8 4.2Yb_(0.9)Bi_(0.1)Ni_(0.9)Ti_(0.1)O₃ −23 3.7 4.3Yb_(0.9)Bi_(0.1)Ni_(0.9)V_(0.1)O₃ −24 3.4 4.9Yb_(0.9)Bi_(0.1)Ni_(0.9)Cr_(0.1)O₃ −25 2.8 3.9Yb_(0.9)Bi_(0.1)Ni_(0.9)Mn_(0.1)O₃ −16 3 4.2Yb_(0.9)Bi_(0.1)Ni_(0.9)Fe_(0.1)O₃ −20 2.9 4Yb_(0.9)Bi_(0.1)Ni_(0.9)Co_(0.1)O₃ −22 1.8 4.7Yb_(0.9)Bi_(0.1)Ni_(0.9)Cu_(0.1)O₃ −29 2.9 4.6Yb_(0.9)Bi_(0.1)Ni_(0.9)Mo_(0.1)O₃ −22 3.1 4.5Yb_(0.9)Bi_(0.1)Ni_(0.9)W_(0.1)O₃ −19 2.2 4.2Yb_(0.9)Bi_(0.1)Ni_(0.9)Nb_(0.1)O₃ −25 2.1 4.7Yb_(0.9)Bi_(0.1)Ni_(0.9)Ta_(0.1)O₃ −30 3 4.8

TABLE 98 Seebeck Electrical Thermal Coefficient Resistivity ConductivityComposition μV/K mΩcm W/mK (Ln_(s)R³ _(t))₂Ni_(u)R⁴ _(v)O_(w) (700° C.)(700° C.) (700° C.) La₂NiO₄ −25 6.1 4.3 Ce₂NiO₄ −28 5 4.2 Pr₂NiO₄ −28 74.3 Nd₂NiO₄ −22 4.9 4.5 Sm₂NiO₄ −20 5 4.6 Eu₂NiO₄ −25 6 4.7 Gd₂NiO₄ −275.2 4.4 Dy₂NiO₄ −30 7 4.9 Ho₂NiO₄ −29 8.1 4.7 Er₂NiO₄ −30 6.9 4.6Yb₂NiO₄ −28 6.7 4.6 La_(1.8)Na_(0.2)NiO₄ −25 6.9 4.2 La_(1.8)K_(0.2)NiO₄−18 5.9 4.7 La_(1.8)Sr_(0.2)NiO₄ −22 6.3 4.8 La_(1.8)Ca_(0.2)NiO₄ −10 74.1 La_(1.8)Bi_(0.2)NiO₄ −26 7.1 3.8 Ce_(1.8)Na_(0.2)NiO₄ −19 7 4.6Ce_(1.8)K_(0.2)NiO₄ −17 6.8 4.2 Ce_(1.8)Sr_(0.2)NiO₄ −23 6.9 4.5Ce_(1.8)Ca_(0.2)NiO₄ −22 6.7 4.3 Ce_(1.8)Bi_(0.2)NiO₄ −18 7.1 4.1Pr_(1.8)Na_(0.2)NiO₄ −21 6.3 4 Pr_(1.8)K_(0.2)NiO₄ −21 7.1 3.8Pr_(1.8)Sr_(0.2)NiO₄ −22 6.4 3.7 Pr_(1.8)Ca_(0.2)NiO₄ −18 5.9 4Pr_(1.8)Bi_(0.2)NiO₄ −25 6.4 3.9 Nd_(1.8)Na_(0.2)NiO₄ −28 7 4.1Nd_(1.8)K_(0.2)NiO₄ −19 6.8 3.9 Nd_(1.8)Sr_(0.2)NiO₄ −20 7.1 4.6Nd_(1.8)Ca_(0.2)NiO₄ −26 6.8 4.3 Nd_(1.8)Bi_(0.2)NiO₄ −23 5.9 4

TABLE 99 Sm_(1.8)Na_(0.2)NiO₄ −19 7 4.2 Sm_(1.8)K_(0.2)NiO₄ −17 6.8 4.3Sm_(1.8)Sr_(0.2)NiO₄ −20 5 4.9 Sm_(1.8)Ca_(0.2)NiO₄ −22 7 3.9Sm_(1.8)Bi_(0.2)NiO₄ −20 4.9 4.2 Eu_(1.8)Na_(0.2)NiO₄ −23 6 4.7Eu_(1.8)K_(0.2)NiO₄ −18 5.2 4.6 Eu_(1.8)Sr_(0.2)NiO₄ −28 7 4.5Eu_(1.8)Ca_(0.2)NiO₄ −19 8.1 4.2 Eu_(1.8)Bi_(0.2)NiO₄ −24 6.9 4.7Gd_(1.8)Na_(0.2)NiO₄ −16 7.2 4.1 Gd_(1.8)K_(0.2)NiO₄ −20 6.9 3.8Gd_(1.8)Sr_(0.2)NiO₄ −22 5.9 4 Gd_(1.8)Ca_(0.2)NiO₄ −24 6.3 4.6Gd_(1.8)Bi_(0.2)NiO₄ −23 7 4.2 Dy_(1.8)Na_(0.2)NiO₄ −28 7.3 4.3Dy_(1.8)K_(0.2)NiO₄ −19 7 4.2 Dy_(1.8)Sr_(0.2)NiO₄ −21 6.8 4.1Dy_(1.8)Ca_(0.2)NiO₄ −22 6.9 3.9 Dy_(1.8)Bi_(0.2)NiO₄ −24 6.7 4Ho_(1.8)Na_(0.2)NiO₄ −29 5.8 3.7 Ho_(1.8)K_(0.2)NiO₄ −17 6.3 4Ho_(1.8)Sr_(0.2)NiO₄ −18 7.1 3.9 Ho_(1.8)Ca_(0.2)NiO₄ −24 6.4 3.6Ho_(1.8)Bi_(0.2)NiO₄ −22 5.9 4.1 Er_(1.8)Na_(0.2)NiO₄ −27 7.1 4.6Er_(1.8)K_(0.2)NiO₄ −25 7 4.3 Er_(1.8)Sr_(0.2)NiO₄ −30 6.8 4Er_(1.8)Ca_(0.2)NiO₄ −28 7.1 4.7 Er_(1.8)Bi_(0.2)NiO₄ −24 6.8 4.2Yb_(1.8)Na_(0.2)NiO₄ −25 5.9 4.3

TABLE 100 Yb_(1.8)K_(0.2)NiO₄ −16 6.5 4.9 Yb_(1.8)Sr_(0.2)NiO₄ −20 7 3.9Yb_(1.8)Ca_(0.2)NiO₄ −22 6.8 4.2 Yb_(1.8)Bi_(0.2)NiO₄ −24 5.8 4La₂Ni_(1.8)Ti_(0.2)O₄ −26 7.1 4.6 La₂Ni_(1.8)V_(0.2)O₄ −28 6.4 4.5La₂Ni_(1.8)Cr_(0.2)O₄ −19 5.9 4.2 La₂Ni_(1.8)Mn_(0.2)O₄ −21 6.4 4.7La₂Ni_(1.8)Fe_(0.2)O₄ −22 7.1 4.8 La₂Ni_(1.8)Co_(0.2)O₄ −24 7 4.1La₂Ni_(1.8)Cu_(0.2)O₄ −21 6.8 3.8 La₂Ni_(1.8)Mo_(0.2)O₄ −29 7.1 4La₂Ni_(1.8)W_(0.2)O₄ −17 6.8 4.7 La₂Ni_(1.8)Nb_(0.2)O₄ −18 5.9 4.6La₂Ni_(1.8)Ta_(0.2)O₄ −24 6.5 4.5 Ce₂Ni_(0.9)Ti_(0.1)O₄ −21 5 4.7Ce₂Ni_(0.9)V_(0.1)O₄ −27 7 4.8 Ce₂Ni_(0.9)Cr_(0.1)O₄ −25 4.9 4.1Ce₂Ni_(0.9)Mn_(0.1)O₄ −30 5 3.8 Ce₂Ni_(0.9)Fe_(0.1)O₄ −28 6 4.1Ce₂Ni_(0.9)Co_(0.1)O₄ −27 5.2 3.9 Ce₂Ni_(0.9)Cu_(0.1)O₄ −25 7 4.6Ce₂Ni_(0.9)Mo_(0.1)O₄ −18 8.1 4.3 Ce₂Ni_(0.9)W_(0.1)O₄ −22 6.9 4Ce₂Ni_(0.9)Nb_(0.1)O₄ −10 5.7 4.7 Ce₂Ni_(0.9)Ta_(0.1)O₄ −26 7.2 4.2Pr₂Ni_(0.9)Ti_(0.1)O₄ −19 5.9 4.9 Pr₂Ni_(0.9)V_(0.1)O₄ −17 6.3 3.9Pr₂Ni_(0.9)Cr_(0.1)O₄ −23 7 4.2 Pr₂Ni_(0.9)Mn_(0.1)O₄ −22 7.1 4Pr₂Ni_(0.9)Fe_(0.1)O₄ −18 7.3 4.7 Pr₂Ni_(0.9)Co_(0.1)O₄ −20 7 4.6Pr₂Ni_(0.9)Cu_(0.1)O₄ −21 6.8 4.5 Pr₂Ni_(0.9)Mo_(0.1)O₄ −21 6.9 4.2

TABLE 101 Pr₂Ni_(0.9)W_(0.1)O₄ −22 6.7 4.7 Pr₂Ni_(0.9)Nb_(0.1)O₄ −18 7.14.8 Pr₂Ni_(0.9)Ta_(0.1)O₄ −25 5.8 4.1 Nd₂Ni_(0.9)Ti_(0.1)O₄ −28 7.1 4Nd₂Ni_(0.9)V_(0.1)O₄ −19 6.4 4.6 Nd₂Ni_(0.9)Cr_(0.1)O₄ −20 5.9 4.2Nd₂Ni_(0.9)Mn_(0.1)O₄ −26 6.4 4.5 Nd₂Ni_(0.9)Fe_(0.1)O₄ −23 7.1 4.3Nd₂Ni_(0.9)Co_(0.1)O₄ −22 7 4.1 Nd₂Ni_(0.9)Cu_(0.1)O₄ −19 6.8 3.9Nd₂Ni_(0.9)Mo_(0.1)O₄ −17 7.1 4 Nd₂Ni_(0.9)W_(0.1)O₄ −20 6.8 3.8Nd₂Ni_(0.9)Nb_(0.1)O₄ −22 5.9 3.7 Nd₂Ni_(0.9)Ta_(0.1)O₄ −20 6.5 4Sm₂Ni_(0.9)Ti_(0.1)O₄ −23 6.8 3.6 Sm₂Ni_(0.9)V_(0.1)O₄ −18 5 4.1Sm₂Ni_(0.9)Cr_(0.1)O₄ −28 7 3.9 Sm₂Ni_(0.9)Mn_(0.1)O₄ −19 4.9 4.6Sm₂Ni_(0.9)Fe_(0.1)O₄ −24 5 4.3 Sm₂Ni_(0.9)Co_(0.1)O₄ −25 6 4Sm₂Ni_(0.9)Cu_(0.1)O₄ −16 5.2 4.7 Sm₂Ni_(0.9)Mo_(0.1)O₄ −20 7 4.2Sm₂Ni_(0.9)W_(0.1)O₄ −22 8.1 4.3 Sm₂Ni_(0.9)Nb_(0.1)O₄ −24 6.9 4.9Sm₂Ni_(0.9)Ta_(0.1)O₄ −23 6.7 3.9 Eu₂Ni_(0.9)Ti_(0.1)O₄ −26 7.2 4.2Eu₂Ni_(0.9)V_(0.1)O₄ −28 6.9 4 Eu₂Ni_(0.9)Cr_(0.1)O₄ −19 5.9 4.7Eu₂Ni_(0.9)Mn_(0.1)O₄ −21 6.3 4.6 Eu₂Ni_(0.9)Fe_(0.1)O₄ −22 7 4.5Eu₂Ni_(0.9)Co_(0.1)O₄ −24 7.1 4.2 Eu₂Ni_(0.9)Cu_(0.1)O₄ −21 7.3 4.7Eu₂Ni_(0.9)Mo_(0.1)O₄ −29 7 4.8 Eu₂Ni_(0.9)W_(0.1)O₄ −17 6.8 4.1Eu₂Ni_(0.9)Nb_(0.1)O₄ −18 6.9 3.8

TABLE 102 Eu₂Ni_(0.9)Ta_(0.1)O₄ −24 6.7 4 Gd₂Ni_(0.9)Ti_(0.1)O₄ −21 5.84.2 Gd₂Ni_(0.9)V_(0.1)O₄ −27 6.3 4.3 Gd₂Ni_(0.9)Cr_(0.1)O₄ −21 7.1 4.5Gd₂Ni_(0.9)Mn_(0.1)O₄ −23 6.4 4.6 Gd₂Ni_(0.9)Fe_(0.1)O₄ −19 5.9 4.7Gd₂Ni_(0.9)Co_(0.1)O₄ −23 6.4 4.4 Gd₂Ni_(0.9)Cu_(0.1)O₄ −24 7.1 4.9Gd₂Ni_(0.9)Mo_(0.1)O₄ −25 7 4.7 Gd₂Ni_(0.9)W_(0.1)O₄ −16 6.8 4.6Gd₂Ni_(0.9)Nb_(0.1)O₄ −20 7.1 4.6 Gd₂Ni_(0.9)Ta_(0.1)O₄ −22 6.8 4.5Dy₂Ni_(0.9)Ti_(0.1)O₄ −10 6.5 4.7 Dy₂Ni_(0.9)V_(0.1)O₄ −26 7 4.8Dy₂Ni_(0.9)Cr_(0.1)O₄ −20 6.8 4.1 Dy₂Ni_(0.9)Mn_(0.1)O₄ −19 5.8 3.8Dy₂Ni_(0.9)Fe_(0.1)O₄ −17 6.3 4 Dy₂Ni_(0.9)Co_(0.1)O₄ −23 7.1 4.6Dy₂Ni_(0.9)Cu_(0.1)O₄ −22 6.4 4.2 Dy₂Ni_(0.9)Mo_(0.1)O₄ −18 5.9 4.5Dy₂Ni_(0.9)W_(0.1)O₄ −20 6.4 4.3 Dy₂Ni_(0.9)Nb_(0.1)O₄ −21 7.1 4.1Dy₂Ni_(0.9)Ta_(0.1)O₄ −21 7 3.9 Ho₂Ni_(0.9)Ti_(0.1)O₄ −18 7.1 3.8Ho₂Ni_(0.9)V_(0.1)O₄ −25 6.8 3.7 Ho₂Ni_(0.9)Cr_(0.1)O₄ −24 5.9 4Ho₂Ni_(0.9)Mn_(0.1)O₄ −28 5 3.9 Ho₂Ni_(0.9)Fe_(0.1)O₄ −19 7 3.6Ho₂Ni_(0.9)Co_(0.1)O₄ −20 4.9 4.1 Ho₂Ni_(0.9)Cu_(0.1)O₄ −26 5 3.9Ho₂Ni_(0.9)Mo_(0.1)O₄ −23 6 4.6 Ho₂Ni_(0.9)W_(0.1)O₄ −22 5.2 4.3Ho₂Ni_(0.9)Nb_(0.1)O₄ −19 7 4 Ho₂Ni_(0.9)Ta_(0.1)O₄ −17 8.1 4.7

TABLE 103 Er₂Ni_(0.9)Ti_(0.1)O₄ −22 6.7 4.3 Er₂Ni_(0.9)V_(0.1)O₄ −20 7.24.9 Er₂Ni_(0.9)Cr_(0.1)O₄ −21 6.9 3.9 Er₂Ni_(0.9)Mn_(0.1)O₄ −23 5.9 4.2Er₂Ni_(0.9)Fe_(0.1)O₄ −18 6.3 4 Er₂Ni_(0.9)Co_(0.1)O₄ −28 7 4.7Er₂Ni_(0.9)Cu_(0.1)O₄ −19 7.1 4.6 Er₂Ni_(0.9)Mo_(0.1)O₄ −24 7.3 4.5Er₂Ni_(0.9)W_(0.1)O₄ −25 7 4.2 Er₂Ni_(0.9)Nb_(0.1)O₄ −16 6.8 4.7Er₂Ni_(0.9)Ta_(0.1)O₄ −20 6.9 4.8 Yb₂Ni_(0.9)Ti_(0.1)O₄ −24 7.1 3.8Yb₂Ni_(0.9)V_(0.1)O₄ −23 5.8 4 Yb₂Ni_(0.9)Cr_(0.1)O₄ −26 6.3 4.6Yb₂Ni_(0.9)Mn_(0.1)O₄ −28 7.1 4.2 Yb₂Ni_(0.9)Fe_(0.1)O₄ −19 6.4 4.5Yb₂Ni_(0.9)Co_(0.1)O₄ −21 5.9 4.3 Yb₂Ni_(0.9)Cu_(0.1)O₄ −22 6.4 4.2Yb₂Ni_(0.9)Mo_(0.1)O₄ −24 7.1 4.1 Yb₂Ni_(0.9)W_(0.1)O₄ −21 7 3.9Yb₂Ni_(0.9)Nb_(0.1)O₄ −29 6.8 4 Yb₂Ni_(0.9)Ta_(0.1)O₄ −17 7.1 3.8La_(1.8)Na_(0.2)Ni_(0.9)Ti_(0.1)O₄ −24 5.9 4La_(1.8)Na_(0.2)Ni_(0.9)V_(0.1)O₄ −22 6.5 3.9La_(1.8)Na_(0.2)Ni_(0.9)Cr_(0.1)O₄ −21 7 3.6La_(1.8)Na_(0.2)Ni_(0.9)Mn_(0.1)O₄ −30 6.8 4.1La_(1.8)Na_(0.2)Ni_(0.9)Fe_(0.1)O₄ −29 5 3.9La_(1.8)Na_(0.2)Ni_(0.9)Co_(0.1)O₄ −30 7 4.6La_(1.8)Na_(0.2)Ni_(0.9)Cu_(0.1)O₄ −28 4.9 4.3La_(1.8)Na_(0.2)Ni_(0.9)Mo_(0.1)O₄ −27 5 4La_(1.8)Na_(0.2)Ni_(0.9)W_(0.1)O₄ −25 6 4.7La_(1.8)Na_(0.2)Ni_(0.9)Nb_(0.1)O₄ −18 5.2 4.4La_(1.8)Na_(0.2)Ni_(0.9)Ta_(0.9)O₄ −22 7 4.9

TABLE 104 La_(1.8)K_(0.2)Ni_(0.9)Ti_(0.1)O₄ −26 6.9 4.6La_(1.8)K_(0.2)Ni_(0.9)V_(0.1)O₄ −20 6.7 4.6La_(1.8)K_(0.2)Ni_(0.9)Cr_(0.1)O₄ −19 7.2 4.5La_(1.8)K_(0.2)Ni_(0.9)Mn_(0.1)O₄ −17 6.9 4.2La_(1.8)K_(0.2)Ni_(0.9)Fe_(0.1)O₄ −23 5.9 4.7La_(1.8)K_(0.2)Ni_(0.9)Co_(0.1)O₄ −22 6.3 4.8La_(1.8)K_(0.2)Ni_(0.9)Cu_(0.1)O₄ −18 7 4.1La_(1.8)K_(0.2)Ni_(0.9)Mo_(0.1)O₄ −20 7.1 3.8La_(1.8)K_(0.2)Ni_(0.9)W_(0.1)O₄ −21 7.3 4La_(1.8)K_(0.2)Ni_(0.9)Nb_(0.1)O₄ −21 7 4.6La_(1.8)K_(0.2)Ni_(0.9)Ta_(0.1)O₄ −22 6.8 4.2La_(1.8)Sr_(0.2)Ni_(0.9)Ti_(0.1)O₄ −25 6.7 4.3La_(1.8)Sr_(0.2)Ni_(0.9)V_(0.1)O₄ −24 7.1 4.1La_(1.8)Sr_(0.2)Ni_(0.9)Cr_(0.1)O₄ −28 5.8 3.9La_(1.8)Sr_(0.2)Ni_(0.9)Mn_(0.1)O₄ −19 6.3 4La_(1.8)Sr_(0.2)Ni_(0.9)Fe_(0.1)O₄ −20 7.1 3.8La_(1.8)Sr_(0.2)Ni_(0.9)Co_(0.1)O₄ −26 6.4 3.7La_(1.8)Sr_(0.2)Ni_(0.9)Cu_(0.1)O₄ −23 5.9 4La_(1.8)Sr_(0.2)Ni_(0.9)Mo_(0.1)O₄ −22 6.4 3.9La_(1.8)Sr_(0.2)Ni_(0.9)W_(0.1)O₄ −19 7.1 3.6La_(1.8)Sr_(0.2)Ni_(0.9)Nb_(0.1)O₄ −17 7 4.1La_(1.8)Sr_(0.2)Ni_(0.9)Ta_(0.1)O₄ −20 6.8 3.9La_(1.8)Ca_(0.2)Ni_(0.9)Ti_(0.1)O₄ −20 6.8 4.3La_(1.8)Ca_(0.2)Ni_(0.9)V_(0.1)O₄ −21 5.9 4La_(1.8)Ca_(0.2)Ni_(0.9)Cr_(0.1)O₄ −23 6.5 4.7La_(1.8)Ca_(0.2)Ni_(0.9)Mn_(0.1)O₄ −18 7 4.2La_(1.8)Ca_(0.2)Ni_(0.9)Fe_(0.1)O₄ −28 6.8 4.3La_(1.8)Ca_(0.2)Ni_(0.9)Co_(0.1)O₄ −19 5.8 4.9La_(1.8)Ca_(0.2)Ni_(0.9)Cu_(0.1)O₄ −24 6.3 3.9La_(1.8)Ca_(0.2)Ni_(0.9)Mo_(0.1)O₄ −25 7.1 4.2La_(1.8)Ca_(0.2)Ni_(0.9)W_(0.1)O₄ −16 6.4 4La_(1.8)Ca_(0.2)Ni_(0.9)Nb_(0.1)O₄ −20 5.9 4.7La_(1.8)Ca_(0.2)Ni_(0.9)Ta_(0.1)O₄ −22 6.4 4.6La_(1.8)Bi_(0.2)Ni_(0.9)Ti_(0.1)O₄ −23 7 4.2

TABLE 105 La_(1.8)Bi_(0.2)Ni_(0.9)V_(0.1)O₄ −26 6.8 4.7La_(1.8)Bi_(0.2)Ni_(0.9)Cr_(0.1)O₄ −28 7.1 4.8La_(1.8)Bi_(0.2)Ni_(0.9)Mn_(0.1)O₄ −19 6.8 4.1La_(1.8)Bi_(0.2)Ni_(0.9)Fe_(0.1)O₄ −21 5.9 3.8La_(1.8)Bi_(0.2)Ni_(0.9)Co_(0.1)O₄ −22 6.5 4La_(1.8)Bi_(0.2)Ni_(0.9)Cu_(0.1)O₄ −24 7 4.6La_(1.8)Bi_(0.2)Ni_(0.9)Mo_(0.1)O₄ −21 5 4.2La_(1.8)Bi_(0.2)Ni_(0.9)W_(0.1)O₄ −29 7 4.5La_(1.8)Bi_(0.2)Ni_(0.9)Nb_(0.1)O₄ −17 4.9 4.3La_(1.8)Bi_(0.2)Ni_(0.9)Ta_(0.1)O₄ −18 5 4.2Ce_(1.8)Na_(0.2)Ni_(0.9)Ti_(0.1)O₄ −22 5.2 3.9Ce_(1.8)Na_(0.2)Ni_(0.9)V_(0.1)O₄ −21 7 4Ce_(1.8)Na_(0.2)Ni_(0.9)Cr_(0.1)O₄ −27 8.1 3.8Ce_(1.8)Na_(0.2)Ni_(0.9)Mn_(0.1)O₄ −25 6.9 3.7Ce_(1.8)Na_(0.2)Ni_(0.9)Fe_(0.1)O₄ −30 6.7 4Ce_(1.8)Na_(0.2)Ni_(0.9)Co_(0.1)O₄ −28 7.2 3.9Ce_(1.8)Na_(0.2)Ni_(0.9)Cu_(0.1)O₄ −24 6.9 3.6Ce_(1.8)Na_(0.2)Ni_(0.9)Mo_(0.1)O₄ −25 5.9 4.1Ce_(1.8)Na_(0.2)Ni_(0.9)W_(0.1)O₄ −16 6.3 3.9Ce_(1.8)Na_(0.2)Ni_(0.9)Nb_(0.1)O₄ −20 7 4.6Ce_(1.8)Na_(0.2)Ni_(0.9)Ta_(0.1)O₄ −22 7.1 4.3Ce_(1.8)K_(0.2)Ni_(0.9)Ti_(0.1)O₄ −23 7 4Ce_(1.8)K_(0.2)Ni_(0.9)V_(0.1)O₄ −26 6.8 4.7Ce_(1.8)K_(0.2)Ni_(0.9)Cr_(0.1)O₄ −28 5.2 4.2Ce_(1.8)K_(0.2)Ni_(0.9)Mn_(0.1)O₄ −19 7 4.3Ce_(1.8)K_(0.2)Ni_(0.9)Fe_(0.1)O₄ −21 8.1 4.9Ce_(1.8)K_(0.2)Ni_(0.9)Co_(0.1)O₄ −22 6.9 3.9Ce_(1.8)K_(0.2)Ni_(0.9)Cu_(0.1)O₄ −24 6.7 4.2Ce_(1.8)K_(0.2)Ni_(0.9)Mo_(0.1)O₄ −21 7.2 4Ce_(1.8)K_(0.2)Ni_(0.9)W_(0.1)O₄ −29 6.9 4.7Ce_(1.8)K_(0.2)Ni_(0.9)Nb_(0.1)O₄ −17 5.9 4.6Ce_(1.8)K_(0.2)Ni_(0.9)Ta_(0.1)O₄ −18 6.3 4.5Ce_(1.8)Sr_(0.2)Ni_(0.9)Ti_(0.1)O₄ −22 7.1 4.7Ce_(1.8)Sr_(0.2)Ni_(0.9)V_(0.1)O₄ −21 7.3 4.8

TABLE 106 Ce_(1.8)Sr_(0.2)Ni_(0.9)Cr_(0.1)O₄ −27 7.0 4.1Ce_(1.8)Sr_(0.2)Ni_(0.9)Mn_(0.1)O₄ −25 6.8 3.8Ce_(1.8)Sr_(0.2)Ni_(0.9)Fe_(0.1)O₄ −30 6.9 4Ce_(1.8)Sr_(0.2)Ni_(0.9)Co_(0.1)O₄ −28 6.7 4.6Ce_(1.8)Sr_(0.2)Ni_(0.9)Cu_(0.1)O₄ −27 7.1 4.2Ce_(1.8)Sr_(0.2)Ni_(0.9)Mo_(0.1)O₄ −25 5.8 4.5Ce_(1.8)Sr_(0.2)Ni_(0.9)W_(0.1)O₄ −18 6.3 4.3Ce_(1.8)Sr_(0.2)Ni_(0.9)Nb_(0.1)O₄ −22 7.1 4.2Ce_(1.8)Sr_(0.2)Ni_(0.9)Ta_(0.1)O₄ −10 6.4 4.1Ce_(1.8)Ca_(0.2)Ni_(0.9)Ti_(0.1)O₄ −23 6.4 4Ce_(1.8)Ca_(0.2)Ni_(0.9)V_(0.1)O₄ −22 7.1 3.8Ce_(1.8)Ca_(0.2)Ni_(0.9)Cr_(0.1)O₄ −19 7 3.7Ce_(1.8)Ca_(0.2)Ni_(0.9)Mn_(0.1)O₄ −17 6.8 4Ce_(1.8)Ca_(0.2)Ni_(0.9)Fe_(0.1)O₄ −20 7.1 3.9Ce_(1.8)Ca_(0.2)Ni_(0.9)Co_(0.1)O₄ −22 6.8 3.6Ce_(1.8)Ca_(0.2)Ni_(0.9)Cu_(0.1)O₄ −20 5.9 4.1Ce_(1.8)Ca_(0.2)Ni_(0.9)Mo_(0.1)O₄ −21 6.5 4.5Ce_(1.8)Ca_(0.2)Ni_(0.9)W_(0.1)O₄ −23 7 4.6Ce_(1.8)Ca_(0.2)Ni_(0.9)Nb_(0.1)O₄ −18 6.8 4.3Ce_(1.8)Ca_(0.2)Ni_(0.9)Ta_(0.1)O₄ −28 5 4Ce_(1.8)Bi_(0.2)Ni_(0.9)Ti_(0.1)O₄ −24 4.9 4.2Ce_(1.8)Bi_(0.2)Ni_(0.9)V_(0.1)O₄ −25 5 4.3Ce_(1.8)Bi_(0.2)Ni_(0.9)Cr_(0.1)O₄ −16 6 4.9Ce_(1.8)Bi_(0.2)Ni_(0.9)Mn_(0.1)O₄ −20 5.2 3.9Ce_(1.8)Bi_(0.2)Ni_(0.9)Fe_(0.1)O₄ −22 7 4.2Ce_(1.8)Bi_(0.2)Ni_(0.9)Co_(0.1)O₄ −24 8.1 4Ce_(1.8)Bi_(0.2)Ni_(0.9)Cu_(0.1)O₄ −23 6.9 4.7Ce_(1.8)Bi_(0.2)Ni_(0.9)Mo_(0.1)O₄ −26 6.7 4.6Ce_(1.8)Bi_(0.2)Ni_(0.9)W_(0.1)O₄ −28 7.2 4.5Ce_(1.8)Bi_(0.2)Ni_(0.9)Nb_(0.1)O₄ −19 6.9 4.2Ce_(1.8)Bi_(0.2)Ni_(0.9)Ta_(0.1)O₄ −21 5.9 4.7Pr_(1.8)Na_(0.2)Ni_(0.9)Ti_(0.1)O₄ −24 7 4.1Pr_(1.8)Na_(0.2)Ni_(0.9)V_(0.1)O₄ −21 7.1 3.8Pr_(1.8)Na_(0.2)Ni_(0.9)Cr_(0.1)O₄ −29 7.3 4

TABLE 107 Pr_(1.8)Na_(0.2)Ni_(0.9)Mn_(0.1)O₄ −17 7 4.7Pr_(1.8)Na_(0.2)Ni_(0.9)Fe_(0.1)O₄ −18 6.8 4.6Pr_(1.8)Na_(0.2)Ni_(0.9)Co_(0.1)O₄ −24 6.9 4.5Pr_(1.8)Na_(0.2)Ni_(0.9)Cu_(0.1)O₄ −22 6.7 4.2Pr_(1.8)Na_(0.2)Ni_(0.9)Mo_(0.1)O₄ −21 7.1 4.7Pr_(1.8)Na_(0.2)Ni_(0.9)W_(0.1)O₄ −27 5.8 4.8Pr_(1.8)Na_(0.2)Ni_(0.9)Nb_(0.1)O₄ −25 6.3 4.1Pr_(1.8)Na_(0.2)Ni_(0.9)Ta_(0.1)O₄ −30 7.1 3.8Pr_(1.8)K_(0.2)Ni_(0.9)Ti_(0.1)O₄ −24 5.9 3.9Pr_(1.8)K_(0.2)Ni_(0.9)V_(0.1)O₄ −25 6.4 4.6Pr_(1.8)K_(0.2)Ni_(0.9)Cr_(0.1)O₄ −16 7.1 4.3Pr_(1.8)K_(0.2)Ni_(0.9)Mn_(0.1)O₄ −20 7 4Pr_(1.8)K_(0.2)Ni_(0.9)Fe_(0.1)O₄ −22 6.8 4.7Pr_(1.8)K_(0.2)Ni_(0.9)Co_(0.1)O₄ −24 7.1 4.2Pr_(1.8)K_(0.2)Ni_(0.9)Cu_(0.1)O₄ −23 6.8 4.3Pr_(1.8)K_(0.2)Ni_(0.9)Mo_(0.1)O₄ −26 5.9 4.9Pr_(1.8)K_(0.2)Ni_(0.9)W_(0.1)O₄ −28 6.5 3.9Pr_(1.8)K_(0.2)Ni_(0.9)Nb_(0.1)O₄ −19 7 4.2Pr_(1.8)K_(0.2)Ni_(0.9)Ta_(0.1)O₄ −21 6.8 4Pr_(1.8)Sr_(0.2)Ni_(0.9)Ti_(0.1)O₄ −24 6.3 4.6Pr_(1.8)Sr_(0.2)Ni_(0.9)V_(0.1)O₄ −21 7.1 4.5Pr_(1.8)Sr_(0.2)Ni_(0.9)Cr_(0.1)O₄ −29 6.4 4.2Pr_(1.8)Sr_(0.2)Ni_(0.9)Mn_(0.1)O₄ −17 5.9 4.7Pr_(1.8)Sr_(0.2)Ni_(0.9)Fe_(0.1)O₄ −18 6.4 4.8Pr_(1.8)Sr_(0.2)Ni_(0.9)Co_(0.1)O₄ −24 7.1 4.1Pr_(1.8)Sr_(0.2)Ni_(0.9)Cu_(0.1)O₄ −22 7 3.8Pr_(1.8)Sr_(0.2)Ni_(0.9)Mo_(0.1)O₄ −21 6.8 4Pr_(1.8)Sr_(0.2)Ni_(0.9)W_(0.1)O₄ −27 7.1 4.6Pr_(1.8)Sr_(0.2)Ni_(0.9)Nb_(0.1)O₄ −25 6.8 4.2Pr_(1.8)Sr_(0.2)Ni_(0.9)Ta_(0.1)O₄ −30 5.9 4.5Pr_(1.8)Ca_(0.2)Ni_(0.9)Ti_(0.1)O₄ −27 7 4.1Pr_(1.8)Ca_(0.2)Ni_(0.9)V_(0.1)O₄ −25 4.9 3.9Pr_(1.8)Ca_(0.2)Ni_(0.9)Cr_(0.1)O₄ −18 5.0 4Pr_(1.8)Ca_(0.2)Ni_(0.9)Mn_(0.1)O₄ −22 6.0 3.8

TABLE 108 Pr_(1.8)Ca_(0.2)Ni_(0.9)Fe_(0.1)O₄ −10 5.2 3.7Pr_(1.8)Ca_(0.2)Ni_(0.9)Co_(0.1)O₄ −26 7.0 4Pr_(1.8)Ca_(0.2)Ni_(0.9)Cu_(0.1)O₄ −20 8.1 3.9Pr_(1.8)Ca_(0.2)Ni_(0.9)Mo_(0.1)O₄ −19 6.9 3.6Pr_(1.8)Ca_(0.2)Ni_(0.9)W_(0.1)O₄ −17 6.7 4.1Pr_(1.8)Ca_(0.2)Ni_(0.9)Nb_(0.1)O₄ −23 7.2 3.9Pr_(1.8)Ca_(0.2)Ni_(0.9)Ta_(0.1)O₄ −22 6.9 4.6Pr_(1.8)Bi_(0.2)Ni_(0.9)Ti_(0.1)O₄ −20 6.3 4Pr_(1.8)Bi_(0.2)Ni_(0.9)V_(0.1)O₄ −21 7 4.7Pr_(1.8)Bi_(0.2)Ni_(0.9)Cr_(0.1)O₄ −21 7.1 4.2Pr_(1.8)Bi_(0.2)Ni_(0.9)Mn_(0.1)O₄ −22 7.3 4.3Pr_(1.8)Bi_(0.2)Ni_(0.9)Fe_(0.1)O₄ −18 7 4.9Pr_(1.8)Bi_(0.2)Ni_(0.9)Co_(0.1)O₄ −25 6.8 3.9Pr_(1.8)Bi_(0.2)Ni_(0.9)Cu_(0.1)O₄ −24 6.9 4.2Pr_(1.8)Bi_(0.2)Ni_(0.9)Mo_(0.1)O₄ −28 6.7 4Pr_(1.8)Bi_(0.2)Ni_(0.9)W_(0.1)O₄ −19 7.1 4.7Pr_(1.8)Bi_(0.2)Ni_(0.9)Nb_(0.1)O₄ −20 5.8 4.6Pr_(1.8)Bi_(0.2)Ni_(0.9)Ta_(0.1)O₄ −26 6.3 4.5Nd_(1.8)Na_(0.2)Ni_(0.9)Ti_(0.1)O₄ −22 6.4 4.7Nd_(1.8)Na_(0.2)Ni_(0.9)V_(0.1)O₄ −19 5.9 4.8Nd_(1.8)Na_(0.2)Ni_(0.9)Cr_(0.1)O₄ −17 6.4 4.1Nd_(1.8)Na_(0.2)Ni_(0.9)Mn_(0.1)O₄ −20 7.1 3.8Nd_(1.8)Na_(0.2)Ni_(0.9)Fe_(0.1)O₄ −22 7 4Nd_(1.8)Na_(0.2)Ni_(0.9)Co_(0.1)O₄ −20 6.8 4.3Nd_(1.8)Na_(0.2)Ni_(0.9)Cu_(0.1)O₄ −21 7.1 4.2Nd_(1.8)Na_(0.2)Ni_(0.9)Mo_(0.1)O₄ −23 6.8 4.3Nd_(1.8)Na_(0.2)Ni_(0.9)W_(0.1)O₄ −18 5.9 4.5Nd_(1.8)Na_(0.2)Ni_(0.9)Nb_(0.1)O₄ −28 6.5 4.6Nd_(1.8)Na_(0.2)Ni_(0.9)Ta_(0.1)O₄ −19 7 4.7Nd_(1.8)K_(0.2)Ni_(0.9)Ti_(0.1)O₄ −25 5 4.9Nd_(1.8)K_(0.2)Ni_(0.9)V_(0.1)O₄ −16 7 4.7Nd_(1.8)K_(0.2)Ni_(0.9)Cr_(0.1)O₄ −20 4.9 4.6Nd_(1.8)K_(0.2)Ni_(0.9)Mn_(0.1)O₄ −22 5 4.6Nd_(1.8)K_(0.2)Ni_(0.9)Fe_(0.1)O₄ −24 6 4.5

TABLE 109 Nd_(1.8)K_(0.2)Ni_(0.9)Co_(0.1)O₄ −23 5.2 4.2Nd_(1.8)K_(0.2)Ni_(0.9)Cu_(0.1)O₄ −26 7 4.7Nd_(1.8)K_(0.2)Ni_(0.9)Mo_(0.1)O₄ −28 8.1 4.8Nd_(1.8)K_(0.2)Ni_(0.9)W_(0.1)O₄ −19 6.9 4.1Nd_(1.8)K_(0.2)Ni_(0.9)Nb_(0.1)O₄ −21 6.7 3.8Nd_(1.8)K_(0.2)Ni_(0.9)Ta_(0.1)O₄ −22 7.2 4Nd_(1.8)Sr_(0.2)Ni_(0.9)Ti_(0.1)O₄ −21 5.9 4.2Nd_(1.8)Sr_(0.2)Ni_(0.9)V_(0.1)O₄ −29 6.3 4.5Nd_(1.8)Sr_(0.2)Ni_(0.9)Cr_(0.1)O₄ −17 7 4.3Nd_(1.8)Sr_(0.2)Ni_(0.9)Mn_(0.1)O₄ −18 7.1 4.1Nd_(1.8)Sr_(0.2)Ni_(0.9)Fe_(0.1)O₄ −24 7.3 3.9Nd_(1.8)Sr_(0.2)Ni_(0.9)Co_(0.1)O₄ −22 7 4Nd_(1.8)Sr_(0.2)Ni_(0.9)Cu_(0.1)O₄ −21 6.8 3.8Nd_(1.8)Sr_(0.2)Ni_(0.9)Mo_(0.1)O₄ −27 6.9 3.7Nd_(1.8)Sr_(0.2)Ni_(0.9)W_(0.1)O₄ −21 6.7 4Nd_(1.8)Sr_(0.2)Ni_(0.9)Nb_(0.1)O₄ −23 7.1 3.9Nd_(1.8)Sr_(0.2)Ni_(0.9)Ta_(0.1)O₄ −19 5.8 3.6Nd_(1.8)Ca_(0.2)Ni_(0.9)Ti_(0.1)O₄ −24 7.1 3.9Nd_(1.8)Ca_(0.2)Ni_(0.9)V_(0.1)O₄ −25 6.4 4.6Nd_(1.8)Ca_(0.2)Ni_(0.9)Cr_(0.1)O₄ −16 5.9 4.3Nd_(1.8)Ca_(0.2)Ni_(0.9)Mn_(0.1)O₄ −20 6.4 4Nd_(1.8)Ca_(0.2)Ni_(0.9)Fe_(0.1)O₄ −22 7.1 4.7Nd_(1.8)Ca_(0.2)Ni_(0.9)Co_(0.1)O₄ −22 7 4.2Nd_(1.8)Ca_(0.2)Ni_(0.9)Cu_(0.1)O₄ −10 6.8 4.3Nd_(1.8)Ca_(0.2)Ni_(0.9)Mo_(0.1)O₄ −26 7.1 4.9Nd_(1.8)Ca_(0.2)Ni_(0.9)W_(0.1)O₄ −20 6.8 3.9Nd_(1.8)Ca_(0.2)Ni_(0.9)Nb_(0.1)O₄ −19 5.9 4.2Nd_(1.8)Ca_(0.2)Ni_(0.9)Ta_(0.1)O₄ −17 6.5 4Nd_(1.8)Bi_(0.2)Ni_(0.9)Ti_(0.1)O₄ −22 6.8 4.6Nd_(1.8)Bi_(0.2)Ni_(0.9)V_(0.1)O₄ −18 5.8 4.5Nd_(1.8)Bi_(0.2)Ni_(0.9)Cr_(0.1)O₄ −20 6.3 4.2Nd_(1.8)Bi_(0.2)Ni_(0.9)Mn_(0.1)O₄ −21 7.1 4.7Nd_(1.8)Bi_(0.2)Ni_(0.9)Fe_(0.1)O₄ −21 6.4 4.8Nd_(1.8)Bi_(0.2)Ni_(0.9)Co_(0.1)O₄ −22 5.9 4.1

TABLE 110 Nd_(1.8)Bi_(0.2)Ni_(0.9)Cu_(0.1)O₄ −18 6.4 3.8Nd_(1.8)Bi_(0.2)Ni_(0.9)Mo_(0.1)O₄ −25 7.1 4Nd_(1.8)Bi_(0.2)Ni_(0.9)W_(0.1)O₄ −24 7 4.6Nd_(1.8)Bi_(0.2)Ni_(0.9)Nb_(0.1)O₄ −28 6.8 4.2Nd_(1.8)Bi_(0.2)Ni_(0.9)Ta_(0.1)O₄ −19 7.1 4.5Sm_(1.8)Na_(0.2)Ni_(0.9)Ti_(0.1)O₄ −26 5.9 4.2Sm_(1.8)Na_(0.2)Ni_(0.9)V_(0.1)O₄ −23 6.5 4.1Sm_(1.8)Na_(0.2)Ni_(0.9)Cr_(0.1)O₄ −22 7 3.9Sm_(1.8)Na_(0.2)Ni_(0.9)Mn_(0.1)O₄ −19 5 4Sm_(1.8)Na_(0.2)Ni_(0.9)Fe_(0.1)O₄ −17 7 3.8Sm_(1.8)Na_(0.2)Ni_(0.9)Co_(0.1)O₄ −20 4.9 3.7Sm_(1.8)Na_(0.2)Ni_(0.9)Cu_(0.1)O₄ −22 5 4Sm_(1.8)Na_(0.2)Ni_(0.9)Mo_(0.1)O₄ −20 6 3.9Sm_(1.8)Na_(0.2)Ni_(0.9)W_(0.1)O₄ −21 5.2 3.6Sm_(1.8)Na_(0.2)Ni_(0.9)Nb_(0.1)O₄ −23 7 4.1Sm_(1.8)Na_(0.2)Ni_(0.9)Ta_(0.1)O₄ −18 8.1 3.9Sm_(1.8)K_(0.2)Ni_(0.9)Ti_(0.1)O₄ −19 6.7 4.3Sm_(1.8)K_(0.2)Ni_(0.9)V_(0.1)O₄ −24 7.2 4Sm_(1.8)K_(0.2)Ni_(0.9)Cr_(0.1)O₄ −25 6.9 4.7Sm_(1.8)K_(0.2)Ni_(0.9)Mn_(0.1)O₄ −16 5.9 4.4Sm_(1.8)K_(0.2)Ni_(0.9)Fe_(0.1)O₄ −20 6.3 4.9Sm_(1.8)K_(0.2)Ni_(0.9)Co_(0.1)O₄ −22 7 4.7Sm_(1.8)K_(0.2)Ni_(0.9)Cu_(0.1)O₄ −24 7.1 4.6Sm_(1.8)K_(0.2)Ni_(0.9)Mo_(0.1)O₄ −23 7.3 4.6Sm_(1.8)K_(0.2)Ni_(0.9)W_(0.1)O₄ −26 7 4.5Sm_(1.8)K_(0.2)Ni_(0.9)Nb_(0.1)O₄ −28 7.1 4.2Sm_(1.8)K_(0.2)Ni_(0.9)Ta_(0.1)O₄ −19 6.4 4.7Sm_(1.8)Sr_(0.2)Ni_(0.9)Ti_(0.1)O₄ −22 6.4 4.1Sm_(1.8)Sr_(0.2)Ni_(0.9)V_(0.1)O₄ −24 7.1 3.8Sm_(1.8)Sr_(0.2)Ni_(0.9)Cr_(0.1)O₄ −21 7 4Sm_(1.8)Sr_(0.2)Ni_(0.9)Mn_(0.1)O₄ −29 6.8 4.6Sm_(1.8)Sr_(0.2)Ni_(0.9)Fe_(0.1)O₄ −17 7.1 4.2Sm_(1.8)Sr_(0.2)Ni_(0.9)Co_(0.1)O₄ −18 6.8 4.5Sm_(1.8)Sr_(0.2)Ni_(0.9)Cu_(0.1)O₄ −24 5.9 4.3

TABLE 111 Sm_(1.8)Sr_(0.2)Ni_(0.9)Mo_(0.1)O₄ −22 5.0 4.1Sm_(1.8)Sr_(0.2)Ni_(0.9)W_(0.1)O₄ −21 7.0 3.9Sm_(1.8)Sr_(0.2)Ni_(0.9)Nb_(0.1)O₄ −30 4.9 4Sm_(1.8)Sr_(0.2)Ni_(0.9)Ta_(0.1)O₄ −20 5.0 3.8Sm_(1.8)Ca_(0.2)Ni_(0.9)Ti_(0.1)O₄ −20 5.2 4Sm_(1.8)Ca_(0.2)Ni_(0.9)V_(0.1)O₄ −21 7 3.9Sm_(1.8)Ca_(0.2)Ni_(0.9)Cr_(0.1)O₄ −23 8.1 3.6Sm_(1.8)Ca_(0.2)Ni_(0.9)Mn_(0.1)O₄ −18 6.9 3.8Sm_(1.8)Ca_(0.2)Ni_(0.9)Fe_(0.1)O₄ −28 6.7 3.7Sm_(1.8)Ca_(0.2)Ni_(0.9)Co_(0.1)O₄ −19 7.2 4Sm_(1.8)Ca_(0.2)Ni_(0.9)Cu_(0.1)O₄ −24 6.9 3.9Sm_(1.8)Ca_(0.2)Ni_(0.9)Mo_(0.1)O₄ −25 5.9 3.6Sm_(1.8)Ca_(0.2)Ni_(0.9)W_(0.1)O₄ −16 6.3 4.1Sm_(1.8)Ca_(0.2)Ni_(0.9)Nb_(0.1)O₄ −20 7 3.9Sm_(1.8)Ca_(0.2)Ni_(0.9)Ta_(0.1)O₄ −22 7.1 4.6Sm_(1.8)Bi_(0.2)Ni_(0.9)Ti_(0.1)O₄ −23 7 4Sm_(1.8)Bi_(0.2)Ni_(0.9)V_(0.1)O₄ −26 6.8 4.7Sm_(1.8)Bi_(0.2)Ni_(0.9)Cr_(0.1)O₄ −28 6.9 4.2Sm_(1.8)Bi_(0.2)Ni_(0.9)Mn_(0.1)O₄ −19 6.7 4.3Sm_(1.8)Bi_(0.2)Ni_(0.9)Fe_(0.1)O₄ −21 7.1 4.9Sm_(1.8)Bi_(0.2)Ni_(0.9)Co_(0.1)O₄ −22 5.8 3.9Sm_(1.8)Bi_(0.2)Ni_(0.9)Cu_(0.1)O₄ −24 6.3 4.2Sm_(1.8)Bi_(0.2)Ni_(0.9)Mo_(0.1)O₄ −21 7.1 4Sm_(1.8)Bi_(0.2)Ni_(0.9)W_(0.1)O₄ −29 6.4 4.7Sm_(1.8)Bi_(0.2)Ni_(0.9)Nb_(0.1)O₄ −17 5.9 4.6Sm_(1.8)Bi_(0.2)Ni_(0.9)Ta_(0.1)O₄ −18 6.4 4.5Eu_(1.8)Na_(0.2)Ni_(0.9)Ti_(0.1)O₄ −22 7.0 4.7Eu_(1.8)Na_(0.2)Ni_(0.9)V_(0.1)O₄ −21 6.8 4.8Eu_(1.8)Na_(0.2)Ni_(0.9)Cr_(0.1)O₄ −30 7.1 4.1Eu_(1.8)Na_(0.2)Ni_(0.9)Mn_(0.1)O₄ −29 6.8 3.8Eu_(1.8)Na_(0.2)Ni_(0.9)Fe_(0.1)O₄ −30 5.9 4Eu_(1.8)Na_(0.2)Ni_(0.9)Co_(0.1)O₄ −28 6.5 4.3Eu_(1.8)Na_(0.2)Ni_(0.9)Cu_(0.1)O₄ −27 7.0 4.2Eu_(1.8)Na_(0.2)Ni_(0.9)Mo_(0.1)O₄ −25 6.8 4.3

TABLE 112 Eu_(1.8)Na_(0.2)Ni_(0.9)W_(0.1)O₄ −18 5.0 4.5Eu_(1.8)Na_(0.2)Ni_(0.9)Nb_(0.1)O₄ −22 7.0 4.6Eu_(1.8)Na_(0.2)Ni_(0.9)Ta_(0.1)O₄ −10 4.9 4.7Eu_(1.8)K_(0.2)Ni_(0.9)Ti_(0.1)O₄ −20 6.0 4.9Eu_(1.8)K_(0.2)Ni_(0.9)V_(0.1)O₄ −19 5.2 4.7Eu_(1.8)K_(0.2)Ni_(0.9)Cr_(0.1)O₄ −17 7 4.6Eu_(1.8)K_(0.2)Ni_(0.9)Mn_(0.1)O₄ −23 8.1 4.6Eu_(1.8)K_(0.2)Ni_(0.9)Fe_(0.1)O₄ −22 6.9 4.5Eu_(1.8)K_(0.2)Ni_(0.9)Co_(0.1)O₄ −18 6.7 4.2Eu_(1.8)K_(0.2)Ni_(0.9)Cu_(0.1)O₄ −20 7.2 4.7Eu_(1.8)K_(0.2)Ni_(0.9)Mo_(0.1)O₄ −21 6.9 4.8Eu_(1.8)K_(0.2)Ni_(0.9)W_(0.1)O₄ −21 5.9 4.1Eu_(1.8)K_(0.2)Ni_(0.9)Nb_(0.1)O₄ −22 6.3 3.8Eu_(1.8)K_(0.2)Ni_(0.9)Ta_(0.1)O₄ −18 7 4Eu_(1.8)Sr_(0.2)Ni_(0.9)Ti_(0.1)O₄ −24 7.3 4.2Eu_(1.8)Sr_(0.2)Ni_(0.9)V_(0.1)O₄ −28 7 4.5Eu_(1.8)Sr_(0.2)Ni_(0.9)Cr_(0.1)O₄ −19 6.8 4.3Eu_(1.8)Sr_(0.2)Ni_(0.9)Mn_(0.1)O₄ −20 6.9 4.1Eu_(1.8)Sr_(0.2)Ni_(0.9)Fe_(0.1)O₄ −26 6.7 3.9Eu_(1.8)Sr_(0.2)Ni_(0.9)Co_(0.1)O₄ −23 7.1 4Eu_(1.8)Sr_(0.2)Ni_(0.9)Cu_(0.1)O₄ −22 5.8 3.8Eu_(1.8)Sr_(0.2)Ni_(0.9)Mo_(0.1)O₄ −19 6.3 3.7Eu_(1.8)Sr_(0.2)Ni_(0.9)W_(0.1)O₄ −17 7.1 4Eu_(1.8)Sr_(0.2)Ni_(0.9)Nb_(0.1)O₄ −20 6.4 3.9Eu_(1.8)Sr_(0.2)Ni_(0.9)Ta_(0.1)O₄ −22 5.9 3.6Eu_(1.8)Ca_(0.2)Ni_(0.9)Ti_(0.1)O₄ −21 7.1 3.9Eu_(1.8)Ca_(0.2)Ni_(0.9)V_(0.1)O₄ −23 7 4.6Eu_(1.8)Ca_(0.2)Ni_(0.9)Cr_(0.1)O₄ −18 6.8 4.3Eu_(1.8)Ca_(0.2)Ni_(0.9)Mn_(0.1)O₄ −28 7.1 4Eu_(1.8)Ca_(0.2)Ni_(0.9)Fe_(0.1)O₄ −19 6.8 4.7Eu_(1.8)Ca_(0.2)Ni_(0.9)Co_(0.1)O₄ −24 5.9 4.2Eu_(1.8)Ca_(0.2)Ni_(0.9)Cu_(0.1)O₄ −25 6.5 4.3Eu_(1.8)Ca_(0.2)Ni_(0.9)Mo_(0.1)O₄ −16 7 4.9Eu_(1.8)Ca_(0.2)Ni_(0.9)W_(0.1)O₄ −20 6.8 3.9

TABLE 113 Eu_(1.8)Ca_(0.2)Ni_(0.9)Nb_(0.1)O₄ −22 5.8 4.2Eu_(1.8)Ca_(0.2)Ni_(0.9)Ta_(0.1)O₄ −24 6.3 4Eu_(1.8)Bi_(0.2)Ni_(0.9)Ti_(0.1)O₄ −26 6.4 4.6Eu_(1.8)Bi_(0.2)Ni_(0.9)V_(0.1)O₄ −28 5.9 4.5Eu_(1.8)Bi_(0.2)Ni_(0.9)Cr_(0.1)O₄ −19 6.4 4.2Eu_(1.8)Bi_(0.2)Ni_(0.9)Mn_(0.1)O₄ −21 7.1 4.7Eu_(1.8)Bi_(0.2)Ni_(0.9)Fe_(0.1)O₄ −22 7 4.8Eu_(1.8)Bi_(0.2)Ni_(0.9)Co_(0.1)O₄ −24 6.8 4.1Eu_(1.8)Bi_(0.2)Ni_(0.9)Cu_(0.1)O₄ −21 7.1 3.8Eu_(1.8)Bi_(0.2)Ni_(0.9)Mo_(0.1)O₄ −29 6.8 4Eu_(1.8)Bi_(0.2)Ni_(0.9)W_(0.1)O₄ −17 5.9 4.6Eu_(1.8)Bi_(0.2)Ni_(0.9)Nb_(0.1)O₄ −18 6.5 4.2Eu_(1.8)Bi_(0.2)Ni_(0.9)Ta_(0.1)O₄ −24 7 4.5Gd_(1.8)Na_(0.2)Ni_(0.9)Ti_(0.1)O₄ −21 7 4.2Gd_(1.8)Na_(0.2)Ni_(0.9)V_(0.1)O₄ −27 4.9 4.1Gd_(1.8)Na_(0.2)Ni_(0.9)Cr_(0.1)O₄ −25 5 3.9Gd_(1.8)Na_(0.2)Ni_(0.9)Mn_(0.1)O₄ −30 6 4Gd_(1.8)Na_(0.2)Ni_(0.9)Fe_(0.1)O₄ −28 5.2 3.8Gd_(1.8)Na_(0.2)Ni_(0.9)Co_(0.1)O₄ −24 7 3.7Gd_(1.8)Na_(0.2)Ni_(0.9)Cu_(0.1)O₄ −25 8.1 4Gd_(1.8)Na_(0.2)Ni_(0.9)Mo_(0.1)O₄ −16 6.9 3.9Gd_(1.8)Na_(0.2)Ni_(0.9)W_(0.1)O₄ −20 6.7 3.6Gd_(1.8)Na_(0.2)Ni_(0.9)Nb_(0.1)O₄ −22 7.2 4.1Gd_(1.8)Na_(0.2)Ni_(0.9)Ta_(0.1)O₄ −24 6.9 3.9Gd_(1.8)K_(0.2)Ni_(0.9)Ti_(0.1)O₄ −26 6.3 4.3Gd_(1.8)K_(0.2)Ni_(0.9)V_(0.1)O₄ −28 7 4Gd_(1.8)K_(0.2)Ni_(0.9)Cr_(0.1)O₄ −19 7.1 4.7Gd_(1.8)K_(0.2)Ni_(0.9)Mn_(0.1)O₄ −21 7.3 4.4Gd_(1.8)K_(0.2)Ni_(0.9)Fe_(0.1)O₄ −22 7 4.9Gd_(1.8)K_(0.2)Ni_(0.9)Co_(0.1)O₄ −24 6.8 4.7Gd_(1.8)K_(0.2)Ni_(0.9)Cu_(0.1)O₄ −21 5.2 4.6Gd_(1.8)K_(0.2)Ni_(0.9)Mo_(0.1)O₄ −29 7 4.6Gd_(1.8)K_(0.2)Ni_(0.9)W_(0.1)O₄ −17 8.1 4.5Gd_(1.8)K_(0.2)Ni_(0.9)Nb_(0.1)O₄ −18 6.9 4.2

TABLE 114 Gd_(1.8)K_(0.2)Ni_(0.9)Ta_(0.1)O₄ −24 6.7 4.7Gd_(1.8)Sr_(0.2)Ni_(0.9)Ti_(0.1)O₄ −21 6.9 4.1Gd_(1.8)Sr_(0.2)Ni_(0.9)V_(0.1)O₄ −27 5.9 3.8Gd_(1.8)Sr_(0.2)Ni_(0.9)Cr_(0.1)O₄ −25 6.3 4Gd_(1.8)Sr_(0.2)Ni_(0.9)Mn_(0.1)O₄ −30 7 4.6Gd_(1.8)Sr_(0.2)Ni_(0.9)Fe_(0.1)O₄ −28 7.1 4.2Gd_(1.8)Sr_(0.2)Ni_(0.9)Co_(0.1)O₄ −27 7.3 4.5Gd_(1.8)Sr_(0.2)Ni_(0.9)Cu_(0.1)O₄ −25 7 4.3Gd_(1.8)Sr_(0.2)Ni_(0.9)Mo_(0.1)O₄ −18 6.8 4.1Gd_(1.8)Sr_(0.2)Ni_(0.9)W_(0.1)O₄ −22 6.9 3.9Gd_(1.8)Sr_(0.2)Ni_(0.9)Nb_(0.1)O₄ −10 6.7 4Gd_(1.8)Sr_(0.2)Ni_(0.9)Ta_(0.1)O₄ −26 7.1 3.8Gd_(1.8)Ca_(0.2)Ni_(0.9)Ti_(0.1)O₄ −24 7.1 4Gd_(1.8)Ca_(0.2)Ni_(0.9)V_(0.1)O₄ −22 6.8 3.9Gd_(1.8)Ca_(0.2)Ni_(0.9)Cr_(0.1)O₄ −21 5.9 4.1Gd_(1.8)Ca_(0.2)Ni_(0.9)Mn_(0.1)O₄ −27 6.5 3.8Gd_(1.8)Ca_(0.2)Ni_(0.9)Fe_(0.1)O₄ −25 7 4Gd_(1.8)Ca_(0.2)Ni_(0.9)Co_(0.1)O₄ −30 6.8 4.6Gd_(1.8)Ca_(0.2)Ni_(0.9)Cu_(0.1)O₄ −28 5 4.2Gd_(1.8)Ca_(0.2)Ni_(0.9)Mo_(0.1)O₄ −27 7 4.5Gd_(1.8)Ca_(0.2)Ni_(0.9)W_(0.1)O₄ −25 4.9 4.3Gd_(1.8)Ca_(0.2)Ni_(0.9)Nb_(0.1)O₄ −18 5 4.2Gd_(1.8)Ca_(0.2)Ni_(0.9)Ta_(0.1)O₄ −22 6 4.1Gd_(1.8)Bi_(0.2)Ni_(0.9)Ti_(0.1)O₄ −26 7 4Gd_(1.8)Bi_(0.2)Ni_(0.9)V_(0.1)O₄ −20 8.1 3.8Gd_(1.8)Bi_(0.2)Ni_(0.9)Cr_(0.1)O₄ −19 6.9 3.7Gd_(1.8)Bi_(0.2)Ni_(0.9)Mn_(0.1)O₄ −17 6.7 4Gd_(1.8)Bi_(0.2)Ni_(0.9)Fe_(0.1)O₄ −23 7.2 3.9Gd_(1.8)Bi_(0.2)Ni_(0.9)Co_(0.1)O₄ −22 6.9 3.6Gd_(1.8)Bi_(0.2)Ni_(0.9)Cu_(0.1)O₄ −18 5.9 4.1Gd_(1.8)Bi_(0.2)Ni_(0.9)Mo_(0.1)O₄ −20 6.3 3.9Gd_(1.8)Bi_(0.2)Ni_(0.9)W_(0.1)O₄ −21 7 4.6Gd_(1.8)Bi_(0.2)Ni_(0.9)Nb_(0.1)O₄ −21 7.1 4.3Gd_(1.8)Bi_(0.2)Ni_(0.9)Ta_(0.1)O₄ −22 7.3 4

TABLE 115 Dy_(1.8)Na_(0.2)Ni_(0.9)Ti_(0.1)O₄ −25 6.8 4.4Dy_(1.8)Na_(0.2)Ni_(0.9)V_(0.1)O₄ −24 6.9 4.9Dy_(1.8)Na_(0.2)Ni_(0.9)Cr_(0.1)O₄ −28 6.7 4.7Dy_(1.8)Na_(0.2)Ni_(0.9)Mn_(0.1)O₄ −19 7.1 4.6Dy_(1.8)Na_(0.2)Ni_(0.9)Fe_(0.1)O₄ −20 5.8 4.6Dy_(1.8)Na_(0.2)Ni_(0.9)Co_(0.1)O₄ −26 6.3 4.5Dy_(1.8)Na_(0.2)Ni_(0.9)Cu_(0.1)O₄ −23 7.1 4.2Dy_(1.8)Na_(0.2)Ni_(0.9)Mo_(0.1)O₄ −22 6.4 4.7Dy_(1.8)Na_(0.2)Ni_(0.9)W_(0.1)O₄ −19 5.9 4.8Dy_(1.8)Na_(0.2)Ni_(0.9)Nb_(0.1)O₄ −17 6.4 4.1Dy_(1.8)Na_(0.2)Ni_(0.9)Ta_(0.1)O₄ −20 7.1 3.8Dy_(1.8)K_(0.2)Ni_(0.9)Ti_(0.1)O₄ −20 6.8 4.6Dy_(1.8)K_(0.2)Ni_(0.9)V_(0.1)O₄ −21 7.1 4.2Dy_(1.8)K_(0.2)Ni_(0.9)Cr_(0.1)O₄ −23 6.8 4.5Dy_(1.8)K_(0.2)Ni_(0.9)Mn_(0.1)O₄ −18 5.9 4.3Dy_(1.8)K_(0.2)Ni_(0.9)Fe_(0.1)O₄ −28 6.5 4.1Dy_(1.8)K_(0.2)Ni_(0.9)Co_(0.1)O₄ −19 7 3.9Dy_(1.8)K_(0.2)Ni_(0.9)Cu_(0.1)O₄ −24 6.8 4Dy_(1.8)K_(0.2)Ni_(0.9)Mo_(0.1)O₄ −25 5.8 3.8Dy_(1.8)K_(0.2)Ni_(0.9)W_(0.1)O₄ −16 6.3 3.7Dy_(1.8)K_(0.2)Ni_(0.9)Nb_(0.1)O₄ −20 7.1 4Dy_(1.8)K_(0.2)Ni_(0.9)Ta_(0.1)O₄ −22 6.4 3.9Dy_(1.8)Sr_(0.2)Ni_(0.9)Ti_(0.1)O₄ −23 6.4 3.8Dy_(1.8)Sr_(0.2)Ni_(0.9)V_(0.1)O₄ −26 7.1 3.7Dy_(1.8)Sr_(0.2)Ni_(0.9)Cr_(0.1)O₄ −28 7 4Dy_(1.8)Sr_(0.2)Ni_(0.9)Mn_(0.1)O₄ −19 6.8 3.9Dy_(1.8)Sr_(0.2)Ni_(0.9)Fe_(0.1)O₄ −21 7.1 3.6Dy_(1.8)Sr_(0.2)Ni_(0.9)Co_(0.1)O₄ −22 6.8 4.1Dy_(1.8)Sr_(0.2)Ni_(0.9)Cu_(0.1)O₄ −24 5.9 3.9Dy_(1.8)Sr_(0.2)Ni_(0.9)Mo_(0.1)O₄ −21 6.5 4.6Dy_(1.8)Sr_(0.2)Ni_(0.9)W_(0.1)O₄ −29 7.0 4.3Dy_(1.8)Sr_(0.2)Ni_(0.9)Nb_(0.1)O₄ −17 5.0 4Dy_(1.8)Sr_(0.2)Ni_(0.9)Ta_(0.1)O₄ −18 7.0 4.7

TABLE 116 Dy_(1.8)Ca_(0.2)Ni_(0.9)Ti_(0.1)O₄ −22 5.0 4.3Dy_(1.8)Ca_(0.2)Ni_(0.9)V_(0.1)O₄ −21 6.0 4.9Dy_(1.8)Ca_(0.2)Ni_(0.9)Cr_(0.1)O₄ −27 5.2 3.9Dy_(1.8)Ca_(0.2)Ni_(0.9)Mn_(0.1)O₄ −21 7.0 4.2Dy_(1.8)Ca_(0.2)Ni_(0.9)Fe_(0.1)O₄ −23 8.1 4Dy_(1.8)Ca_(0.2)Ni_(0.9)Co_(0.1)O₄ −19 6.9 4.7Dy_(1.8)Ca_(0.2)Ni_(0.9)Cu_(0.1)O₄ −23 6.7 4.6Dy_(1.8)Ca_(0.2)Ni_(0.9)Mo_(0.1)O₄ −24 7.2 4.5Dy_(1.8)Ca_(0.2)Ni_(0.9)W_(0.1)O₄ −25 6.9 4.2Dy_(1.8)Ca_(0.2)Ni_(0.9)Nb_(0.1)O₄ −16 5.9 4.7Dy_(1.8)Ca_(0.2)Ni_(0.9)Ta_(0.1)O₄ −20 6.3 4.8Dy_(1.8)Bi_(0.2)Ni_(0.9)Ti_(0.1)O₄ −22 7.1 3.8Dy_(1.8)Bi_(0.2)Ni_(0.9)V_(0.1)O₄ −10 7.3 4Dy_(1.8)Bi_(0.2)Ni_(0.9)Cr_(0.1)O₄ −26 7 4.3Dy_(1.8)Bi_(0.2)Ni_(0.9)Mn_(0.1)O₄ −20 7.1 4.2Dy_(1.8)Bi_(0.2)Ni_(0.9)Fe_(0.1)O₄ −19 6.4 4.3Dy_(1.8)Bi_(0.2)Ni_(0.9)Co_(0.1)O₄ −17 5.9 4.5Dy_(1.8)Bi_(0.2)Ni_(0.9)Cu_(0.1)O₄ −23 6.4 4.6Dy_(1.8)Bi_(0.2)Ni_(0.9)Mo_(0.1)O₄ −22 7.1 4.7Dy_(1.8)Bi_(0.2)Ni_(0.9)W_(0.1)O₄ −18 7 4.4Dy_(1.8)Bi_(0.2)Ni_(0.9)Nb_(0.1)O₄ −20 6.8 4.9Dy_(1.8)Bi_(0.2)Ni_(0.9)Ta_(0.1)O₄ −21 7.1 4.7Ho_(1.8)Na_(0.2)Ni_(0.9)Ti_(0.1)O₄ −22 5.9 4.6Ho_(1.8)Na_(0.2)Ni_(0.9)V_(0.1)O₄ −18 5 4.5Ho_(1.8)Na_(0.2)Ni_(0.9)Cr_(0.1)O₄ −25 7 4.2Ho_(1.8)Na_(0.2)Ni_(0.9)Mn_(0.1)O₄ −24 4.9 4.7Ho_(1.8)Na_(0.2)Ni_(0.9)Fe_(0.1)O₄ −28 5 4.8Ho_(1.8)Na_(0.2)Ni_(0.9)Co_(0.1)O₄ −19 6 4.1Ho_(1.8)Na_(0.2)Ni_(0.9)Cu_(0.1)O₄ −20 5.2 3.8Ho_(1.8)Na_(0.2)Ni_(0.9)Mo_(0.1)O₄ −26 7 4Ho_(1.8)Na_(0.2)Ni_(0.9)W_(0.1)O₄ −23 8.1 4.6Ho_(1.8)Na_(0.2)Ni_(0.9)Nb_(0.1)O₄ −22 6.9 4.2Ho_(1.8)Na_(0.2)Ni_(0.9)Ta_(0.1)O₄ −19 6.7 4.5Ho_(1.8)K_(0.2)Ni_(0.9)Ti_(0.1)O₄ −20 6.9 4.1

TABLE 117 Ho_(1.8)K_(0.2)Ni_(0.9)V_(0.1)O₄ −22 5.9 3.9Ho_(1.8)K_(0.2)Ni_(0.9)Cr_(0.1)O₄ −20 6.3 4Ho_(1.8)K_(0.2)Ni_(0.9)Mn_(0.1)O₄ −21 7 3.8Ho_(1.8)K_(0.2)Ni_(0.9)Fe_(0.1)O₄ −23 7.1 3.7Ho_(1.8)K_(0.2)Ni_(0.9)Co_(0.1)O₄ −18 7.3 4Ho_(1.8)K_(0.2)Ni_(0.9)Cu_(0.1)O₄ −28 7 3.9Ho_(1.8)K_(0.2)Ni_(0.9)Mo_(0.1)O₄ −19 6.8 3.6Ho_(1.8)K_(0.2)Ni_(0.9)W_(0.1)O₄ −24 6.9 4.1Ho_(1.8)K_(0.2)Ni_(0.9)Nb_(0.1)O₄ −25 6.7 3.9Ho_(1.8)K_(0.2)Ni_(0.9)Ta_(0.1)O₄ −16 7.1 4.6Ho_(1.8)Sr_(0.2)Ni_(0.9)Ti_(0.1)O₄ −22 6.3 4Ho_(1.8)Sr_(0.2)Ni_(0.9)V_(0.1)O₄ −24 7.1 4.7Ho_(1.8)Sr_(0.2)Ni_(0.9)Cr_(0.1)O₄ −23 6.4 4.2Ho_(1.8)Sr_(0.2)Ni_(0.9)Mn_(0.1)O₄ −26 5.9 4.3Ho_(1.8)Sr_(0.2)Ni_(0.9)Fe_(0.1)O₄ −28 6.4 4.9Ho_(1.8)Sr_(0.2)Ni_(0.9)Co_(0.1)O₄ −19 7.1 4Ho_(1.8)Sr_(0.2)Ni_(0.9)Cu_(0.1)O₄ −21 7 3.8Ho_(1.8)Sr_(0.2)Ni_(0.9)Mo_(0.1)O₄ −22 6.8 3.7Ho_(1.8)Sr_(0.2)Ni_(0.9)W_(0.1)O₄ −24 7.1 4Ho_(1.8)Sr_(0.2)Ni_(0.9)Nb_(0.1)O₄ −21 6.8 3.9Ho_(1.8)Sr_(0.2)Ni_(0.9)Ta_(0.1)O₄ −29 5.9 4.1Ho_(1.8)Ca_(0.2)Ni_(0.9)Ti_(0.1)O₄ −18 7 4Ho_(1.8)Ca_(0.2)Ni_(0.9)V_(0.1)O₄ −24 6.8 4.6Ho_(1.8)Ca_(0.2)Ni_(0.9)Cr_(0.1)O₄ −22 5 4.2Ho_(1.8)Ca_(0.2)Ni_(0.9)Mn_(0.1)O₄ −21 7 4.5Ho_(1.8)Ca_(0.2)Ni_(0.9)Fe_(0.1)O₄ −30 4.9 4.3Ho_(1.8)Ca_(0.2)Ni_(0.9)Co_(0.1)O₄ −20 5 4.2Ho_(1.8)Ca_(0.2)Ni_(0.9)Cu_(0.1)O₄ −22 6 4.1Ho_(1.8)Ca_(0.2)Ni_(0.9)Mo_(0.1)O₄ −20 5.2 3.9Ho_(1.8)Ca_(0.2)Ni_(0.9)W_(0.1)O₄ −21 7 4Ho_(1.8)Ca_(0.2)Ni_(0.9)Nb_(0.1)O₄ −23 8.1 3.8Ho_(1.8)Ca_(0.2)Ni_(0.9)Ta_(0.1)O₄ −18 6.9 3.7Ho_(1.8)Bi_(0.2)Ni_(0.9)Ti_(0.1)O₄ −19 7.2 3.9Ho_(1.8)Bi_(0.2)Ni_(0.9)V_(0.1)O₄ −24 6.9 3.6

TABLE 118 Ho_(1.8)Bi_(0.2)Ni_(0.9)Cr_(0.1)O₄ −25 5.9 4.1Ho_(1.8)Bi_(0.2)Ni_(0.9)Mn_(0.1)O₄ −16 6.3 3.9Ho_(1.8)Bi_(0.2)Ni_(0.9)Fe_(0.1)O₄ −20 7 4.6Ho_(1.8)Bi_(0.2)Ni_(0.9)Co_(0.1)O₄ −22 7.1 4.3Ho_(1.8)Bi_(0.2)Ni_(0.9)Cu_(0.1)O₄ −24 7.3 4Ho_(1.8)Bi_(0.2)Ni_(0.9)Mo_(0.1)O₄ −23 7 4.7Ho_(1.8)Bi_(0.2)Ni_(0.9)W_(0.1)O₄ −26 6.8 4.4Ho_(1.8)Bi_(0.2)Ni_(0.9)Nb_(0.1)O₄ −28 6.9 4.9Ho_(1.8)Bi_(0.2)Ni_(0.9)Ta_(0.1)O₄ −19 6.7 4.7Er_(1.8)Na_(0.2)Ni_(0.9)Ti_(0.1)O₄ −22 5.8 4.6Er_(1.8)Na_(0.2)Ni_(0.9)V_(0.1)O₄ −24 6.3 4.5Er_(1.8)Na_(0.2)Ni_(0.9)Cr_(0.1)O₄ −21 7.1 4.2Er_(1.8)Na_(0.2)Ni_(0.9)Mn_(0.1)O₄ −29 6.4 4.7Er_(1.8)Na_(0.2)Ni_(0.9)Fe_(0.1)O₄ −17 5.9 4.8Er_(1.8)Na_(0.2)Ni_(0.9)Co_(0.1)O₄ −18 6.4 4.1Er_(1.8)Na_(0.2)Ni_(0.9)Cu_(0.1)O₄ −24 7.1 3.8Er_(1.8)Na_(0.2)Ni_(0.9)Mo_(0.1)O₄ −22 7 4Er_(1.8)Na_(0.2)Ni_(0.9)W_(0.1)O₄ −21 6.8 4.6Er_(1.8)Na_(0.2)Ni_(0.9)Nb_(0.1)O₄ −30 7.1 4.2Er_(1.8)Na_(0.2)Ni_(0.9)Ta_(0.1)O₄ −29 6.8 4.5Er_(1.8)K_(0.2)Ni_(0.9)Ti_(0.1)O₄ −28 6.5 4.1Er_(1.8)K_(0.2)Ni_(0.9)V_(0.1)O₄ −27 7 3.9Er_(1.8)K_(0.2)Ni_(0.9)Cr_(0.1)O₄ −25 6.8 4Er_(1.8)K_(0.2)Ni_(0.9)Mn_(0.1)O₄ −18 5.8 3.8Er_(1.8)K_(0.2)Ni_(0.9)Fe_(0.1)O₄ −22 6.3 3.7Er_(1.8)K_(0.2)Ni_(0.9)Co_(0.1)O₄ −10 7.1 4Er_(1.8)K_(0.2)Ni_(0.9)Cu_(0.1)O₄ −26 6.4 3.9Er_(1.8)K_(0.2)Ni_(0.9)Mo_(0.1)O₄ −20 5.9 3.6Er_(1.8)K_(0.2)Ni_(0.9)W_(0.1)O₄ −19 6.4 3.8Er_(1.8)K_(0.2)Ni_(0.9)Nb_(0.1)O₄ −17 7.1 3.7Er_(1.8)K_(0.2)Ni_(0.9)Ta_(0.1)O₄ −23 7 4Er_(1.8)Sr_(0.2)Ni_(0.9)Ti_(0.1)O₄ −18 7.1 3.6Er_(1.8)Sr_(0.2)Ni_(0.9)V_(0.1)O₄ −20 6.8 4.1Er_(1.8)Sr_(0.2)Ni_(0.9)Cr_(0.1)O₄ −21 5.9 3.9

TABLE 119 Er_(1.8)Sr_(0.2)Ni_(0.9)Mn_(0.1)O₄ −21 6.5 4.6Er_(1.8)Sr_(0.2)Ni_(0.9)Fe_(0.1)O₄ −22 7 4.3Er_(1.8)Sr_(0.2)Ni_(0.9)Co_(0.1)O₄ −18 5 4Er_(1.8)Sr_(0.2)Ni_(0.9)Cu_(0.1)O₄ −25 7 4.7Er_(1.8)Sr_(0.2)Ni_(0.9)Mo_(0.1)O₄ −24 4.9 4.2Er_(1.8)Sr_(0.2)Ni_(0.9)W_(0.1)O₄ −28 5 4.3Er_(1.8)Sr_(0.2)Ni_(0.9)Nb_(0.1)O₄ −19 6 4.9Er_(1.8)Sr_(0.2)Ni_(0.9)Ta_(0.1)O₄ −20 5.2 3.9Er_(1.8)Ca_(0.2)Ni_(0.9)Ti_(0.1)O₄ −23 8.1 4Er_(1.8)Ca_(0.2)Ni_(0.9)V_(0.1)O₄ −22 6.9 4.7Er_(1.8)Ca_(0.2)Ni_(0.9)Cr_(0.1)O₄ −19 6.7 4.6Er_(1.8)Ca_(0.2)Ni_(0.9)Mn_(0.1)O₄ −17 7.2 4.5Er_(1.8)Ca_(0.2)Ni_(0.9)Fe_(0.1)O₄ −20 6.9 4.2Er_(1.8)Ca_(0.2)Ni_(0.9)Co_(0.1)O₄ −22 5.9 4.7Er_(1.8)Ca_(0.2)Ni_(0.9)Cu_(0.1)O₄ −20 6.3 4.8Er_(1.8)Ca_(0.2)Ni_(0.9)Mo_(0.1)O₄ −21 7 4.1Er_(1.8)Ca_(0.2)Ni_(0.9)W_(0.1)O₄ −23 7.1 3.8Er_(1.8)Ca_(0.2)Ni_(0.9)Nb_(0.1)O₄ −18 7.3 4Er_(1.8)Ca_(0.2)Ni_(0.9)Ta_(0.1)O₄ −28 7 4.3Er_(1.8)Bi_(0.2)Ni_(0.9)Ti_(0.1)O₄ −24 5.2 4.3Er_(1.8)Bi_(0.2)Ni_(0.9)V_(0.1)O₄ −25 7 4.5Er_(1.8)Bi_(0.2)Ni_(0.9)Cr_(0.1)O₄ −16 8.1 4.6Er_(1.8)Bi_(0.2)Ni_(0.9)Mn_(0.1)O₄ −20 6.9 4.7Er_(1.8)Bi_(0.2)Ni_(0.9)Fe_(0.1)O₄ −22 6.7 4.4Er_(1.8)Bi_(0.2)Ni_(0.9)Co_(0.1)O₄ −24 7.2 4.9Er_(1.8)Bi_(0.2)Ni_(0.9)Cu_(0.1)O₄ −23 6.9 4.7Er_(1.8)Bi_(0.2)Ni_(0.9)Mo_(0.1)O₄ −26 5.9 4.6Er_(1.8)Bi_(0.2)Ni_(0.9)W_(0.1)O₄ −28 6.3 4.6Er_(1.8)Bi_(0.2)Ni_(0.9)Nb_(0.1)O₄ −19 7 4.5Er_(1.8)Bi_(0.2)Ni_(0.9)Ta_(0.1)O₄ −21 7.1 4.2Yb_(1.8)Na_(0.2)Ni_(0.9)Ti_(0.1)O₄ −24 7 4.8Yb_(1.8)Na_(0.2)Ni_(0.9)V_(0.1)O₄ −21 6.8 4.1Yb_(1.8)Na_(0.2)Ni_(0.9)Cr_(0.1)O₄ −29 6.9 3.8Yb_(1.8)Na_(0.2)Ni_(0.9)Mn_(0.1)O₄ −17 6.7 4

TABLE 120 Yb_(1.8)Na_(0.2)Ni_(0.9)Fe_(0.1)O₄ −18 7.1 4.6Yb_(1.8)Na_(0.2)Ni_(0.9)Co_(0.1)O₄ −24 5.9 4.2Yb_(1.8)Na_(0.2)Ni_(0.9)Cu_(0.1)O₄ −22 6.4 4.5Yb_(1.8)Na_(0.2)Ni_(0.9)Mo_(0.1)O₄ −21 7.1 4.3Yb_(1.8)Na_(0.2)Ni_(0.9)W_(0.1)O₄ −27 7 4.1Yb_(1.8)Na_(0.2)Ni_(0.9)Nb_(0.1)O₄ −25 6.8 3.9Yb_(1.8)Na_(0.2)Ni_(0.9)Ta_(0.1)O₄ −30 7.1 4Yb_(1.8)K_(0.2)Ni_(0.9)Ti_(0.1)O₄ −24 5.9 3.7Yb_(1.8)K_(0.2)Ni_(0.9)V_(0.1)O₄ −25 6.5 4Yb_(1.8)K_(0.2)Ni_(0.9)Cr_(0.1)O₄ −16 7 3.9Yb_(1.8)K_(0.2)Ni_(0.9)Mn_(0.1)O₄ −20 6.8 3.6Yb_(1.8)K_(0.2)Ni_(0.9)Fe_(0.1)O₄ −22 5 4.1Yb_(1.8)K_(0.2)Ni_(0.9)Co_(0.1)O₄ −24 7 3.9Yb_(1.8)K_(0.2)Ni_(0.9)Cu_(0.1)O₄ −23 4.9 4.6Yb_(1.8)K_(0.2)Ni_(0.9)Mo_(0.1)O₄ −26 5 4.3Yb_(1.8)K_(0.2)Ni_(0.9)W_(0.1)O₄ −28 6 4Yb_(1.8)K_(0.2)Ni_(0.9)Nb_(0.1)O₄ −19 5.2 4.7Yb_(1.8)K_(0.2)Ni_(0.9)Ta_(0.1)O₄ −21 7 4.2Yb_(1.8)Sr_(0.2)Ni_(0.9)Ti_(0.1)O₄ −24 6.9 4.6Yb_(1.8)Sr_(0.2)Ni_(0.9)V_(0.1)O₄ −21 6.7 4.5Yb_(1.8)Sr_(0.2)Ni_(0.9)Cr_(0.1)O₄ −29 7.2 4.2Yb_(1.8)Sr_(0.2)Ni_(0.9)Mn_(0.1)O₄ −17 6.9 4.7Yb_(1.8)Sr_(0.2)Ni_(0.9)Fe_(0.1)O₄ −18 5.9 4.8Yb_(1.8)Sr_(0.2)Ni_(0.9)Co_(0.1)O₄ −24 6.3 4.1Yb_(1.8)Sr_(0.2)Ni_(0.9)Cu_(0.1)O₄ −22 7 3.8Yb_(1.8)Sr_(0.2)Ni_(0.9)Mo_(0.1)O₄ −21 7.1 4Yb_(1.8)Sr_(0.2)Ni_(0.9)W_(0.1)O₄ −27 7.3 4.6Yb_(1.8)Sr_(0.2)Ni_(0.9)Nb_(0.1)O₄ −25 7 4.2Yb_(1.8)Sr_(0.2)Ni_(0.9)Ta_(0.1)O₄ −30 6.8 4.5Yb_(1.8)Ca_(0.2)Ni_(0.9)Ti_(0.1)O₄ −27 6.7 4.1Yb_(1.8)Ca_(0.2)Ni_(0.9)V_(0.1)O₄ −25 7.1 3.9Yb_(1.8)Ca_(0.2)Ni_(0.9)Cr_(0.1)O₄ −18 5.8 4Yb_(1.8)Ca_(0.2)Ni_(0.9)Mn_(0.1)O₄ −22 6.3 3.8Yb_(1.8)Ca_(0.2)Ni_(0.9)Fe_(0.1)O₄ −10 7.1 3.7

TABLE 121 Yb_(1.8)Ca_(0.2)Ni_(0.9)Co_(0.1)O₄ −26 6.4 4Yb_(1.8)Ca_(0.2)Ni_(0.9)Cu_(0.1)O₄ −22 5.9 3.9Yb_(1.8)Ca_(0.2)Ni_(0.9)Mo_(0.1)O₄ −18 6.4 3.6Yb_(1.8)Ca_(0.2)Ni_(0.9)W_(0.1)O₄ −25 7.1 3.8Yb_(1.8)Ca_(0.2)Ni_(0.9)Nb_(0.1)O₄ −24 7 3.7Yb_(1.8)Ca_(0.2)Ni_(0.9)Ta_(0.1)O₄ −28 6.8 4Yb_(1.8)Bi_(0.2)Ni_(0.9)Ti_(0.1)O₄ −20 6.8 3.6Yb_(1.8)Bi_(0.2)Ni_(0.9)V_(0.1)O₄ −26 5.9 4.1Yb_(1.8)Bi_(0.2)Ni_(0.9)Cr_(0.1)O₄ −23 6.5 3.9Yb_(1.8)Bi_(0.2)Ni_(0.9)Mn_(0.1)O₄ −22 7 4.6Yb_(1.8)Bi_(0.2)Ni_(0.9)Fe_(0.1)O₄ −19 6.8 4.3Yb_(1.8)Bi_(0.2)Ni_(0.9)Co_(0.1)O₄ −17 5.8 4Yb_(1.8)Bi_(0.2)Ni_(0.9)Cu_(0.1)O₄ −20 6.3 4.7Yb_(1.8)Bi_(0.2)Ni_(0.9)Mo_(0.1)O₄ −22 7.1 4.2Yb_(1.8)Bi_(0.2)Ni_(0.9)W_(0.1)O₄ −20 6.4 4.3Yb_(1.8)Bi_(0.2)Ni_(0.9)Nb_(0.1)O₄ −21 5.9 4.9Yb_(1.8)Bi_(0.2)Ni_(0.9)Ta_(0.1)O₄ −23 6.4 3.9

As is clear from the above results, the complex oxides represented bythe formulae shown in Tables 75 to 121 exhibit excellent properties asan n-type thermoelectric material and have favorable electricalconductivity. Therefore, the complex oxides can possibly demonstrateexcellent thermoelectric generation properties when used in place of then-type thermoelectric materials of the Examples.

1. A thermoelectric element comprising: a thin film of p-typethermoelectric material, a thin film of n-type thermoelectric material,and the thin film of p-type thermoelectric material and the thin film ofn-type thermoelectric material being formed on the electricallyinsulating substrate and being electrically connected, (i) the p-typethermoelectric material comprising at least one complex oxide selectedfrom the group consisting of: complex oxides represented by FormulaBi_(f)Pb_(g)M_(h) ¹CO_(i)M_(j) ²O_(k), wherein M¹ is one or moreelements selected from the group consisting of Na, K, Li, Ti, V, Cr, Mn,Fe, Ni, Cu, Zn, Pb, Ca, Sr, Ba, Al, Y, and lanthanoids; M² is one ormore elements selected from the group consisting of Ti, V, Cr, Mn, Fe,Ni, Cu, Ag, Mo, W, Nb, and Ta; 1.8≦f≦2.20≦g≦0.4; 1.8≦h≦2.2; 1.6≦i≦2.2;0≦j≦0.5;and 8≦k≦10; and (ii) the n-type thermoelectric materialcomprising at least one complex oxide selected from the group consistingof: complex oxides represented by the Formula Ln_(x)R_(y) ⁵Ni_(p)R_(q′)⁶O_(r′), wherein Ln is lanthanoid; R⁵ is one or more elements selectedfrom the group consisting of Na, K, Sr, Ca, Bi, and Nd; R⁶ is one ormore elements selected from the group consisting of Ti, V, Cr, and Cu0.5≦x≦1.2; 0≦y≦0.5; 0.5≦p≦1.2; 0.01≦q′≦0.5; and 2.8≦r′≦3.2 .
 2. Thethermoelectric element according to claim 1, wherein the p-typethermoelectric material comprises at least one complex oxide selectedfrom the group consisting of complex oxides represented by the formula:Bi_(f)Pb_(g)M_(h) ¹CO₂O_(k), wherein M¹ is one or more elements selectedfrom the group consisting of Sr, Ca and Ba; 1.8≦f≦2.2; 0≦g≦0.4;1.8≦h≦2.2; and 8≦k≦10; the n-type thermoelectric material comprises atleast one complex oxide selected from the group consisting of complexoxides represented by the formula: Ln_(x)R_(y) ⁵Ni_(p)R_(q′) ⁶O_(r′),wherein Ln is lanthanoid; R⁵ is one or more elements selected from thegroup consisting of Na, K, Sr, Ca, Bi, and Nd; and R⁶ is one or moreelements selected from the group consisting of Ti, V, Cr, and Cu;0.5≦x≦1.2; 0≦y≦0.5; 0.5≦p≦1.2; 0.01≦q′≦0.5; and 2.8≦r′≦3.2.
 3. Thethermoelectric element according to claim 1, wherein the thin film ofp-type thermoelectric material and the thin film of n-typethermoelectric material are electrically connected by one of thefollowing methods: bringing one end portion of the thin film of p-typethermoelectric material into direct contact with one end portion of thethin film of n-type thermoelectric material; bringing one end portion ofthe thin film of p-type thermoelectric material into contact with oneend portion of the thin film of n-type thermoelectric material via anelectrically conductive material; bringing one end portion of the thinfilm of p-type thermoelectric material into direct contact with one endportion of the thin film of n-type thermoelectric material and coveringthe contact portion with an electrically conductive material.
 4. Thethermoelectric element according to claim 1, wherein the thin film ofp-type thermoelectric material and the thin film of n-typethermoelectric material are formed on the same surface or on differentsurfaces of the electrically insulating substrate.
 5. The thermoelectricelement according to claim 1, wherein the electrically insulatingsubstrate is a substrate comprising a plastic material.
 6. Thethermoelectric element according to claim 1, wherein thermoelectromotiveforce is at least 60 μV/K in a temperature range of 293 K to 1073K. 7.The thermoelectric element according to claim 1, wherein electricalresistance is 1 KΩ or lower in a temperature range of 293 K to 1073 K.8. A thermoelectric module comprising a plurality of the thermoelectricelements of claim 1, wherein the thermoelectric elements areelectrically connected in series such that an unconnected end portion ofa p-type thermoelectric material of one thermoelectric element iselectrically connected to an unconnected end portion of an n-typethermoelectric material of another thermoelectric element.
 9. Athermoelectric conversion method comprising positioning one end of thethermoelectric module of claim 8 at a high-temperature portion andpositioning the other end of the module at a low-temperature portion.